CN107267063A - A kind of pure plant albumen interior wall coating - Google Patents
A kind of pure plant albumen interior wall coating Download PDFInfo
- Publication number
- CN107267063A CN107267063A CN201710695433.7A CN201710695433A CN107267063A CN 107267063 A CN107267063 A CN 107267063A CN 201710695433 A CN201710695433 A CN 201710695433A CN 107267063 A CN107267063 A CN 107267063A
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- China
- Prior art keywords
- resin
- water
- soybean protein
- rosin
- interior wall
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of pure plant albumen interior wall coating, its binding agent included in coating is composited using soybean protein resin and emulsification rosin resin, the soybean protein resin is that soybean protein is gelatinized into more than 0.5h at 70 100 DEG C in water, the emulsification rosin resin includes the composition of following parts by weight, 50 150 parts of rosin, 50 150 parts of water, 10 20 parts of sodium acid carbonate, the quality of paraffin is the 2 5% of rosin, water and sodium acid carbonate gross mass；Coating of the present invention includes the component of following mass percent：Soybean protein resin 10 30%；Emulsify rosin resin 20 30%, pigment 10 30%, filler 30 50%, water 20 50%.Present component is natural, and bonding strength is strong, without harmful substances such as any chemical synthesis resin, chemical assistant, chemical solvent, bactericide, mould inhibitors.
Description
Technical field
The invention belongs to technical field of coatings, specifically, it is related to a kind of pure plant albumen interior wall coating.
Background technology
All interior wall coatings are all to do adhesive by chemical industry synthesis resin currently on the market, add substantial amounts of chemistry and help
The harmful substances such as agent, solvent, bactericide, mould inhibitor, then add the wall finiss of the scattered grinding of some color stuffings, and chemistry is helped
Agent and solvent discharge substantial amounts of pernicious gas, damage, are polluted to environment to human health.As the people are to life matter
The raising that amount is required is, it is necessary to research and develop a kind of complete pure natural interior wall coating of composition.
The content of the invention
It is an object of the invention to provide a kind of natural harmless pure plant albumen interior wall coating of composition.
To achieve the above object, the binding agent in coating of the present invention is combined using soybean protein resin and emulsification rosin resin
Form.
Further, the soybean protein resin is by soybean protein at 70-100 DEG C, more than 0.5h to be gelatinized in water, greatly
Mass fraction of the legumin in water is 25%-60%, forms soybean protein resin.
Further, the emulsification rosin resin is made by following steps,
A, the composition for weighing following parts by weight, 50-150 parts of rosin, 50-150 parts of water, 10-20 parts of sodium acid carbonate；Weigh stone
Wax, the quality of paraffin is the 2-5% of rosin, water and sodium acid carbonate gross mass；
B. 1-2h is heated after the rosin, water, sodium acid carbonate and the paraffin mixing that step a are weighed at 70-120 DEG C；
C. regulating step b obtains the pH value of solution to 8；
D. the solution that step c is obtained is incubated 2-3h at 100 DEG C.
Further：Include the component of following mass percent,
Soybean protein resin 10-30%；
Emulsify rosin resin 20-30%；
Pigment： 10-30%；
Filler： 30-50%；
Water： 20-50%.
Further, in addition to paraffin, the quality of the paraffin is soybean protein resin, emulsification rosin resin, pigment, filled out
The 2-10% of material and water gross mass.
Further, preparation method comprises the following steps,
A. pH value is adjusted after being well mixed soybean protein resin, emulsification rosin resin and water to more than 8；
B. the obtained solution of step a is stirred, obtains adhesive；
C. by pigment and filling material grinding to 10-20 microns, then add in the solution that step b is obtained, be well mixed.
Further, in addition to step d, step d be ultraviolet disinfection after be vacuum-packed.
Further, the pigment includes titanium dioxide.
Further, the titanium dioxide is nano titanium oxide.
Further, filler includes calcite or diatomite.
Good effect of the present invention is as follows：
The present invention is compound as adhesive using soybean protein gelatinization resin and emulsification rosin is extracted, and composition is natural, and viscosity is big, glue
Close intensity strong.Coating of the present invention has without any chemical synthesis resin, chemical assistant, chemical solvent, bactericide, mould inhibitor etc.
Evil material, has accomplished the product of real net taste environmental protection, and indices meet the requirement of application, are adapted to marketing, can be significantly
Lift the living environment and air quality of user.
Embodiment
Embodiment 1
It is composited obtained binding agent using soybean protein resin and emulsification rosin resin in coating of the present invention.Soybean protein tree
The binding agent that fat and emulsification rosin resin are composited is compound according to following percentage by weight, and gained binding agent can also be used in non-
Paint field：
Soybean protein resin 10-30%；
Emulsify rosin resin 20-30%.
Soybean protein resin and emulsification rosin resin are due to being difficult to be merged so both generals of the invention
Fusion, prepares that viscosity is good, meets the adhesive of coating requirement.
In the present embodiment, the soybean protein resin is that soybean protein is gelatinized into more than 0.5h, soybean at 80 DEG C in water
Mass fraction of the albumen in water is 40%, forms soybean protein resin.
The emulsification rosin resin is made by following steps, a, the composition for weighing following parts by weight, 100 parts of rosin,
80 parts of water, 15 parts of sodium acid carbonate；Paraffin is weighed, the quality of paraffin is the 4% of rosin, water and sodium acid carbonate gross mass；
B. 1-2h is heated after the rosin, water, sodium acid carbonate and the paraffin mixing that step a are weighed at 100 DEG C；
C. regulating step b obtains the pH value of solution to 8；
D. the solution that step c is obtained is incubated 2-3h at 100 DEG C, has obtained emulsification rosin resin.
After above-mentioned soybean protein resin and emulsification rosin resin are mixed, the binding agent of coating of the present invention is obtained.
Coating of the present invention includes the component of following percetage by weight：Soybean protein resin 15%, emulsifies rosin resin 25%,
Pigment nano titanium oxide 10%, filler diatomite 50%, water 40%, the quality of the paraffin is soybean protein resin, emulsifies rosin
Resin, pigment, the 5% of filler and water gross mass.
Preparation method of the present invention comprises the following steps,
A. pH value is adjusted after being well mixed soybean protein resin, emulsification rosin resin and water to more than 8；
B. the obtained solution of step a is stirred；
C. by pigment and filling material grinding to 10-20 microns, then add in the solution that step b is obtained, be well mixed.
It is vacuum-packed after step d. ultraviolet disinfections.
After soybean protein resin and emulsification rosin resin mixing, the viscosity needs that can meet coating are not added with formaldehyde etc. again
Harmful substance.
Nano titanium oxide has good photocatalysis effect, can decompose aerial pernicious gas and part is inorganization
Compound, and the activity of bacteria growing inhibiting and virus, reach air cleaning, sterilize, and deodorization is mould proof.Nano titanium oxide has
Antibacterial,
After coating addition diatomite, with porosity is big, absorbability is strong, chemical property is stable, it is wear-resisting, heat-resisting the features such as, can be
Coating provides excellent surface property, increase-volume, thickening.Because it has larger pore volume, film can be made to shorten drying time.
At present by large-scale coating material production business numerous in the world as specified articles for use, can be dried for diatom ooze coating, deodorization and
And the characteristics of air, sound insulation, waterproof and good heat-insulated, permeability can also be purified.It is super on humidity in regulation room, kieselguhr wall material
Micropore can be in automatic absorption air moisture content, stored.If under the moisture content reduction, humidity in room air
Drop, kieselguhr wall material can just discharge the moisture content being stored in ultra micro pore.
Coating in the present embodiment is without any chemical synthesis resin, chemical assistant, chemical solvent, bactericide, mould proof
The harmful substances such as agent, have accomplished the product of real net taste environmental protection.
Embodiment 2
The soybean protein resin is that soybean protein is gelatinized into more than 0.5h, quality of the soybean protein in water at 70 DEG C in water
Fraction is 25%, forms soybean protein resin.
The emulsification rosin resin is made by following steps, a, the composition for weighing following parts by weight, 50 parts of rosin, water
50 parts, 10 parts of sodium acid carbonate；Paraffin is weighed, the quality of paraffin is the 2% of rosin, water and sodium acid carbonate gross mass；
B. 1-2h is heated after the rosin, water, sodium acid carbonate and the paraffin mixing that step a are weighed at 120 DEG C；
C. regulating step b obtains the pH value of solution to 8；
D. the solution that step c is obtained is incubated 2-3h at 100 DEG C, has obtained emulsification rosin resin.
After above-mentioned soybean protein resin and emulsification rosin resin are mixed, the binding agent of coating of the present invention is obtained.
The binding agent that soybean protein resin and emulsification rosin resin are composited is compound according to following percentage by weight, gained
Binding agent can be used in non-paint field：
Soybean protein resin 10-30%；
Emulsify rosin resin 20-30%.
The present embodiment coating specifically includes the component of following percetage by weight：Soybean protein resin 10%, emulsifies rosin tree
Fat 30%, pigmentary titanium dioxide 20%, filler diatomite：30%, water 20%, paraffin, the quality of the paraffin is soybean protein resin,
Emulsify the 10% of rosin resin, pigment, filler and water gross mass.Preparation method be the same as Example 1.
Embodiment 3
The soybean protein resin is that soybean protein is gelatinized into more than 0.5h, matter of the soybean protein in water at 100 DEG C in water
It is 60% to measure fraction, forms soybean protein resin.
The emulsification rosin resin is made by following steps, a, the composition for weighing following parts by weight, 150 parts of rosin,
150 parts of water, 20 parts of sodium acid carbonate；Paraffin is weighed, the quality of paraffin is the 5% of rosin, water and sodium acid carbonate gross mass；
B. 1-2h is heated after the rosin, water, sodium acid carbonate and the paraffin mixing that step a are weighed at 70 DEG C；
C. regulating step b obtains the pH value of solution to 8；
D. the solution that step c is obtained is incubated 2-3h at 100 DEG C, has obtained emulsification rosin resin.
After above-mentioned soybean protein resin and emulsification rosin resin are mixed, the binding agent of coating of the present invention is obtained.
The present embodiment specifically includes the component of following percetage by weight：Soybean protein resin 30%, emulsifies rosin resin
20%, pigment nano titanium oxide 30%, filler calcite：40%, water 50% and paraffin, the quality of the paraffin is soybean protein tree
Fat, emulsify rosin resin, pigment, filler and water gross mass 2%..Preparation method be the same as Example 1.
Comparative example 1
Soybean protein Resin adhesive：Soybean protein is gelatinized more than 0.5h at 70-100 DEG C, soybean protein resin is formed.
Comparative example 2
Emulsify rosin resin adhesive：
The emulsification rosin resin is made by following steps,
A, the composition for weighing following parts by weight, 100 parts of rosin, 80 parts of water, 15 parts of sodium acid carbonate；Weigh paraffin, the matter of paraffin
Amount is the 4% of rosin, water and sodium acid carbonate gross mass；
B. 1.5h is heated after the rosin, water, sodium acid carbonate and the paraffin mixing that step a are weighed at 100 DEG C；
C. regulating step b obtains the pH value of solution to 8；
D. the solution that step c is obtained is incubated 2.5h at 100 DEG C.
Above example 1-3 and comparative example 1-2 are tested, test result is as follows.
In binding agent and comparative example 1-2 that embodiment 1-3 soybean proteins resin and emulsification rosin resin are composited
Adhesive carries out following test respectively：（1）Take 10g glues, plus 90g distilled water to be well mixed, counted and determined with PH.（2）Viscosity is surveyed
Method for testing：Take 400g glues to be positioned in 500mL glass beakers, determine viscosity with NDJ viscosimeters at room temperature.（3）Bonding strength
Method of testing：The Eucalyptus veneer one side brushing adhesive for being 6%-12% in 1.6mm thickness and moisture content, glue-spread is 130g/m2（With
Liquid glue quality meter）；Gluing Eucalyptus veneer is constituted into 7 laminate embryos, in room temperature precompressed 30min under 1MPa pressure, then 120
DEG C and 1MPa under hot pressing 14min, unload be depressed into 0.3MPa be incubated 5 minutes, that is, obtain 7 layers of glued board；Glued board is according to GB/T
98465-2004 methods test the dry state bonding strength of sandwich layer（Standard value >=0.7）.（4）Storage period assay method：Take 250g glue
Liquid is positioned in sealed plastic bag, and metamorphic epoch is observed at room temperature.Test structure is as shown in table 1.
The test result of binding agent in the embodiment 1-3 of table 1 and comparative example 1-2
From experimental data, the binding agent viscosity in coating of the present invention is high, and bonding strength is high, and pH value meets the requirements, pure
Naturally, period of storage is long in the case of without chemical anti mildew agent.
Under normal circumstances, soybean protein and rosin can not be merged, the invention will using suitable method difference
The two is modified, then the two is merged with suitable method, more powerful viscosity and stability is produced, improves
Soybean protein and the respective defect of rosin, such as the modified toughness for substantially increasing binding agent.
Obtained coating in embodiment 1-3 is subjected to following test, as a result as shown in table 2.
The test result of coating in the embodiment 1-3 of table 2
As can be seen that raw material of the present invention is pure natural from experimental data, so without the release of any harmful substance, antiwear property
By force, contamination rate is high.
Embodiment 1 is detected according to standard GB/T/TB 756-1955, shown in test result table 3.
Table 3 is according to standard GB/T/TB 756-1955 test performances
To sum up, the present invention is compound as adhesive using soybean protein gelatinization resin and emulsification rosin is extracted, and composition is natural, viscosity
Greatly, bonding strength is strong.Coating of the present invention is without any chemical synthesis resin, chemical assistant, chemical solvent, bactericide, mould proof
The harmful substances such as agent, have accomplished the product of real net taste environmental protection, and indices meet the requirement of application, are adapted to marketing,
The living environment and air quality of user can be greatly promoted.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or using the present invention.
A variety of modifications to these embodiments will be apparent for those skilled in the art, as defined herein
General Principle can in other embodiments be realized in the case where not departing from the spirit or scope of patent of the present invention.Therefore, originally
Invention is not intended to be limited to the embodiments shown herein, and is to fit to and principles disclosed herein and features of novelty
Consistent most wide scope.
Claims (10)
1. a kind of pure plant albumen interior wall coating, it is characterised in that：Binding agent in coating uses soybean protein resin and emulsification
Rosin resin is composited.
2. a kind of pure plant albumen interior wall coating according to claim 1, it is characterised in that：The soybean protein resin is
Soybean protein is gelatinized more than 0.5h in 70-100 DEG C of water, mass fraction of the soybean protein in water is 25%-60%.
3. a kind of pure plant albumen interior wall coating according to claim 1, it is characterised in that：The emulsification rosin resin leads to
Following steps are crossed to be made,
A, the composition for weighing following parts by weight, 50-150 parts of rosin, 50-150 parts of water, 10-20 parts of sodium acid carbonate；Weigh stone
Wax, the quality of paraffin is the 2-5% of rosin, water and sodium acid carbonate gross mass；
B. 1-2h is heated after the rosin, water, sodium acid carbonate and the paraffin mixing that step a are weighed at 70-120 DEG C；
C. regulating step b obtains the pH value of solution to 8；
D. the solution that step c is obtained is incubated 2-3h at 100 DEG C.
4. according to a kind of any described pure plant albumen interior wall coatings of claim 1-3, it is characterised in that：Including following quality
The component of percentage,
Soybean protein resin 10-30%；
Emulsify rosin resin 20-30%；
Pigment： 10-30%；
Filler： 30-50%；
Water： 20-50%.
5. a kind of pure plant albumen interior wall coating according to claim 4, it is characterised in that：Also include paraffin, the stone
The quality of wax is the 2-10% of soybean protein resin, emulsification rosin resin, pigment, filler and water gross mass.
6. a kind of pure plant albumen interior wall coating according to claim 5, it is characterised in that：
Preparation method comprises the following steps,
A. pH value is adjusted after being well mixed soybean protein resin, emulsification rosin resin and water to more than 8；
B. the obtained solution of step a is stirred, obtains adhesive；
C. by pigment and filling material grinding to 10-20 microns, then add in the solution that step b is obtained, be well mixed.
7. a kind of pure plant albumen interior wall coating according to claim 6, it is characterised in that：Also include step d, step d
To be vacuum-packed after ultraviolet disinfection.
8. a kind of pure plant albumen interior wall coating according to claim 4, it is characterised in that：The pigment includes titanium dioxide
Titanium.
9. a kind of pure plant albumen interior wall coating according to claim 4, it is characterised in that：The titanium dioxide is nanometer
Titanium dioxide.
10. a kind of pure plant albumen interior wall coating according to claim 4, it is characterised in that：Filler include calcite or
Diatomite.
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| CN201710695433.7A CN107267063B (en) | 2017-08-15 | 2017-08-15 | A kind of pure plant albumen interior wall coating |
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| CN201710695433.7A CN107267063B (en) | 2017-08-15 | 2017-08-15 | A kind of pure plant albumen interior wall coating |
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| CN107267063B CN107267063B (en) | 2018-04-24 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115151616A (en) * | 2019-12-30 | 2022-10-04 | 太阳化学公司 | High biorenewable content printing inks |
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| CN1446870A (en) * | 2002-03-27 | 2003-10-08 | 馨乐丽康野田株式会社 | Natural paint and its producing process |
| CN103525300A (en) * | 2013-09-27 | 2014-01-22 | 吴润秀 | Emulsified environment-friendly coating |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115151616A (en) * | 2019-12-30 | 2022-10-04 | 太阳化学公司 | High biorenewable content printing inks |
| JP2022552442A (en) * | 2019-12-30 | 2022-12-15 | サン ケミカル コーポレイション | High bio-renewable content printing inks |
| CN115151616B (en) * | 2019-12-30 | 2023-10-31 | 太阳化学公司 | Printing ink with high biorenewable content |
| US11820902B2 (en) | 2019-12-30 | 2023-11-21 | Sun Chemical Corporation | High bio-renewable content printing inks |
| JP7393554B2 (en) | 2019-12-30 | 2023-12-06 | サン ケミカル コーポレイション | High biorenewable content printing ink |
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| CN107267063B (en) | 2018-04-24 |
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Address after: 050000 East Village, Zhengding County, Shijiazhuang, Hebei Patentee after: Hebei platinum run industry and Trade Technology Co., Ltd Address before: 050000 East Village, Zhengding County, Shijiazhuang, Hebei Patentee before: HEBEI BO RUN CHEMICAL TECHNOLOGY Co.,Ltd. |