CN107254078A - A kind of lightweight rubber soles material - Google Patents

A kind of lightweight rubber soles material Download PDF

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Publication number
CN107254078A
CN107254078A CN201710543021.1A CN201710543021A CN107254078A CN 107254078 A CN107254078 A CN 107254078A CN 201710543021 A CN201710543021 A CN 201710543021A CN 107254078 A CN107254078 A CN 107254078A
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China
Prior art keywords
weight
rubber
parts
lightweight
agent
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Pending
Application number
CN201710543021.1A
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Chinese (zh)
Inventor
黄劲煌
宋光社
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Quanzhou Huayang Shoe Material Science And Technology Co Ltd Jinjiang Branch
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Quanzhou Huayang Shoe Material Science And Technology Co Ltd Jinjiang Branch
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Priority to CN201710543021.1A priority Critical patent/CN107254078A/en
Publication of CN107254078A publication Critical patent/CN107254078A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2206Oxides; Hydroxides of metals of calcium, strontium or barium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/222Magnesia, i.e. magnesium oxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention provides a kind of lightweight rubber soles material, and the lightweight rubber soles material is made up of base-material, reinforcing agent, age resistor, antifoggant, activating agent, vulcanizing agent and accelerator.The features such as lightweight rubber soles material that the present invention is provided has lightweight, long lifespan, elasticity is big, the sole that the lightweight elastomeric material provided using the present invention is manufactured not only has the very long life-span, and with high comfortableness, moreover, due to the special molecular structure of lightweight rubber, the characteristics of its material is maximum is to be not required to severing, it is not required that open molding jig in addition, production cost is reduced, very high commercial value is made it have.

Description

A kind of lightweight rubber soles material
Technical field
The present invention relates to rubber sole formula, specifically, it is related to a kind of lightweight rubber soles material.
Background technology
With expanding economy and the progress of society, the income level and living standard of people are also improved therewith, people couple The demand of life comfort level also more and more higher.Shoes are indispensable daily necessitiess in people's daily life, and everybody is to shoes Use also constantly propose new requirement.Traditional shoe sole production material mainly has rubber, PU, PVC, MD, TPR, TPU and EVA It is always the raw material that the domestic line brand of footwear one is favored Deng, rubber soles with its advantage such as wear-resisting, anti-skidding, not easy to break, But traditional rubber soles have the problems such as weight is larger, virtually increase the physical consumption of wearer, while to foot joint again Damage it is also very big, make the comfortableness of its footwear relatively low, make its commercially pouplarity reduce.
The content of the invention
In order to solve above-mentioned the deficiencies in the prior art part, it is an object of the invention to provide a kind of lightweight rubber boots ground Material, to overcome defect of the prior art.
To achieve these goals, the invention provides a kind of lightweight rubber soles material, the lightweight elastomeric material bag Include:45~55 parts by weight base-materials, 15.3~25.5 parts by weight reinforcing agents, 1.3~3 parts by weight age resistor, 0.6~2 parts by weight are prevented Mist agent, 2.5~4.5 parts by weight of activated doses, 1~1.5 parts by weight vulcanizing agent, 0.4~0.6 parts by weight accelerator.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the base-material is selected from by poly- fourth The group of diene rubber and fluorubber composition.It is highly preferred that the base-material includes 40~45 parts by weight of polybutadiene rubber and 5~10 Parts by weight fluorubber.Most preferably, the base-material includes 42 parts by weight of polybutadiene rubber and 6 parts by weight fluorubber.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the reinforcing agent is selected from by gathering What carbonic ester (double (4- hydroxy phenyls) the propane makrolon of also referred to as 2,2'- or IR2200), white cigarette and styrene (ST) were constituted Group, wherein, the white cigarette is more than 95% hydration SiO2With a small amount of Al2O3、Fe2O3, MgO, CaO and NaO composition mixing Thing.It is highly preferred that the reinforcing agent includes 10~15 weight part polycarbonates, 5~10 parts by weight white cigarettes and 0.3~0.5 weight Part styrene.Most preferably, the reinforcing agent includes 12 weight part polycarbonates, 6 parts by weight white cigarettes and 0.36 parts by weight benzene second Alkene.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the age resistor is selected from by rubber The group of glue antioxidant MB and PEG4000 compositions, wherein the rubber antioxidant MB is 2- mercapto benzimidazoles.It is highly preferred that The age resistor includes 0.3~0.5 parts by weight of rubber antioxidant MB and 1~2.5 parts by weight PEG4000.Most preferably, it is described anti- Old agent includes 0.36 parts by weight of rubber antioxidant MB and 1.8 parts by weight PEG4000.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the antifoggant is selected from by preventing The group that creme SK and rubber antifoggant 1956 are constituted is told, wherein the anti-creme SK that tells is available commercially from Margaret Abbott (Jinjiang) rubber science and technology Co., Ltd, the rubber antifoggant 1956 is available commercially from Gaoyi Jin Hong chemical plant.It is highly preferred that the antifoggant include 0.5~ 1.5 parts by weight are anti-to tell creme SK and 0.1~0.5 parts by weight of rubber antifoggant 1956.Most preferably, the antifoggant includes 1 weight Amount part is anti-to tell creme SK and 0.3 parts by weight of rubber antifoggant 1956.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the activating agent is selected from by white The group of smoke active agent and zinc oxide composition, wherein the white smoke active agent is 25% pentaerythrite, 70% Meng's alkane ethamine and 5%N- The mixture of cyclohexyl-2-benzothiazole sulfonamide composition.It is highly preferred that the activating agent is lived including 1~2 parts by weight white cigarette Property agent and 1.5~2.5 part by weight of zinc oxide.Most preferably, the activating agent includes 1.5 parts by weight white smoke active agents and 2 weight Part zinc oxide.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the vulcanizing agent is S-80, its Described in S-80 to pass through the pre-dispersed obtained sulphur of 80% sulphur and 20% high polymer (ethylene propylene diene rubber, acrylic rubber etc.) Sulphur master batch.It is highly preferred that the vulcanizing agent includes 0.95~1.4 parts by weight S-80.Most preferably, the vulcanizing agent includes 0.96 Parts by weight S-80.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the accelerator is selected from by rubber Promoter for rubber TS-80, rubber accelerator DM and rubber accelerator DPG compositions group, wherein the rubber accelerator TS-80 is one Vulcanize the adhesive bond of tetra methylthiuram, the rubber accelerator DM is 2, and 2 '-dithio-bis-benzothiazole, the rubber promotes Agent DPG is diphenylguanidine (being also referred to as thiofide DPG, 1,3- diphenylguanidine, N, N '-diphenylguanidine or melaniline). Promote it is highly preferred that the accelerator includes 0.05~0.1 parts by weight of rubber accelerator TS-80,0.35~0.5 parts by weight of rubber Agent DM and 0.05~0.1 parts by weight of rubber diphenylguanidine PG.Most preferably, the accelerator promotes including 0.08 parts by weight of rubber Agent TS-80,0.4 parts by weight of rubber altax and 0.08 parts by weight of rubber diphenylguanidine PG.
Further illustrated as to lightweight elastomeric material of the present invention, it is preferable that the lightweight elastomeric material bag Include 42 parts by weight of polybutadiene rubber, 6 parts by weight fluorubber, 12 weight part polycarbonates, 6 parts by weight white cigarettes, 0.36 parts by weight Styrene, 0.36 parts by weight of rubber antioxidant MB, 1.8 parts by weight PEG4000,1 parts by weight are anti-to tell creme SK, 0.3 parts by weight rubber Glue antifoggant 1956,1.5 parts by weight white smoke active agents, 2 part by weight of zinc oxide, 0.96 parts by weight vulcanizing agent S-80,0.08 weight Part rubber accelerator TS-80,0.4 parts by weight of rubber altax and 0.08 parts by weight of rubber diphenylguanidine PG.
The detection performance of lightweight rubber soles material provided by the present invention is as shown in table 1, of the present invention as shown in Table 1 Lightweight rubber soles material proportion be less than 1g/cm3, less than 1.05~1.25g/ of general proportion index of traditional rubber sole cm3, weight reduction 10% significantly reduces the weight of sole, and the material has good abrasion resistance, extensibility and anti- Tear resistance, using the sole of the material manufacture is lightweight, long lifespan and with elasticity well, reduces wearer's foot fatigue Degree, makes dress lighter comfortable, moreover, due to the special molecular structure of lightweight rubber, the characteristics of its material is maximum It is to be not required to severing, it is not required that open molding jig in addition, reduces production cost, make it have very high commercial value.
The lightweight elastomeric material of table 1 detects performance
Embodiment
It is detailed in conjunction with appended preferred embodiment in order to further appreciate that structure, feature and the other purposes of the present invention Carefully it is described as follows, embodiment is merely to illustrate technical scheme, and the non-limiting present invention.
Polybutadiene rubber that the present invention is provided, fluorubber, makrolon, white cigarette, styrene, rubber antioxidant MB, PEG4000, anti-tell creme SK, rubber antifoggant 1956, white smoke active agent, zinc oxide, vulcanizing agent S-80, rubber accelerator TS- 80th, rubber accelerator DM and rubber accelerator DPG source are as follows:、
Polybutadiene rubber is purchased from platform rubber space portion (Nantong) Chemical Co., Ltd., model VCR617 types;
Fluorubber is purchased from Hangzhou ten thousand along Fu Jiao Science and Technology Ltd.s, the type of model 26;
Makrolon dissolves light petrochemistry limited company, model IR2200 types purchased from platform;
White cigarette is purchased from Hefei Zai Qi lubriation materials Co., Ltd, model B200 types;
Styrene is purchased from the multifarious Chemical Company in Jiangyin, and rank is A grades of industry;
Rubber antioxidant MB is purchased from Nanjing Guohai Biology Engineering Co., Ltd;
PEG4000 is purchased from Jiangsu Hai'an Petrochemical Plant;
The anti-creme SK that tells is purchased from Margaret Abbott (Jinjiang) rubber Science and Technology Ltd.;
Rubber antifoggant 1956 is purchased from Gaoyi Jin Hong chemical plant;
White smoke active agent is purchased from Guangzhou white clouds Xin Gang Chemical Co., Ltd.s, model ZH-550 types;
Zinc oxide is purchased from Guangzhou Lu Chang Chemical Co., Ltd.s;
Vulcanizing agent S-80 is purchased from Guangzhou Fu Yu Chemical Co., Ltd.s;
Rubber accelerator TS-80 is purchased from Shanghai Yu Ku Chemical Industry Science Co., Ltd;
Rubber accelerator DM is purchased from Ming Feng Chemical Co., Ltd.s of Quzhou City of Zhejiang Province;
Rubber accelerator DPG is purchased from Tianjin Yihua Chemical Industry Co., Ltd..
Raw material prepare:Polybutadiene rubber and fluorubber are cut in 65 DEG C of drying rooms again after softened by baking glue, broken glue be cut into it is small Block is stand-by;Bulk is prevented telling creme SK and rubber antifoggant 1956 crushes stand-by;By styrene liquid through evaporating moisture, filtering miscellaneous It is stand-by after matter;By remaining powdery or graininess chemicals after removing mechanical admixture and drying it is stand-by.
Embodiment 1
(1) 40kg polybutadiene rubbers and 5kg fluorubber are put into banbury and plasticated, plasticated 5 minutes time, temperature of plasticating 70 DEG C of degree, rotating speed 45r/min;
(2) by 10kg makrolon, 5kg white cigarettes, 0.3kg styrene, 0.3kg rubber antioxidant MB, 1kg PEG4000, 0.5kg is anti-to be told in creme SK, 0.1kg rubber antifoggant 1956,1kg white smoke active agents and 1.5kg zinc oxide input banbury Row mixing, mixing time 5 minutes, 85 DEG C of melting temperature, rotating speed 45r/min;
(3) mixture for obtaining mixing after mixing terminates parks 24h, then will knead obtained mixture, 0.95kg sulphur Agent S-80,0.05kg rubber accelerator TS-80,0.35kg rubber accelerator DM and 0.05kg rubber accelerator DPG inputs are close Vulcanized in mill, cure time 5 minutes, 120 DEG C of curing temperature, rotating speed 45r/min;
(4) colloidal mixture obtained in (3) is parked and die for molding is imported after 12h;
(5) sole formed obtained in (4) is carried out flattening the rest and reorganization with secondary retraction.
After testing, particular product performance parameters of the invention are as follows:
Hardness Proportion Pulling force
68+/-4c 0.78g/CC 40.2kg/cm2
Extensibility C-type is torn Abrasion
345% 18kg/cm 270mm3
Embodiment 2
(1) 43kg polybutadiene rubbers and 7kg fluorubber are put into banbury and plasticated, plasticated 5 minutes time, temperature of plasticating 70 DEG C of degree, rotating speed 45r/min;
(2) by 13kg makrolon, 7kg white cigarettes, 0.4kg styrene, 0.4kg rubber antioxidants MB, 1.5kg PEG4000,0.8kg are anti-to tell creme SK, 0.2kg rubber antifoggant 1956,1.3kg white smoke active agents and 1.8kg zinc oxide input Kneaded in banbury, mixing time 5 minutes, 85 DEG C of melting temperature, rotating speed 45r/min;
(3) mixture for obtaining mixing after mixing terminates parks 24h, then will knead obtained mixture, 1.15kg sulphur Agent S-80,0.06kg rubber accelerator TS-80,0.38kg rubber accelerator DM and 0.06kg rubber accelerator DPG inputs are close Vulcanized in mill, cure time 5 minutes, 120 DEG C of curing temperature, rotating speed 45r/min;
(4) colloidal mixture obtained in (3) is parked and die for molding is imported after 12h;
(5) sole formed obtained in (4) is carried out flattening the rest and reorganization with secondary retraction.
After testing, particular product performance parameters of the invention are as follows:
Embodiment 3
(1) 42kg polybutadiene rubbers and 6kg fluorubber are put into banbury and plasticated, plasticated 5 minutes time, temperature of plasticating 70 DEG C of degree, rotating speed 45r/min;
(2) by 12kg makrolon, 6kg white cigarettes, 0.36kg styrene, 0.36kg rubber antioxidants MB, 1.8kg PEG4000,1kg are anti-to tell creme SK, 0.3kg rubber antifoggant 1956,1.5kg white smoke active agents and the input banburying of 2kg zinc oxide Kneaded in machine, mixing time 5 minutes, 85 DEG C of melting temperature, rotating speed 45r/min;
(3) mixture for obtaining mixing after mixing terminates parks 24h, then will knead obtained mixture, 0.96kg sulphur Agent S-80,0.08kg rubber accelerator TS-80,0.4kg rubber accelerator DM and 0.08kg rubber accelerator DPG puts into banburying Vulcanized in machine, cure time 5 minutes, 120 DEG C of curing temperature, rotating speed 45r/min;
(4) colloidal mixture obtained in (3) is parked and die for molding is imported after 12h;
(5) sole formed obtained in (4) is carried out flattening the rest and reorganization with secondary retraction.
After testing, particular product performance parameters of the invention are as follows:
Hardness Proportion Pulling force
70+/-4c 0.832g/CC 44kg/cm2
Extensibility C-type is torn Abrasion
350% 24kg/cm 280mm3
Embodiment 4
(1) 44kg polybutadiene rubbers and 9kg fluorubber are put into banbury and plasticated, plasticated 5 minutes time, temperature of plasticating 70 DEG C of degree, rotating speed 45r/min;
(2) by 14kg makrolon, 9kg white cigarettes, 0.45kg styrene, 0.45kg rubber antioxidants MB, 2.3kg PEG4000,1.2kg are anti-to tell creme SK, 0.4kg rubber antifoggant 1956,1.8kg white smoke active agents and 2.3kg zinc oxide input Kneaded in banbury, mixing time 5 minutes, 85 DEG C of melting temperature, rotating speed 45r/min;
(3) mixture for obtaining mixing after mixing terminates parks 24h, then will knead obtained mixture, 1.3kg vulcanizations Agent S-80,0.09kg rubber accelerator TS-80,0.45kg rubber accelerator DM and 0.07kg rubber accelerator DPG puts into banburying Vulcanized in machine, cure time 5 minutes, 120 DEG C of curing temperature, rotating speed 45r/min;
(4) colloidal mixture obtained in (3) is parked and die for molding is imported after 12h;
(5) sole formed obtained in (4) is carried out flattening the rest and reorganization with secondary retraction.
After testing, particular product performance parameters of the invention are as follows:
Hardness Proportion Pulling force
71+/-4c 0.9g/CC 42.7kg/cm2
Extensibility C-type is torn Abrasion
338% 20.5kg/cm 276mm3
Embodiment 5
(1) 45kg polybutadiene rubbers and 10kg fluorubber are put into banbury and plasticated, plasticated 5 minutes time, plasticate Temperature 70 C, rotating speed 45r/min;
(2) by 15kg makrolon, 10kg white cigarettes, 0.5kg styrene, 0.5kg rubber antioxidants MB, 2.5kg PEG4000,1.5kg be anti-, and to tell creme SK, 0.5kg rubber antifoggant 1956,2kg white smoke active agents and 2.5kg zinc oxide input close Kneaded in mill, mixing time 5 minutes, 85 DEG C of melting temperature, rotating speed 45r/min;
(3) mixture for obtaining mixing after mixing terminates parks 24h, then will knead obtained mixture, 1.4kg vulcanizations In agent S-80,0.1kg rubber accelerator TS-80,0.5kg rubber accelerator DM and 0.1kg rubber accelerator DPG input banburies Vulcanized, cure time 5 minutes, 120 DEG C of curing temperature, rotating speed 45r/min;
(4) colloidal mixture obtained in (3) is parked and die for molding is imported after 12h;
(5) sole formed obtained in (4) is carried out flattening the rest and reorganization with secondary retraction.
After testing, particular product performance parameters of the invention are as follows:
Hardness Proportion Pulling force
73+/-4c 0.93g/CC 43.4kg/cm2
Extensibility C-type is torn Abrasion
321% 22kg/cm 290mm3
It is to be understood that, foregoing invention content and embodiment are intended to prove technical scheme provided by the present invention Practical application, should not be construed as limiting the scope of the present invention.Those skilled in the art are in spirit and principles of the present invention It is interior, when can various modifications may be made, equivalent substitution or improvement.Protection scope of the present invention is defined by appended claims.

Claims (9)

1. a kind of lightweight rubber soles material, it is characterised in that the lightweight elastomeric material includes:45~55 parts by weight base-materials, 15.3~25.5 parts by weight reinforcing agents, 1.3~3 parts by weight age resistor, 0.6~2 parts by weight antifoggant, 2.5~4.5 parts by weight are lived Property agent, 1~1.5 parts by weight vulcanizing agent, 0.4~0.6 parts by weight accelerator.
2. lightweight rubber soles material as claimed in claim 1, it is characterised in that the base-material is selected from by polybutadiene rubber The group constituted with fluorubber.
3. lightweight rubber soles material as claimed in claim 1, it is characterised in that the reinforcing agent be selected from by makrolon, The group of white cigarette and styrene composition.
4. lightweight rubber soles material as claimed in claim 1, it is characterised in that the age resistor is selected from by rubber antioxidant The group of MB and PEG4000 compositions.
5. lightweight rubber soles material as claimed in claim 1, it is characterised in that the antifoggant is selected from tells creme SK by anti- The group constituted with rubber antifoggant 1956.
6. lightweight rubber soles material as claimed in claim 1, it is characterised in that the activating agent is selected from by white smoke active agent The group constituted with zinc oxide.
7. lightweight rubber soles material as claimed in claim 1, it is characterised in that the vulcanizing agent is S-80.
8. lightweight rubber soles material as claimed in claim 1, it is characterised in that the accelerator is selected from by rubber accelerator TS-80, rubber accelerator DM and rubber accelerator DPG compositions group.
9. lightweight rubber soles material as claimed in claim 1, it is characterised in that the lightweight elastomeric material includes 42 weight Part polybutadiene rubber, 6 parts by weight fluorubber, 12 weight part polycarbonates, 6 parts by weight white cigarettes, 0.36 parts by weight of styrene, 0.36 parts by weight of rubber antioxidant MB, 1.8 parts by weight PEG4000,1 parts by weight are anti-to tell creme SK, 0.3 parts by weight of rubber antifoggant 1956th, 1.5 parts by weight white smoke active agents, 2 part by weight of zinc oxide, 0.96 parts by weight vulcanizing agent S-80,0.08 parts by weight of rubber promote Enter agent TS-80,0.4 parts by weight of rubber altax and 0.08 parts by weight of rubber diphenylguanidine PG.
CN201710543021.1A 2017-07-05 2017-07-05 A kind of lightweight rubber soles material Pending CN107254078A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110302805A1 (en) * 2010-06-11 2011-12-15 Vito Robert A Adjustable and interchangebale insole and arch support system
CN102850607A (en) * 2012-09-24 2013-01-02 吴江市信许塑料鞋用配套有限公司 Elastic puncture-proof sole material
CN103497370A (en) * 2013-10-11 2014-01-08 昆山纯柏精密五金有限公司 Shoe sole rubber composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110302805A1 (en) * 2010-06-11 2011-12-15 Vito Robert A Adjustable and interchangebale insole and arch support system
CN102850607A (en) * 2012-09-24 2013-01-02 吴江市信许塑料鞋用配套有限公司 Elastic puncture-proof sole material
CN103497370A (en) * 2013-10-11 2014-01-08 昆山纯柏精密五金有限公司 Shoe sole rubber composition

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