CN107254295A - One kind is without asbestos low metal automotive friction material - Google Patents
One kind is without asbestos low metal automotive friction material Download PDFInfo
- Publication number
- CN107254295A CN107254295A CN201710708838.XA CN201710708838A CN107254295A CN 107254295 A CN107254295 A CN 107254295A CN 201710708838 A CN201710708838 A CN 201710708838A CN 107254295 A CN107254295 A CN 107254295A
- Authority
- CN
- China
- Prior art keywords
- friction material
- raw material
- low metal
- yarn
- asbestos
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002783 friction material Substances 0.000 title claims abstract description 37
- 239000010425 asbestos Substances 0.000 title claims abstract description 23
- 229910052895 riebeckite Inorganic materials 0.000 title claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 21
- 239000002184 metal Substances 0.000 title claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 12
- 239000000919 ceramic Substances 0.000 claims abstract description 8
- 239000012779 reinforcing material Substances 0.000 claims abstract description 8
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 7
- -1 polypropylene Polymers 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 239000011230 binding agent Substances 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 claims abstract description 5
- 239000000945 filler Substances 0.000 claims abstract description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 239000005864 Sulphur Substances 0.000 claims description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 239000010439 graphite Substances 0.000 claims description 5
- 229910002804 graphite Inorganic materials 0.000 claims description 5
- 238000000227 grinding Methods 0.000 claims description 5
- 238000007731 hot pressing Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229920001568 phenolic resin Polymers 0.000 claims description 5
- 238000007592 spray painting technique Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000010456 wollastonite Substances 0.000 claims description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000003902 lesion Effects 0.000 description 1
- 201000005202 lung cancer Diseases 0.000 description 1
- 208000020816 lung neoplasm Diseases 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002685 pulmonary effect Effects 0.000 description 1
- 230000036301 sexual development Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/149—Antislip compositions
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
- F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
- F16D69/02—Composition of linings ; Methods of manufacturing
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Braking Arrangements (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
It is a kind of to be constituted without asbestos low metal automotive friction material, including following percentage by weight raw material：Reinforcing material 45% ~ 50%, binding agent 20% ~ 25%, filler 15% ~ 28%, auxiliary additive 1% ~ 5%, the reinforcing material includes glass composite yarn, core yarn, aramid fiber core spun yarn, polypropylene fibre and ceramic fibre.Friction material proposed by the invention has good anti-wear performance, simultaneously, with excellent flexility, the problem of content of metal is very low in material, solves friction material easy-to-rust, and noise is big during work, and it is low to prepare cost, environment is safe from harm, coefficient of friction is more stable, service life is longer.
Description
Technical field
The present invention relates to friction materials technology field, and in particular to one kind is without asbestos low metal automotive friction material.
Background technology
Friction material is for playing transmission, braking, deceleration, steering, parking etc. in many movable machineries and equipment
Since functional accessory, it may be said that having mechanical movement, the mankind just have a requirement of skidding, and wooden unit, ox-hide, rubber etc. were all once
Through being used as brake material.Before the 1970s and 1980s in last century asbestos friction material as traditional product always by people
Class is largely used, after this, because known widely asbestos can cause pulmonary lesion and celiothelioma and relevant with the generation of lung cancer.
International medical oncology discussion in 1972 confirms that asbestos fibre contains carcinogen, hereafter, friction goods without asbestos and nothing
Pollutionization is increasingly becoming the common recognition of world's sexual development.
With the development and the raising of modern society's environmental consciousness of auto industry, the condition of work of automotive brake friction material
It is increasingly harsher, to its performance requirement also more and more higher, for example require brake friction material have enough and stable coefficient of friction,
Good thermal conductivity, larger thermal capacity, certain high temperature mechanical strength, good wearability and block resistance, it is difficult scratch
Mating plate, noiseless, low cost, environmentally safe etc..Current most widely used brake friction material has two classes, and a class is
Using the semimetal braking friction material of Stainless-steel fibre, the shortcoming of this kind of material is to cause product when dosage of steel fiber is excessive
Excessive high hardness, easy-to-rust, easily cause shriek and produce and tremble during braking；Another kind of is without asbestos organic friction material, mainly
Be addition glass fibre, potassium titanate crystal whisker or Fanglun slurry cake etc. as reinforcing material, but aramid fiber is expensive, shredding compared with
Difficult the problems such as, limits the application of the material.
Therefore, in view of the above-mentioned problems, the present invention proposes a kind of new technical scheme.
The content of the invention
It is free of contamination without asbestos low metal car it is an object of the invention to provide a kind of pliability is good, noise is low, wearability good
Use friction material.
The present invention is achieved through the following technical solutions：
It is a kind of to be constituted without asbestos low metal automotive friction material, including following percentage by weight raw material：Reinforcing material 45% ~ 50%,
Binding agent 20% ~ 25%, filler 15% ~ 28%, auxiliary additive 1% ~ 5%, the reinforcing material includes glass composite yarn, core spun yarn
Line, aramid fiber core spun yarn, polypropylene fibre and ceramic fibre.
Further, the reinforcing material includes the raw material composition of following percentage by weight：Glass composite yarn 0 ~ 45%, bag
Heart yarn 0 ~ 35%, aramid fiber core spun yarn 0 ~ 40%, polypropylene fibre 1% ~ 10%, ceramic fibre 3 ~ 10%.
Further, the binding agent includes the raw material composition of following percentage by weight：Phenol-formaldehyde resin modified 10% ~ 12%,
Butadiene-styrene rubber 10 ~ 13%.
Further, the filler includes the raw material composition of following percentage by weight：Sulphur 5% ~ 6%, zinc oxide 5% ~ 6%,
Barium sulfate 1% ~ 2%, graphite 2% ~ 5%, diatomite 1% ~ 2%, carbon black 0 ~ 5%, mica powder 1% ~ 3%, acicular wollastonite 1% ~ 4%, iron oxide
0~1.5%。
A kind of preparation method without asbestos low metal automotive friction material, comprises the following steps：
A, by above-mentioned percentage by weight weigh required raw material, then by each raw material be put into stirring mixing 20 in batch mixer ~
30min；
B, the material mixed be put into hot forming machine carry out hot forming, in hot pressing temperature control 150 DEG C ~
200 DEG C, Stress control is in 10 ~ 25MPa, and the press time is 5 ~ 10min；
C, compressing product is put into baking box, first by 135 DEG C ~ 150 DEG C of temperature, is incubated 1.5 ~ 2h, then temperature is risen to 180
DEG C ~ 220 DEG C, 1 ~ 1.5h is incubated, room temperature is finally cooled to；
D, by the product of cooling pass through grinding, spray painting processing and annex assembly process, you can to required friction material.
The beneficial effects of the invention are as follows：Friction material proposed by the invention has good anti-wear performance, meanwhile, have
The content of metal is very low in excellent flexility, material, solves friction material easy-to-rust, and noise asking greatly during work
Topic, and preparation cost is low, environment is safe from harm, coefficient of friction is more stable, service life is longer.
Embodiment
The present invention is described further with reference to embodiment.
Embodiment 1
It is a kind of to be constituted without asbestos low metal automotive friction material, including following percentage by weight raw material：
Glass composite yarn 45%, polypropylene fibre 5%, ceramic fibre 5%, phenol-formaldehyde resin modified 10%, butadiene-styrene rubber 10%, sulphur 5%,
Zinc oxide 5%, barium sulfate 2%, graphite 2%, diatomite 1%, carbon black 4%, mica powder 2%, acicular wollastonite 2%, auxiliary additive 2%,
A kind of preparation method without asbestos low metal automotive friction material, comprises the following steps：
A, by above-mentioned percentage by weight required raw material are weighed, each raw material are then put into stirring mixing 20min in batch mixer；
B, the material mixed is put into hot forming machine carries out hot forming, temperature control is at 150 DEG C in hot pressing, pressure
Power is controlled in 13MPa, and the press time is 5min；
C, compressing product is put into baking box, first by 135 DEG C of temperature, is incubated 1.5h, then temperature is risen into 180 DEG C, insulation
1h, is finally cooled to room temperature；
D, by the product of cooling pass through grinding, spray painting processing and annex assembly process, you can to required friction material.
Embodiment 2
It is a kind of to be constituted without asbestos low metal automotive friction material, including following percentage by weight raw material：
Core yarn 35%, polypropylene fibre 6%, ceramic fibre 8%, phenol-formaldehyde resin modified 12%, butadiene-styrene rubber 12%, sulphur 5%, oxygen
Change zinc 5%, barium sulfate 2%, graphite 5%, diatomite 2%, carbon black 5%, acicular wollastonite 2%, auxiliary additive 1%.
A kind of preparation method without asbestos low metal automotive friction material, comprises the following steps：
A, by above-mentioned percentage by weight required raw material are weighed, each raw material are then put into stirring mixing 25min in batch mixer；
B, the material mixed is put into hot forming machine carries out hot forming, temperature control is at 155 DEG C in hot pressing, pressure
Power is controlled in 15MPa, and the press time is 8min；
C, compressing product is put into baking box, first by 145 DEG C of temperature, is incubated 2h, then temperature is risen into 200 DEG C, insulation
1.5h, is finally cooled to room temperature；
D, by the product of cooling pass through grinding, spray painting processing and annex assembly process, you can to required friction material.
Embodiment 3
It is a kind of to be constituted without asbestos low metal automotive friction material, including following percentage by weight raw material：
Aramid fiber core spun yarn 40%, polypropylene fibre 6%, ceramic fibre 5%, phenol-formaldehyde resin modified 10%, butadiene-styrene rubber 12.5%, sulphur
6%, zinc oxide 3%, barium sulfate 2%, graphite 4%, diatomite 2%, carbon black 4%, acicular wollastonite 2%, iron oxide 1.5%, auxiliary addition
Agent 2%,
A kind of preparation method without asbestos low metal automotive friction material, comprises the following steps：
A, by above-mentioned percentage by weight required raw material are weighed, each raw material are then put into stirring mixing 30min in batch mixer；
B, the material mixed is put into hot forming machine carries out hot forming, temperature control is at 200 DEG C in hot pressing, pressure
Power is controlled in 25MPa, and the press time is 10min；
C, compressing product is put into baking box, first by 150 DEG C of temperature, is incubated 1.5 ~ 2h, then temperature is risen into 220 DEG C, guarantor
Warm 1.5h, is finally cooled to room temperature；
D, by the product of cooling pass through grinding, spray painting processing and annex assembly process, you can to required friction material.
Friction material proposed by the invention has good anti-wear performance, meanwhile, with excellent flexility, material
The problem of content of interior metal is very low, solves friction material easy-to-rust, and noise is big during work, and it is low to prepare cost,
Environment is safe from harm, coefficient of friction is more stable, service life is longer.
It is described above, only it is embodiments of the invention, is not the limitation for making any other form to the present invention, and
Any modification made according to embodiment proposed by the invention or equivalent variations, still fall within model claimed of the invention
Enclose.
Claims (5)
1. one kind is without asbestos low metal automotive friction material, it is characterised in that：Including following percentage by weight raw material composition：Enhancing
Material 45% ~ 50%, binding agent 20% ~ 25%, filler 15% ~ 28%, auxiliary additive 1% ~ 5%, the reinforcing material is multiple including glass
Close yarn, core yarn, aramid fiber core spun yarn, polypropylene fibre and ceramic fibre.
2. one kind is without asbestos low metal automotive friction material according to claim 1, it is characterised in that：The reinforcing material bag
Include the raw material composition of following percentage by weight：Glass composite yarn 0 ~ 45%, core yarn 0 ~ 35%, aramid fiber core spun yarn 0 ~ 40%, poly- third
Alkene fiber 1% ~ 5%, ceramic fibre 3 ~ 8%.
3. one kind is without asbestos low metal automotive friction material according to claim 1, it is characterised in that：The binding agent includes
The raw material composition of following percentage by weight：Phenol-formaldehyde resin modified 10% ~ 12%, butadiene-styrene rubber 10 ~ 13%.
4. one kind is without asbestos low metal automotive friction material according to claim 1, it is characterised in that：The filler include with
The raw material composition of lower percentage by weight：Sulphur 5% ~ 6%, zinc oxide 5% ~ 6%, barium sulfate 1% ~ 2%, graphite 2% ~ 5%, diatomite 1% ~
2%, carbon black 0 ~ 5%, mica powder 1% ~ 3%, acicular wollastonite 1% ~ 3%, iron oxide 0 ~ 1.5%.
5. a kind of preparation method without asbestos low metal automotive friction material according to claim 1 ~ 4, it is characterised in that：Bag
Include following steps：
A, by above-mentioned percentage by weight weigh required raw material, then by each raw material be put into stirring mixing 20 in batch mixer ~
30min；
B, the material mixed be put into hot forming machine carry out hot forming, in hot pressing temperature control 150 DEG C ~
200 DEG C, Stress control is in 10 ~ 25MPa, and the press time is 5 ~ 10min；
C, compressing product is put into baking box, first by 135 DEG C ~ 150 DEG C of temperature, is incubated 1.5 ~ 2h, then temperature is risen to 180
DEG C ~ 220 DEG C, 1 ~ 1.5h is incubated, room temperature is finally cooled to；
D, by the product of cooling pass through grinding, spray painting processing and annex assembly process, you can to required friction material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710708838.XA CN107254295A (en) | 2017-08-17 | 2017-08-17 | One kind is without asbestos low metal automotive friction material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710708838.XA CN107254295A (en) | 2017-08-17 | 2017-08-17 | One kind is without asbestos low metal automotive friction material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107254295A true CN107254295A (en) | 2017-10-17 |
Family
ID=60026801
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710708838.XA Pending CN107254295A (en) | 2017-08-17 | 2017-08-17 | One kind is without asbestos low metal automotive friction material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107254295A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203326A (en) * | 1997-06-20 | 1998-12-30 | 宋勤正 | Asbestos-free friction material and producing method thereof |
| CN106084646A (en) * | 2016-06-28 | 2016-11-09 | 东台市华阳玻纤有限责任公司 | A kind of basalt fibre friction material and preparation method thereof |
| CN107504106A (en) * | 2017-07-12 | 2017-12-22 | 苏州翠南电子科技有限公司 | One kind is without asbestos low metal automotive friction material |
-
2017
- 2017-08-17 CN CN201710708838.XA patent/CN107254295A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203326A (en) * | 1997-06-20 | 1998-12-30 | 宋勤正 | Asbestos-free friction material and producing method thereof |
| CN106084646A (en) * | 2016-06-28 | 2016-11-09 | 东台市华阳玻纤有限责任公司 | A kind of basalt fibre friction material and preparation method thereof |
| CN107504106A (en) * | 2017-07-12 | 2017-12-22 | 苏州翠南电子科技有限公司 | One kind is without asbestos low metal automotive friction material |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171017 |
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