CN107263985A - A kind of ASA and PVC composite material for decoration and preparation method thereof - Google Patents
A kind of ASA and PVC composite material for decoration and preparation method thereof Download PDFInfo
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- CN107263985A CN107263985A CN201710331218.9A CN201710331218A CN107263985A CN 107263985 A CN107263985 A CN 107263985A CN 201710331218 A CN201710331218 A CN 201710331218A CN 107263985 A CN107263985 A CN 107263985A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/06—Embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/552—Fatigue strength
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2601/00—Upholstery
Abstract
The invention discloses a kind of ASA and PVC composite material for decoration and preparation method thereof, the composite material for decoration includes layer of PVC and is fitted in the ASA layers of layer of PVC upper surface.ASA and PVC composite material for decoration preparation method, including the step of the step of the step of the step of the step of preheating, laminating, insulation, sizing, winding.ASA is fitted on PVC and forms composite by the present invention, with high temperature resistant, color stability is good, ultraviolet stability is strong, weatherability is good the characteristics of, be particularly suitable for use as outdoor use, higher ornament materials, which is used, to be required to color.The preparation method is simple, production efficiency is high, process conditions are gentle, be produced on a large scale.
Description
Technical field
The present invention relates to a kind of home decoration material technology, more particularly to a kind of ASA and PVC composite material for decoration and its system
Preparation Method.
Background technology
PVC is the white powder of impalpable structure, and the degree of branching is smaller.Industrial PVC molecular weight is general 50,000-12
In the range of ten thousand, with larger polydispersity, the reduction of molecular weight with polymerisation temperature and increase；Without definite melting point, 80-85 DEG C is opened
Begin to soften, 130 DEG C are changed into viscoelastic state, and 160-180 DEG C starts to be changed into viscous state；There are preferable mechanical performance, tensile strength
60MPa or so, impact strength 5-10kJ/m2；There are excellent dielectric properties.PVC is also just with its good performance, simple technique
And other plurality of advantages have won the favor of people gradually, received and approved by increasing people, extensive use is in
Occupy in ornament materials.
But PVC decorative material is poor to the stability of light and heat, more than 100 DEG C or through long-time exposure in sunshine, Jiu Huifen
Solve and produce hydrogen chloride, and further autocatalysis is decomposed, and causes discoloration, physical and mechanical properties also declines rapidly.Therefore, for
The PVC decorative material that open air is used, by the time verifying exposed to the sun and rain, these PVC decorative material weatherabilities are poor, use 1 year
The phenomenons such as colour fading, discoloration just occur in left and right.Therefore, for outdoor use and higher ornament materials is required to color, it is existing
Some PVC decorative materials can not meet its use requirement.
The content of the invention
In order to overcome the deficiencies in the prior art, an object of the present invention is to provide a kind of ASA and PVC composite decoration materials
Material.ASA is fitted on PVC by the present invention forms composite, and with high temperature resistant, color stability is good, ultraviolet stability is strong, resistance to
The characteristics of time property is good, is particularly suitable for use as outdoor use, requires that higher ornament materials is used to color.
The second object of the present invention is the preparation method for providing a kind of ASA and PVC composite material for decoration.The preparation method
Simply, production efficiency is high, process conditions are gentle, be produced on a large scale, and the composite material for decoration that thus technique productions go out has resistance to
The characteristics of high temperature, color stability are good, ultraviolet stability is strong, weatherability is good.
An object of the present invention adopts the following technical scheme that realization：
A kind of ASA and PVC composite material for decoration, including layer of PVC and the ASA layers for being fitted in layer of PVC upper surface.
Further, the thickness of the layer of PVC is 0.05-20mm, and described ASA layers thickness is 0.05-0.5mm.
Further, the layer of PVC is divided into membrane material and sheet material according to the difference of thickness, and wherein PVC film material thickness is 0.05-
0.5mm, PVC sheet thickness is 2.7-6mm.
The second object of the present invention adopts the following technical scheme that realization：
ASA and PVC composite material for decoration a kind of preparation method, including,
The step of preheating：
The ASA coiled materials that volume has ASA drive it to move under the rotation of the first importing roller；The PVC roll material that volume has PVC passes through
Drive it to move under the rotation of second importing roller, when ASA and PVC is moved, preheated at 110-150 DEG C；
The step of laminating：
The ASA and PVC carries out thermal-adhering on heat posted roller, and the thermal-adhering temperature is 150-160 DEG C；
The step of insulation：
Composite after heat posted carries out isothermal holding around being located on thermal-insulation roller successively, and the temperature of the isothermal holding is
170-180℃；
The step of sizing：
Warm composite carries out heat treatment around being located on chill roll successively, and the temperature of the heat treatment is
15-30℃；
The step of winding：
Composite by sizing is final around being located on reel.
Further, in the step of preheating, laminating, insulation, sizing, winding, the ASA coiled materials are defeated with PVC roll material
It is 10 meters/min-50 meters/min to send speed.
Further, in the step of preheating, the first importing roller is at least three, and the ASA is successively around being located at
First imports on roller, and the second importing roller is at least three, and the PVC is successively around being located on the second importing roller.
Further, in the step of laminating, a diameter of 150cm of the heat posted roller.
Further, in the step of insulation, the thermal-insulation roller is at least four, the composite after heat posted according to
It is secondary around being located on four thermal-insulation rollers.
Further, in the step of sizing, the chill roll is at least seven, it is described it is warm after composite according to
It is secondary around being located on seven chill rolls.
Further, the composite also includes carrying out embossed before fixating shape step.
Compared with prior art, the beneficial effects of the present invention are：
(1) ASA is fitted on PVC by the present invention forms composite, good, ultraviolet steady with high temperature resistant, color stability
It is qualitative it is strong, the characteristics of weatherability is good, is particularly suitable for use as outdoor use, higher ornament materials, which is used, to be required to color.Separately
Outer ASA is a kind of antistatic material, and surface can be made to lack dust stratification dirt, can keep the color gloss of ornament materials constant for a long time.
(2) in addition, the preparation method is simple, production efficiency is high, process conditions are gentle, be produced on a large scale, thus technique
The composite material for decoration produced has the characteristics of high temperature resistant, color stability are good, ultraviolet stability is strong, weatherability is good.
(3) experiment proves that, the ASA prepared by preparation method of the present invention and its weatherability of PVC composite material for decoration
It is good, compared with existing its service life of PVC decorative material is 1 year, the use of ASA Yu PVC composite material for decoration of the invention
Life-span is 15 years, during which colour-fast, nondiscolouring, high temperature resistant.
Brief description of the drawings
Fig. 1 is ASA of the present invention and the schematic diagram of the preparation method of PVC composite material for decoration.
Embodiment
Below, with reference to accompanying drawing and embodiment, the present invention is described further, it is necessary to which explanation is, not
Under the premise of afoul, new implementation can be formed between various embodiments described below or between each technical characteristic in any combination
Example.
A kind of ASA and PVC composite material for decoration, including layer of PVC and the ASA layers for being fitted in layer of PVC upper surface.
Further, the thickness of the layer of PVC is 0.05-20mm, and described ASA layers thickness is 0.05-0.5mm.
Further, the layer of PVC is divided into membrane material and sheet material according to the difference of thickness, and wherein PVC film material thickness is 0.05-
0.5mm, PVC sheet thickness is 2.7-6mm.
ASA is by a kind of impact-resistant modified of the ter-polymers combined polymerizations such as styrene, acrylonitrile and acryl rubber
Resin, with good mechanical and physical performance, in addition, ASA resin has outdoor weather-proof ability, is fitted on PVC and forms compound
Material, with high temperature resistant, color stability is good, ultraviolet stability is strong, weatherability is good the characteristics of, being particularly suitable for use as open air makes
With, higher ornament materials, which is used, to be required to color.Other ASA is a kind of antistatic material, and surface can be made to lack dust stratification dirt, can be grown
Phase keeps the color gloss of ornament materials constant.
As shown in figure 1, the ASA and PVC composite material for decoration preparation method, including,
The step of preheating：
The ASA coiled materials that volume has ASA drive it to move under the rotation of the first importing roller；The PVC roll material that volume has PVC passes through
Drive it to move under the rotation of second importing roller, when ASA and PVC is moved, preheated at 110-150 DEG C；Described first
Import roller and be at least three, the ASA is successively around being located on the first importing roller, and the second importing roller is at least three
Individual, the PVC is successively around being located on the second importing roller.Set at least three to import roller, ensure that ASA and PVC more
Fully, make laminating more docile, non-foaming.
The step of laminating：
The ASA and PVC carries out thermal-adhering on heat posted roller, and the thermal-adhering temperature is 150-160 DEG C；The heat posted roller
A diameter of 150cm.Wherein, the diameter of heat posted roller, which is defined, enables ASA and PVC in the cylinder surface product of sufficient length
Thermal-adhering is carried out, makes laminating effect more excellent, non-foaming, not fold, docile.
The step of insulation：
Composite after heat posted carries out isothermal holding around being located on thermal-insulation roller successively, and the temperature of the isothermal holding is
170-180℃；The thermal-insulation roller is at least four, and the composite after heat posted is successively around being located on four thermal-insulation rollers.
The purpose for setting at least four thermal-insulation rollers is to ensure that ASA more fully fits at such a temperature with PVC, compound obtained decoration material
Material disclosure satisfy that required.
The step of embossing：
The need for according to decoration, embossed is carried out to composite material for decoration, embossed uses existing conventional technique
Embossed.
The step of sizing：
Warm composite carries out heat treatment around being located on chill roll successively, and the temperature of the heat treatment is
15-30℃；The chill roll is at least seven, it is described it is warm after composite successively around being located on seven chill rolls.If
The purpose for putting at least seven chill rolls is by the ASA of high temperature and PVC composite cooling and shapings, by least seven chill rolls
Multiple cooling effect, its fixed effect is good, and composite shrinks uniform, non-foaming, not fold.
The step of winding：
Composite by sizing is final around being located on reel.
Further, in the step of preheating, laminating, insulation, sizing, winding, the ASA coiled materials are defeated with PVC roll material
It is 10 meters/min-50 meters/min to send speed.The present invention is by controlling ASA and PVC transporting velocity, so as to control in different phase
Middle carry out different disposal, can reach laminating Compound Degree well, the property of the composite finally given is also to meet dress
Decorations require, i.e., with high temperature resistant, color stability is good, ultraviolet stability is strong, weatherability is good the characteristics of.
Embodiment 1
A kind of ASA and PVC composite material for decoration, including layer of PVC and the ASA layers for being fitted in layer of PVC upper surface；The PVC
Layer is membrane material, and thickness is 0.5mm, and described ASA layers thickness is 0.5mm.
Embodiment 2
A kind of ASA and PVC composite material for decoration, including layer of PVC and the ASA layers for being fitted in layer of PVC upper surface；The PVC
Layer is sheet material, and thickness is 6mm, and described ASA layers thickness is 0.5mm.
Embodiment 3
The preparation method of ASA and the PVC composite material for decoration of embodiment 1, including,
The step of preheating：
The ASA coiled materials that volume has ASA drive it to move under the rotation of the first importing roller；The PVC roll material that volume has PVC passes through
Drive it to move under the rotation of second importing roller, when ASA and PVC is moved, preheated at 110-150 DEG C；Described first
It is three to import roller, and the ASA is successively around being located on the first importing roller, and the second importing roller is three, the PVC
Successively around being located on the second importing roller.
The step of laminating：
The ASA and PVC carries out thermal-adhering on heat posted roller, and the thermal-adhering temperature is 150-160 DEG C；The heat posted roller
A diameter of 150cm.
The step of insulation：
Composite after heat posted carries out isothermal holding around being located on thermal-insulation roller successively, and the temperature of the isothermal holding is
170-180℃；The thermal-insulation roller is four, and the composite after heat posted is successively around being located on four thermal-insulation rollers.
The step of embossing：
The need for according to decoration, embossed is carried out to composite material for decoration, embossed uses existing conventional technique
Embossed.
The step of sizing：
Warm composite carries out heat treatment around being located on chill roll successively, and the temperature of the heat treatment is
15-30℃；The chill roll is seven, it is described it is warm after composite successively around being located on seven chill rolls.
The step of winding：
Composite by sizing is final around being located on reel.
Wherein, in the step of preheating, laminating, insulation, sizing, winding, the conveying speed of the ASA coiled materials and PVC roll material
Spend for 10 meters/min.
Embodiment 4
The preparation method of ASA and the PVC composite material for decoration of embodiment 1, including,
The step of preheating：
The ASA coiled materials that volume has ASA drive it to move under the rotation of the first importing roller；The PVC roll material that volume has PVC passes through
Drive it to move under the rotation of second importing roller, when ASA and PVC is moved, preheated at 110-150 DEG C；Described first
It is five to import roller, and the ASA is successively around being located on the first importing roller, and the second importing roller is five, the PVC
Successively around being located on the second importing roller.
The step of laminating：
The ASA and PVC carries out thermal-adhering on heat posted roller, and the thermal-adhering temperature is 150-160 DEG C；The heat posted roller
A diameter of 150cm.
The step of insulation：
Composite after heat posted carries out isothermal holding around being located on thermal-insulation roller successively, and the temperature of the isothermal holding is
170-180℃；The thermal-insulation roller is six, and the composite after heat posted is successively around being located on six thermal-insulation rollers.
The step of embossing：
The need for according to decoration, embossed is carried out to composite material for decoration, embossed uses existing conventional technique
Embossed.
The step of sizing：
Warm composite carries out heat treatment around being located on chill roll successively, and the temperature of the heat treatment is
15-30℃；The chill roll is nine, it is described it is warm after composite successively around being located on nine chill rolls.
The step of winding：
Composite by sizing is final around being located on reel.
Wherein, in the step of preheating, laminating, insulation, sizing, winding, the conveying speed of the ASA coiled materials and PVC roll material
Spend for 30 meters/min.
Embodiment 5
The preparation method of ASA and the PVC composite material for decoration of embodiment 1, including,
The step of preheating：
The ASA coiled materials that volume has ASA drive it to move under the rotation of the first importing roller；The PVC roll material that volume has PVC passes through
Drive it to move under the rotation of second importing roller, when ASA and PVC is moved, preheated at 110-150 DEG C；Described first
It is five to import roller, and the ASA is successively around being located on the first importing roller, and the second importing roller is five, the PVC
Successively around being located on the second importing roller.
The step of laminating：
The ASA and PVC carries out thermal-adhering on heat posted roller, and the thermal-adhering temperature is 150-160 DEG C；The heat posted roller
A diameter of 150cm.
The step of insulation：
Composite after heat posted carries out isothermal holding around being located on thermal-insulation roller successively, and the temperature of the isothermal holding is
170-180℃；The thermal-insulation roller is six, and the composite after heat posted is successively around being located on six thermal-insulation rollers.
The step of embossing：
The need for according to decoration, embossed is carried out to composite material for decoration, embossed uses existing conventional technique
Embossed.
The step of sizing：
Warm composite carries out heat treatment around being located on chill roll successively, and the temperature of the heat treatment is
15-30℃；The chill roll is nine, it is described it is warm after composite successively around being located on nine chill rolls.
The step of winding：
Composite by sizing is final around being located on reel.
Wherein, in the step of preheating, laminating, insulation, sizing, winding, the conveying speed of the ASA coiled materials and PVC roll material
Spend for 50 meters/min.
Experiment proves that, the ASA and its good weatherability of PVC composite material for decoration prepared by preparation method of the present invention,
Compared with existing its service life of PVC decorative material is 1 year, ASA of the invention and the service life of PVC composite material for decoration
It is during which colour-fast for 15 years, nondiscolouring, high temperature resistant.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to limit the scope of protection of the invention with this,
The change and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (10)
1. a kind of ASA and PVC composite material for decoration, it is characterised in that including layer of PVC and the ASA for being fitted in layer of PVC upper surface
Layer.
2. ASA as claimed in claim 1 and PVC composite material for decoration, it is characterised in that the thickness of the layer of PVC is 0.05-
6mm, described ASA layers thickness is 0.05-0.5mm.
3. ASA as claimed in claim 1 and PVC composite material for decoration, it is characterised in that the layer of PVC according to thickness not
With membrane material and sheet material is divided into, wherein PVC film material thickness is 0.05-0.5mm, and PVC sheet thickness is 2.7-6mm.
4. a kind of ASA and PVC composite material for decoration preparation method, it is characterised in that including,
The step of preheating：
The ASA coiled materials that volume has ASA drive it to move under the rotation of the first importing roller；The PVC roll material that rolling up has PVC passes through second
Drive it to move under the rotation for importing roller, when ASA and PVC is moved, preheated at 110-150 DEG C；
The step of laminating：
The ASA and PVC carries out thermal-adhering on heat posted roller, and the thermal-adhering temperature is 150-160 DEG C；
The step of insulation：
Composite after heat posted carries out isothermal holding around being located on thermal-insulation roller successively, and the temperature of the isothermal holding is 170-
180℃；
The step of sizing：
Warm composite carries out heat treatment around being located on chill roll successively, and the temperature of the heat treatment is 15-30
℃；
The step of winding：
Composite by sizing is final around being located on reel.
5. preparation method as claimed in claim 4, it is characterised in that the step of preheating, laminating, insulation, sizing, winding
In, the transporting velocity of the ASA coiled materials and PVC roll material is 10 meters/min-50 meters/min.
6. preparation method as claimed in claim 4, it is characterised in that in the step of preheating, described first imports roller extremely
Be three less, the ASA is successively around being located on the first importing roller, and the second importing roller is at least three, the PVC according to
It is secondary around being located on the second importing roller.
7. preparation method as claimed in claim 4, it is characterised in that in the step of laminating, the heat posted roller it is a diameter of
150cm。
8. preparation method as claimed in claim 4, it is characterised in that in the step of insulation, the thermal-insulation roller is at least four
Individual, the composite after heat posted is successively around being located on four thermal-insulation rollers.
9. preparation method as claimed in claim 4, it is characterised in that in the step of sizing, the chill roll is at least seven
It is individual, it is described it is warm after composite successively around being located on seven chill rolls.
10. preparation method as claimed in claim 4, it is characterised in that the composite also includes before fixating shape step
Carry out embossed.
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| CN201710331218.9A CN107263985A (en) | 2017-05-11 | 2017-05-11 | A kind of ASA and PVC composite material for decoration and preparation method thereof |
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| CN201710331218.9A CN107263985A (en) | 2017-05-11 | 2017-05-11 | A kind of ASA and PVC composite material for decoration and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111171492A (en) * | 2020-01-16 | 2020-05-19 | 江苏凯伦建材股份有限公司 | PVC waterproof coiled material |
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| CN2617572Y (en) * | 2003-04-25 | 2004-05-26 | 佛山市红波建材有限公司 | Atmospheric composite plastic board |
| CN101492987A (en) * | 2009-03-05 | 2009-07-29 | 华之杰塑料建材有限公司 | Weather resistant wood-grain imitating PVC plastic profiled bar and method for manufacturing same |
| CN103421257A (en) * | 2012-05-15 | 2013-12-04 | 金昌市省力多粮油器材发展有限责任公司 | Sheet material with high weatherability and processing method |
| CN103707608A (en) * | 2013-12-20 | 2014-04-09 | 浙江美格机械股份有限公司 | Continuous production equipment for performing multi-layer adhesive-free composite embossing on PVC (polyvinyl chloride) decorative film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111171492A (en) * | 2020-01-16 | 2020-05-19 | 江苏凯伦建材股份有限公司 | PVC waterproof coiled material |
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Application publication date: 20171020 |