CN107261772A - A kind of method and device for being used to gather dust with purification containing volatility valuable element gas - Google Patents

A kind of method and device for being used to gather dust with purification containing volatility valuable element gas Download PDF

Info

Publication number
CN107261772A
CN107261772A CN201710584175.5A CN201710584175A CN107261772A CN 107261772 A CN107261772 A CN 107261772A CN 201710584175 A CN201710584175 A CN 201710584175A CN 107261772 A CN107261772 A CN 107261772A
Authority
CN
China
Prior art keywords
gas
tower
tower body
liquid
absorbing liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710584175.5A
Other languages
Chinese (zh)
Inventor
董辉
李含竹
张井凡
屈文杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Northeastern University China
Original Assignee
Northeastern University China
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Northeastern University China filed Critical Northeastern University China
Priority to CN201710584175.5A priority Critical patent/CN107261772A/en
Publication of CN107261772A publication Critical patent/CN107261772A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/12Washers with plural different washing sections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1406Multiple stage absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/204Inorganic halogen compounds
    • B01D2257/2047Hydrofluoric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention discloses a kind of method and device for being used to gather dust with purification containing volatility valuable element gas, gas liquid mixture is entered by the gas feed on middle part tower body top, tangential motion on the inside of along outer tower, under the influence of centrifugal force, absorbed dust etc. can get rid of the inner wall surface of outside tower, and gone downstream in the presence of spiral guide plate, finally flow into the bottom tower body;Absorbing liquid is entered by absorbing liquid import, spray to each spherical sieve tray top absorbing liquid and by bottom tower body go up Lai gas mixing;Mixed gas enters top tower body and carries out gas-liquid separation, and the liquid after separation flows into bottom tower body along inner cylinder;Gas is discharged.The present invention has the advantages that absorptivity is high, energy consumption is relatively low, simple in construction, easily overhaul, and the rate of recovery for valuable element can reach more than 98%;Corresponding pernicious gas can be removed by configuring corresponding elution absorbing liquid, absorptivity can reach more than 96%.

Description

一种用于含有挥发性有价元素气体收尘与净化的方法及装置A method and device for dust collection and purification of gas containing volatile valuable elements

技术领域technical field

本发明专利属于气体净化处理技术领域,具体涉及一种用于含有挥发性有价元素气体收尘净化的方法及装置。The patent of the invention belongs to the technical field of gas purification treatment, and specifically relates to a method and device for dust collection and purification of gas containing volatile valuable elements.

背景技术Background technique

工业生产过程中,通常会产生很多的工业废气,所排放的废气中含有粉尘、SO2、NOx、HF、CO2等成分;一些工艺过程,会在烟气中留有挥发性有价元素,如果不对这些废气进行有效处理,直接排放,会造成严重的环境污染及资源浪费。为了满足环保要求,这些废气均应处理达到排放标准后可排放。In the process of industrial production, a lot of industrial waste gas is usually produced, and the discharged waste gas contains dust, SO 2 , NOx, HF, CO 2 and other components; some processes will leave volatile valuable elements in the flue gas, If these waste gases are not effectively treated and discharged directly, it will cause serious environmental pollution and waste of resources. In order to meet the requirements of environmental protection, these exhaust gases should be treated and discharged after meeting the emission standards.

工业废气的处理通常有干法和湿法,干法除尘很难对挥发性有价元素进行回收,而工业大型装置一般以湿法为主。较常见的湿法吸收净化装置各有优缺点,缺点主要有吸收率较低,效果不好,存在“死区”,设备较高等。There are usually dry and wet methods for the treatment of industrial waste gas. Dry dust removal is difficult to recover volatile valuable elements, while large-scale industrial devices generally use wet methods. The more common wet absorption and purification devices have their own advantages and disadvantages. The disadvantages mainly include low absorption rate, poor effect, "dead zone" and high equipment.

发明内容Contents of the invention

为解决上述技术问题,本发明的目的是提供一种高效的方法及装置,具体技术方案如下:For solving the problems of the technologies described above, the object of the present invention is to provide a kind of efficient method and device, and concrete technical scheme is as follows:

一种用于含有挥发性有价元素气体收尘与净化的方法,气液混合体由中部塔体上部的气体进口进入,沿外塔内侧切线运动,在离心力的作用下,被吸收的粉尘等会甩向外塔的内壁表面,并在螺旋导向板的作用下顺流而下,最终流入所述下部塔体;吸收液由吸收液进口进入,喷淋到每个球面筛板上部的吸收液与由下部塔体升上来的气体混合;混合后的气体进入上部塔体进行气液分离,分离后的液体顺内筒流入下部塔体;气体排放。A method for dust collection and purification of gas containing volatile valuable elements. The gas-liquid mixture enters from the gas inlet in the upper part of the middle tower, moves along the tangent line inside the outer tower, and under the action of centrifugal force, the absorbed dust, etc. It will be thrown to the inner wall surface of the outer tower, and flow down under the action of the spiral guide plate, and finally flow into the lower tower body; the absorption liquid enters from the absorption liquid inlet, and sprays the absorption liquid on the upper part of each spherical sieve plate It is mixed with the gas rising from the lower tower body; the mixed gas enters the upper tower body for gas-liquid separation, and the separated liquid flows into the lower tower body along the inner cylinder; the gas is discharged.

本发明进一步公开了实现所述方法的装置,包括上部塔体、中部塔体、下部塔体;所述中部塔体为套筒式双塔结构,包括内塔和外塔;内塔与外塔之间的间隙中设置有喷淋式螺旋导向板,气体进口设置在外塔的上端,且气体进口的方向为外塔内壁的切线方向;内塔中布置有筛板,每个筛板的上方设置吸收液进口;上部塔体设置气液分离板,下部塔体设置吸收液水槽,上部塔体与下部塔体通过内塔连通。The invention further discloses a device for realizing the method, including an upper tower body, a middle tower body, and a lower tower body; the middle tower body is a sleeve-type double tower structure, including an inner tower and an outer tower; the inner tower and the outer tower A spray-type spiral guide plate is set in the gap between them, the gas inlet is set on the upper end of the outer tower, and the direction of the gas inlet is the tangential direction of the inner wall of the outer tower; a sieve plate is arranged in the inner tower, and a The absorption liquid inlet; the upper tower body is equipped with a gas-liquid separation plate, the lower tower body is equipped with an absorption liquid water tank, and the upper tower body and the lower tower body are connected through the inner tower.

所述筛板为球面筛板。The sieve plate is a spherical sieve plate.

本发明的优点是:本发明具有吸收率高、能耗较低、结构简单、容易检修等优点,克服了常见湿法除尘(立式旋风水膜除尘和喷淋式除尘)存在“死区”,设备较高,吸收率较低,效果不好等缺点。本发明专利对于有价元素的回收率可达到98%以上;对含有有害气体的工业废气可脱除,如:SO2、NOx,通过配置相应的淋洗吸收液可脱除相应的有害气体,脱除率可达到96%以上。The advantages of the present invention are: the present invention has the advantages of high absorption rate, low energy consumption, simple structure, easy maintenance, etc., and overcomes the "dead zone" existing in common wet dust removal (vertical cyclone water film dust removal and spray dust removal) , high equipment, low absorption rate, poor effect and other shortcomings. The recovery rate of valuable elements in the patent of the present invention can reach more than 98%; industrial waste gas containing harmful gases can be removed, such as: SO 2 , NOx, and corresponding harmful gases can be removed by configuring corresponding rinsing and absorbing liquids. The removal rate can reach more than 96%.

附图说明Description of drawings

图1为收尘净化装置结构示意图;Fig. 1 is a schematic diagram of the structure of the dust collection and purification device;

图2为进气口的布置方式示意图;Figure 2 is a schematic diagram of the layout of the air inlet;

图3为球面筛板的示意图;Fig. 3 is the schematic diagram of spherical sieve plate;

图4为内外塔体及其夹层的结构示意图。Figure 4 is a structural schematic diagram of the inner and outer towers and their interlayers.

图中,1为上部塔体,2为吸收液进口,3为中部塔体,4为下部塔体,5为外塔,6为螺旋导向板,7为内塔,8为球面筛板,9为气体进口,10为气体出口。In the figure, 1 is the upper tower body, 2 is the absorption liquid inlet, 3 is the middle tower body, 4 is the lower tower body, 5 is the outer tower, 6 is the spiral guide plate, 7 is the inner tower, 8 is the spherical sieve plate, 9 For gas inlet, 10 is for gas outlet.

具体实施方式detailed description

下面结合附图具体说明本发明。The present invention will be described in detail below in conjunction with the accompanying drawings.

含有挥发性有价元素的气体与吸收液混合体从中部塔体3上部的气体进口9进入内塔7与外塔5的间隙中,在喷淋式螺旋导向板的引导下螺旋下行,烟尘及有害气体在外塔7与内塔5的间隙中被吸收液吸收,完成第一次吸收与净化;气液混合物流入下部塔体4后,液体从排水口流出,而气体向上升腾,此时,与从吸收液进口2流入的吸收液在球面筛板8处汇聚,在球面筛板8每个小的球面下形成涡旋式的沸腾状态,完成第二次吸收与净化;第二次吸收后的气体进入上部塔体1,在上部塔体1内完成气水分离,气体由顶部的气体出口10 排出,吸收液经内筒7流入下部塔体4,由下部塔体排出进行处理。The mixture of gas and absorption liquid containing volatile valuable elements enters the gap between the inner tower 7 and the outer tower 5 from the gas inlet 9 on the upper part of the middle tower body 3, and spirals downward under the guidance of the spray-type spiral guide plate, and the smoke and dust The harmful gas is absorbed by the absorption liquid in the gap between the outer tower 7 and the inner tower 5, and the first absorption and purification are completed; after the gas-liquid mixture flows into the lower tower body 4, the liquid flows out from the drain, and the gas rises upward. The absorption liquid flowing in from the absorption liquid inlet 2 converges at the spherical sieve plate 8, and forms a vortex boiling state under each small spherical surface of the spherical sieve plate 8, completing the second absorption and purification; after the second absorption The gas enters the upper tower body 1, and the gas-water separation is completed in the upper tower body 1. The gas is discharged from the gas outlet 10 at the top, and the absorption liquid flows into the lower tower body 4 through the inner cylinder 7, and is discharged from the lower tower body for treatment.

所述的气体进口9沿中部塔体3上部切线方向布置,目的是气体液体混合后在压力的作用下,沿外塔内侧切线运动,在离心力的作用下,被吸收的粉尘会甩向外塔筒体的内壁表面,并顺流而下,最终流入下部塔体4,即吸收液槽内;由于气体是切向进入塔内,沿外筒内壁做圆周运动,故在中部塔体的横截面中心部形成“死区”,因此在中心区域设置了多层球面筛板塔,充分利用了塔内空间形成了内外塔组成的合理结构。中心区域中的球面筛板大于平面筛板的开孔率,其气体的通量大,能够形成沸腾状滴雾区,对气体的粉尘、有害气体成份吸收,效率好。The gas inlet 9 is arranged along the tangent direction of the upper part of the middle tower body 3. The purpose is that after the gas and liquid are mixed, they will move along the tangent line inside the outer tower under the action of pressure. Under the action of centrifugal force, the absorbed dust will be thrown towards the outer tower. The surface of the inner wall of the cylinder, and flows down, and finally flows into the lower tower body 4, that is, the absorption liquid tank; since the gas enters the tower tangentially and moves circularly along the inner wall of the outer cylinder, the cross-section of the middle tower body The center forms a "dead zone", so a multi-layer spherical sieve plate tower is set in the center area, making full use of the space inside the tower to form a reasonable structure composed of inner and outer towers. The spherical sieve plate in the central area is larger than the opening ratio of the flat sieve plate, and its gas flux is large, which can form a boiling drop mist area, which absorbs the dust and harmful gas components of the gas, and has good efficiency.

上述设备的内外塔之间间隙设置了喷淋式螺旋导向板,解决了间隙喷淋吸收液的问题,同时起到气体的引导走向问题,提高了气体在塔内的停留时间,即提高了吸收率。The gap between the inner and outer towers of the above-mentioned equipment is equipped with a spray-type spiral guide plate, which solves the problem of spraying the absorption liquid in the gap, and at the same time plays a role in guiding the gas, increasing the residence time of the gas in the tower, that is, improving the absorption. Rate.

所述喷淋式螺旋导向板是指导向板上设置很多小孔,气液流经导向板时,一部分液体自所述小孔坠落,与升腾的气体混合,形成喷淋状混合。该结构增加了气液混合面积,因此,对有害气体的回收效果更好。The spray-type spiral guide plate means that many small holes are set on the guide plate. When the gas and liquid flow through the guide plate, a part of the liquid falls from the small holes and mixes with the rising gas to form a spray-like mixture. This structure increases the gas-liquid mixing area, so the recovery effect of harmful gas is better.

内部塔筒的气流速度v1一般为1~1.5m/s,为了保证气体在内部塔筒的处理时间在3s以上,内部塔筒的高度H1应大于4.5m。高与直径之比一般在4~7范围内。直径D1由经验式确定,如下:The air velocity v 1 of the inner tower is generally 1-1.5m/s. In order to ensure that the gas processing time in the inner tower is more than 3s, the height H 1 of the inner tower should be greater than 4.5m. height to diameter ratio Generally in the range of 4 to 7. Diameter D1 is determined by empirical formula, as follows:

式中Q为气体处理量,m3/h。In the formula, Q is the gas processing capacity, m 3 /h.

外部塔筒在操作状态下筒体截面速度v2一般为4~6m/s。从外部塔筒进入的气体Q全部进入内部塔筒,因此可以确定内部塔筒与外部塔筒之间的距离S。单位高度h(1m)下,气体处理量Q的表达式如下:The cross-sectional velocity v 2 of the external tower is generally 4-6m/s in the operating state. The gas Q entering from the outer tower all enters the inner tower, so the distance S between the inner tower and the outer tower can be determined. Under the unit height h (1m), the expression of the gas handling capacity Q is as follows:

Q=h·S·v2 (2)Q=h·S·v 2 (2)

与下式联立:Simultaneously with:

Q=900πv1D1 2 (3)Q=900πv 1 D 1 2 (3)

由此得出内部塔筒与外部塔筒之间的距离S:This gives the distance S between the inner tower and the outer tower:

进而得出外部塔筒直径D2Then the outer tower diameter D 2 is obtained:

D2=D1+2S (5)。D 2 =D 1 +2S (5).

Claims (3)

1. a kind of method for being used to gather dust with purifying containing volatility valuable element gas, it is characterised in that:Gas liquid mixture by The gas feed on middle part tower body top enters, along outer tower inner side tangential motion, under the influence of centrifugal force, absorbed dust etc. The inner wall surface of outside tower can be got rid of, and is gone downstream in the presence of spiral guide plate, the bottom tower body is finally flowed into;Absorb Liquid is entered by absorbing liquid import, spray to each spherical sieve tray top absorbing liquid with by bottom tower body go up Lai gas mix Close;Mixed gas enters top tower body and carries out gas-liquid separation, and the liquid after separation flows into bottom tower body along inner cylinder;Gas is arranged Put.
2. a kind of device for realizing claim 1 methods described, it is characterised in that:Including top tower body, middle part tower body, lower tower Body;The middle part tower body is telescopic Double-Tower Structure, including inner tower and outside tower;Spray is provided with gap between Nei Ta and outer tower Pouring formula spiral guide plate, gas feed is set in the upper end of outer tower, and the direction of gas feed is the tangential direction of outer inner wall of tower; Sieve plate is disposed with interior tower, the top of each sieve plate sets absorbing liquid import;Top tower body sets gas-liquid separation plate, bottom tower body Absorbing liquid tank is set, and top tower body is connected with bottom tower body by interior tower.
3. device according to claim 2, it is characterised in that:The sieve plate is spherical sieve tray.
CN201710584175.5A 2017-07-18 2017-07-18 A kind of method and device for being used to gather dust with purification containing volatility valuable element gas Withdrawn CN107261772A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710584175.5A CN107261772A (en) 2017-07-18 2017-07-18 A kind of method and device for being used to gather dust with purification containing volatility valuable element gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710584175.5A CN107261772A (en) 2017-07-18 2017-07-18 A kind of method and device for being used to gather dust with purification containing volatility valuable element gas

Publications (1)

Publication Number Publication Date
CN107261772A true CN107261772A (en) 2017-10-20

Family

ID=60077776

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710584175.5A Withdrawn CN107261772A (en) 2017-07-18 2017-07-18 A kind of method and device for being used to gather dust with purification containing volatility valuable element gas

Country Status (1)

Country Link
CN (1) CN107261772A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109550339A (en) * 2017-09-27 2019-04-02 东北大学 A kind of method and device for gathering dust containing volatility valuable element gas with purification
CN111495137A (en) * 2020-04-26 2020-08-07 安徽顺达环保科技股份有限公司 Desulfurization and denitrification equipment and method for industrial flue gas catalytic cracking
CN112933901A (en) * 2019-12-11 2021-06-11 青岛双瑞海洋环境工程股份有限公司 Integrated device for waste gas desulfurization and inert gas supply
CN113230870A (en) * 2020-12-15 2021-08-10 岑顺彬 Desulfurizing tower dual cycle wet process filtration system for chemical production
CN114917716A (en) * 2022-05-23 2022-08-19 广州兴丰能源科技有限公司 Spiral adsorption tower structure and process method for gas purification of biomass derived gas
CN115594205A (en) * 2022-10-17 2023-01-13 东北大学(Cn) Device and method for dust exhaust and heat insulation ring gap of spray pyrolysis furnace

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109550339A (en) * 2017-09-27 2019-04-02 东北大学 A kind of method and device for gathering dust containing volatility valuable element gas with purification
CN112933901A (en) * 2019-12-11 2021-06-11 青岛双瑞海洋环境工程股份有限公司 Integrated device for waste gas desulfurization and inert gas supply
CN111495137A (en) * 2020-04-26 2020-08-07 安徽顺达环保科技股份有限公司 Desulfurization and denitrification equipment and method for industrial flue gas catalytic cracking
CN113230870A (en) * 2020-12-15 2021-08-10 岑顺彬 Desulfurizing tower dual cycle wet process filtration system for chemical production
CN113230870B (en) * 2020-12-15 2022-07-01 山东莱钢节能环保工程有限公司 Desulfurizing tower dual cycle wet process filtration system for chemical production
CN114917716A (en) * 2022-05-23 2022-08-19 广州兴丰能源科技有限公司 Spiral adsorption tower structure and process method for gas purification of biomass derived gas
CN115594205A (en) * 2022-10-17 2023-01-13 东北大学(Cn) Device and method for dust exhaust and heat insulation ring gap of spray pyrolysis furnace
CN115594205B (en) * 2022-10-17 2023-09-19 东北大学 A dust exhaust and heat insulation annular device and method for a spray pyrolysis furnace

Similar Documents

Publication Publication Date Title
CN206343056U (en) A kind of high efficiency removes the water washing device of aerosol
CN206566678U (en) A kind of spray column
CN205570081U (en) Two district's circulation desulfurization column equipment
CN207871876U (en) A kind of wet desulphurization swirling flow atomizing spray equipment
CN206778108U (en) A kind of rotary spraying type water dust scrubber
CN102343215A (en) Dual-chamber multi-absorption wet flue gas desulfurizing device
CN205886590U (en) Gas wash tower and SOx/NOx control system
CN206064045U (en) A kind of desulfurized dust collection column
CN202191835U (en) Granite spraying desulphurization equipment
CN203235395U (en) Flue gas desulfurization equipment
CN203540266U (en) Exhaust gas purifying tower
CN205182373U (en) Desulfurization dust collecting tower
CN202844856U (en) Double-tower type quenching and spraying desulfuration and purification integrated smoke purification device
CN106823619B (en) One kind penetrating liquid film absorption plant
CN2808276Y (en) Large-volume high-concentration fume purifying equipment
CN109550339A (en) A kind of method and device for gathering dust containing volatility valuable element gas with purification
CN201799202U (en) Combined waste gas treatment device of tornado tower
CN203355524U (en) Spray tower
CN114146538B (en) Absorption dust removal tower and dust removal method thereof
CN201848202U (en) Novel cyclone waste gas absorption tower
CN202044892U (en) Reverse-umbrella type directional liquid film smoke-elimination dust-collection desulfurization and denitrification unit
CN207307591U (en) High-efficiency desulfurizing scrubber
CN206229146U (en) A kind of rotational flow and spray combination unit of efficient desulfurizing and dust collecting
CN205461734U (en) Desulfurization and prevent scale deposit integration system
CN206483267U (en) A kind of duct type gas treatment equipment

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20171020