CN107244786A - A kind of coal chemical industry device for high concentration waste water treatment - Google Patents

A kind of coal chemical industry device for high concentration waste water treatment Download PDF

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Publication number
CN107244786A
CN107244786A CN201710650177.XA CN201710650177A CN107244786A CN 107244786 A CN107244786 A CN 107244786A CN 201710650177 A CN201710650177 A CN 201710650177A CN 107244786 A CN107244786 A CN 107244786A
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CN
China
Prior art keywords
waste water
purifying box
chemical industry
coal chemical
high concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710650177.XA
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Chinese (zh)
Inventor
王亚茹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhengzhou Jiachen Chemical Technology Co Ltd
Original Assignee
Zhengzhou Jiachen Chemical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhengzhou Jiachen Chemical Technology Co Ltd filed Critical Zhengzhou Jiachen Chemical Technology Co Ltd
Priority to CN201710650177.XA priority Critical patent/CN107244786A/en
Publication of CN107244786A publication Critical patent/CN107244786A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2866Particular arrangements for anaerobic reactors

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention discloses a kind of coal chemical industry device for high concentration waste water treatment, including purifying box, purifying box upper end centre position is provided with feed pipe, stone filter layer and activated charcoal strainer are sequentially provided with feed pipe from top to bottom, the string bag is provided with the purifying box of stone filter layer bottom, the water side of purifying box lower right side is connected by conduit and is equipped with suction pump on the feed tube of flocculation reaction device, feed tube.The present invention is simple and reasonable for structure, ensure biochemical treatment effect, so as to advantageously reduce fouling membrane, cleaning frequency membrane is low, service life is long, and MBR stable water outlets, no suspended substance, it ensure that advanced treating effect, and the mixing of material can also be accelerated by puddle support while acidifying is hydrolyzed, and hydrolysis efficiency is greatly improved, it is practical.

Description

A kind of coal chemical industry device for high concentration waste water treatment
Technical field
The present invention relates to wastewater treatment equipment, specifically a kind of coal chemical industry device for high concentration waste water treatment.
Background technology
In global range, coal reserves is than oil and natural gas more horn of plenty, and price is relatively low, and oil shortage is existing As increasingly serious.Some rich coals national such as U.S., Australia, India, Germany, are all stepping up research or development coal chemical industry Mesh.China also researchs and develops New Coal Chemical technique in recent years, sets up multiple coal chemical industry demonstration projects, and build up coal the biggest in the world Direct liquefaction project.But for rich coal resources but the Coal Chemical Engineering Project in shortage of water resources area, arranged in water consumption and sewage In the case of high-volume all big, it is badly in need of practicable coal chemical industry high concentration wastewater treatment technique, to ensure that Coal Chemical Engineering Project is being worked as The economic society steady development on ground and ecological environmental protection.Current coal chemical industry technique burning hot developing stage, but coal chemical industry The handling process of waste water relatively falls behind.Coal chemical industrial waste water is divided between DCL/Direct coal liquefaction liquefaction waste water and coal according to the difference of technique Connect liquefaction liquefaction waste water.Coal chemical industry high-concentration waste water refer to through air lift, dephenolize device processing after water outlet, mainly including coal liquefaction, Hydrofinishing, be hydrocracked and the discharge of the device such as sulphur recovery sulfur-bearing, phenol wastewater.Coal chemical industrial waste water contains exhibiting high surface work Property agent, with colourity is big, emulsification degree is high, biodegradability difference and the water surface be the features such as easily form a large amount of foams, belongs to intractable Coal chemical industrial waste water.
MBR (Membrane Bio-Reactor, membrane bioreactor) is one kind by film separation unit and biological treatment list The new water technology that member is combined, it is more universal in the application of sewage treatment area, there is aqueous suspension and turbidity Low, effluent quality is good, and sludge concentration is high, and floor space is small, control, it is easy to operate the advantages of.But when coal chemical industrial waste water is handled, Need to optimize MBR technology, improve MBR flux, reduce MBR fouling membranes.
The content of the invention
It is an object of the invention to provide a kind of coal chemical industry device for high concentration waste water treatment, to solve in above-mentioned background technology The problem of proposition.
To achieve the above object, the present invention provides following technical scheme:
A kind of coal chemical industry device for high concentration waste water treatment, including purifying box, the purifying box upper end interposition are installed Have and be sequentially provided with stone filter layer and activated charcoal strainer in feed pipe, feed pipe from top to bottom, stone filter layer bottom it is net Change and the string bag is provided with case, the water side of purifying box lower right side is connected by conduit on the feed tube of flocculation reaction device, feed tube Suction pump is equipped with, flocculation plant, which is used to remove, can be flocculated the suspension colloid for precipitating and divide in the waste water that purifying box is discharged Scattered, the air inlet pipe upper end of flocculation plant bottom is provided with even gas disk, and air inlet pipe lower end connects the output end of ozone generator, ozone Generator causes impurity to float by being supplied in even gas disk case flocculation generating means, while being also to dirty in flocculation plant The oxidation processes of water, flocculation plant inner right side is provided with filter mantle, and filter mantle surface is evenly distributed with filter bores, filter mantle upper end Drinking-water pipe is equipped with, drinking-water pipe is above-mentioned to be provided with liquid pump, the water side connection hydrolysis acidification device of liquid pump connection, hydrolysis acidification device For macromolecular substances to be degraded, it is further transformed to the organic matter of difficult for biological degradation in the waste water of flocculation reaction device discharge The organic matter of easily biological-degradable, improves and stirring motor is provided with the top of the biodegradability of waste water, hydrolysis acidification device, stirring motor Output end is provided with puddle support, and the water side connection nitrogen rejection facility of the hydrolysis acidification device lower right side, nitrogen rejection facility is used to remove A large amount of ammonia nitrogens and total nitrogen in the waste water of the hydrolysis acidification device discharge, the exhaust end connection hypoxia device of nitrogen rejection facility, lack The effect of oxygen device is nitrate nitrogen and nitrite nitrogen is reacted under biological agent with organic matter, is arranged with removing the nitrogen rejection facility Not removed ammonia nitrogen and total nitrogen in the waste water gone out, the discharge end of hypoxia device connect aerobic MBR devices, and aerobic MBR devices are used The waste water discharged in the hypoxia device carries out being provided with several MBR films in Aerobic Process for Treatment, aerobic MBR devices.
It is used as further scheme of the invention:The MBR films is in Flat Membrane, hollow-fibre membrane, tubular membrane, spiral films Any one.
It is used as further scheme of the invention:The aerobic MBR devices are Nets impregnated or separate film Bioreactor.
It is used as further scheme of the invention:Puddler structure of the puddle support by agitating shaft and positioned at agitating shaft both sides Into.
It is used as further scheme of the invention:The air inlet pipe is provided with check valve.
Compared with prior art, the beneficial effects of the invention are as follows:Simple and reasonable for structure, coal of the present invention of the invention Chemical industry device for high concentration waste water treatment, pre-processes perfect, reduces subsequent treatment difficulty, and its biochemical treatment is using hydrolysis acidification-de- Nitrogen-anaerobic-aerobic MBR group technology, first improves the biodegradability of waste water, then carries out denitrogenation, finally carries out at aerobic biochemical Reason, it is ensured that biochemical treatment effect, so as to advantageously reduce fouling membrane, cleaning frequency membrane is low, service life is long, and MBR goes out Water is stable, and no suspended substance ensure that advanced treating effect, and can also add while acidifying is hydrolyzed by puddle support The mixing of fast material, greatly improves hydrolysis efficiency, practical.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Wherein:Purifying box 1, activated charcoal strainer 2, stone filter layer 3, feed pipe 4, flocculation reaction device 5, feed tube 6, Filter mantle 7, even gas disk 8, ozone generator 9, stirring motor 10, hydrolysis acidification device 11, puddle support 12, nitrogen rejection facility 13, lack Oxygen device 14, aerobic MBR devices 15, buffer tank 16.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
Referring to Fig. 1, in the embodiment of the present invention, a kind of coal chemical industry device for high concentration waste water treatment, including purifying box 1, institute The upper end centre position of purifying box 1 is stated provided with feed pipe 4, stone filter layer 3 is sequentially provided with feed pipe 4 from top to bottom and living Property charcoal screen pack 2, be provided with the string bag in the purifying box 1 of the bottom of stone filter layer 3, the water side of the lower right side of purifying box 1 passes through conduit Connect and suction pump is equipped with the feed tube 6 of flocculation reaction device 5, feed tube 6, flocculation plant 5 is discharged for removing purifying box 1 Waste water in can be flocculated the suspension colloid and scattered that precipitation falls, the air inlet pipe upper end of the bottom of flocculation plant 5 is provided with even gas Disk 8, air inlet pipe is provided with check valve, and air inlet pipe lower end connects the output end of ozone generator 9, and ozone generator 9 passes through even gas Supplied in the flocculation generating means 5 of disk 8 casees, and then impurity is floated, while being also in flocculation plant 5 at the oxidation of sewage Reason, the inner right side of flocculation plant 5 is provided with filter mantle 7, and the surface of filter mantle 7 is evenly distributed with filter bores, and the upper end of filter mantle 7 is equipped with Drinking-water pipe, drinking-water pipe is above-mentioned to be provided with liquid pump, and the water side connection hydrolysis acidification device 11 of liquid pump connection, hydrolysis acidification device 11 is used Degraded in by macromolecular substances, the organic matter of difficult for biological degradation in the waste water of flocculation reaction device discharge is further transformed to easily Biodegradable organic matter, improves the biodegradability of waste water, and the top of hydrolysis acidification device 11 is provided with stirring motor 10, stirring motor 10 output end is provided with puddle support 12, and puddler of the puddle support 12 by agitating shaft and positioned at agitating shaft both sides is constituted, stirring motor 10 drive puddle supports 12 are stirred to the material in hydrolysis acidification device 11, so that degradation efficiency is favorably improved, the water The water side connection nitrogen rejection facility 13 of the lower right side of acidizing device 11 is solved, nitrogen rejection facility 13 is used to remove the hydrolysis acidification device 11 A large amount of ammonia nitrogens and total nitrogen in the waste water of discharge, the exhaust end connection hypoxia device 14 of nitrogen rejection facility 13, the work of hypoxia device 14 With being nitrate nitrogen and nitrite nitrogen is reacted under biological agent with organic matter, to remove in the waste water that the nitrogen rejection facility is discharged Not removed ammonia nitrogen and total nitrogen, the discharge end of hypoxia device 14 connect aerobic MBR devices 15, and aerobic MBR devices 15 are used for pair The waste water discharged in the hypoxia device 14 carries out being provided with several MBR films in Aerobic Process for Treatment, aerobic MBR devices, and MBR films are flat Any one in plate film, hollow-fibre membrane, tubular membrane, spiral film, aerobic MBR devices 15 are Nets impregnated Or separate film biological reactor.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.Any reference in claim should not be considered as to the claim involved by limitation.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It may be appreciated other embodiment.

Claims (5)

1. a kind of coal chemical industry device for high concentration waste water treatment, including purifying box (1), it is characterised in that the purifying box (1) Upper end centre position is provided with feed pipe (4), feed pipe (4) and is sequentially provided with stone filter layer (3) and activated carbon mistake from top to bottom The string bag is provided with filter screen (2), the purifying box (1) of stone filter layer (3) bottom, the water side of purifying box (1) lower right side is by leading Suction pump is equipped with the feed tube (6) of pipe connection flocculation reaction device (5), feed tube (6), flocculation plant (5) is used to remove Suspension colloid and scattered, the air inlet of flocculation plant (5) bottom that precipitation is fallen can be flocculated in the waste water of purifying box (1) discharge Pipe upper end is provided with even gas disk (8), and the output end of air inlet pipe lower end connection ozone generator (9), ozone generator (9) passes through even gas Supplied in disk (8) case flocculation generating means (5), and then impurity is floated, while being also the oxygen to flocculation plant (5) interior sewage Change is handled, and flocculation plant (5) inner right side is provided with filter mantle (7), and filter mantle (7) surface is evenly distributed with filter bores, filter mantle (7) upper end is equipped with drinking-water pipe, and drinking-water pipe is above-mentioned to be provided with liquid pump, and the water side of liquid pump connection connects hydrolysis acidification device (11), Hydrolysis acidification device (11) is used to degrade macromolecular substances, there is difficult for biological degradation in the waste water that flocculation reaction device discharges Machine thing is further transformed to the organic matter of easily biological-degradable, improves and is set at the top of the biodegradability of waste water, hydrolysis acidification device (11) There is stirring motor (10), the output end of stirring motor (10) is provided with puddle support (12), hydrolysis acidification device (11) lower right side Water side connection nitrogen rejection facility (13), nitrogen rejection facility (13) be used for remove the hydrolysis acidification device (11) discharge waste water in A large amount of ammonia nitrogens and total nitrogen, nitrogen rejection facility (13) exhaust end connection hypoxia device (14), the effect of hypoxia device (14) is to make Nitrate nitrogen and nitrite nitrogen react under biological agent with organic matter, are not gone in the waste water to remove the nitrogen rejection facility discharge The ammonia nitrogen and total nitrogen removed, the discharge end of hypoxia device (14) connects aerobic MBR devices (15), and aerobic MBR devices (15) are used for pair The waste water of discharge carries out being provided with several MBR films in Aerobic Process for Treatment, aerobic MBR devices in the hypoxia device (14).
2. a kind of coal chemical industry device for high concentration waste water treatment according to claim 1, it is characterised in that the MBR films are Any one in Flat Membrane, hollow-fibre membrane, tubular membrane, spiral film.
3. a kind of coal chemical industry device for high concentration waste water treatment according to claim 1, it is characterised in that the aerobic MBR Device (15) is Nets impregnated or separate film biological reactor.
4. a kind of coal chemical industry device for high concentration waste water treatment according to claim 1, it is characterised in that the puddle support (12) puddler by agitating shaft and positioned at agitating shaft both sides is constituted.
5. a kind of coal chemical industry device for high concentration waste water treatment according to claim 1, it is characterised in that in the air inlet pipe Provided with check valve.
CN201710650177.XA 2017-08-02 2017-08-02 A kind of coal chemical industry device for high concentration waste water treatment Withdrawn CN107244786A (en)

Priority Applications (1)

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CN201710650177.XA CN107244786A (en) 2017-08-02 2017-08-02 A kind of coal chemical industry device for high concentration waste water treatment

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CN201710650177.XA CN107244786A (en) 2017-08-02 2017-08-02 A kind of coal chemical industry device for high concentration waste water treatment

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CN107244786A true CN107244786A (en) 2017-10-13

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108395065A (en) * 2018-06-05 2018-08-14 海宁泓环境科技有限公司 Triple hollow-fibre membrane dyeing and printing sewage processing systems
CN108439733A (en) * 2018-06-11 2018-08-24 淄博职业学院 A kind of petrochemical effluent comprehensive purifying equipment and its application method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108395065A (en) * 2018-06-05 2018-08-14 海宁泓环境科技有限公司 Triple hollow-fibre membrane dyeing and printing sewage processing systems
CN108395065B (en) * 2018-06-05 2020-06-09 海宁一泓环境科技有限公司 Triple hollow fiber membrane printing and dyeing sewage treatment system
CN108439733A (en) * 2018-06-11 2018-08-24 淄博职业学院 A kind of petrochemical effluent comprehensive purifying equipment and its application method

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Application publication date: 20171013