CN107254783A - Improve the method and system of processing of synthetic leather peel strength - Google Patents

Improve the method and system of processing of synthetic leather peel strength Download PDF

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Publication number
CN107254783A
CN107254783A CN201710701975.0A CN201710701975A CN107254783A CN 107254783 A CN107254783 A CN 107254783A CN 201710701975 A CN201710701975 A CN 201710701975A CN 107254783 A CN107254783 A CN 107254783A
Authority
CN
China
Prior art keywords
hopper
peel strength
scraper
synthetic leather
knife
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710701975.0A
Other languages
Chinese (zh)
Inventor
吴立东
李新弟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG SUNENEW SYNTHETIC LEATHER CO Ltd
Original Assignee
ZHEJIANG SUNENEW SYNTHETIC LEATHER CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG SUNENEW SYNTHETIC LEATHER CO Ltd filed Critical ZHEJIANG SUNENEW SYNTHETIC LEATHER CO Ltd
Priority to CN201710701975.0A priority Critical patent/CN107254783A/en
Publication of CN107254783A publication Critical patent/CN107254783A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/04Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface with blades
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C3/00Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material
    • B05C3/02Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material
    • B05C3/12Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length
    • B05C3/125Apparatus in which the work is brought into contact with a bulk quantity of liquid or other fluent material the work being immersed in the liquid or other fluent material for treating work of indefinite length the work being a web, band, strip or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C9/00Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important
    • B05C9/06Apparatus or plant for applying liquid or other fluent material to surfaces by means not covered by any preceding group, or in which the means of applying the liquid or other fluent material is not important for applying two different liquids or other fluent materials, or the same liquid or other fluent material twice, to the same side of the work
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1664Releasability
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

Abstract

The invention discloses the method and system of processing for improving synthetic leather peel strength, this method is first to be unreeled and pre-processed, then using scraper, and one layer of clear material is scraped in scrim surfaces, and the constituent expected clearly is pure polyurethane and DMF;Then using knife is applied, one layer of slurry is applied on surface, the constituent of slurry is polyurethane and inserts;Solidified, washed and dried successively again, got product;The system of processing built according to the above method, it includes being provided with the first hopper (4) and the second hopper (5) above the delivery platform (2) of transmission base fabric (1), delivery platform (2);Pure polyurethane (6) is provided with first hopper (4), the side of the first hopper (4) is connected with scraper (7);Filling polyurethane material (8) is provided with second hopper (5), the side of the second hopper (5) is connected with painting knife (9).The present invention can not only improve peel strength, increase the service life, and also have the advantages that safety in utilization is good.

Description

Improve the method and system of processing of synthetic leather peel strength
Technical field
It is particularly a kind of to improve synthetic leather peel strength the present invention relates to a kind of processing method of synthetic leather and system of processing Method and system of processing.
Background technology
Existing synthetic leather, typically all using the method processing that one layer of layer of polyurethane is applied in scrim surfaces;Poly- ammonia therein Ester layer is slurry, is typically made up of by a certain percentage polyurethane and inserts.But, the top layer (layer of polyurethane) of this synthetic leather Bonding strength with nexine (base fabric) is relatively low, the situation that layer of polyurethane comes off easily occurs, especially with middle by other objects When catching on, easily it is stripped, peel strength is relatively low, service life is shorter.If adding glue layer between top layer and nexine to carry High bonding strength, then can cause content of formaldehyde excessive, can influence the health of user, safety in utilization is undesirable.Therefore, it is existing Synthetic leather the problem of there is relatively low peel strength, shorter service life and undesirable safety in utilization.
The content of the invention
It is an object of the present invention to provide a kind of method and system of processing for improving synthetic leather peel strength.The present invention is not Peel strength can be only improved, is increased the service life, also has the advantages that safety in utilization is good.
Technical scheme:The method for improving synthetic leather peel strength, comprises the following steps:
A, unreel;
B, the base fabric for unreeling out is pre-processed, obtain B product;
C, using scraper, one layer of clear material is scraped on B product surface, the constituent expected clearly is pure polyurethane and DMF, obtains C product;
D, using knife is applied, one layer of slurry is applied on C product surface, the constituent of slurry is polyurethane and inserts, obtains D product;
F, solidification;
G, washing;
H, drying, obtain finished product.
In the method for foregoing raising synthetic leather peel strength, one layer of thickness expected clearly is scraped for 0.2mm in the step c ~0.8mm.
In the method for foregoing raising synthetic leather peel strength, the thickness of one layer of slurry of painting in the step d is 1.5mm ~2.5mm.
In the method for foregoing raising synthetic leather peel strength, being solidified as in the step f is solid into water-setting, and the time is 8min~12min;Washing in the step g removes DMF for washing, and washing temperature is 25 DEG C~30 DEG C;In the step h Drying time is 5min~10min, and drying temperature is 130 DEG C~150 DEG C.
According to the system of processing constructed by the method for foregoing raising synthetic leather peel strength, include the transmission of transmission base fabric The first hopper and the second hopper are provided with above platform, delivery platform;Pure polyurethane, the one of the first hopper are provided with first hopper Side is connected with scraper;Filling polyurethane material is provided with second hopper, the side of the second hopper is connected with painting knife.
In foregoing system of processing, the distance between the scraper bottom and base fabric are 0.2mm~0.8mm.
In foregoing system of processing, the distance between the knife bottom and base fabric of applying is 1.5mm~2.5mm.
In foregoing system of processing, feed pipe is provided with first hopper and the second hopper.
In foregoing system of processing, the scraper side and painting knife side are respectively connected with banking stop, and scraper is located at the first material Between groove and banking stop, cutter spacing is applied between the second hopper and banking stop;Walking speed of the base fabric on delivery platform is 8m/min.
Compared with prior art, the present invention devises a kind of method and system of processing for improving synthetic leather peel strength;First By scraper, the clear material of one layer of 0.2mm~0.8mm thickness is scraped in scrim surfaces, i.e., the pure poly- ammonia of last layer is scraped in base fabric upper surface The compound of ester and DMF;Then again by applying cutter painting last layer slurry, i.e., a strata urethane is coated in clear bed of material upper surface and is filled out The compound of charge;Transition bonding is carried out using pure polyurethane, so that the bonding strength of slurry is improved, without glue layer In the case of, the bonding strength between top layer and nexine is improved, the peel strength of finished product is improved, removed from office compared to conventional synthesis The peel strength of 0.5~0.7 kg per cm, peel strength of the invention can be improved to 0.9~1.2 kg per cm, no Peel strength can be only improved, is increased the service life, additionally it is possible to avoids formaldehyde unhealthful, safety in utilization is good.In addition, this hair It is bright also by enter the solid 8min~12min of water-setting, 25 DEG C~30 DEG C washings remove DMF and 130 DEG C~150 DEG C drying 5min~ 10min, to solidify the clear bed of material and pulp layer and remove DMF therein, forms constitutionally stable finished product.Therefore, the present invention not only Peel strength can be improved, is increased the service life, also has the advantages that safety in utilization is good.
Brief description of the drawings
Fig. 1 is the structural representation of the present invention.
Mark in accompanying drawing for:1- base fabrics, 2- delivery platforms, the hoppers of 3- first, the hoppers of 4- second, the pure polyurethane of 5-, 6- Scraper, 7- filling polyurethane material, 8- applies knife, 9- feed pipes, 10- banking stops.
Embodiment
With reference to embodiment, the present invention is further illustrated, but is not intended as to the foundation of the invention limited.
Embodiment one.The method for improving synthetic leather peel strength, comprises the following steps:
A, unreel;
B, the base fabric 1 for unreeling out is pre-processed, obtain B product;
C, as shown in figure 1, using scraper 6, scrape one layer of clear material on B product surface, the constituent expected clearly be pure polyurethane and DMF, obtains C product;
D, as shown in figure 1, using knife 8 is applied, one layer of slurry is applied on C product surface, the constituent of slurry is polyurethane and fills out Charge, obtains D product;
F, solidification;
G, washing;
H, drying, obtain finished product.
One layer of thickness expected clearly is scraped for 0.2mm~0.8mm in the step c;One layer of slurry of painting in the step d Thickness is 1.5mm~2.5mm;Being solidified as in the step f is solid into water-setting, and the time is 8min~12min;In the step g Washing for washing remove DMF, washing temperature be 25 DEG C~30 DEG C;Drying time in the step h is 5min~10min, Drying temperature is 130 DEG C~150 DEG C.
According to the system of processing constructed by the method for foregoing raising synthetic leather peel strength, constitute as shown in figure 1, including The delivery platform 2 of base fabric 1 is transmitted, the top of delivery platform 2 is provided with the first hopper 3 and the second hopper 4;It is provided with first hopper 3 Pure polyurethane 5 (pure polyurethane 5 is clear material, includes pure polyurethane and DMF), the side of the first hopper 3 is connected with scraper 6;Second Provided with filling polyurethane material 7 (filling polyurethane material 7 is slurry, includes polyurethane and inserts) in hopper 4, the second hopper 4 Side is connected with painting knife 8.
The distance between the bottom of scraper 6 and base fabric 1 are 0.2mm~0.8mm;Between the painting bottom of knife 8 and base fabric 1 Distance be 1.5mm~2.5mm;Feed pipe 9 is provided with the hopper 4 of first hopper 3 and second;The side of scraper 6 Banking stop 10 is respectively connected with the side of knife 8 is applied, scraper 6 is located between the first hopper 3 and banking stop 10, applies knife 8 and is located at the second material Between groove 4 and banking stop 10.
Embodiment two, the method for improving synthetic leather peel strength, comprise the following steps:
A, unreel;
B, the base fabric 1 for unreeling out is pre-processed, obtain B product;
C, as shown in figure 1, using scraper 6, scrape one layer of clear material on B product surface, the constituent expected clearly be pure polyurethane and DMF, obtains C product;
D, as shown in figure 1, using knife 8 is applied, one layer of slurry is applied on C product surface, the constituent of slurry is polyurethane and fills out Charge, obtains D product;
F, solidification;
G, washing;
H, drying, obtain finished product.
One layer of thickness expected clearly is scraped for 0.5mm in the step c;The thickness of one layer of slurry of painting in the step d is 2mm;Being solidified as in the step f is solid into water-setting, and the time is 10min;Washing in the step g removes DMF, water for washing Temperature is washed for 25 DEG C~30 DEG C;Drying time in the step h is 5min~10min, and drying temperature is 140 DEG C.
According to the system of processing constructed by the method for foregoing raising synthetic leather peel strength, constitute as shown in figure 1, including The delivery platform 2 of base fabric 1 is transmitted, the top of delivery platform 2 is provided with the first hopper 3 and the second hopper 4;It is provided with first hopper 3 Pure polyurethane 5 (pure polyurethane 5 is clear material, includes pure polyurethane and DMF), the side of the first hopper 3 is connected with scraper 6;Second Provided with filling polyurethane material 7 (filling polyurethane material 7 is slurry, includes polyurethane and inserts) in hopper 4, the second hopper 4 Side is connected with painting knife 8.
The distance between the bottom of scraper 6 and base fabric 1 are 0.5mm;It is described to apply the distance between the bottom of knife 8 and base fabric 1 For 2.5mm;Feed pipe 9 is provided with the hopper 4 of first hopper 3 and second;The side of scraper 6 and painting knife 8 side are equal Banking stop 10 is connected with, scraper 6 is located between the first hopper 3 and banking stop 10, applies knife 8 and be located at the second hopper 4 and banking stop 10 Between.
Operation principle:In use, delivery platform 2 transmits base fabric 1 along the direction of arrow in Fig. 1, the first material is first passed through Feed pipe 9 in groove 3 and scraper 6, the first hopper 3 inputted into the first hopper 3 pure polyurethane 5 (clear material, be pure polyurethane and DMF is mixed);Banking stop 10 overlays scraper 6 on the first hopper 3, and the pure polyurethane 5 in the first hopper 3 is flow to along scraper 6 In base fabric 1;Because base fabric 1 is moved relative to scraper 6, the distance between scraper 6 and base fabric 1 are 0.5mm, so scraper 6 is in base The clear bed of material that last layer thickness is 0.5mm is scraped on cloth 1;Then, base fabric 1 is by the second hopper 4 and applies in knife 8, the second hopper 4 Feed pipe 9 inputs filling polyurethane material 7 into the second hopper 4 (slurry is polyurethane and inserts mixing);Similarly, banking stop 10 are overlayed knife 8 is applied on the second hopper 4, and the filling polyurethane material 7 in the second hopper 4 is flow on the clear bed of material along knife 8 is applied, and are applied Knife 8 coats the pulp layer that a layer thickness is 2mm on the clear bed of material;Transition is carried out using the clear bed of material between pulp layer and base fabric to glue Close, improve bonding of the pulp layer in base fabric, that is, the bonding strength between top layer and nexine is improved, so as to improve finished product Peel strength, extends service life.
Peel strength contrast test is as shown in the table:Wherein A, B, C are conventionally produced synthetic leather, and D, E, F are this The synthetic leather of invented technology production.
Sample Maximum, force (kg) used when peeling off 1cm width
A 0.53
B 0.65
C 0.58
D 1.16
E 0.98
F 1.07

Claims (9)

1. improve the method for synthetic leather peel strength, it is characterised in that comprise the following steps:
A, unreel;
B, the base fabric for unreeling out is pre-processed, obtain B product;
C, using scraper, one layer of clear material is scraped on B product surface, the constituent expected clearly is pure polyurethane and DMF, obtains C product;
D, using knife is applied, one layer of slurry is applied on C product surface, the constituent of slurry is polyurethane and inserts, obtains D product;
F, solidification;
G, washing;
H, drying, obtain finished product.
2. the method according to claim 1 for improving synthetic leather peel strength, it is characterised in that:Scraping in the step c One layer of thickness expected clearly is 0.2mm~0.8mm.
3. the method according to claim 1 for improving synthetic leather peel strength, it is characterised in that:Painting in the step d The thickness of one layer of slurry is 1.5mm~2.5mm.
4. the method for the raising synthetic leather peel strength according to claim 1,2 or 3, it is characterised in that:In the step f Be solidified as solid into water-setting, the time is 8min~12min;Washing in the step g removes DMF for washing, and washing temperature is 25 DEG C~30 DEG C;Drying time in the step h is 5min~10min, and drying temperature is 130 DEG C~150 DEG C.
5. according to adding constructed by the method for the raising synthetic leather peel strength described in any claim in Claims 1-4 Work system, it is characterised in that:Include being provided with the first hopper above the delivery platform (2) of transmission base fabric (1), delivery platform (2) And the second hopper (4) (3);Pure polyurethane (5) is provided with first hopper (3), the side of the first hopper (3) is connected with scraper (6); Filling polyurethane material (7) is provided with second hopper (4), the side of the second hopper (4) is connected with painting knife (8).
6. system of processing according to claim 5, it is characterised in that:Between scraper (6) bottom and base fabric (1) away from From for 0.2mm~0.8mm.
7. system of processing according to claim 5, it is characterised in that:It is described apply between knife (8) bottom and base fabric (1) away from From for 1.5mm~2.5mm.
8. system of processing according to claim 5, it is characterised in that:In first hopper (3) and the second hopper (4) It is provided with feed pipe (9).
9. the system of processing according to any claim in claim 5 to 8, it is characterised in that:Scraper (6) side Banking stop (10) is respectively connected with knife (8) side is applied, scraper (6) is located between the first hopper (3) and banking stop (10), applies knife (8) it is located between the second hopper (4) and banking stop (10).
CN201710701975.0A 2017-08-16 2017-08-16 Improve the method and system of processing of synthetic leather peel strength Pending CN107254783A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710701975.0A CN107254783A (en) 2017-08-16 2017-08-16 Improve the method and system of processing of synthetic leather peel strength

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710701975.0A CN107254783A (en) 2017-08-16 2017-08-16 Improve the method and system of processing of synthetic leather peel strength

Publications (1)

Publication Number Publication Date
CN107254783A true CN107254783A (en) 2017-10-17

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710701975.0A Pending CN107254783A (en) 2017-08-16 2017-08-16 Improve the method and system of processing of synthetic leather peel strength

Country Status (1)

Country Link
CN (1) CN107254783A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103981729A (en) * 2014-05-07 2014-08-13 安安(中国)有限公司 Aqueous polyurethane making method used for superfine fiber synthetic leather production
CN104878615A (en) * 2015-06-23 2015-09-02 佛山市飞凌皮革化工有限公司 Solvent-free synthetic leather production method using rotation teflon and specially-used production line
CN105113267A (en) * 2015-09-02 2015-12-02 安徽安利材料科技股份有限公司 Method for preparing anti-siphon hydrolysis-resistant polyurethane synthetic leather
CN105603736A (en) * 2016-01-19 2016-05-25 陕西科技大学 Preparation method of low-smoke-amount high-flame-retardancy synthetic leather
CN205463013U (en) * 2016-04-01 2016-08-17 江西科技学院 Automatic change gluey equipment that spouts
CN106269388A (en) * 2016-08-19 2017-01-04 南通皋鑫电子股份有限公司 High-voltage diode inside courtyard apparatus for coating

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103981729A (en) * 2014-05-07 2014-08-13 安安(中国)有限公司 Aqueous polyurethane making method used for superfine fiber synthetic leather production
CN104878615A (en) * 2015-06-23 2015-09-02 佛山市飞凌皮革化工有限公司 Solvent-free synthetic leather production method using rotation teflon and specially-used production line
CN105113267A (en) * 2015-09-02 2015-12-02 安徽安利材料科技股份有限公司 Method for preparing anti-siphon hydrolysis-resistant polyurethane synthetic leather
CN105603736A (en) * 2016-01-19 2016-05-25 陕西科技大学 Preparation method of low-smoke-amount high-flame-retardancy synthetic leather
CN205463013U (en) * 2016-04-01 2016-08-17 江西科技学院 Automatic change gluey equipment that spouts
CN106269388A (en) * 2016-08-19 2017-01-04 南通皋鑫电子股份有限公司 High-voltage diode inside courtyard apparatus for coating

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