CN107265638A - Integral type high ammonia-nitrogen wastewater biological removal reaction unit - Google Patents

Integral type high ammonia-nitrogen wastewater biological removal reaction unit Download PDF

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Publication number
CN107265638A
CN107265638A CN201710526533.7A CN201710526533A CN107265638A CN 107265638 A CN107265638 A CN 107265638A CN 201710526533 A CN201710526533 A CN 201710526533A CN 107265638 A CN107265638 A CN 107265638A
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China
Prior art keywords
high ammonia
integral type
body region
type high
nitrogen wastewater
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CN201710526533.7A
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Chinese (zh)
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CN107265638B (en
Inventor
王怡
黄瑞雪
郭羽
韦存智
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Xian University of Architecture and Technology
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Xian University of Architecture and Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/301Aerobic and anaerobic treatment in the same reactor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/163Nitrates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/15N03-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)

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  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

The invention discloses a kind of integral type high ammonia-nitrogen wastewater biological removal reaction filter post, using the up flow type method of operation, intake by bottom, top gravity water outlet, filter post uses larger ratio of height to diameter structure, inside fills out proportion close to the porous large scale filler of water, filter column bottom sets Multifunctional taper area, micropore adjustable aeration apparatus, water inlet and mud discharging mouth are laid, is maintained with cultivating based on short distance nitration activated sludge, biomembrane and unnecessary excess sludge is discharged while receiving filtrate area and coming off.Present apparatus perfect technology, floor space is small, and operation operation is simple, flexible, cost is low, good to ammonia nitrogen removal effect stability in waste water, it is a kind of biological treatment on energy-efficient province ground, effective removal available for percolate, sludge water and other high ammonia-nitrogen wastewaters.

Description

Integral type high ammonia-nitrogen wastewater biological removal reaction unit
Technical field
The invention belongs to environmental protection development technique field, it is related to a kind of new high ammonia-nitrogen sewage treatment system, specifically It is related to a kind of integral type high ammonia-nitrogen wastewater biological removal reaction unit.
Background technology
High ammonia-nitrogen wastewater be mainly derived from the industry productions such as petrochemical industry, cultivation, herding, meat packing discharge waste water with And city domestic refuse percolation liquid etc..Harm of the ammonia nitrogen to environment, which mainly enters, turns into the biological nutrition member such as algae after water body Element, causes the dissolved oxygen in amount reproduction in the algae short time, consumption water, causes body eutrophication, destroy aquatic ecosystem. Ammonia nitrogen in water body can change into nitrite under certain condition, organism in water and human health be seriously endangered, to city Ecological Civilization Construction brings puzzlement.High ammonia nitrogen is always the problem of wastewater treatment, and the processing method to this kind of waste water is main at present There are Physical (as added alkali blow-off method, steam blow-off method and absorption method), chemical method (such as chemical precipitation method, chemical oxidization method, electrolysis Method and ion-exchange) and bioanalysis etc..
Blow-off method is adapted to the primary treatment of high ammonia-nitrogen wastewater, and this method is ripe simple, but operating cost is high, equipment corrosion is tight Weight, and easily cause air secondary pollution.Rule is adsorbed using the modified natural zeolite selection adsorption capacity stronger to ammonia nitrogen, is had The characteristics of efficiency high, small equipment volume, but regeneration is frequent, operational administrative is complicated.Chemical oxidization method, chemical precipitation in chemical method Method, electrolysis and ion-exchange, though technological process and equipment are simple, react quick, processing cost is high or power consumption is larger. When bioanalysis removes the ammonia nitrogen in waste water, single aerobe method and it is single detest (scarce) oxygen bioanalysis can not be straight by ammonia nitrogen Switch through and turn to nitrogen, and conventional method typically uses the anaerobic bio-treated or anoxic treatment on the basis of Aerobic biological process, Can be nitrogen by mineralized nitrogen, therefore, conventional method has that structures are more, equipment investment is big, aerobic condition is whard to control and energy The problem of consuming big.Therefore, a kind of efficient new high ammonia-nitrogen wastewater processing equipment is sought necessary.
The content of the invention
For the defect and deficiency of existing technology of preparing, it is an object of the invention to provide a kind of life of integral type high ammonia-nitrogen wastewater Thing removes reaction unit, in the biologic filter of integral type larger ratio of height to diameter by activated sludge process and biomembrance process, aerobic-anoxic with Anaerobic environment is combined, and effective removal to high ammonia-nitrogen wastewater is realized under the conditions of low energy consumption, small footprint size, reduction ammonia nitrogen is to water ring The influence in border.
To achieve these goals, the present invention, which is adopted the following technical scheme that, is achieved:
Integral type high ammonia-nitrogen wastewater biological removal reaction unit, including filter post, filtrate, aeration unit and heating unit;
Described filter post includes body region and pyramidal area, and dividing plate is provided between described body region and pyramidal area, described Dividing plate is provided with hole;
Described filtrate is filled in body region;Described body region end is provided with delivery port and exhaust outlet;
Described aeration unit is located at pyramidal area, and described pyramidal area is provided with water inlet and mud discharging mouth;
Described heating unit provides energy to filter the body region of post;
The diameter ratio of body region of the height of described filter post with filtering post is 10~13:1.
Further, described pyramidal area volume is less than the 8% of whole filter column volume.
Further, the shaft of described body region is provided with multiple filler thief hatch and water quality sampling mouthful.
Further, described aeration unit includes aeration pump, flowmeter and aeration head, and described aeration head is located at cone Qu Zhong.
Further, described heating unit is heater strip, on the shaft for being wrapped in filter post body region.
Further, described filtrate is the porous large scale filler of organic or inorganic of proportion close to water.
Further, a diameter of 8mm~12mm of described filler.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) present invention in the biologic filter of integral type larger ratio of height to diameter by activated sludge process and biomembrance process, aerobic-anoxic It is combined with anaerobic environment, effective removal to high ammonia-nitrogen wastewater is realized under the conditions of low energy consumption, small footprint size, reduces ammonia nitrogen Influence to water environment.
(2) apparatus of the present invention can reach the low energy consumption removal purpose of high ammonia-nitrogen wastewater, and can save more than 90% Floor space and more than 70% equipment investment, TN clearance averagely reach more than 80%.Operation is convenient, simple to operate, It can disperse independently installed in each high-concentration ammonia nitrogenous wastewater generation point, receive water body nitrogen load to cut down, ensure and receive water body Water quality, prevents and treats body eutrophication.
Brief description of the drawings
Fig. 1 is apparatus of the present invention structural representation.
The implication of each label in accompanying drawing:5- dividing plates, 6- water inlets, 7- mud discharging mouths, 8- delivery ports, 9- exhaust outlets, 10- is filled out Expect thief hatch, 11- water quality samplings mouthful;
(1-1)-body region, (1-2)-pyramidal area;(3-1)-aeration pump, (3-2)-flowmeter, (3-3)-aeration head;(4- 1)-heater strip.
Explanation is further explained in detail to the particular content of the present invention with reference to embodiments.
Embodiment
Integral type high ammonia-nitrogen wastewater biological removal reaction unit includes filter post, filtrate, aeration unit and heating unit, filters post Including body region 1-1 and pyramidal area 1-2, dividing plate 5 is provided between body region 1-1 and pyramidal area 1-2, dividing plate 5 is provided with hole;Aeration Unit is located at pyramidal area, and heating unit provides temperature to filter the body region 1-1 of post;Filtrate is filled in the 1-1 of body region;Pyramidal area 1-2 is provided with water inlet 6 and mud discharging mouth 7, and body region 1-1 ends are provided with delivery port 8 and exhaust outlet 9.
Whole filter post forms activated sludge area and biomembrane area from pyramidal area to body region respectively, and (microorganism is attached to filler Upper formation biomembrane);Further, the transition of aerobic section, micro- oxygen to anoxic is sequentially formed from activated sludge area and biomembrane area Section, anaerobism section, wherein, the naturally occurring of changeover portion enriches the flora type of reactor, enhances the shock resistance energy of reactor Power.
The pyramidal area of the present invention not only has water inlet pooling feature, and whole pyramidal area formation activated sludge area, culture Maintain aerobic activated sludge to carry out part aerobic ammonia oxidation, additionally receive the biomembrane progress excess sludge row that body region comes off Go out.
The present invention is combined aerobic part ammoxidation process, denitrification with anaerobic ammonium oxidation process the big Gao Jing in integral type In the biologic filter of ratio, aerobic section is located at the bottom of whole filter post, without backflow.Utilize the micro- aeration in biologic filter bottom pyramidal area The characteristics of, realize that sludge area, with contacting, completes high ammonia nitrogen in waste water with the oxygen environment functional areasization in Lv Zhu areas and Lv Zhu areas To the conversion of nitrogen.
By activated sludge process and biomembrance process, aerobic-anoxic and anaerobic environment in the biologic filter of the larger ratio of height to diameter of the present invention It is combined, filters the height of post and the diameter ratio of the body region of filter post up to 10~13:1;Further, filtrate of the invention is adopted With the porous large scale filler of large-sized organic or inorganic, the proportion of filler is close to water, a diameter of 8mm~12mm of filler, Under the filler of the size, water being not easily blocked in uphill process, resistance in filter post is smaller, ordinary water pump can make waste water from The pyramidal area of filter post is promoted to body region discharge.Large-sized filler can prevent filler to be lost in water outlet simultaneously.
The present invention lays aeration unit in pyramidal area, on the one hand can ensure input of the air by micro- aeration, actively realize The part aerobic oxidation of ammonia nitrogen.On the other hand, 80% intrinsic nitrogen exists in dioxygen oxidation is produced in air gas and air Filter the rising effusion in post, under the conditions of filter post is not required to backwash, the blocking of filler can be prevented, be also beneficial to promote pyramidal area with The mutual migration of body region microorganism, that is, filter biomembrane in post come off sinking and pyramidal area suspension microorganism is moved up, it is to avoid System crash caused by different zones microorganism is lost in.
Specific embodiment of the invention given below is, it is necessary to which explanation is that the invention is not limited in implement in detail below Example, all equivalents done on the basis of technical scheme each fall within protection scope of the present invention.
Embodiment 1
As shown in figure 1, the present embodiment provides a kind of integral type high ammonia-nitrogen wastewater biological removal reaction unit, its feature exists In:Including filter post, filtrate, aeration unit and heating unit, filter post includes body region 1-1 and pyramidal area 1-2, body region 1-1 and Dividing plate 5 is provided between pyramidal area 1-2, dividing plate 5 is provided with hole;Aeration unit is located at pyramidal area, and heating unit is the main body of filter post Area 1-1 provides temperature;Filtrate is filled in the 1-1 of body region;Pyramidal area 1-2 is provided with water inlet 6 and mud discharging mouth 7, body region 1-1 End is provided with delivery port 8 and exhaust outlet 9
The ratio of height to diameter for filtering post is 10~13:1, pyramidal area 1-2 volume are less than the 8% of whole filter column volume.Aeration unit bag Aeration pump 3-1, flowmeter 3-2 and aeration head 3-3 are included, aeration head 3-3 is located in pyramidal area 1-2.
Heating unit is heater strip 4-1, on the shaft for being wrapped in filter post body region, and temperature keeps 30 when safeguards system is run ± 2 DEG C, to monitor the evolution with distance of water quality, lean to one side to set water quality sampling mouthful 11 along cylinder;For the edge of microorganism on monitoring filler Cheng Bianhua, leans to one side to set filler thief hatch 10 along cylinder;The excess sludge that system is produced is discharged by discharge pipeline 4.
The course of reaction of high ammonia-nitrogen wastewater:High ammonia-nitrogen wastewater initially enters pyramidal area 1-2, is controlled by gas flowmeter 3-2 Aeration pump 3-1 limited aeration is carried out by aeration head 3-3, the waste water upward flow of limited aeration enters filter post body region 1-1, Filter in phosphor bodies area, body region 1-1 lower ends biofilm microorganisms continue to consume remnant oxygen progress part aerobic ammonia oxidation, work as filter Dissolved oxygen depletion totally and when there is organic matter carries out denitrification in post, then filters epimere in post and enters anaerobic zone, now waste water Middle remaining ammonia nitrogen and nitrite nitrogen occur Anammox and produce nitrogen.Ammonia nitrogen and total nitrogen are minimized to delivery port 8, the biochemistry The gas of nitrogen, the nitrogen of aeration input and oxidation generation that process is produced is discharged from exhaust outlet 9.
2016.8.01-2017.1.15 the long run test carried out, NH of intaking4 +- N is 600.0mg/L, hydraulic detention time (HRT) under the conditions of 24h, aeration quantity 40ml/min, 30 DEG C of temperature, reactor water outlet NH4 +- N is 42.0mg/L, NO3 -- N is 75.0mg/L、NO3 -- N is 2.0mg/L, NH4 +- N clearance reaches 93%, TN clearance averagely reaches 80%.
2017.1.15-2017.02.15 the long run test carried out, NH of intaking4 +- N is 400.0mg/L, hydraulic detention time (HRT) under the conditions of 16h, aeration quantity 40ml/min, 30 DEG C of temperature, reactor water outlet NH4 +- N is 24.0mg/L, NO3 -- N is 42.0mg/L、NO3 -- N is 6.0mg/L, NH4 +- N clearance reaches 94%, TN clearance averagely reaches 82%.
2017.2.15-2017.03.15 the long run test carried out, NH of intaking4 +- N is 800.0mg/L, hydraulic detention time (HRT) under the conditions of 32h, aeration quantity 40ml/min, temperature 30OC, reactor water outlet NH4 +- N is 80.0mg/L, NO3 -- N is 86.0mg/L、NO3 -- N is 8.0mg/L, NH4 +- N clearance reaches that 90%, TN clearance averagely reaches 78%.
According to above-mentioned experimental result, high ammonia nitrogen biological removal reaction filters post in ammonia nitrogen in waste water concentration in Integral waste water 400mg/L~800mg/L, influent ammonia nitrogen volumetric loading are 0.6~0.8kg/m3.d, can be to NH in the range of4 +- N is removed More than 90%, 80% or so is removed to TN.

Claims (7)

1. integral type high ammonia-nitrogen wastewater biological removal reaction unit, it is characterised in that:Including filtering post, filtrate, aeration unit and adding Hot cell;
Described filter post includes body region (1-1) and pyramidal area (1-2), between described body region (1-1) and pyramidal area (1-2) Provided with dividing plate (5), described dividing plate (5) is provided with hole;
Described filtrate is filled in body region (1-1);Described body region (1-1) end is provided with delivery port (8) and exhaust outlet (9);
Described aeration unit is located at pyramidal area, and described pyramidal area (1-2) is provided with water inlet (6) and mud discharging mouth (7);
Described heating unit provides heat for the body region (1-1) of filter post;
The diameter ratio of body region of the height of described filter post with filtering post is 10~13:1.
2. integral type high ammonia-nitrogen wastewater biological removal reaction unit as claimed in claim 1, it is characterised in that:Described cone Area (1-2) volume is less than the 8% of whole filter column volume.
3. integral type high ammonia-nitrogen wastewater biological removal reaction unit as claimed in claim 1, it is characterised in that:Described main body The shaft in area (1-1) is provided with multiple filler thief hatch (10) and water quality sampling mouthful (11).
4. integral type high ammonia-nitrogen wastewater biological removal reaction unit as claimed in claim 1, it is characterised in that:Described aeration Unit includes aeration pump (3-1), flowmeter (3-2) and aeration head (3-3), and described aeration head (3-3) is located at pyramidal area (1-2) In.
5. integral type high ammonia-nitrogen wastewater biological removal reaction unit as claimed in claim 1, it is characterised in that:Described heating Unit is heater strip (4-1), on the shaft for being wrapped in filter post body region.
6. integral type high ammonia-nitrogen wastewater biological removal reaction unit as claimed in claim 1, it is characterised in that:Described filtrate (2) it is the porous large scale filler of organic or inorganic of proportion close to water.
7. integral type high ammonia-nitrogen wastewater biological removal reaction unit as claimed in claim 6, it is characterised in that:Described filler A diameter of 8mm~12mm.
CN201710526533.7A 2017-06-30 2017-06-30 Integrated high ammonia-nitrogen wastewater biological removal reaction device Expired - Fee Related CN107265638B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111196626A (en) * 2020-01-14 2020-05-26 浙江大学 Embedded cage type anaerobic ammonia oxidation reactor and method thereof
CN111333181A (en) * 2020-03-23 2020-06-26 西安建筑科技大学 Rapid filtration type anaerobic ammonia oxidation reaction method for treating low-concentration nitrogen-containing wastewater

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204958514U (en) * 2015-09-14 2016-01-13 北京工业大学 Realize nitrifying device of high ammonia -nitrogen concentration waste water bological aerated filter short distance fast
CN205035225U (en) * 2015-09-16 2016-02-17 徐雪祥 High -concentration ammonia nitrogen organic waste water's processing system
CN105523635A (en) * 2016-01-28 2016-04-27 西安建筑科技大学 Integrated biological contact device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204958514U (en) * 2015-09-14 2016-01-13 北京工业大学 Realize nitrifying device of high ammonia -nitrogen concentration waste water bological aerated filter short distance fast
CN205035225U (en) * 2015-09-16 2016-02-17 徐雪祥 High -concentration ammonia nitrogen organic waste water's processing system
CN105523635A (en) * 2016-01-28 2016-04-27 西安建筑科技大学 Integrated biological contact device

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111196626A (en) * 2020-01-14 2020-05-26 浙江大学 Embedded cage type anaerobic ammonia oxidation reactor and method thereof
CN111333181A (en) * 2020-03-23 2020-06-26 西安建筑科技大学 Rapid filtration type anaerobic ammonia oxidation reaction method for treating low-concentration nitrogen-containing wastewater
CN111333181B (en) * 2020-03-23 2022-04-01 西安建筑科技大学 Rapid filtration type anaerobic ammonia oxidation reaction method for treating low-concentration nitrogen-containing wastewater

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