CN107286719A - A kind of self-cleaned by photocatalyst AB combines film forming agent - Google Patents
A kind of self-cleaned by photocatalyst AB combines film forming agent Download PDFInfo
- Publication number
- CN107286719A CN107286719A CN201710300713.3A CN201710300713A CN107286719A CN 107286719 A CN107286719 A CN 107286719A CN 201710300713 A CN201710300713 A CN 201710300713A CN 107286719 A CN107286719 A CN 107286719A
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- China
- Prior art keywords
- agent
- film forming
- photocatalyst
- cleaned
- self
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Catalysts (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of self-cleaned by photocatalyst AB combinations film forming agent；The film forming agent is applied in combination by A agent and B agent, wherein, A agent composition is：Absolute ethyl alcohol, poly- titanate esters, hydrochloric acid, esters of silicon acis, acetylacetone,2,4-pentanedione, triethanolamine and distilled water；B agent is constituted：Absolute ethyl alcohol, titanium dioxide, hydrochloric acid, silica, acetylacetone,2,4-pentanedione, distilled water.The present invention is on the basis of original self-cleaned by photocatalyst film forming agent, add the use of A agent, it is set to form stabilizing films prior to basic unit, again by B agent spraying and A agent films, it is easy to the attachment of B agent films by the coating of film, and B agent composition can react with component in A agent films, form it into the self-cleaned by photocatalyst coating of firm stable.
Description
Technical field
The present invention relates to a kind of self-cleaned by photocatalyst film forming agent, and in particular to a kind of AB self-cleaned by photocatalyst combines film forming
Agent.
Background technology
Photocatalyst in 1967 by Tokyo Univ Japan rattan island it is clear professor find, people by this material have " automatically cleaning,
The magical function of mould proof, antibacterial, deodorization, removing VOC gases " is subdued, therefore one " photocatalyst " has been swept in world wide
Wind, in glass, metal, weaving, building, automobile, weaving, residential equipment, household electrical appliances, light industry, air cleaning, water process, inner-outer wall
Many fields such as coating realize the application of industrialization.There are many enterprises being engaged in so-called photocatalyst production in Chinese the nineties
Product, but stop figthing quickly because quality problems are unqualified.Japan grinds with company of Greece in the technology of photocatalyst industry at present
Study carefully the most advanced, but price is all more than 400 yuan/liter, allows yearning of the people to this magical product to pursue and has to hope and stop
Step, the one kind studied for this for the present situation that the wide market demand and external existing photocatalyst product hold at high price
Self-cleaned by photocatalyst AB combination film forming agent formula practicality technologies.
The content of the invention
In view of the above-mentioned problems, combining film forming agent it is an object of the invention to provide a kind of self-cleaned by photocatalyst AB.It includes A
Agent and B agent, A agent is first infiltrated with painting objects surface and combined during spraying, and B agent is then sprayed again and plays photocatalyst effect, so into
Film is thin, firm, transparent, and photocatalyst effect is good.
To achieve the above object, the technical solution used in the present invention is：A kind of self-cleaned by photocatalyst AB is provided to be combined into
Film；The film forming agent is applied in combination by A agent and B agent, wherein, A agent composition is：Absolute ethyl alcohol 65%~75%, poly- titanate esters
3.5%~5.5%, hydrochloric acid 0.3%~0.5%, esters of silicon acis 10%~14%, acetylacetone,2,4-pentanedione 0.05%~0.15%, triethanolamine 8%~
12%th, distilled water 2%~5%；B agent is constituted：Absolute ethyl alcohol 68%~72%, titanium dioxide 4.5%~5.5%, hydrochloric acid 3.4%~
5.4%th, silica 7.2%~8.4%, acetylacetone,2,4-pentanedione 3.8%~4.4%, distilled water 6.8%~7.8%.
During use, first by the A agent spraying prepared and substrate surface, the knot for making it form adhesion-tight with basic unit
Close film；Retell B agent to be sprayed on the film that A agent is formed, make itself and A agent film strong bondeds, so as to realize film forming agent
The stable purpose for being attached to substrate surface.
The beneficial effects of the invention are as follows：On the basis of original self-cleaned by photocatalyst film forming agent, the use of A agent is added, is made
It forms stabilizing films prior to basic unit, then by B agent spraying with A agent films, the attached of B agent films is easy to by the coating of film
, and B agent composition can react with component in A agent films, form it into the self-cleaned by photocatalyst coating of firm stable.
Embodiment
The present invention is described by the following examples.
Embodiment 1
A agent is constituted：Absolute ethyl alcohol 65%, poly- titanate esters 5.5%, hydrochloric acid 0.3%, esters of silicon acis 14%, acetylacetone,2,4-pentanedione 0.15%,
Triethanolamine 8%, distilled water 2%；B agent is constituted：Absolute ethyl alcohol 68.23%, titanium dioxide 5.4%, hydrochloric acid 5.38%, silica
7.2%th, acetylacetone,2,4-pentanedione 3.8%, distilled water 6.8%.
During use, first by the A agent spraying prepared and substrate surface, the knot for making it form adhesion-tight with basic unit
Close film；Retell B agent to be sprayed on the film that A agent is formed, make itself and A agent film strong bondeds, so as to realize film forming agent
The stable purpose for being attached to substrate surface.
Embodiment 2
A agent is constituted：Absolute ethyl alcohol 70%, poly- titanate esters 4.5%, hydrochloric acid 0.4%, esters of silicon acis 12%, acetylacetone,2,4-pentanedione 0.1%, three
Monoethanolamine 10%, distilled water 3%；B agent is constituted：Absolute ethyl alcohol 70.89%, titanium dioxide 5.2%, hydrochloric acid 4.45%, silica
7.93%th, acetylacetone,2,4-pentanedione 4.12%, distilled water 7.41%.
During use, first by the A agent spraying prepared and substrate surface, the knot for making it form adhesion-tight with basic unit
Close film；Retell B agent to be sprayed on the film that A agent is formed, make itself and A agent film strong bondeds, so as to realize film forming agent
The stable purpose for being attached to substrate surface.
Embodiment 3
A agent is constituted：Absolute ethyl alcohol 74.8%, poly- titanate esters 3.46%, hydrochloric acid 0.48%, esters of silicon acis 10%, acetylacetone,2,4-pentanedione
0.06%th, triethanolamine 12%, distilled water 5%；B agent is constituted：Absolute ethyl alcohol 72%, titanium dioxide 4.48%, hydrochloric acid 3.42%, dioxy
SiClx 8.38%, acetylacetone,2,4-pentanedione 4.4%, distilled water 7.78%.
During use, first by the A agent spraying prepared and substrate surface, the knot for making it form adhesion-tight with basic unit
Close film；Retell B agent to be sprayed on the film that A agent is formed, make itself and A agent film strong bondeds, so as to realize film forming agent
The stable purpose for being attached to substrate surface.
Claims (2)
1. a kind of self-cleaned by photocatalyst AB combines film forming agent, it is characterised in that：The film forming agent is applied in combination by A agent and B agent, its
In, A agent composition is：Absolute ethyl alcohol 65%~75%, poly- titanate esters 3.5%~5.5%, hydrochloric acid 0.3%~0.5%, esters of silicon acis 10%
~14%, acetylacetone,2,4-pentanedione 0.05%~0.15%, triethanolamine 8%~12%, distilled water 2%~5%；B agent is constituted：Absolute ethyl alcohol
68%~72%, titanium dioxide 4.5%~5.5%, hydrochloric acid 3.4%~5.4%, silica 7.2%~8.4%, acetylacetone,2,4-pentanedione 3.8%~
4.4%th, distilled water 6.8%~7.8%；
During use, first by the A agent spraying prepared and substrate surface, make the combination of itself and basic unit's formation adhesion-tight thin
Film；Retell B agent to be sprayed on the film that A agent is formed, make itself and A agent film strong bondeds.
2. a kind of self-cleaned by photocatalyst AB combinations film forming agent according to claim 1, it is characterised in that：The film forming agent by
A agent and B agent are applied in combination, and are preferable over, and A agent composition is：Absolute ethyl alcohol 70%, poly- titanate esters 4.5%, hydrochloric acid 0.4%, esters of silicon acis
12%th, acetylacetone,2,4-pentanedione 0.1%, triethanolamine 10%, distilled water 3%；B agent is constituted：Absolute ethyl alcohol 70.89%, titanium dioxide
5.2%th, hydrochloric acid 4.45%, silica 7.93%, acetylacetone,2,4-pentanedione 4.12%, distilled water 7.41%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710300713.3A CN107286719A (en) | 2017-05-02 | 2017-05-02 | A kind of self-cleaned by photocatalyst AB combines film forming agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710300713.3A CN107286719A (en) | 2017-05-02 | 2017-05-02 | A kind of self-cleaned by photocatalyst AB combines film forming agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107286719A true CN107286719A (en) | 2017-10-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710300713.3A Pending CN107286719A (en) | 2017-05-02 | 2017-05-02 | A kind of self-cleaned by photocatalyst AB combines film forming agent |
Country Status (1)
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| CN (1) | CN107286719A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752983A (en) * | 2018-04-23 | 2018-11-06 | 山西艾珂灵环境科技有限公司 | A kind of single coating photocatalyst film forming agent |
| CN108855226A (en) * | 2018-04-23 | 2018-11-23 | 山西艾珂灵环境科技有限公司 | A kind of AB that can play photocatalysis under visible light is combined into photocatalyst film forming agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101980379A (en) * | 2010-09-27 | 2011-02-23 | 彩虹集团公司 | Method for preparing anti-reflection and self-cleaning composite membrane for solar cell |
| CN102977648A (en) * | 2012-11-19 | 2013-03-20 | 镇江市富来尔制冷工程技术有限公司 | Nanoscale self-cleaning anti-reflection coating material and preparation method thereof |
| CN103740292A (en) * | 2013-12-25 | 2014-04-23 | 东莞市纳利光学材料有限公司 | Self-cleaning nano-coating protective film and preparation method thereof |
| CN104231683A (en) * | 2014-08-25 | 2014-12-24 | 北京市建筑工程研究院有限责任公司 | Titanium dioxide-silicon dioxide composite photocatalytic coating and preparation method thereof |
-
2017
- 2017-05-02 CN CN201710300713.3A patent/CN107286719A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101980379A (en) * | 2010-09-27 | 2011-02-23 | 彩虹集团公司 | Method for preparing anti-reflection and self-cleaning composite membrane for solar cell |
| CN102977648A (en) * | 2012-11-19 | 2013-03-20 | 镇江市富来尔制冷工程技术有限公司 | Nanoscale self-cleaning anti-reflection coating material and preparation method thereof |
| CN103740292A (en) * | 2013-12-25 | 2014-04-23 | 东莞市纳利光学材料有限公司 | Self-cleaning nano-coating protective film and preparation method thereof |
| CN104231683A (en) * | 2014-08-25 | 2014-12-24 | 北京市建筑工程研究院有限责任公司 | Titanium dioxide-silicon dioxide composite photocatalytic coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752983A (en) * | 2018-04-23 | 2018-11-06 | 山西艾珂灵环境科技有限公司 | A kind of single coating photocatalyst film forming agent |
| CN108855226A (en) * | 2018-04-23 | 2018-11-23 | 山西艾珂灵环境科技有限公司 | A kind of AB that can play photocatalysis under visible light is combined into photocatalyst film forming agent |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20171024 |