CN107285544A - A kind of seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy - Google Patents
A kind of seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy Download PDFInfo
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- CN107285544A CN107285544A CN201710605706.4A CN201710605706A CN107285544A CN 107285544 A CN107285544 A CN 107285544A CN 201710605706 A CN201710605706 A CN 201710605706A CN 107285544 A CN107285544 A CN 107285544A
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 151
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 151
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 149
- 239000013535 sea water Substances 0.000 title claims abstract description 63
- 238000010248 power generation Methods 0.000 title claims abstract description 53
- 238000010612 desalination reaction Methods 0.000 title claims abstract description 20
- 239000000446 fuel Substances 0.000 claims abstract description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 31
- 239000013505 freshwater Substances 0.000 claims description 29
- 238000005984 hydrogenation reaction Methods 0.000 claims description 28
- 238000003860 storage Methods 0.000 claims description 27
- 230000007246 mechanism Effects 0.000 claims description 24
- 239000011232 storage material Substances 0.000 claims description 22
- 239000012528 membrane Substances 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 238000001223 reverse osmosis Methods 0.000 claims description 16
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 12
- 230000005611 electricity Effects 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 9
- 239000013206 MIL-53 Substances 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 5
- 239000010936 titanium Substances 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000006227 byproduct Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 238000009434 installation Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- 230000005055 memory storage Effects 0.000 claims description 2
- 230000001954 sterilising effect Effects 0.000 claims description 2
- 238000004659 sterilization and disinfection Methods 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 238000011033 desalting Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 description 9
- 238000003795 desorption Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- QRRKZFCXXBFHSV-UHFFFAOYSA-N 1-ethylindole Chemical class C1=CC=C2N(CC)C=CC2=C1 QRRKZFCXXBFHSV-UHFFFAOYSA-N 0.000 description 5
- BLRHMMGNCXNXJL-UHFFFAOYSA-N 1-methylindole Chemical class C1=CC=C2N(C)C=CC2=C1 BLRHMMGNCXNXJL-UHFFFAOYSA-N 0.000 description 5
- PLAZXGNBGZYJSA-UHFFFAOYSA-N 9-ethylcarbazole Chemical group C1=CC=C2N(CC)C3=CC=CC=C3C2=C1 PLAZXGNBGZYJSA-UHFFFAOYSA-N 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000005868 electrolysis reaction Methods 0.000 description 4
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- 125000003118 aryl group Chemical group 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000002737 fuel gas Substances 0.000 description 3
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- 230000001590 oxidative effect Effects 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
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- 150000004678 hydrides Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 150000002475 indoles Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- JJKOKMLNXTYCHL-UHFFFAOYSA-N C1=CC=CC=2C3=CC=CC=C3CC12.[N] Chemical class C1=CC=CC=2C3=CC=CC=C3CC12.[N] JJKOKMLNXTYCHL-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
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- 239000002826 coolant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
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- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
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- 238000002955 isolation Methods 0.000 description 1
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- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
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- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
- H01M8/04216—Reactant storage and supply, e.g. means for feeding, pipes characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0656—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
- H02J7/34—Parallel operation in networks using both storage and other dc sources, e.g. providing buffering
- H02J7/35—Parallel operation in networks using both storage and other dc sources, e.g. providing buffering with light sensitive cells
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/14—Treatment of water, waste water, or sewage by heating by distillation or evaporation using solar energy
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/009—Apparatus with independent power supply, e.g. solar cells, windpower, fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/56—Power conversion systems, e.g. maximum power point trackers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/70—Wind energy
- Y02E10/76—Power conversion electric or electronic aspects
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P90/00—Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
- Y02P90/50—Energy storage in industry with an added climate change mitigation effect
Abstract
The present invention relates to field of sea water desalting technology, more particularly to a kind of seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy, including wind light mutual complementing power generation module, Hydrogen Energy power supply module and desalinization module.Wind light mutual complementing power generation module includes wind power generation plant, photovoltaic power generation apparatus, the wind/light complementation controller for controlling wind power generation plant and photovoltaic power generation apparatus, and the accumulator being electrically connected with wind/light complementation controller.Hydrogen Energy power supply module, including the fuel generating device being connected respectively with wind light mutual complementing power generation module and the hydrogen electrolyzer of accumulator electric connection, with hydrogen electrolyzer, the PLC control devices being connected respectively with hydrogen electrolyzer and fuel generating device, and the Water Energy retracting device being connected with fuel generating device.Desalinization module, is connected with fuel generating device.Wind light mutual complementing power generation module is used in combination with Hydrogen Energy power supply module by design, and directly applies to desalinization, generating efficiency is high.
Description
Technical field
The present invention relates to field of sea water desalting technology, more particularly to a kind of sea powered based on wind light mutual complementing power generation and Hydrogen Energy
Water desalination system.
Background technology
It is well known that the surface of the earth 71% is all covered with water, and can only it be accounted for entirely for the freshwater resources of people's life
The 2.5% of portion's water resource, seawater content corresponding thereto but occupies 97.5%, increases with world population, modern industry
High speed development, the demand to water resource, particularly freshwater resources is increasing.Therefore, scarcity of fresh water resources has become
The very severe global problem that the world today faces.
In recent years, the attention with increasing country to water resources shortage problem, by method for desalting seawater, is obtained
Freshwater resources are also considered as optimal path.Desalinization be by the salinity in seawater and moisture separation, finally give fresh water and
Concentrate the process of salt solution.Method for desalting seawater the more commonly used at present has multistage flash evaporation (MSF), multiple-effect evaporation (MED) and reverse osmosis
(RO) these three methods thoroughly.Above-mentioned three kinds of methods are required to use electric energy in use.
China coast island are numerous, general lack of electric power and water supply on island, and wind energy, solar energy and sea on island
Water resource is sufficient, therefore has good development prospect using regenerative resource progress desalinization.Solar energy and wind energy are
A kind of inexhaustible and without the energy of pollution, it has the disadvantage that energy density is low and difference is big round the clock, unstable, storage with
Transport is again extremely difficult.There is hydrogen cleanliness without any pollution, accumulating to facilitate, utilization rate is high, can be by fuel cell that chemical energy is direct
Be converted to electric energy.Hydrogen also can utilize to store energy, be a kind of important secondary energy sources.Hydrogen Energy is contained in hydrogen
Energy, with environment-friendly, aboundresources, calorific value is high, have good burning performance, potential high financial profit the characteristics of.
The content of the invention
It is an object of the invention to provide a kind of seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy, to solve
Technical problem be：A kind of generating efficiency height and the high seawater desalination system of energy utilization rate are provided.
In order to solve the above-mentioned technical problem, the invention provides a kind of sea powered based on wind light mutual complementing power generation and Hydrogen Energy
Water desalination system, including:
Wind light mutual complementing power generation module, including wind power generation plant, photovoltaic power generation apparatus, for controlling the wind-power electricity generation to fill
Put the wind/light complementation controller with photovoltaic power generation apparatus, and the accumulator being electrically connected with the wind/light complementation controller；
Hydrogen Energy power supply module, including the Hydrogen Energy being electrically connected with respectively with the wind light mutual complementing power generation module and accumulator are electrolysed
Pond, the fuel generating device being connected with the hydrogen electrolyzer, respectively with the hydrogen electrolyzer and the fuel generating device
The PLC control devices of connection, and the Water Energy retracting device being connected with fuel generating device；And
Desalinization module, is connected with the fuel generating device.
Further, the desalinization module includes seawater withdrawal device and the institute being connected with the fuel generating device
The sea for stating the filter of seawater withdrawal device connection, being connected and being electrically connected with the fuel generating device with the filter
Water high-voltage booster, the reverse osmosis membrane apparatus being connected with the seawater high-voltage booster, it is connected to the reverse osmosis membrane apparatus one
Side and the energy recycle device that is connected with the hydrogen electrolyzer, and be connected with the reverse osmosis membrane apparatus opposite side it is light
Apparatus for recovering.
Further, the Hydrogen Energy power supply module be also connected including one end with the hydrogen electrolyzer and the other end with it is described
The Hydrogen Energy memory of fuel generating device connection；
It is electrically connected between the hydrogen electrolyzer and the fuel generating device provided with one with the PLC control devices
Gas flowmeter；
It is electrically connected between the hydrogen electrolyzer and the fuel generating device provided with one with the PLC control devices
First magnetic valve；
The be electrically connected between the hydrogen electrolyzer and the Hydrogen Energy memory provided with one with the PLC control devices
Two magnetic valves；And
It is electrically connected between the Hydrogen Energy memory and the fuel generating device provided with one with the PLC control devices
3rd magnetic valve；I.e.
The PLC control devices signal is passed to by the gas flowmeter, the Hydrogen Energy is judged by PLC control devices
The size of Hydrogen Energy flow in electrolytic cell, so as to judge whether to need by the unnecessary Hydrogen Energy of the Hydrogen Energy memory storage, works as Hydrogen Energy
When not enough, then controlled by the PLC control devices to provide Hydrogen Energy by the Hydrogen Energy memory for the fuel generating device.
Further, the Hydrogen Energy memory includes hydrogenation mechanism and dehydrogenation mechanism；Provided with organic in the hydrogenation mechanism
Hydrogen storage material；Wherein
The organic hydrogen storage material in the hydrogenation mechanism be hydrogenated with and obtains hydrogenating organic hydrogen storage material, by organic storage
Hydrogen material is transferred in dehydrogenation mechanism, and hydrogenation organic hydrogen storage material carries out dehydrogenation in dehydrogenation mechanism, and the hydrogen of abjection enters combustion
Expect TRT；And
Hydrogenation catalyst is housed, the hydrogenation catalyst is Ni/MIL-53 (Al), Ru-B/MIL- in the hydrogenation mechanism
One kind in 53 (Cr), Ru/Al2O3；
Dehydrogenation is housed, the dehydrogenation is or Pd/MIL-53 (Al), palladium load three in the dehydrogenation mechanism
One kind in aluminum oxide or palladium load type active carbon.
Further, the seawater withdrawal device and the fuel generating device are provided with DC/AC inverters.
Further, anticorrosion electrode titanium, and hydrogen electrolyzer side inwall are used in the hydrogen electrolyzer
On activated carbon is installed；And
The hydrogen electrolyzer is also associated with a byproduct collecting apparatus.
Further, the Water Energy retracting device includes a heat exchanger being connected with the fuel generating device, led to
Cross after the heat exchanger be used to storing the first fresh water storage tank of fresh water, be connected with the heat exchanger for evaporating seawater
Solar energy heat collection pipe, and be connected with the steam outlet of the solar energy heat collection pipe and with the first fresh water storage tank
The condenser of connection；Wherein
The steam outlet of the solar energy heat collection pipe is additionally provided with a fan for being used to be blown into steam in condenser.
Further, the water leg that a collection stores rainwater is additionally provided with the solar thermal collector.
Further, the filter includes the more medium filter that is sequentially connected, active carbon filter and ensures public security
Filter.
Further, the fresh water retracting device include be connected with the reverse osmosis membrane apparatus ultraviolet sterilizer, and
The remineralization device of the ultraviolet sterilizer connection, and the second fresh water storage tank being connected with the remineralization device.
Beneficial effects of the present invention are：Being combined wind light mutual complementing power generation module with Hydrogen Energy power supply module by design makes
With, and directly apply to desalinization, it is to avoid and fortune hydrogen problem, have complementary advantages, generating efficiency is high, storage is convenient, practical, should
It is high with value.
Further, the Water Energy retracting device of design, suitable for hydrogen fuel cell heat production is made full use of, saves the energy.
Further, design the high concentration seawater in energy recycle device in reverse osmosis membrane apparatus as electrolyte, can
To improve electrolyzing rate, a large amount of addition products such as salt, oxygen are produced, are increased economic efficiency.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples.
Fig. 1 is the structural representation of the seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy of the present invention；
Fig. 2 is the Hydrogen Energy power supply module of the seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy of the present invention
Structural representation.
In figure：Wind power generation plant 1, photovoltaic power generation apparatus 2, wind/light complementation controller 3, accumulator 4, hydrogen electrolyzer 5,
Byproduct collecting apparatus 6, Hydrogen Energy memory 7, fuel generating device 8, the first fresh water storage tank 9, condenser 10, fan 11, too
Positive energy thermal-collecting tube 12, heat exchanger 13, seawater withdrawal device 14, more medium filter 15, active carbon filter 16, cartridge filter
17th, seawater high-voltage booster 18, reverse osmosis membrane apparatus 19, energy recycle device 20, ultraviolet sterilizer 21, remineralization device 22,
Second fresh water storage tank 23, gas flowmeter 24, the first magnetic valve 25, the second magnetic valve 26, the 3rd magnetic valve 27, PLC controls
Device 28, DC/AC inverters 29.
Embodiment
To make the purpose, technical scheme and advantage of embodiment of the present invention clearer, below in conjunction with present invention implementation
Accompanying drawing in mode, the technical scheme in embodiment of the present invention is clearly and completely described, it is clear that described reality
The mode of applying is a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, ability
The every other embodiment that domain those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Therefore, the detailed description of embodiments of the present invention below to providing in the accompanying drawings is not intended to limit requirement and protected
The scope of the present invention of shield, but it is merely representative of the selected embodiment of the present invention.Based on the embodiment in the present invention, ability
The every other embodiment that domain those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
In the description of the invention, it is to be understood that the term of indicating position or position relationship is based on shown in accompanying drawing
Orientation or position relationship, be for only for ease of the description present invention and simplify description, rather than indicate or imply signified equipment
Or element there must be specific orientation, with specific azimuth configuration and operation, therefore it is not considered as limiting the invention.
In the present invention, unless otherwise clearly defined and limited, term " installation ", " connected ", " connection ", " fixation " etc.
Term should be interpreted broadly, for example, it may be fixedly connected or be detachably connected, or integrally；Can be that machinery connects
Connect or electrically connect；Can be joined directly together, can also be indirectly connected to by intermediary, can be in two elements
The connection in portion or the interaction relationship of two elements.For the ordinary skill in the art, can be according to specific feelings
Condition understands the concrete meaning of above-mentioned term in the present invention.
In the description of the invention, it is necessary to explanation, term " " center ", " on ", " under ", "left", "right", " vertical ",
The orientation or position relationship of the instruction such as " level ", " interior ", " outer " be based on orientation shown in the drawings or position relationship, or should
Orientation or position relationship that invention product is usually put when using, are for only for ease of the description present invention and simplify description, without
It is that instruction or the signified device of hint or element must have specific orientation, with specific azimuth configuration and operation, therefore not
It is understood that as limitation of the present invention.In addition, term " first ", " second ", " the 3rd " etc. are only used for distinguishing description, and it can not manage
Solve to indicate or imply relative importance.
In addition, the term such as term " level ", " vertical ", " pendency " is not offered as requiring part abswolute level or pendency, and
It is to be slightly tilted.As " level " only refers to that its direction, with respect to more level for " vertical ", is not the expression structure
Must be fully horizontal, but can be slightly tilted.
As depicted in figs. 1 and 2, the invention provides a kind of desalinization system powered based on wind light mutual complementing power generation and Hydrogen Energy
System, including wind light mutual complementing power generation module, Hydrogen Energy power supply module and desalinization module.
Wind light mutual complementing power generation module, including wind power generation plant 1, photovoltaic power generation apparatus 2, for controlling the wind-power electricity generation
The wind/light complementation controller 3 of device 1 and photovoltaic power generation apparatus 2, and the accumulation of energy being electrically connected with the wind/light complementation controller 3
Device 4.
Wind power generation plant 1 includes blower fan, and photovoltaic power generation apparatus 2 includes solar panel.
The electric energy that wind power generation plant 1 and photovoltaic power generation apparatus 2 are produced, is filled by wind/light complementation controller 3 to accumulator 4
Electricity.Wind/light complementation controller 3 can charge to accumulator 4 according to the voltage change of accumulator 4, discharge.Accumulator 4 plays storage and adjusted
The effect of economize on electricity energy, when sunshine is sufficient or wind-force is very big, powers directly to electrolysis water trough.For the electric energy that prevents it is superfluous when,
Unnecessary electrical power storage is got up by accumulator 4；When system generated energy is not enough, then electricity is provided from accumulator 4 to electrolysis water trough
Can, keep the stabilization of supply voltage.
Hydrogen Energy power supply module, including the Hydrogen Energy electricity being electrically connected with respectively with the wind light mutual complementing power generation module and accumulator 4
Pond 5 is solved, the fuel generating device 8 being connected with the hydrogen electrolyzer 5 is sent out with the hydrogen electrolyzer 5 and the fuel respectively
The PLC control devices 28 that electric installation 8 is connected, and the Water Energy retracting device being connected with fuel generating device 8.
Desalinization module, is connected with the fuel generating device 8, including is electrically connected with the fuel generating device 8
Seawater withdrawal device 14, the filter being connected with the seawater withdrawal device 14, be connected with the filter and with the combustion
Expect the seawater high-voltage booster 18 that TRT 8 is electrically connected with, the reverse osmosis membrane dress being connected with the seawater high-voltage booster 18
19 are put, energy recycle device 20 that is with the side of reverse osmosis membrane apparatus 19 and being connected with the hydrogen electrolyzer 5 is connected,
And the fresh water retracting device being connected with the opposite side of reverse osmosis membrane apparatus 19.
Wherein, seawater withdrawal device 14 uses suction pump, and seawater high-voltage booster 18 uses high-pressure pump.Energy recycle device 20
Using turbine type, low pressure high concentration seawater will be discharged, import electrolysis water trough, be used as electrolyte.
The Hydrogen Energy power supply module is also connected and the other end and the fuel power generation function including one end with the hydrogen electrolyzer 5
The Hydrogen Energy memory 7 that device 8 is connected.
Electrically connect with the PLC control devices 28 provided with one between the hydrogen electrolyzer 5 and the fuel generating device 8
The gas flowmeter 24 connect.
It is electrically connected between the hydrogen electrolyzer 5 and fuel generating device 8 provided with one with the PLC control devices 28
First magnetic valve 25.Provided with one and the electricity of PLC control devices 28 between the hydrogen electrolyzer 5 and the Hydrogen Energy memory 7
Property connection the second magnetic valve 26.Controlled between the Hydrogen Energy memory 7 and the fuel generating device 8 provided with one with the PLC
The 3rd magnetic valve 27 that device 28 processed is electrically connected with.The PLC control devices 28 are passed to by the gas flowmeter 24
Signal, the size of Hydrogen Energy flow in the hydrogen electrolyzer 4 is judged by PLC control devices 28, so as to judge whether to need by institute
State Hydrogen Energy memory 7 and store unnecessary Hydrogen Energy, controlled when Hydrogen Energy is not enough, then by the PLC control devices 28 by the Hydrogen Energy
Memory 7 is that the fuel generating device 8 provides Hydrogen Energy.
The Hydrogen Energy memory 7 includes hydrogenation mechanism and dehydrogenation mechanism；Organic hydrogen storage material is provided with the hydrogenation mechanism.
The organic hydrogen storage material in the hydrogenation mechanism be hydrogenated with and obtains hydrogenating organic hydrogen storage material, by organic storage
Hydrogen material is transferred in dehydrogenation mechanism, and hydrogenation organic hydrogen storage material carries out dehydrogenation in dehydrogenation mechanism, and the hydrogen of abjection enters combustion
Expect TRT 8.
Specifically, the organic hydrogen storage material is by N- methyl indols, N- ethylindoles, carboline and N- ethyl carbazole groups
Into；And N- methyl indols in the organic hydrogen storage material, N- ethylindoles, the mass ratio of carboline and N- ethyl carbazoles are 5:
1∶2∶2。
The organic hydrogen storage material selected in the present invention is N- methyl indols, N- ethylindoles, carboline and N- ethyl carbazoles
Mixture, each of which can selectivity progress be hydrogenated with and dehydrogenation reaction, in the course of the work be not in decompose.Two
Nitrogen fluorenes has six double bonds, and each carboline altogether can be plus 12 hydrogen atoms, with higher hydrogen-storage density, but carboline
Fusing point is higher, because dehydrogenation reaction is endothermic process, in order that dehydrogenation reaction can be carried out in lower temperature, so as to consume less
Heat, the absolute value of the heat of hydrogenation of organic hydrogen storage material should be as far as possible small, and nitrogen heteroatom is introduced into fused ring compound, its hydride
Desorption temperature can be reduced substantially.In addition, with the increase of fused ring compound number of aromatic rings, its heat of hydrogenation can accordingly be reduced, made
The desorption temperature of its hydride can also be decreased, and the temperature difference between one-level desorption temperature and highest desorption temperature can also become
It is small.Therefore, in order to obtain, desorption temperature is convenient, the differential less hydrogen storage molecule of desorption temperature, it is contemplated that using existing simultaneously
Nitrogen heteroatom and increase molecule aromatic ring two kinds of means of number are introduced in molecule, however as the increase of number of aromatic rings, fused ring compound
Molten boiling point would generally increase sharply, although higher boiling can guarantee that they be unlikely under desorption temperature boiling, if thick
Cycle compound fusing point is too high, is solid even under dehydrogenation operating temperature, and with the progress of dehydrogenation reaction, what dehydrogenation was produced consolidates
Body product may be covered in the surface of catalyst and catalyst can not be normally played catalytic action.
It is used for fuel cell for convenience, as preferably liquid under the fused ring compound normal temperature of hydrogen storage material, because liquid
State hydrogen storage material has more significant engineering advantage than solid-state, either in the process of running or in delivery process they
All it is easier to be drawn.
According to thermodynamic argument, if the exchange energy of two kinds of liquid components is negative, then their mixture can occur pair
The negative bias of ideal mixture is possible to largely be less than any pure group from, that is to say, that the minimum fusing point of its mixture
The fusing point divided, for more polynary system, as long as the exchange energy between any two component is negative, then the minimum fusing point of mixture is just
It can become lower, this thermodynamics conclusion is also applied for the polycomponent system being made up of the fused ring compound containing side base, can pass through
Adjusting the type of the side base of fused ring compound makes its exchange energy be negative, and according to this principle, we are obtained by the way of compounding
Organic hydrogen storage material is mixed, while higher hydrogen-storage density is ensured, the fusing point of hydrogen storage system is reduced as far as possible, while to ensure
Without limitation on mutual hydrogenation and dehydrogenation.The present invention by introduced in indoles and carbazole molecules methyl or ethyl obtain fusing point compared with
Low N- methyl indols, N- ethylindoles and N- ethyl carbazoles, in the prior art by indoles and its derivative, carbazole and its
Derivative is used as the data of hydrogen storage material, but the data that they are not compounded to they, in addition, though they are each
It can be individually hydrogenated with and dehydrogenation reaction, but, it is necessary to select suitable proportioning, catalyst type, temperature after being grouped together
The factors such as degree just can guarantee that they after mixing mutual hydrogenation and dehydrogenation be not suppressed, it is of the invention by by N- methyl indols,
N- ethylindoles, carboline and N- ethyl carbazoles are mixed by a certain percentage, obtain eutectic point in subzero eutectic liquid
Mixture hydrogen storage material system, hydrogen-storage density is up to 5.89wt%, and will not suppress mutual hydrogenation reaction each other and de-
The progress of hydrogen reaction.
Optionally, hydrogenation catalyst is housed in the hydrogenation mechanism, the hydrogenation catalyst is Ni/MIL-53 (Al), Ru-
One kind in B/MIL-53 (Cr), Ru/Al2O3；The hydrogenation temperature of the hydrogenation plant is 120-150 DEG C.
Dehydrogenation is housed, the dehydrogenation is or Pd/MIL-53 (Al), palladium load three in the dehydrogenation mechanism
One kind in aluminum oxide or palladium load type active carbon；The desorption temperature of the dehydrogenation unit is 170-190 DEG C.
Optionally, the weight ratio of catalyst and raw material is 1: 10.
The seawater withdrawal device 14 is provided with DC/AC inverters 29 with the fuel generating device 8.Fuel generating device 8
By being that seawater withdrawal device 14 and seawater high-voltage booster 18 provide electric energy after DC/AC inverters 29.
It is preferred that, anticorrosion electrode titanium, and the side inwall of the hydrogen electrolyzer 5 are used in the hydrogen electrolyzer 5
On activated carbon is installed；And the hydrogen electrolyzer 5 is also associated with a byproduct collecting apparatus 6.
Hydrogen electrolyzer 5, can sea water resistance, various chlorides and time chlorate, oxidisability using anticorrosion electrode titanium (Ti)
Sour (including smoke, nitric acid), organic acid, the corrosion of alkali etc..Activated carbon, activated carbon are installed on the side inwall of hydrogen electrolyzer 5
Seawater electrolysis hydrogen manufacturing is aided in, the voltage of electrolytic seawater is greatly lowered, while inhibiting the generation of chlorine, saving electricity is realized
The requirement of energy.
Concentrated seawater is 2 times of the dense height of nature seawater, and salt content is high, can obtain a large amount of crude salt, magnesium, potassium, bromine and rare member
Element.Hydrogen electrolyzer 5 can obtain pure oxygen, and collecting can be as commodity.Mechanic factory workers are sold to as steel to cut and have
Oxygen when non-ferrous metal is welded.Economic benefit is big, can promote making full use of for seawater resources, promotes island development.
The Water Energy retracting device includes a heat exchanger 13 being connected with the fuel generating device 8, by described
Be used to store the first fresh water storage tank 9 of fresh water after heat exchanger 13, be connected with the heat exchanger 13 for evaporating seawater
Solar energy heat collection pipe 12, and be connected with the steam outlet of the solar energy heat collection pipe 12 and with first fresh water
The condenser 10 that storage tank 9 is connected.
The steam outlet of the solar energy heat collection pipe 12 is additionally provided with a fan for being used to be blown into steam in condenser 10
11。
Optionally, the water leg that a collection stores rainwater is additionally provided with the solar thermal collector 12.Can by water leg
Preferably to recycle rainwater resource, do not waste.
The filter includes the more medium filter 15 being sequentially connected, active carbon filter 16 and cartridge filter
17.Again antisludging agent is added in the seawater after cartridge filter 17.
The fresh water retracting device includes the ultraviolet sterilizer 21 being connected with the reverse osmosis membrane apparatus 19, with the purple
The remineralization device 22 that outside line sterilizer 21 is connected, and the second fresh water storage tank 23 being connected with the remineralization device 22.
Optionally, the fuel generating device 8 can be using such as, but not limited to pem cell or basic fuel electricity
Pond.
When using Proton Exchange Membrane Fuel Cells, it is used as electrolyte, including two pieces using solid macromolecule copolymer film
Porous gas diffusive electrode and solid macromolecule copolymer dielectric film, the side of porous electrode be volt in catalyst, another pole with
Pole plate is contacted, and opens up recess channels on pole plate, one side fuel gas, oxidant or cooling agent pass through, and the electrical contact with electrode can
Realized with the plate electrode by these flow fields, the solid macromolecule copolymer dielectric film between two electrodes, with matter
The function of proton exchange, also plays a part of isolation fuel gas and oxidant, Proton Exchange Membrane Fuel Cells is with hydrogen or net
It is fuel gas to change fuel reforming gas, and using air or purity oxygen as oxidant, battery is divided into negative electrode and anode by electrolyte
Two parts, if supply hydrogen and oxygen, in the anode, hydrogen to anode and negative electrode respectively reduces work under the catalysis of catalyst
Performance, chemically reacts.The product of Proton Exchange Membrane Fuel Cells is water, electricity and heat.Therefore more environmentally-friendly and saving
The energy.
The operation principle of the seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy of the present invention is：Wind light mutual complementing
TRT is powered to accumulator 4, and accumulator 4 is powered to hydrogen electrolyzer 5, and hydrogen electrolyzer 5 produces hydrogen, part storage
In Hydrogen Energy memory 7, part supply fuel generating device 8.Fuel generating device 8 will give seawater withdrawal device 14 and seawater high pressure
Booster 18 is powered, in the water storage that this process is produced to the first fresh water storage tank 9.The heat of generation enters through heat exchanger 13
Enter solar thermal collector 12, seawater produces steam through solar thermal collector 12, is condensed into after being discharged to condenser 10 through fan 11 light
Water, flows into the first fresh water storage tank 9.Desalinization module, the extracting seawater of seawater withdrawal device 14 through more medium filter 15, is lived
Property carbon filter 16, cartridge filter 17 are tentatively pre-processed, and antisludging agent is added afterwards, is increased through seawater high-voltage booster 18
Pressure, by reverse osmosis membrane apparatus 19, filters out fresh water.Energy recycle device 20 recovers energy and by the high concentration seawater stream of discharge
Enter hydrogen electrolyzer 5.Most afterwards after ultraviolet sterilization and remineralization, fresh water is stored in the second fresh water storage tank 23.
Using the above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property scope is not limited to the content on specification, it is necessary to its technical scope is determined according to right.
Claims (10)
1. a kind of seawater desalination system powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that including:
Wind light mutual complementing power generation module, including wind power generation plant, photovoltaic power generation apparatus, for control the wind power generation plant and
The wind/light complementation controller of photovoltaic power generation apparatus, and the accumulator being electrically connected with the wind/light complementation controller；
Hydrogen Energy power supply module, including be electrically connected with respectively with the wind light mutual complementing power generation module and accumulator hydrogen electrolyzer,
The fuel generating device that is connected with the hydrogen electrolyzer, it is connected respectively with the hydrogen electrolyzer and the fuel generating device
PLC control devices, and the Water Energy retracting device being connected with fuel generating device；And
Desalinization module, is connected with the fuel generating device.
2. the seawater desalination system according to claim 1 powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that
Seawater withdrawal device that the desalinization module includes being connected with the fuel generating device, it is connected with the seawater withdrawal device
Filter, the seawater high-voltage booster for being connected with the filter and being electrically connected with the fuel generating device and institute
State seawater high-voltage booster connection reverse osmosis membrane apparatus, be connected to the reverse osmosis membrane apparatus side and with the Hydrogen Energy electricity
The energy recycle device of Xie Chi connections, and the fresh water retracting device being connected with the reverse osmosis membrane apparatus opposite side.
3. the seawater desalination system according to claim 1 or 2 powered based on wind light mutual complementing power generation and Hydrogen Energy, its feature is existed
In the Hydrogen Energy power supply module is also connected including one end with the hydrogen electrolyzer and the other end connects with the fuel generating device
The Hydrogen Energy memory connect；
Provided with the gas being electrically connected with the PLC control devices between the hydrogen electrolyzer and the fuel generating device
Flowmeter；
Provided with first electromagnetism being electrically connected with the PLC control devices between the hydrogen electrolyzer and fuel generating device
Valve；
Provided with second electricity being electrically connected with the PLC control devices between the hydrogen electrolyzer and the Hydrogen Energy memory
Magnet valve；And
The 3rd be electrically connected between the Hydrogen Energy memory and the fuel generating device provided with one with the PLC control devices
Magnetic valve；I.e.
The PLC control devices signal is passed to by the gas flowmeter, judges that the Hydrogen Energy is electrolysed by PLC control devices
The size of Hydrogen Energy flow in pond, so as to judge whether to need by the unnecessary Hydrogen Energy of the Hydrogen Energy memory storage, when Hydrogen Energy is not enough
When, then controlled by the PLC control devices to provide Hydrogen Energy by the Hydrogen Energy memory for the fuel generating device.
4. the seawater desalination system according to claim 3 powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that
The Hydrogen Energy memory includes hydrogenation mechanism and dehydrogenation mechanism；Organic hydrogen storage material is provided with the hydrogenation mechanism；Wherein
The organic hydrogen storage material in the hydrogenation mechanism be hydrogenated with and obtains hydrogenating organic hydrogen storage material, by organic hydrogen storage material
Material is transferred in dehydrogenation mechanism, and hydrogenation organic hydrogen storage material carries out dehydrogenation, the hydrogen incoming fuel hair of abjection in dehydrogenation mechanism
Electric installation；And
Hydrogenation catalyst is housed, the hydrogenation catalyst is Ni/MIL-53 (Al), Ru-B/MIL-53 in the hydrogenation mechanism
(Cr), one kind in Ru/Al2O3；
Dehydrogenation is housed, the dehydrogenation is or Pd/MIL-53 (Al), palladium load three are aoxidized in the dehydrogenation mechanism
One kind in aluminium or palladium load type active carbon.
5. the seawater desalination system according to claim 2 powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that
The seawater withdrawal device is provided with DC/AC inverters with the fuel generating device.
6. the seawater desalination system according to claim 1 powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that
Used in the hydrogen electrolyzer on anticorrosion electrode titanium, and hydrogen electrolyzer side inwall and activated carbon is installed；With
And
The hydrogen electrolyzer is also associated with a byproduct collecting apparatus.
7. the seawater desalination system according to claim 1 powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that
The Water Energy retracting device includes a heat exchanger being connected with the fuel generating device, by being used after the heat exchanger
The first fresh water storage tank in storage fresh water, the solar energy heat collection pipe for evaporating seawater being connected with the heat exchanger, with
And be connected with the steam outlet of the solar energy heat collection pipe and store tank connected condenser with first fresh water；Wherein
The steam outlet of the solar energy heat collection pipe is additionally provided with a fan for being used to be blown into steam in condenser.
8. the seawater desalination system according to claim 7 powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that
The water leg that a collection stores rainwater is additionally provided with the solar thermal collector.
9. the seawater desalination system according to claim 2 powered based on wind light mutual complementing power generation and Hydrogen Energy, it is characterised in that
The filter includes the more medium filter being sequentially connected, active carbon filter and cartridge filter.
10. the seawater desalination system according to claim 2 powered based on wind light mutual complementing power generation and Hydrogen Energy, its feature is existed
In the fresh water retracting device includes the ultraviolet sterilizer being connected with the reverse osmosis membrane apparatus and the ultraviolet sterilization
The remineralization device of device connection, and the second fresh water storage tank being connected with the remineralization device.
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| CN113283099A (en) * | 2021-06-02 | 2021-08-20 | 国网辽宁省电力有限公司 | Modeling method of wind-solar hydrogen storage seawater desalination system |
| CN114597953A (en) * | 2022-05-07 | 2022-06-07 | 哈尔滨工业大学(深圳)(哈尔滨工业大学深圳科技创新研究院) | Comprehensive energy system and method for jointly developing and utilizing multiple resources in deep open sea |
| CN115449837A (en) * | 2022-08-29 | 2022-12-09 | 中国华能集团清洁能源技术研究院有限公司 | Seawater hydrogen production electrode and preparation method and application thereof |
| CN115449837B (en) * | 2022-08-29 | 2023-09-08 | 中国华能集团清洁能源技术研究院有限公司 | Seawater hydrogen production electrode and preparation method and application thereof |
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