CN107265490A - A kind of method that barite purification is brightened - Google Patents
A kind of method that barite purification is brightened Download PDFInfo
- Publication number
- CN107265490A CN107265490A CN201710628917.XA CN201710628917A CN107265490A CN 107265490 A CN107265490 A CN 107265490A CN 201710628917 A CN201710628917 A CN 201710628917A CN 107265490 A CN107265490 A CN 107265490A
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- barite
- raw material
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- weight
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
- C01F11/462—Sulfates of Sr or Ba
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The invention provides the method that a kind of purification of barite is brightened, first by barite tcrude ore break process repeatedly within 100 mesh, then water and sulfuric acid, hydrochloric acid is progressively added again, fully reaction to the pH value of the aqueous solution is 1, then hydrofluoric acid is added, stirring reaction 8~12 hours finally removes waste liquid, fully clean raw material, it is more than 2 to pH, raw material is diluted to 50% concentration, take a policy powder, stirring makes it fully react in 2~4 hours, then cleaning raw material is more than 6 to pH, and last drying material obtains finished product;The present invention can effectively remove the various magazines in barite tcrude ore, and reducing bleach nonferrous metal oxides and organic matter, play a part of purification and brighten.
Description
Technical field
The present invention relates to the method that a kind of purification of ore is brightened, and in particular to a kind of that barite ore is purified and increased
White method, belongs to technical field of fine.
Background technology
Nonmetal mineral product of the barite using barium sulfate as main component, it is pure barite whitening color, glossy, due to impurity
And the influence of tramp material also normal gray, light red, light yellow etc., being that distributed in nature is most wide contains baryta mineral.Barite
Learn property stable, water insoluble and hydrochloric acid, nonmagnetic and toxicity.
Barite is a kind of critically important nonmetallic ore raw material, with extensive industrial use.In drilling well, pigment, change
All there is important utilization in work raw material, cement industry, road construction, but as high-quality, single type barite deposit are increasingly withered
Exhaust, existing most of barite deposit grade is low, with other metallic ores, the close association of nonmetallic ore, it is necessary to after purification
It can use.
Existing barite method of purification include physical purification and chemical purification, wherein physical purification include picking, gravity treatment,
Magnetic separation, at present in industrial production business with being gravity treatment and magnetic separation extensively, but the purification limited precision of gravity treatment, it is impossible to meet high standard
Accurate requirement, and magnetic separation is simply possible to use in removing magnetic mineral, function is more single;Chemical purification industrially mainly includes flotation
And pickling, wherein flotation is mainly used to distinguish specific two kinds of mineral matters, it is impossible to remove the unknown impuritie of multiple types, acid wash master
To be used for dissolving part acid soluble impurities and organic matter, its impurity-eliminating effect is still not ideal enough.
The content of the invention
For the deficiency in the presence of prior art, the invention provides the method that a kind of purification of barite is brightened, it is used to
Solve existing barite purification method of whitening can not comprehensively and effectively remove plurality of impurities present in barite raw ore and
The problem of effectively being brightened.
To achieve the above object, present invention employs following technical scheme:
A kind of method that barite purification is brightened, comprises the following steps:
(1) ore is pre-processed:Barite tcrude ore break process to diameter is less than 30cm first, washing tcrude ore is removed
Sludge, then carries out second-time breakage and handles tcrude ore to 3cm, be finally ground processing, tcrude ore is handled to 100
Within mesh;
(2) pickling is purified:According to the gross mass of pending raw material, the water and 2% part by weight of 100% part by weight are added
Sulfuric acid, then progressively add hydrochloric acid, fully reaction to the pH value of the aqueous solution is 1, then adds the water of 100% part by weight, then
The hydrofluoric acid of 2% part by weight is added, stirring reaction 8~12 hours finally removes waste liquid, added more than 200% part by weight
Water fully clean raw material, to pH be more than 2;
(3) processing is brightened:Raw material is diluted to 50% concentration, the sodium hydrosulfite of 2% part by weight is added, stirred 2~4 hours
It is fully reacted, then clean raw material and be more than 6 to pH, last drying material obtains finished product.
Compared to prior art, the present invention has the advantages that:
1st, the present invention first adds sulfuric acid and hydrochloric acid removes the acid soluble materials such as carbonate, metal in barite raw material, so
The impurity insoluble in acid such as hydrofluoric acid dissolution silicate is added afterwards, can be by the foreign metal in barite tcrude ore, metal
The impurity such as oxide, organic matter, carbonate, silicate are all removed, and greatly improve the purity of barite, through the present invention's
Method handled after barite in the content of barium sulfate can reach more than 97%, carried compared with prior art with larger
Rise;
2nd, the present invention is additionally added the sodium dithionite tool in sodium hydrosulfite progress bleaching, sodium hydrosulfite after acid pickling step
There is strong reducing property and Bleachability, the nonferrous metal oxides in barite raw material and organic matter etc. can be subjected to reproducibility drift
In vain, the whiteness of barite product is improved, the barite whiteness of method processing of the invention can reach more than 94, it is remote super existing big
Most products;
3rd, step of the invention all uses solution reaction, can disposably operate continuously, it is not necessary to carry out raw material transfer,
It is adapted to large-scale industrial production, is conducive to improving operating efficiency.
Embodiment
The present invention proposes a kind of method that barite purification is brightened, and comprises the following steps:
(1) ore is pre-processed:Barite tcrude ore break process to diameter is less than 30cm first, washing tcrude ore is removed
Sludge, then carries out second-time breakage and handles tcrude ore to 3cm, be finally ground processing, tcrude ore is handled to 100
Within mesh;
(2) pickling is purified:According to the gross mass of pending raw material, the water and 2% part by weight of 100% part by weight are added
Industrial sulphuric acid, sulfuric acid concentration is 40%wt~60%wt, then progressively adds technical hydrochloric acid, and concentration of hydrochloric acid is 30%wt~36%
Wt, fully reaction are 1 to the pH value of the aqueous solution, then add the water of 100% part by weight, add the hydrogen of 2% part by weight
Fluoric acid, hydrofluoric acid concentration is 30%wt~50%wt, and stirring reaction 8~12 hours finally removes waste liquid with filter screen, retains particle
Shape barite raw material, the water added more than 200% part by weight fully cleans raw material, is more than 2 to pH;
(3) processing is brightened:Raw material is diluted to 50% concentration, added in the sodium hydrosulfite of 2% part by weight, the sodium hydrosulfite
Hydrosulfurous acid sodium content is 70%~85%, and stirring makes it fully react in 2~4 hours, then cleans raw material to pH more than 6,
Last drying material, that is, obtain finished product.
It is preferred that, when step (2) cleans raw material, when the water of addition reaches 200% raw material weight ratio, often add
The water of 2% part by weight surveys a pH value, stops adding water when continuous 3 pH value are more than 2.
The present invention is washed using repeatedly broken add water first, and barite tcrude ore is handled to the granularity soaked to suitable solution,
Sludge is fully removed during this;Then conventional two kinds of pickling reagent of sulfuric acid and mixed in hydrochloric acid are used, removing can be dissolved
The impurity such as most of metal, metal oxide, carbonate and insoluble organic in barite raw material;Add hydrofluoric acid,
The silicate impurity insoluble in sulfuric acid and hydrochloric acid can be removed with the silicate reaction in barite raw material;It is eventually adding insurance
Powder is bleached, and the sodium dithionite in sodium hydrosulfite has extremely strong reproducibility, can will the coloured high-valency metal of tool from
Son is restored at a low price, so as to be bleached.
Embodiment 1:
Barite tcrude ore break process to diameter is less than 30cm, washing tcrude ore removes sludge, then carried out secondary
It is broken to handle tcrude ore to 3cm, processing is finally ground, tcrude ore is handled to 100 mesh.
The above-mentioned raw material 100kg being disposed is taken, the water of 100% part by weight and the industrial sulphur of 2% part by weight is added
Acid, sulfuric acid concentration is 40%w, then the technical hydrochloric acid that progressively addition concentration is 30%wt, and fully reaction to the pH value of the aqueous solution is
1, the water of 100% part by weight is then added, the hydrofluoric acid of 2% part by weight is added, hydrofluoric acid concentration is 30%wt, is stirred
After reaction 12 hours, waste liquid is removed with filter screen, retains graininess barite raw material, the water added more than 200% part by weight
Fully cleaning raw material, is more than 2 to pH.
Raw material is diluted to 50% concentration, hydrosulfurous acid sodium content in the sodium hydrosulfite of 2% part by weight, sodium hydrosulfite is added
For 70%, stirring makes it fully react in 4 hours, then cleans raw material and is more than 6 to pH, last drying material obtains finished product.
Barium sulfate content is 97.2% in the barite finished product that the present embodiment is obtained, and the whiteness of barite finished product is 94.
Embodiment 2:
Barite tcrude ore break process to diameter is less than 30cm, washing tcrude ore removes sludge, then carried out secondary
It is broken to handle tcrude ore to 2cm, processing is finally ground, tcrude ore is handled to 500 mesh.
The above-mentioned raw material 100kg being disposed is taken, the water of 100% part by weight and the industrial sulphur of 2% part by weight is added
Acid, sulfuric acid concentration is 50%w, then the technical hydrochloric acid that progressively addition concentration is 33%wt, and fully reaction to the pH value of the aqueous solution is
1, the water of 100% part by weight is then added, the hydrofluoric acid of 2% part by weight is added, hydrofluoric acid concentration is 40%wt, is stirred
After reaction 10 hours, waste liquid is removed with filter screen, retains graininess barite raw material, the water added more than 200% part by weight
Fully cleaning raw material, is more than 2 to pH.
Raw material is diluted to 50% concentration, hydrosulfurous acid sodium content in the sodium hydrosulfite of 2% part by weight, sodium hydrosulfite is added
For 80%, stirring makes it fully react in 3 hours, then cleans raw material and is more than 6 to pH, last drying material obtains finished product.
Barium sulfate content is 97.8% in the barite finished product that the present embodiment is obtained, and the whiteness of barite finished product is 95.
Embodiment 3:
Barite tcrude ore break process to diameter is less than 30cm, washing tcrude ore removes sludge, then carried out secondary
It is broken to handle tcrude ore to 3cm, processing is finally ground, tcrude ore is handled to 1000 mesh.
The above-mentioned raw material 100kg being disposed is taken, the water of 100% part by weight and the industrial sulphur of 2% part by weight is added
Acid, sulfuric acid concentration is 60%w, then the technical hydrochloric acid that progressively addition concentration is 36%wt, and fully reaction to the pH value of the aqueous solution is
1, the water of 100% part by weight is then added, the hydrofluoric acid of 2% part by weight is added, hydrofluoric acid concentration is 50%wt, is stirred
After reaction 8 hours, waste liquid is removed with filter screen, retains graininess barite raw material, the water added more than 200% part by weight fills
Distinguish and wash raw material, be more than 2 to pH.
Raw material is diluted to 50% concentration, hydrosulfurous acid sodium content in the sodium hydrosulfite of 2% part by weight, sodium hydrosulfite is added
For 85%, stirring makes it fully react in 2 hours, then cleans raw material and is more than 6 to pH, last drying material obtains finished product.
Barium sulfate content is 98.3% in the barite finished product that the present embodiment is obtained, and the whiteness of barite finished product is 96.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to skill of the invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of technical solution of the present invention, it all should cover at this
Among the right of invention.
Claims (7)
1. a kind of method that barite purification is brightened, it is characterised in that:Comprise the following steps:
(1) ore is pre-processed:Barite tcrude ore break process to diameter is less than 30cm first, washing tcrude ore removes decontamination
Mud, then carries out second-time breakage and handles tcrude ore to 3cm, be finally ground processing, tcrude ore is handled to 100 mesh
Within;
(2) pickling is purified:According to the gross mass of pending raw material, the water of 100% part by weight and the sulphur of 2% part by weight are added
Acid, then hydrochloric acid is progressively added, fully reaction to the pH value of the aqueous solution is 1, then adds the water of 100% part by weight, adds
The hydrofluoric acid of 2% part by weight, stirring reaction 8~12 hours finally removes waste liquid, the water added more than 200% part by weight
Fully cleaning raw material, is more than 2 to pH;
(3) processing is brightened:Raw material is diluted to 50% concentration, the sodium hydrosulfite of 2% part by weight is added, stirring makes it in 2~4 hours
Fully reaction, then cleans raw material and is more than 6 to pH, last drying material obtains finished product.
2. the method that a kind of barite purification as claimed in claim 1 is brightened, it is characterised in that:The sulfuric acid is industrial sulphur
Acid, its concentration is 40%wt~60%wt.
3. the method that a kind of barite purification as claimed in claim 1 is brightened, it is characterised in that:The hydrochloric acid is Nacl
Acid, its concentration is 30%wt~36%wt.
4. the method that a kind of barite purification as claimed in claim 1 is brightened, it is characterised in that:The hydrofluoric acid concentration is
30%wt~50%wt.
5. the method that a kind of barite purification as claimed in claim 1 is brightened, it is characterised in that:Connect two in the sodium hydrosulfite sub-
Sodium sulphate content is 70%~85%.
6. the method that a kind of barite purification as claimed in claim 1 is brightened, it is characterised in that:Raw material is cleaned in step (2)
When, when the water of addition reaches 200% raw material weight ratio, the water for often adding 2% part by weight surveys a pH value, when continuous 3
Stop adding water when secondary pH value is more than 2.
7. the method that a kind of barite purification as claimed in claim 1 is brightened, it is characterised in that:Raw material is cleaned in step (2)
It is preceding first waste liquid to be removed using filter screen, add water and cleaned.
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108502911A (en) * | 2018-04-24 | 2018-09-07 | 黔南民族师范学院 | A kind of barite purification brightening agent and its purification method of whitening |
CN108816065A (en) * | 2018-04-24 | 2018-11-16 | 中国科学技术大学 | A method of being completely dissolved barite |
CN109127081A (en) * | 2018-08-15 | 2019-01-04 | 贵州紫云月华新材料有限公司 | A kind of barite production method |
CN109264762A (en) * | 2018-11-09 | 2019-01-25 | 长沙万荣粉体设备科技有限公司 | A kind of native sulfate of barium method of purification and equipment |
CN109279639A (en) * | 2018-11-09 | 2019-01-29 | 长沙万荣粉体设备科技有限公司 | A kind of native sulfate of barium method of purification and equipment |
CN112850771A (en) * | 2021-01-23 | 2021-05-28 | 湖南华中矿业有限公司 | Purification and whitening processing technology and processing system for barite ore powder |
CN112919671A (en) * | 2021-01-23 | 2021-06-08 | 湖南华中矿业有限公司 | Treatment process and treatment system for barite ore powder purification and whitening wastewater |
CN113514599A (en) * | 2021-03-25 | 2021-10-19 | 长沙矿冶研究院有限责任公司 | Method for measuring content of barium sulfate in ore |
CN114213874A (en) * | 2021-12-03 | 2022-03-22 | 贵州民族大学 | Processing method for quality improvement and whitening of barite ore |
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CN102616824A (en) * | 2012-04-09 | 2012-08-01 | 武汉理工大学 | Method for preparing ultrafine high-whiteness active barite powder |
CN103130260A (en) * | 2013-03-19 | 2013-06-05 | 冉金友 | Production method of barium sulfate |
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CN102616824A (en) * | 2012-04-09 | 2012-08-01 | 武汉理工大学 | Method for preparing ultrafine high-whiteness active barite powder |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108502911A (en) * | 2018-04-24 | 2018-09-07 | 黔南民族师范学院 | A kind of barite purification brightening agent and its purification method of whitening |
CN108816065A (en) * | 2018-04-24 | 2018-11-16 | 中国科学技术大学 | A method of being completely dissolved barite |
CN109127081A (en) * | 2018-08-15 | 2019-01-04 | 贵州紫云月华新材料有限公司 | A kind of barite production method |
CN109264762A (en) * | 2018-11-09 | 2019-01-25 | 长沙万荣粉体设备科技有限公司 | A kind of native sulfate of barium method of purification and equipment |
CN109279639A (en) * | 2018-11-09 | 2019-01-29 | 长沙万荣粉体设备科技有限公司 | A kind of native sulfate of barium method of purification and equipment |
CN112850771A (en) * | 2021-01-23 | 2021-05-28 | 湖南华中矿业有限公司 | Purification and whitening processing technology and processing system for barite ore powder |
CN112919671A (en) * | 2021-01-23 | 2021-06-08 | 湖南华中矿业有限公司 | Treatment process and treatment system for barite ore powder purification and whitening wastewater |
CN113514599A (en) * | 2021-03-25 | 2021-10-19 | 长沙矿冶研究院有限责任公司 | Method for measuring content of barium sulfate in ore |
CN114213874A (en) * | 2021-12-03 | 2022-03-22 | 贵州民族大学 | Processing method for quality improvement and whitening of barite ore |
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Application publication date: 20171020 |