CN107266092A - A kind of magnesium colloidal sol complex abrasion-proof castable and preparation method thereof - Google Patents
A kind of magnesium colloidal sol complex abrasion-proof castable and preparation method thereof Download PDFInfo
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- CN107266092A CN107266092A CN201710528197.XA CN201710528197A CN107266092A CN 107266092 A CN107266092 A CN 107266092A CN 201710528197 A CN201710528197 A CN 201710528197A CN 107266092 A CN107266092 A CN 107266092A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/66—Monolithic refractories or refractory mortars, including those whether or not containing clay
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
- C04B2235/3222—Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5212—Organic
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Abstract
The invention discloses a kind of magnesium colloidal sol complex abrasion-proof castable and preparation method thereof, the castable component is included by mass parts：15 30 50 parts of 0mmA90 spinelles, 10 15 25 parts of 5mmA95 spinel particles, 5 10 parts of the 0.088mm of particle diameter 0.076 composite inorganic powder, 58 parts of the 100um of particle diameter 2 zirconium gel powder, particle diameter is less than 1 μm of 38 parts of silicon powder, and particle diameter is less than 1.2 μm of Al2O335 parts of micro mist, 13 parts of 625 cement of silicate, 38 parts of magnesium colloidal sol, 0.12 part of sodium pyrophosphate, 0.15 part of defoamer, 0.3 part of explosion-proof fiber, 0.2 part of aluminium carbonate；Complex abrasion-proof castable of the present invention has uniform texture, intensity height, high temperature resistant, good thermal shock, easy working feature.
Description
Technical field
The present invention relates to technical field of refractory materials, more particularly to a kind of magnesium colloidal sol complex abrasion-proof castable and its preparation side
Method.
Background technology
The furnace construction such as limekiln, cement rotary kiln position has alkaline atmosphere composition weight, and clinker and heat smoke wash away work
With strong, circumstance of temperature difference is big, and the special operation condition condition such as refractoriness height is higher to the index request of capabilities of refractory materials, conventional production
Product typically use the corundum porzite flame-proof castable that cement is combined, and the problem of it is present has：The thermal expansion system of corundum
Number is than larger, and thermal shock resistance is bad, and corundum is changed into β phase corundum in cement kiln alkaline atmosphere by α phase corundum, causes volume swollen
It is swollen, structure destruction is easily caused, intolerant to alkaline attack so that the life-span of coal injection pipe shortens dramatically, the need for can not meeting market.
At present, new type nonaqueous cement production line scale expands day by day, and in order to improve the running rate of whole firing system, strengthens the city of enterprise
Field competitiveness, New Type Dry-process Cement Production enterprise is applied to wherein in the urgent need to high-quality castable refractory.
The traditional construction mode of castable is constructed for vibration, there are some shortcomings, for example, vibrator undervibration causes to pour
Not enough, overvibration particle easily produces segregation to injection body density, and easily leaves cavity during vibrating head insertion extraction, in addition vibrator
There is noise pollution, influence construction environment.
The content of the invention
The present invention will provide a kind of magnesium colloidal sol complex abrasion-proof castable, and the magnesium colloidal sol complex abrasion-proof castable can improve group
Structure crystal phase structure uniformity is knitted, optimizes body of material explosion-proof performance, and then a kind of corrosion resistance of acquisition is good, alkali resistant splits, resisted
Thermal shock resistance is good, wear-resistant, changes traditional construction mode, is prepared using from stream mode, a kind of castable of easy construction.
The concrete technical scheme that the present invention is used is as follows：
A kind of magnesium colloidal sol complex abrasion-proof castable, including following components raw material and parts by weight：30-50 parts of 15-0mmA90 spinelles,
15-25 parts of 10-5mmA95 spinel particles, 5-10 parts of particle diameter 0.076-0.088mm composite inorganic powder, particle diameter 2-100um's
5-8 parts of zirconium gel powder, particle diameter is less than 1 μm of 3-8 parts of silicon powder, and particle diameter is less than 1.2 μm of Al2O33-5 parts of micro mist, silicate
625 1-3 parts of cement, 3-8 parts of magnesium colloidal sol, 0.12 part of sodium pyrophosphate, 0.15 part of defoamer, 0.3 part of explosion-proof fiber, aluminium carbonate
0.2 part.
It is preferred that, the A90 spinelles include 15-8mm, 3-8mm and 0-3mm particle.
It is preferred that, the composite inorganic powder is that mass ratio is 1:2：1：1 andalusite, kyanite, sillimanite and modification is not
Carry out the combination of stone flour.
It is preferred that, the defoamer agent is the PA-311 and TCB-1 of crop field chemical production.
It is preferred that, the heat-resistant steel fiber main component is Fe, Ni and Cr, in addition to micro Nb, Mn and C, Yi Jiji
Micro Si, P and S；Specifically component ratio is：Ni-40wt%, Cr-16wt%, Nb-10wt%, Mn-5wt%, C-0.5wt%, Si-
Below 0.1wt%, below P-0.1wt%, below S-0.1wt%, surplus are Fe.
It is preferred that, the explosion-proof fiber is 3 μm of diameter, and length 7mm, fusing point is less than 90 degree of polymer fiber.
Preferential, the fineness of the aluminium carbonate is 180 mesh.
It is a further object to provide a kind of preparation method of magnesium colloidal sol complex abrasion-proof castable.
A kind of preparation method of magnesium colloidal sol complex abrasion-proof castable, comprises the following steps：A. by above-mentioned raw materials（Magnesium colloidal sol is removed
Outside）Pour into agitating device, mixing is stirred at room temperature；B. the magnesium colloidal sol for adding 3-8% stirs；C. the material injection being stirred
Mould, band mould is dried after conserving 48h, demoulding maintenance 36-48h；D. 300 insulation 6h are warming up to 5 DEG C/min, with 10 DEG C/min
It is warming up to 1300 DEG C of insulation 4h, you can obtain product.
Beneficial effects of the present invention are as follows：
The present invention, as aggregate, utilizes the hardness height of spinelle, the characteristics of wearability is good, to improve castable using spinelle
Anti-wear performance and erosion-resisting characteristics；Composite inorganic powder is andalusite, kyanite, sillimanite and modified mullite powder group in castable
Close, andalusite, sillimanite are irreversibly converted into mullite and SiO at high temperature2, SiO2It is substantially inside mullite crystal,
The SiO being softened at high operating temperatures in mullite crystal2Volume Changes caused by temperature change can be absorbed, while aquamaine
The mullite conversion temperature of stone is low compared with andalusite, can form the mullitization reaction of gradient distribution, can be avoided to obtain same
The expansion of sample, all avoids concentrating the caused crackle of expansion using andalusite；Modified mullite used at the same time belongs to a kind of sub-
Kaolin, can absorb the alkaline matter in kiln atmosphere during use, also can continue mullitization with kiln temperature change,
Playing optimization matrix of materials improves material property effect, and three can realize perfect combination to avoid a kind of product not
Foot.By defoamer PA-311 and TCB-1 compound addition, bubble can be preferably eliminated, gas is more easy to discharge, improves stomata
Distribution, it is to avoid inequality, which is homogenized, inside castable avoids material segregation, and 0.15 part of usage amount is proper, more than 0.15 part
Material property is influenceed, less than 0.15 part bubble can not be excluded fully.Zirconium gel powder is added, silicon powder, magnesium colloidal sol, aluminum oxide is micro-
Powder, the cement of silicate 625 can form magnesia spinel forsterite zirconium silicate composite construction so that the principal crystalline phase of matrix is many
Item composite construction, it is engaged to each other, structural homogenity between castable crystalline phase is improved, and then improve the entirety of castable
Performance；Invention also uses aluminium carbonate, explosion-proof fiber is compound to prevent the explosion of castable, and explosion-proof fiber is soft in fire process
Change, shrink, fusing, eventually form stomata and be carbonized, aluminium carbonate can after being cast with water generated reactive gas, in material internal shape
Into small network stomata, aqueous vapor passage is formed, lightening material internal stress improves thermal shock resistance, extends the use longevity of castable
Life, the product after decomposition is active aluminium hydroxide again, can be with component formation high-temperature-phase material in system.
In addition, the present invention changes traditional construction mode, can be automatic stream using vibrator vibration from stream mode, is not required to
Move, shakeout, closely knit and solidification, it is to avoid the problems such as the castable segregation that vibration construction may be brought, while the compound froth breaking of addition
Agent makes castable possess good froth breaking exclusion gas function.The present invention carries out inside to castable using heat-resistant steel fiber and added
Gu, heat-resistant steel fiber rough surface can combine closely with the powder after wetting and play certain supporting role, contribute to castable
It is quickly moulding.With traditional castable ratio, magnesium colloidal sol complex abrasion-proof castable high volume stability is good, alkali resistant corrodes, antiknock
Split, service life is long.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of magnesium colloidal sol complex abrasion-proof castable, including following components raw material and parts by weight：50 parts of 15-0mmA90 spinelles, 10-
15 parts of 5mmA95 spinel particles, 10 parts of particle diameter 0.076-0.088mm composite inorganic powder, particle diameter 2-100um zirconium gel powder
5 parts, particle diameter is less than 1 μm of 5 parts of silicon powder, and particle diameter is less than 1.2 μm of Al2O35 parts of micro mist, 1 part of 625 cement of silicate, magnesium colloidal sol
4 parts, 0.12 part of sodium pyrophosphate, 0.15 part of defoamer, 0.3 part of explosion-proof fiber, 0.2 part of aluminium carbonate.
Castable is prepared as follows：A. by above-mentioned raw materials（Except magnesium colloidal sol）Pour into agitating device, be stirred at room temperature
Mixing；B. the magnesium colloidal sol for adding 4 parts stirs；C. the material injection mould being stirred, band mould conserves 48h, demoulding maintenance
Dried after 36-48h；D. 300 insulation 6h are warming up to 5 DEG C/min, 1300 DEG C of insulation 4h are warming up to 10 DEG C/min, you can obtain
Product.
Embodiment 2
A kind of magnesium colloidal sol complex abrasion-proof castable, including following components raw material and parts by weight：45 parts of 15-0mmA90 spinelles, 10-
20 parts of 5mmA95 spinel particles, 10 parts of particle diameter 0.076-0.088mm composite inorganic powder, particle diameter 2-100um zirconium gel powder
5 parts, particle diameter is less than 1 μm of 5 parts of silicon powder, and particle diameter is less than 1.2 μm of Al2O35 parts of micro mist, 2 parts of 625 cement of silicate, magnesium colloidal sol
5 parts, 0.12 part of sodium pyrophosphate, 0.15 part of defoamer, 0.3 part of explosion-proof fiber, 0.2 part of aluminium carbonate.
Castable is prepared as follows：A. by above-mentioned raw materials（Except magnesium colloidal sol）Pour into agitating device, be stirred at room temperature
Mixing；B. the magnesium colloidal sol for adding 4% stirs；C. the material injection mould being stirred, band mould conserves 48h, demoulding maintenance
Dried after 36-48h；D. 300 insulation 6h are warming up to 5 DEG C/min, 1300 DEG C of insulation 4h are warming up to 10 DEG C/min, you can obtain
Product.
Embodiment 3
A kind of magnesium colloidal sol complex abrasion-proof castable, including following components raw material and parts by weight：48 parts of 15-0mmA90 spinelles, 10-
18 parts of 5mmA95 spinel particles, 8 parts of particle diameter 0.076-0.088mm composite inorganic powder, particle diameter 2-100um zirconium gel powder 5
Part, particle diameter is less than 1 μm of 4 parts of silicon powder, and particle diameter is less than 1.2 μm of Al2O35 parts of micro mist, 1 part of 625 cement of silicate, magnesium colloidal sol 4
Part, 0.12 part of sodium pyrophosphate, 0.15 part of defoamer, 0.3 part of explosion-proof fiber, 0.2 part of aluminium carbonate.
Castable is prepared as follows：A. by above-mentioned raw materials（Except magnesium colloidal sol）Pour into agitating device, be stirred at room temperature
Mixing；B. the magnesium colloidal sol for adding 5 parts stirs；C. the material injection mould being stirred, band mould conserves 48h, demoulding maintenance
Dried after 36-48h；D. 300 insulation 6h are warming up to 5 DEG C/min, 1300 DEG C of insulation 4h are warming up to 10 DEG C/min, you can obtain
Product.
Embodiment 4
A kind of magnesium colloidal sol complex abrasion-proof castable, including following components raw material and parts by weight：50 parts of 15-0mmA90 spinelles, 10-
15 parts of 5mmA95 spinel particles, 10 parts of particle diameter 0.076-0.088mm composite inorganic powder, particle diameter 2-100um zirconium gel powder
5 parts, particle diameter is less than 1 μm of 5 parts of silicon powder, and particle diameter is less than 1.2 μm of Al2O35 parts of micro mist, 3 parts of 625 cement of silicate, magnesium colloidal sol
7 parts, 0.12 part of sodium pyrophosphate, 0.15 part of defoamer, 0.3 part of explosion-proof fiber, 0.2 part of aluminium carbonate.
Castable is prepared as follows：A. by above-mentioned raw materials（Except magnesium colloidal sol）Pour into agitating device, be stirred at room temperature
Mixing；B. the magnesium colloidal sol for adding 6 parts stirs；C. the material injection mould being stirred, band mould conserves 48h, demoulding maintenance
Dried after 36-48h；D. 300 insulation 6h are warming up to 5 DEG C/min, 1300 DEG C of insulation 4h are warming up to 10 DEG C/min, you can obtain
Product.
Castable technical performance index obtained by above-described embodiment is as follows：
The preferred embodiments of the present invention are the foregoing is only, are not limitation of the present invention, those skilled in the art are according to this
The made equivalent transformation of invention and modification, belong to protection scope of the present invention.
Claims (6)
1. a kind of magnesium colloidal sol complex abrasion-proof castable, including following components raw material and parts by weight：15-0mmA90 spinelles 30-50
Part, 15-25 parts of 10-5mmA95 spinel particles, 5-10 parts of particle diameter 0.076-0.088mm composite inorganic powder, particle diameter 2-100um
5-8 parts of zirconium gel powder, particle diameter is less than 1 μm of 3-8 part of silicon powder, Al of the particle diameter less than 1.2 μm2O33-5 parts of micro mist, silicate
625 1-3 parts of cement, 3-8 parts of magnesium colloidal sol, 0.12 part of sodium pyrophosphate, 0.15 part of defoamer, 0.3 part of explosion-proof fiber, aluminium carbonate
0.2 part.
2. magnesium colloidal sol complex abrasion-proof castable according to claim 1, it is characterised in that：The spinelle includes 15-
8mm, 3-8mm and 0-3mm particle.
3. magnesium colloidal sol complex abrasion-proof castable according to claim 1, it is characterised in that：The composite inorganic powder is quality
Than for 1:2：1：1 andalusite, kyanite, sillimanite and the combination for being modified mullite powder.
4. magnesium colloidal sol complex abrasion-proof castable according to claim 1, it is characterised in that：The defoamer agent is crop field
The PA-311 and TCB-1 of student's production.
5. magnesium colloidal sol complex abrasion-proof castable according to claim 1, it is characterised in that：The fineness of the aluminium carbonate is
180 mesh.
6. a kind of preparation method of magnesium colloidal sol complex abrasion-proof castable, it is characterised in that：Comprise the following steps：
A. by above-mentioned raw materials（Except magnesium colloidal sol）Pour into agitating device, mixing is stirred at room temperature；
B. the magnesium colloidal sol for adding 3-8 parts stirs；C. the material injection mould being stirred, band mould conserves 48h, demoulding maintenance
Dried after 36-48h；D. 300 insulation 6h are warming up to 5 DEG C/min, 1300 DEG C of insulation 4h are warming up to 10 DEG C/min, you can obtain
Product.
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| CN201710528197.XA CN107266092A (en) | 2017-07-01 | 2017-07-01 | A kind of magnesium colloidal sol complex abrasion-proof castable and preparation method thereof |
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| CN107266092A true CN107266092A (en) | 2017-10-20 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114213113A (en) * | 2021-12-30 | 2022-03-22 | 河南陇耐耐火材料有限公司 | Steel ladle hot-patching material, preparation method thereof and steel ladle hot-patching method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104973877A (en) * | 2015-07-16 | 2015-10-14 | 陈巨根 | Castable with favorable sintering properties |
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2017
- 2017-07-01 CN CN201710528197.XA patent/CN107266092A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104973877A (en) * | 2015-07-16 | 2015-10-14 | 陈巨根 | Castable with favorable sintering properties |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114213113A (en) * | 2021-12-30 | 2022-03-22 | 河南陇耐耐火材料有限公司 | Steel ladle hot-patching material, preparation method thereof and steel ladle hot-patching method |
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