CN107243231B

CN107243231B - Desulfurizing tower

Info

Publication number: CN107243231B
Application number: CN201710528997.1A
Authority: CN
Inventors: 麻强; 王维江; 王怀金; 李立松; 荀鹏; 王平; 朱伟; 余永红
Original assignee: Chengdu Guohua Environmental Technology Co ltd
Current assignee: Chengdu Guohua Environmental Technology Co ltd
Priority date: 2017-07-01
Filing date: 2017-07-01
Publication date: 2023-08-01
Anticipated expiration: 2037-07-01
Also published as: CN107243231A

Abstract

The utility model relates to an environmental protection trade atmospheric pollution administers technical field, concretely relates to desulfurizing tower, including the filter layer subassembly, the filter layer subassembly is located between desulfurizing tower flue gas import and the flue gas export, makes the flue gas pass through earlier behind the filter layer subassembly, again by the flue gas export discharges, the filter layer subassembly is including the filter layer there are a plurality of flue gas passageways that supply the flue gas to pass through in the filter layer. The desulfurizing tower of this application can improve sulfur dioxide in the flue gas by a wide margin and desulfurizing agent's contact efficiency, and then improves sulfur dioxide's in the flue gas desorption efficiency, and desulfurizing agent in this application can be can take place chemical reaction and then realize sulfur dioxide desorption's chemical formulation with sulfur dioxide, also can be used for catalyzing sulfur dioxide and other substances and take place chemical reaction and then realize sulfur dioxide's catalyst.

Description

Desulfurizing tower

Technical Field

The application relates to the technical field of air pollution control in the environment-friendly industry, in particular to a desulfurizing tower.

Background

Sulfur dioxide is a major pollutant in the atmosphere, has great harm to links and human health, and is also a major cause of acid rain. Therefore, the removal and treatment of sulfur dioxide in the industrial exhaust flue gas is an important subject in the field of environmental protection in China.

For sulfur dioxide removal treatment of industrial flue gas, the common mode is to treat sulfur dioxide in industrial flue gas by adopting a desulfurization equipment line, and the current desulfurization equipment line mainly comprises a gas supply assembly and a desulfurization assembly.

By adopting the mode, the sulfur dioxide content in the industrial flue gas can be greatly reduced, the environmental pollution caused by the industrial flue gas is reduced, and meanwhile, the removed sulfur dioxide can be collected and reused under the conditional condition.

As the research is advanced, the inventor finds that the desulfurization equipment line still has the defects, and the specific reasons are as follows:

in the prior desulfurizing tower structure, the desulfurizing mode is usually dry desulfurizing or wet desulfurizing, and when the desulfurizing work is carried out, industrial flue gas enters the tower body from the lower part of the tower body and contacts with the corresponding desulfurizing agent so as to realize the removal of sulfur dioxide, however, the inventor discovers that in the prior desulfurizing mode, the contact efficiency of the flue gas and the desulfurizing agent is not high, so that the use of the desulfurizing agent is insufficient, the waste of the desulfurizing agent is caused, and the problem of low removal rate of sulfur dioxide in the flue gas is also easily caused.

Disclosure of Invention

The purpose of the present application is: aiming at the problem of low sulfur dioxide removal rate in the existing desulfurization equipment line, the desulfurization equipment capable of improving the sulfur dioxide removal rate is provided.

In order to achieve the above object, the present application provides the following technical solutions:

a filtering layer assembly for desulfurizing tower, filtering layer assembly is located between desulfurizing tower flue gas import and the flue gas export, makes the flue gas pass through earlier after the filtering layer assembly, again by the flue gas export discharges, the filtering layer assembly is including the filter layer there are a plurality of flue gas passageways that supply the flue gas to pass through in the filter layer.

The filtering layer assembly of this application has a plurality of passageway that supply flue gas to pass through in the filter layer, and the flue gas that gets into the tower body is discharged by the flue gas export again through these passageways, adopts such mode, can improve the contact efficiency of sulfur dioxide and desulfurizing agent in the flue gas by a wide margin, and then improves the desorption efficiency of sulfur dioxide in the flue gas, and the desulfurizing agent in this application can take place chemical reaction with sulfur dioxide and then realize the chemical preparation of sulfur dioxide desorption, also can be the catalyst that is used for catalyzing sulfur dioxide and other material and takes place chemical reaction and then realize the sulfur dioxide desorption.

Preferably, the filter layer is formed by stacking or laying a plurality of granular filter units, gaps are formed between adjacent filter units, and a plurality of flue gas channels for flue gas to pass through are formed between the gaps in a mutually connected or mutually independent or partially connected mode.

In this scheme, adopt above-mentioned mode to form the flue gas passageway that supplies the flue gas to pass through, these flue gas passageway shape randomness is high, perhaps crooked or tortuous, for the passing through of flue gas provides longer route, can further improve the contact efficiency of flue gas and desulfurizing agent, and then further improve sulfur dioxide's desorption rate.

Preferably, the filter unit is spherical, ellipsoidal or columnar.

Adopt the filter unit of above-mentioned shape and specification, when piling up or laying, make things convenient for the formation of flue gas passageway to the flue gas passageway that forms also has comparatively suitable size, guarantees that flue gas and desulfurizing agent have higher contact efficiency promptly, has simultaneously to avoid forming too big resistance, makes things convenient for the passage of flue gas.

Further preferably, the filter unit is cylindrical and has a diameter of 3-10mm.

Further preferably, the filter unit is cylindrical and has a diameter of 4-6mm.

In practical design and use, the inventor finds that the filter units are set to the above sizes, so that gaps with proper sizes are formed among the filter units, the smooth circulation of the flue gas is ensured, the gaps inside the filter layers are also ensured to have enough large area, and the removal efficiency of sulfur dioxide is ensured.

As one preferable scheme, the filtering unit is made of a desulfurization catalyst material, and the desulfurization catalyst is used for generating sulfur trioxide from sulfur dioxide and oxygen.

In the scheme, the filter units are made of desulfurization catalyst materials, namely, when flue gas passes through flue gas channels among the filter units, sulfur dioxide reacts with oxygen in the flue gas to form sulfur trioxide under the catalysis of the catalyst materials, and after the sulfur trioxide is formed, certain water vapor or water drops are left in the flue gas, so that when the flue gas passes through the catalyst materials, the sulfur trioxide is formed and then combined with the water vapor or the water drops to form sulfuric acid liquid, the sulfuric acid liquid is attached to the filter units, and further, the removal of sulfur dioxide in the flue gas is realized.

As another preferable scheme, the filtering unit comprises a matrix serving as a framework and a desulfurization catalyst attached to the matrix, wherein the matrix is activated carbon.

In this scheme, adopt active carbon as the base member, adhere to desulfurization catalyst on the base member, in desulfurization process, sulfur dioxide and oxygen are under desulfurization catalyst effect, form sulfur trioxide, sulfur trioxide combines with water and forms sulfuric acid and adhere to on the catalyst, and then realize sulfur dioxide's desorption, further, in this scheme, because the base member adopts active carbon, active carbon surface and inside all have more holes, on the one hand, make the base member can adhere to more desulfurization catalyst, further improve sulfur dioxide's desorption efficiency, on the other hand, the flue gas passageway shape of formation is also more tortuous various, when more being favorable to the flue gas to pass through the filter layer, also be favorable to sulfur dioxide's desorption more.

As another preferable scheme, the filtering unit is made of a sulfur dioxide absorbent, and when the flue gas passes through the filtering layer, sulfur dioxide in the flue gas and the sulfur dioxide absorbent are subjected to chemical reaction, so that the adsorption of sulfur dioxide is realized.

In the scheme, the sulfur dioxide absorbent is an alkaline compound which can chemically react with sulfur dioxide, such as calcium, sodium, magnesium, ammonium and the like.

As another preferred scheme, the filtering unit is made of an inert material, wherein the inert material is a chemically stable material which does not react chemically during the sulfur dioxide removal process.

In the scheme, an inert material is adopted to prepare the filtering unit, for example, stainless steel or activated carbon is adopted as the filtering unit, in a wet desulfurization mode, a desulfurizing agent is sprayed from the upper part of the filtering layer, flue gas enters from the lower part of the filtering layer, when the desulfurizing agent falls onto the filtering layer, the desulfurizing agent is in a spraying state, a plurality of fine liquid drops and liquid mist are formed, and then the flue gas continuously flows to the lower part of the filtering layer, and in the process, the flue gas can be fully contacted with the desulfurizing agent, so that the contact rate of sulfur dioxide and the desulfurizing agent is greatly improved, and the removal rate of sulfur dioxide is greatly improved.

Preferably, the filter layer assembly further comprises a first wire mesh, the filter units are piled or laid on the first wire mesh, and the first edge is matched with the inner wall of the tower body. Through setting up first silk screen, when playing the support to the filter unit, also guaranteed the smoothness and smoothness of flue gas circulation.

Preferably, the first wire mesh is a stainless steel wire mesh. Ensuring good durability of the first wire mesh.

Preferably, the filter layer assembly further comprises a first saddle ring layer, the first saddle ring layer comprises a plurality of first saddle rings, and the first saddle rings are laid below the first wire mesh side by side. Through setting up first different saddle ring layer, because different saddle ring structure has characteristics such as macroporosity and high flux, so, in the scheme of this application, through the bearing structure of a plurality of first different saddle ring first silk screen side by side, when guaranteeing that first silk screen is reliably supported, still improve the homogeneity that the flue gas got into the filter layer, improve sulfur dioxide's desorption efficiency.

Further preferably, the filter layer assembly further comprises a second saddle ring layer, the second saddle ring layer comprises a plurality of second saddle rings, the second saddle rings are laid on the first saddle ring layer side by side, the structural size of the second saddle rings is smaller than that of the first saddle rings, and the structural size of the second saddle rings ensures that the second saddle rings do not fall from the holes of the first saddle rings.

In the scheme, through setting up two-layer structure different in size's different saddle ring, support first silk screen through the different saddle ring layer of second that the size is less, further guaranteed the planarization that first silk screen was supported, and support the different saddle ring layer of second through the different saddle ring layer of first that the size is great, not only guaranteed the smoothness of flue gas circulation, also reduced the laying degree of difficulty on the different saddle ring layer of first simultaneously.

Further preferably, the filter layer assembly further comprises a second wire mesh, the edge of the second wire mesh is matched with the inner wall of the tower body, and the first saddle-shaped ring layer is laid on the second wire mesh.

The application also discloses a catalyst supporting component for desulfurizing tower, supporting component sets up in the body of the desulfurizing tower, supporting component is located filtering layer subassembly below, supporting component is used for supporting filtering layer subassembly, messenger filtering layer subassembly with the bottom of body of the tower separates.

In this scheme, through supporting component, separate filtering layer subassembly and tower body bottom, on the one hand make things convenient for the flue gas to have sufficient space and be full of in filtering layer subassembly's below space, avoid the flue gas to pass from the filtering layer that is close to the inlet portion only, and then guarantee the filtration efficiency of the sulfur dioxide of filtering layer.

Preferably, the support assembly comprises a grid plate, the edge of the grid plate is matched with the inner wall of the tower body, and the second silk screen of the filter layer assembly is laid on the grid plate.

The grid plate is used for supporting the filter layer assembly, so that the filter layer assembly can be effectively guaranteed to have good flatness, and further all parts of the filter layer can be well utilized.

Preferably, the support assembly further comprises a plurality of support beams, the support beams are used for supporting the grid plates, the support beams are arranged side by side, adjacent support beams are separated from each other, two ends of each support beam are matched with the inner wall of the tower body, and the grid plates are located on the support beams.

In the scheme, the grid plate is supported by the supporting beams, so that the supported reliability of the grid plate is ensured, the supported reliability of the filter layer assembly is ensured, and the supporting beams are arranged at intervals to ensure the smoothness of smoke circulation.

Preferably, annular supporting rings are connected between the ends of the adjacent supporting beams, the supporting rings are arranged along the inner wall of the tower body, two ends of each supporting ring are connected with the adjacent supporting beams respectively, and the outer edges of the supporting rings are matched with the inner wall of the tower body.

In the scheme, the annular supporting ring is arranged, so that the edges of the grating plates can be reliably supported, and the reliability of the supporting assembly for supporting the filtering assembly is further ensured; on the other hand, as the supporting beams are connected, the stability of the supporting beams is also enhanced to a certain extent; on the other hand, because the body of the tower is generally of a thin-wall tubular structure, in the application, the combination of the supporting ring and the supporting cross beam is adopted, and the inner wall of the body of the tower forms a circle of reinforcing ring structure when supporting the filter layer assembly, so that the structural strength of the body of the tower is also improved, the risk of deformation of the body of the tower can be greatly reduced, and the body of the tower can well maintain the design form.

Preferably, the supporting beam is I-steel, and the upper side surface of the upper side flange of the supporting beam is matched with the lower side of the grid plate.

Preferably, the support ring is plate-shaped, and two ends of the support ring are respectively butted with the upper side wing edges of the adjacent support beams.

Preferably, the upper side of the support ring and the upper side of the upper side flange of the support beam are located in the same plane.

Through the arrangement of the scheme, the upper side surface of the supporting beam and the upper side surface of the supporting ring form a supporting platform, and the supporting platform and the grid plate have larger matching surfaces, so that the supported reliability of the filter layer is further ensured.

Preferably, a first reinforcing rib is further connected between the support ring and the web plate of the support beam. The connection strength between the support ring and the support beam is increased by arranging the first reinforcing ribs.

Preferably, a plurality of support columns are further arranged below each support beam, the upper ends of the support columns are connected with the support beams, and the lower ends of the support columns are connected with the bottom plate of the tower body.

Preferably, the supporting columns of the same supporting beam are spaced. The adjacent upright posts are separated, so that the reliable support of the supporting cross beam is ensured, and the smooth smoke circulation is also conveniently ensured.

Preferably, the upper end and/or the lower end of the supporting upright post is/are connected with a backing plate. The reliability of connection is ensured by arranging the base plate.

Preferably, the support upright is a steel pipe.

Preferably, a plurality of support pipes are also connected between the adjacent support beams. The support tube, the support beam, the support upright post and the tower body are connected to form a mutually supported frame structure, so that the filter layer assembly is reliably supported on one hand, and the structural strength of the tower body is greatly improved on the other hand.

Preferably, the joint of the support tube and the support cross beam is located above the support upright. That is, the upright posts and the supporting tubes are connected with the same position of the supporting cross beam, so that the stress transmission of each component is facilitated, and the structural stability of the supporting assembly is further improved.

The application also discloses a tower body for the desulfurizing tower,

the novel smoke inlet and smoke outlet device is characterized in that a smoke inlet and a smoke outlet are arranged on the tower body, a smoke inlet pipe is connected to the smoke inlet, one end of the smoke inlet pipe extends into the tower body, and in the vertical direction, the smoke inlet pipe is located in the tower body, and shielding exists above any part of the inner wall of the smoke inlet pipe.

In the scheme, the upper part of any part of the inner wall of the tower body is provided with a shield, so that liquid or other materials above the inner wall of the tower body are prevented from falling into the smoke inlet pipe to influence the smoke gas transmission; the port of the smoke inlet pipe positioned in the tower body can be set to be of a bevel structure; cutting the lower half part of the port to form the upper half part to cover the lower half part; or an independent shielding structure is arranged to shield the port of the smoke inlet pipe.

Preferably, the port of the smoke inlet pipe positioned in the tower body is an inclined port. The inclined port structure is arranged, so that the smoke inlet pipe can achieve the effects, meanwhile, the processing is convenient, the materials are saved, and the manufacturing cost can be effectively reduced.

Preferably, the flue gas inlet is arranged on the side wall of the tower body, and the flue gas inlet pipe enters the tower body from the side wall of the tower body. The smoke inlet pipe enters the tower body from the side wall of the tower body, so that the structure of the bottom of the tower body is simplified, the installation and arrangement of the tower body are facilitated, and the processing and the manufacturing are convenient.

Preferably, the port of the smoke inlet pipe positioned in the tower body is separated from the bottom plate of the tower body by a distance. Further avoid liquid or other materials in the tower body to enter the smoke inlet pipe.

Preferably, the outer wall of the bottom plate of the tower body is also connected with a plurality of first supporting pieces, the first supporting pieces are arranged in parallel, and a distance is reserved between every two adjacent first supporting pieces.

As another preferred aspect, the first support is disposed along a radial direction of the tower body.

As the plurality of first supporting pieces are arranged on the bottom plate of the tower body, on one hand, the installation and arrangement of the tower body are convenient, and on the other hand, the first supporting pieces also play a role in reinforcing the bottom plate of the tower body, so that the structural strength of the tower body is improved.

As another preferable mode, the first supporting piece corresponds to a supporting upright of the supporting assembly, and the supporting piece is located right below the supporting upright. In the scheme of this application, the support stand is used for supporting the filtering layer subassembly, and first support piece is located under the support stand, so, guarantees on the one hand that the support stand has good supporting strength and supporting stability, on the other hand, also can reduce the deformation that the body of the tower bottom plate produced because of dead weight and the pressure that the support stand applyed, further improved the reliability of body of the tower structure.

Preferably, the first supporting piece is i-steel, channel steel or rectangular steel pipe. The I-steel, the channel steel or the rectangular steel pipe is adopted, and other sectional materials can be adopted, so that on one hand, the sectional materials are adopted as standard components, the market purchase is facilitated, the processing cost can be saved, and on the other hand, the sectional materials are provided with grooves or openings, and therefore connection between the first supporting piece and other supporting pieces is also facilitated.

The application also discloses another kind of body of a tower structure, this body of a tower structure can combine with foretell body of a tower structure, also can solitary formation body of a tower:

a tower body for a desulfurizing tower,

The inner side of the top plate of the tower body is provided with a plurality of spray heads, and each spray head is connected with a water inlet pipe.

In the scheme of this application, through setting up the shower head, can spout the desulfurizing agent that reacts with sulfur dioxide in the shower head, also can spout and be used for washing the filtering layer subassembly, guarantee that the filtering layer subassembly is clean or resume the active washing liquid of catalyst, for example clear water, make filtering layer subassembly can reuse to guarantee good filtering effect.

Preferably, the spray heads are uniformly distributed around the flue gas outlet.

Preferably, at least one first partition plate is further arranged in the tower body, and the first partition plate is located above the grid plate of the supporting component and divides the inner space of the tower body above the grid plate into at least two filling cavities for filling the filtering units.

Through setting up first baffle, cut apart the body of a tower inner space of filtering layer subassembly top, conveniently fill the filter unit of intracavity respectively to each respectively and control, for example fill respectively or change respectively, made things convenient for the accuse to filter unit.

Preferably, the upper end of the first partition plate is separated from the inner wall of the top plate of the tower body, so that each filling cavity is communicated with the flue gas outlet. Therefore, the filling cavity can share one smoke outlet, and the structure of the tower body is further simplified.

Preferably, a manhole is provided on the top plate of the tower body corresponding to each filling cavity, a discharge opening for taking out the filtering unit is provided on the side wall of the tower body corresponding to each filling cavity, and a sealing cover is detachably connected to the manhole and the discharge opening. The manhole can be used for workers to get in and out, and can also be used for filling the filter unit, so that the filter unit can be conveniently filled and replaced.

Preferably, the outer wall of the top plate of the tower body is further provided with a plurality of second supporting pieces, the second supporting pieces are arranged in parallel, and a distance is reserved between every two adjacent second supporting pieces.

As another preferred aspect, the second support is disposed along a radial direction of the tower body.

As the second supporting pieces are arranged on the top plate of the tower body, on one hand, the installation and arrangement of the tower body are convenient, and on the other hand, the second supporting pieces also play a role in reinforcing the top plate of the tower body, so that the structural strength of the tower body is improved.

Preferably, the second support is aligned with the first support on the tower floor. Alignment of the second support with the first support further facilitates placement of the tower external connection assembly.

Preferably, the periphery of the tower body is further provided with a plurality of third supporting pieces which are vertically arranged, and the first supporting pieces and the second supporting pieces which are positioned in the same vertical direction are connected with one third supporting piece. Through this kind of mode, at first, the body of a tower can be convenient support through third support piece, for example supports suitable height, in the in-service use, can overlap a plurality of bodies of a tower in same vertical direction, practice thrift area, on the other hand, connect first support piece and second support piece through third support piece, support each other between first support piece, second support piece and the third support piece, further improved the stability and the reliability that the body of a tower was supported, also further improved the intensity and the rigidity of body of a tower structure.

Preferably, a thermometer connecting pipe for placing a thermometer is connected to the top plate of the tower body, and the thermometer connecting pipe is communicated with the inner space of the tower body. Through setting up the thermometer and taking over, when required, can be through setting up the thermometer, further make things convenient for the use.

Preferably, one thermometer connecting pipe is arranged on the top plate of the tower body corresponding to each filling cavity. The temperature of each area can be conveniently mastered.

The application also discloses a liquid return device for the desulfurizing tower,

including setting up the first liquid return pipe on the tower body bottom plate, first liquid return pipe one end with tower body inner space switch-on, the other end is connected with effluent treatment plant or sulfuric acid regeneration system, first liquid return pipe with the tip of tower body inner space switch-on does not surpass the inner wall of bottom plate. Through setting up first liquid return pipe, draw forth the liquid in the tower body, the tip of first liquid return pipe and the interior space switch-on of tower body does not surpass the inner wall of bottom plate, can effectively guarantee the outflow that liquid can be as much as possible in the tower body.

Preferably, the first liquid return pipe comprises a first bent pipe and a second bent pipe, one end of the first bent pipe is communicated with the inner space of the tower body, the other end of the first bent pipe is connected with the second bent pipe, the first bent pipe is provided with a first bent part protruding downwards, and liquid can be converged in the first bent part to form a liquid seal for blocking the first liquid return pipe. In the scheme of the application, the liquid seal is formed through the bent part of the first liquid return pipe, so that the first liquid return pipe is blocked when needed, and the exhaust of the flue gas from the first liquid return pipe is avoided; furthermore, the device has the advantages of simple structure, convenience in processing and manufacturing and the like; on the other hand, sulfur dioxide, sulfuric acid and the like have strong corrosiveness, so compared with the traditional valve structure, the blocking of the first liquid return pipe is realized by adopting a liquid seal, the durability is better, and the structural performance is more stable and reliable.

Further preferably, the second bent pipe has a second bent portion protruding upward, the first bent portion is lower than the second bent portion, and the first bent portion has a horizontal height smaller than that of the second bent portion. In this way, the formation of a liquid seal is achieved.

Preferably, the first elbow and the second elbow are butted to form an inverted S shape. Further facilitating processing and manufacturing.

Preferably, the level of the first elbow inner runner is lower than the level of the tower body bottom plate inner wall. Ensure that the liquid in the body of the tower can be smooth and easy follow first liquid return pipe outflow.

Preferably, a first exhaust pipe is further arranged at the top of the second bent part, the lower end of the first exhaust pipe is communicated with the internal flow passage of the second bent part, and the upper end of the first exhaust pipe is communicated with the external atmosphere. Through setting up first blast pipe, further make things convenient for the outflow of liquid in the tower body, simultaneously, also guarantee to form the liquid seal that blocks first return liquid pipe in first return bend.

Preferably, the upper end of the first exhaust pipe is higher than the highest possible position of the liquid in the tower body. Avoiding the liquid in the tower body from overflowing from the calandria.

Preferably, the top end portion of the first exhaust pipe is bent downward so that the opening of the first exhaust pipe faces downward. External space sundries and/or rainwater can be effectively prevented from entering the first exhaust pipe.

The application also discloses a desulfurizing tower, including foretell filtering layer subassembly. The desulfurizing tower of this application owing to adopted foretell filtering layer subassembly, can improve the contact efficiency of sulfur dioxide and desulfurizing agent in the flue gas by a wide margin, and then improve the desorption efficiency of sulfur dioxide in the flue gas, desulfurizing agent in this application can take place chemical reaction and then realize the chemical preparation of sulfur dioxide desorption with sulfur dioxide, also can be the catalyst that is used for catalyzing sulfur dioxide and other substances and takes place chemical reaction and then realize the sulfur dioxide desorption.

Preferably, the catalyst support assembly is further included. Furthermore, the catalyst supporting component is also adopted in the desulfurizing tower structure, so that a good supporting effect can be achieved on the filtering layer in the desulfurizing tower.

Preferably, the tower body further comprises the tower body, and the tower body can be any one of the two tower bodies or can be a combination of the two tower bodies.

The application also discloses a pickling tank for desulfurization equipment line, the pickling tank includes first cell body, be provided with at least one second baffle in the first cell body, the second baffle will the space in the first cell body is cut apart into two at least first cell body units that are used for independently collecting sulfuric acid, all is provided with the first pipeline that all communicates with the first liquid return pipe of desulfurizing tower on every first cell body unit, all be provided with the valve on the first pipeline.

Preferably, the number of the second partition plates is at least two, and the second partition plates divide the space in the first tank body into at least three first tank body units.

The utility model provides a pickling tank, through setting up the second baffle, cut apart the inner space of pickling tank into two at least independent first cell body units of collecting sulfuric acid, when washing the desulfurizing tower inside, the liquid pump is used for independent sulphuric acid pump to the inlet tube of desulfurizing tower in each first cell body unit, can carry out the washing work of catalyst in carrying out the desulfurizing tower through the cooperation between the first cell body unit, promptly, the sulphuric acid after washing flows into another first cell body unit with the sulphuric acid pumping in one of them first cell body unit, so relapse, wash repeatedly the catalyst layer in the desulfurizing tower, on the one hand is the cleanliness factor that improves the catalyst and is washed, on the other hand also can improve the sulfuric acid concentration in the pickling tank, improve the recovery value of sulphuric acid.

In the scheme, when the number of the first tank units is at least three, the coordination range between the first tank units is enlarged when the flushing operation of the catalyst layer is carried out, so that a more optimized flushing mode can be provided; particularly, in a desulfurization equipment line with a plurality of desulfurization towers, not only the flushing efficiency can be greatly improved, but also the concentration of sulfuric acid can be greatly improved; on the other hand, two or more desulfurizing towers can ensure that at least one desulfurizing tower is in a working state when the catalyst is regenerated, so that uninterrupted flue gas treatment is ensured;

Further, because the first cell body units are at least three, the sulfuric acid is repeatedly used, the concentration of the sulfuric acid in each first cell body unit is different, in the actual flushing process, the high-concentration sulfuric acid is adopted to flush the catalyst layer for the first time, and then the sulfuric acid with the secondary concentration is gradually adopted to flush the catalyst layer for the subsequent time, so that the concentration of the sulfuric acid in one part is continuously improved, after the sulfuric acid with the best concentration reaches the recovery requirement, the sulfuric acid with the other concentration is extracted and recovered, and the flushing operation is repeated for the sulfuric acid with the other concentration, so that the recovery value of the sulfuric acid is further improved.

Preferably, the upper end of the first tank body is further provided with a first sealing plate for sealing the opening at the upper end of the first tank body, and the first pipeline passes through the first sealing plate and is communicated with the inner space of the first tank body unit. Through setting up first shrouding, prevent that sulfuric acid from spilling outside the pickling tank.

Preferably, the first sealing plates corresponding to each first pool body unit are provided with second exhaust pipes, the lower ends of the second exhaust pipes penetrate through the first sealing plates and extend into the first pool body units, and the upper ends of the second exhaust pipes are open. Through setting up the second blast pipe, with the gaseous discharge in the first cell body unit, guarantee the smooth and easy of sulphuric acid circulation.

Preferably, the upper end portion of the second calandria is bent downward, so that the upper end of the second calandria faces downward. Can avoid foreign matters or rainwater from falling into the pickling tank.

Preferably, a drain valve is arranged at the bottom of each first tank unit. The cleaning in the pickling tank is conveniently kept, and the cleaning of sulfuric acid is further ensured.

Preferably, each first tank unit is provided with a liquid level meter for detecting the internal liquid level. Is convenient for controlling the liquid level height in the pickling tank.

Preferably, the first tank body is further connected with a plurality of fourth supporting pieces, and the fourth supporting pieces are matched with the third supporting pieces. In this scheme, through setting up fourth support piece, during the in-service use, can set up the pickling tank of this application on the third support piece of desulfurizing tower below, on the one hand be so that the desulfurizing equipment line occupies the less area, on the other hand, also improved the wholeness between each equipment.

The application also discloses an oil removal pond for flue gas desulfurization equipment line, including the second cell body, be provided with at least one third baffle and at least one fourth baffle in the second cell body, obtain the side reason of the vertical direction of third baffle and four baffles with the inner wall of second cell body is sealed to be connected be formed with first runner in the second cell body of third baffle top be formed with the second runner in the second cell body of fourth baffle below, first runner with the intercommunication has the third runner between the second runner, be provided with the oil removal part that is used for filtering tar in the third runner.

In carrying out flue gas desulfurization process, there is a large amount of tar in the sulfuric acid that the flushing catalyst formed, adopt this application oil removal pond, will have the sulfuric acid of more tar content through the oil removal pond, sulfuric acid is when passing the oil removal part, oil removal part stops in the tar, and then reduced the tar content in the sulfuric acid, through the sulfuric acid of oil removal pond, when concentration reaches the recovery requirement, can directly retrieve, owing to have lower tar content, and then made things convenient for sulfuric acid's recovery work, when the sulfuric acid concentration through the oil removal pond is lower, can make it get into the pickling pond again and wash the work to the catalyst in the desulfurizing tower, because the reduction of tar volume, can wash the catalyst more clean.

Preferably, the lower edge of the third partition plate is in closed connection with the bottom of the second tank body, and the upper edge of the third partition plate is separated from the upper end of the second tank body to form the first flow channel.

Preferably, the upper edge of the fourth partition board is flush with the upper end of the second tank body, and the lower edge of the fourth partition board is separated from the bottom of the second tank body to form a second flow channel.

The arrangement ensures that the sulfuric acid flows in a relief form when passing through the oil separation part, and is beneficial to tar in the sulfuric acid from the oil separation part.

Preferably, the oil separation component comprises a plurality of screen plates connected between the third partition plate and the fourth partition plate, the screen plates, the third partition plate and the fourth partition plate are surrounded to form a closed cavity, and granular filler is filled in the cavity. The packing is coated by the screen plate, so that the sulfuric acid can smoothly pass through the oil separation part.

Preferably, the filler is quartz sand. The quartz sand has stable chemical and physical properties, can be repeatedly used, ensures good oil separation effect, and saves the use cost.

Preferably, a second sealing plate for sealing the second tank body is arranged at the upper end of the second tank body. Through setting up the second shrouding, avoid the sulphuric acid to spill outside the second cell body, also can avoid external impurity to enter into in the second cell body.

Preferably, the second tank body comprises a liquid inlet tank and a liquid outlet tank, the liquid inlet tank is communicated with the second flow channel, the liquid outlet tank is communicated with the first flow channel, and a liquid level meter for detecting the liquid level inside the liquid inlet tank is further arranged on the second tank body corresponding to the liquid inlet tank.

Preferably, a liquid level meter for detecting the liquid level inside the liquid pool is further arranged on the second pool body corresponding to the liquid outlet pool.

Through the setting of liquid level, the convenience is to the grasp of the interior liquid level height of oil removal pond, and another portion can be through comparing the reading of feed liquor pond level gauge and the liquid level gauge reading of play pond, confirms the tar content in the oil removal portion, when the reading difference is great, can the specification have a large amount of tar in the oil removal portion, and then can consider to change or clean the packing in the oil removal portion.

Preferably, a third exhaust pipe is further arranged on the second sealing plate corresponding to the liquid outlet pool, and one end of the third exhaust pipe extends into the liquid outlet pool and is flush with the inner wall of the second sealing plate.

Preferably, the second sealing plate is provided with a plurality of reinforcing ribs.

Preferably, drain valves are arranged at the bottoms of the liquid inlet tank and the liquid outlet tank. The cleaning of the inside of the oil separation tank can be conveniently ensured.

The application also discloses a regeneration system for the flue gas desulfurization equipment line,

the acid pickling tank comprises the acid pickling tank and at least one first liquid pump assembly, wherein the first liquid pump assembly is further connected with a water inlet pipe of the desulfurization tower, and the first liquid pump assembly is used for independently pumping sulfuric acid in each first tank body unit to the water inlet pipe.

For the desulfurizing tower with the catalyst adopted by the filter layer assembly, along with the continuous desulfurization work, the formed sulfuric acid is more and more adhered to the catalyst, so that the catalyst can not be well contacted with flue gas to reduce the removal effect of sulfur dioxide, and the flow of flue gas is not facilitated to reduce the desulfurization efficiency of the desulfurizing tower;

Therefore, after the desulfurizing tower operation certain time, start the regeneration system of this application, adopt water to wash the sulphuric acid that adheres to on the catalyst, the sulphuric acid that forms flows down to the pickling tank, realize the regeneration of catalyst, in this scheme, the sulphuric acid that flows into the pickling tank is used for washing the catalyst layer repeatedly, until the sulphuric acid concentration reaches the recovery requirement, adopt the pickling tank of this application, through setting up the second baffle, the inner space of pickling tank is cut apart into two at least independent first cell body units of collecting sulphuric acid, when washing the desulfurizing tower inside, the liquid pump is used for independent to pump the sulphuric acid in each first cell body unit to the inlet tube of desulfurizing tower, can be through the cooperation between the first cell body units, namely, carry out the washing work of catalyst with the sulphuric acid in one of them first cell body unit in the pumping to the desulfurizing tower, the sulphuric acid after the washing flows into another first cell body unit, so repeatedly, wash the catalyst layer in the desulfurizing tower repeatedly, the cleanliness factor that the catalyst was washed is improved, on the other hand also can improve the value of sulphuric acid in the pickling tank, the recovery of sulphuric acid.

Preferably, the first liquid pump assembly is at least two. By arranging at least two liquid pump components, the flushing operation of a plurality of desulfurizing towers can be simultaneously carried out, and the flushing efficiency is improved; on the other hand, one or more liquid pump components can be used as spare, so that the reliable operation of the equipment is ensured.

Preferably, the regeneration system further comprises a liquid return main pipe, the first liquid return pipe of each desulfurization tower is connected with the liquid return main pipe, and the pickling tank is communicated with the first liquid return pipe through the liquid return main pipe.

The application also discloses sulfuric acid recovery equipment line, including foretell oil removal pond and regeneration system, regeneration system's back liquid be responsible for still with the feed liquor pond intercommunication of oil removal pond the back liquid be responsible for with be provided with the valve on the pipeline between the feed liquor pond, the play liquid pond of oil removal pond still with regeneration system's pickling pond intercommunication be provided with the valve on the pipeline of intercommunication between play liquid pond and the pickling pond.

The utility model provides a sulfuric acid recovery equipment line carries out catalyst flushing operation at the desulfurization equipment line, when the tar content in the sulfuric acid is higher, in carrying the feed liquor pond of oil removal pond with the sulfuric acid, filter the tar in the sulfuric acid, then carry the pickling towards carrying out the flushing operation of catalyst with the sulfuric acid after filtering again, so, on the one hand because the tar is filtered in the sulfuric acid for the catalyst can be washed more the sensation, on the other hand, also can make the sulfuric acid can wash the catalyst more times, so, improvement sulfuric acid concentration by a wide margin, improvement sulfuric acid's recovery value.

Preferably, the filter and the pump body are further included, an inlet of the pump body is communicated with a liquid outlet pool of the oil separation pool, and an outlet of the pump body is communicated with an inlet of the filter. When the sulfuric acid in the oil separation tank is sufficiently high, the sulfuric acid is pumped into the filter through the pump body after oil separation, and clean sulfuric acid is obtained through further filtration, so that the recovery of the sulfuric acid is realized.

Preferably, the outlet of the filter is also connected with a finished acid tank for collecting sulfuric acid.

Preferably, the pump body is a membrane filtration pump. The adoption of the membrane filter pump can further filter the sulfuric acid, so that the cleanliness of the sulfuric acid is further improved.

Preferably, the number of the pump bodies is two, and the two pump bodies are connected in parallel between the liquid outlet pool and the filter inlet. One of the pump bodies is ready for use, including reliable operation of the device.

Preferably, the filtering comprises a filter cartridge, wherein a plurality of filter membrane components are arranged in the filter cartridge, and the filter membrane components are used for filtering sulfuric acid pumped by the pump body.

Preferably, a flushing pipeline is further arranged on the filter cylinder, one end of the flushing pipeline extends into the filter cylinder, and the other end of the flushing pipeline is communicated with an external clean water source. When the impurities on the filter membrane component are too much, the filter membrane component is washed through the washing pipeline, so that the filter membrane component can keep a good filtering effect.

Preferably, the filter cylinder is further provided with a blast pipe, one end of the blast pipe extends into the filter cylinder, and the other end of the blast pipe is connected with a blast device. After the filter membrane component is washed, a blast device is used for blowing high-speed air flow, so that the inner space of the filter cartridge is dried, and the residual cleaning liquid in the filter cartridge is prevented from diluting or polluting sulfuric acid.

The application also discloses a liquid seal system for desulfurization equipment line, including the U-shaped pipe and be used for adorning the liquid seal pond of flourishing liquid seal liquid, U-shaped pipe one end and the pipeline intercommunication of carrying untreated flue gas, the other end and desulfurizing tower advance the tobacco pipe intercommunication the U-shaped pipe with be provided with the second liquid pump subassembly between the liquid seal pond, the second liquid pump subassembly be used for with liquid seal liquid pump in the liquid seal pond arrives in the U-shaped pipe. By adopting the liquid seal system, the on-off of the smoke inlet pipeline is realized, and as described above, the liquid seal system is simple in structure and has better durability and reliability.

Preferably, the second liquid pump assembly is two sets. One group is standby, and the reliability of the equipment is ensured.

Preferably, the bottom of the U-shaped pipe is also connected with a second liquid return pipe, the second liquid return pipe is communicated with a pickling tank of the catalyst regeneration system, and a valve is arranged on a pipeline communicated with the pickling tank. When the desulfurization tower is used for flue gas treatment, the liquid seal liquid in the U-shaped pipe is put into the pickling tank for regeneration flushing of the rest of desulfurization tower catalysts, so that sulfuric acid and use cost are saved.

Preferably, a drain valve is further arranged at the bottom of the liquid seal tank.

The application also discloses a flue gas desulfurization equipment line, desulfurization equipment line includes at least one foretell desulfurizing tower.

The desulfurization equipment line of this application owing to adopted foretell desulfurizing tower, can improve the contact efficiency of sulfur dioxide and desulfurizing agent in the flue gas by a wide margin, and then improve the desorption efficiency of sulfur dioxide in the flue gas, desulfurizing agent in this application can take place chemical reaction and then realize sulfur dioxide desorption with sulfur dioxide's chemical formulation, also can be used for catalyzing sulfur dioxide and other substances and take place chemical reaction and then realize sulfur dioxide's catalyst

Preferably, the liquid sealing system is further included. Due to the adoption of the liquid sealing system, the on-off of the smoke inlet pipeline is realized, and as described above, the device has the advantages of simple structure, better durability and reliability

Preferably, the sulfuric acid recovery equipment line is further included.

The desulfurizing tower of this application owing to adopted foretell filtering layer subassembly, can improve the contact efficiency of sulfur dioxide and desulfurizing agent in the flue gas by a wide margin, and then improve the desorption efficiency of sulfur dioxide in the flue gas, desulfurizing agent in this application can take place chemical reaction and then realize the chemical preparation of sulfur dioxide desorption with sulfur dioxide, also can be the catalyst that is used for catalyzing sulfur dioxide and other substances and takes place chemical reaction and then realize the sulfur dioxide desorption.

Compared with the prior art, the beneficial effect of this application:

according to the liquid return device, the liquid seal is formed through the bent part of the first liquid return pipe, so that the first liquid return pipe is blocked when needed, and smoke is prevented from being discharged from the first liquid return pipe; furthermore, the device has the advantages of simple structure, convenience in processing and manufacturing and the like; on the other hand, sulfur dioxide, sulfuric acid and the like have strong corrosiveness, so compared with the traditional valve structure, the blocking of the first liquid return pipe is realized by adopting a liquid seal, the durability is better, and the structural performance is more stable and reliable.

Description of the drawings:

FIG. 1 is a schematic structural view of an arrangement of filter layer components inside a desulfurizing tower;

FIG. 2 is a schematic view of a partial structure of the filter assembly mated with the support assembly;

FIG. 3 is a schematic view of the support beam and support ring mated configuration;

FIG. 4 is a schematic view of a partial structure of the support columns mated with the support beams;

FIG. 5 is a schematic view of an arrangement of support tubes, first support members and third support members in a desulfurizing tower;

FIG. 6 is a top view of the desulfurizing tower body;

FIG. 7 is a schematic view of the structure of the liquid return device of the desulfurizing tower;

FIG. 8 is a schematic structural view of the pickling tank;

FIG. 9 is a schematic view of the structure of an oil separator

FIG. 10 is a schematic view of a partial structure of an oil separator;

FIG. 11 is a schematic diagram of an equipment arrangement of a regeneration system;

FIG. 12 is a schematic view of the equipment layout of a flue gas desulfurization plant line when one desulfurization tower is employed;

FIG. 13 is a schematic view showing the arrangement of the flue gas desulfurization equipment line when one desulfurizing tower is employed,

the labels in figures 1-13: 100-tower body, 101-flue gas inlet, 102-flue gas outlet, 103-filter layer assembly, 104-first silk screen, 105-first saddle ring layer, 106-second saddle ring layer, 107-second silk screen,

108-grid plates, 109-supporting beams, 110-supporting rings, 111-first reinforcing ribs, 112-supporting columns, 113-backing plates, 114-supporting tubes,

115-smoke inlet pipe, 116-bottom plate, 117-first support, 118-shower head, 119-water inlet pipe, 120-first baffle, 121-top plate, 122-manhole, 123-discharge opening, 124-second support, 125-third support, 126-thermometer nipple, 127-first elbow, 128-second elbow, 129-first elbow, 130-second elbow, 131-first exhaust pipe, 132-filter layer,

133-first tank, 134-second separator, 135-first tank unit, 136-first duct, 137-first closure plate, 138-second vent tube, 139-fourth support,

140-second tank body, 141-third baffle, 142-fourth baffle, 143-oil separating component, 144-screen, 145-second sealing plate, 146-liquid inlet tank, 147-liquid outlet tank, 148-third exhaust pipe, 149-liquid level meter, 150-reinforcing rib,

151-first liquid pump assembly, 152-liquid return main pipe, 153-first liquid return pipe, 154-filter, 155-pump body, 156-finished acid tank, 157-filter cartridge, 158-flushing pipe, 159-blast pipe, 160-filter membrane assembly, 161-liquid seal tank, 162-second liquid pump assembly, 163-second liquid return pipe.

Detailed Description

The present application will be described in further detail with reference to test examples and specific embodiments. It should not be understood that the scope of the subject matter described above is limited to the following examples, and that all techniques implemented based on the content of this application fall within the scope of this application.

Example 1, as shown in fig. 1-13:

the filter layer assembly 103 is positioned between the flue gas inlet 101 and the flue gas outlet 102 of the desulfurizing tower, so that the flue gas passes through the filter layer assembly 103 first and then is discharged from the flue gas outlet 102, the filter layer assembly 103 comprises a filter layer 132, and a plurality of flue gas channels for the flue gas to pass through exist in the filter layer 132.

The filtering layer assembly 103 of the application has a plurality of channels that supply the flue gas to pass through in the filter layer 132, and the flue gas that gets into the tower body 100 is discharged by the flue gas export 102 again through these channels, adopts such a mode, can improve the contact efficiency of sulfur dioxide and desulfurizing agent in the flue gas by a wide margin, and then improves the desorption efficiency of sulfur dioxide in the flue gas, and the desulfurizing agent in this application can take place chemical reaction and then realize the chemical preparation of sulfur dioxide desorption with sulfur dioxide, also can be used for catalyzing sulfur dioxide and other substances and take place chemical reaction and then realize the catalyst of sulfur dioxide desorption.

Preferably, the filter layer 132 is formed by stacking or laying a plurality of granular filter units, gaps are formed between adjacent filter units, and a plurality of flue gas channels for flue gas to pass through are formed between the gaps in a mutually connected or mutually independent or partially connected mode.

Preferably, the filter unit is spherical, ellipsoidal or columnar.

Further preferably, the filter unit is cylindrical and has a diameter of 4-6mm.

In practical design and use, the inventor finds that the filter units are set to the above sizes, so that gaps with proper sizes are formed among the filter units, the smooth circulation of the flue gas is ensured, and meanwhile, the gaps inside the filter layer 132 are ensured to have a large enough area, so that the removal efficiency of sulfur dioxide is ensured.

In this scheme, adopt the active carbon as the base member, adhere to desulfurization catalyst on the base member, in desulfurization process, sulfur dioxide and oxygen are under desulfurization catalyst effect, form sulfur trioxide, sulfur trioxide combines with water and forms sulfuric acid and adhere to on the catalyst, and then realize sulfur dioxide's desorption, further, in this scheme, because the base member adopts the active carbon, active carbon surface and inside all have more holes, on the one hand, make the base member can adhere to more desulfurization catalyst, further improve sulfur dioxide's desorption efficiency, on the other hand, the flue gas passageway shape of formation is also more tortuous various, when more being favorable to the flue gas to pass through filter layer 132, also be favorable to the desorption of sulfur dioxide more.

In this scheme, the sulfur dioxide absorbent is an alkaline compound that can chemically react with sulfur dioxide, for example, a compound such as calcium, sodium, magnesium, ammonium, etc., and in this way, when the flue gas passes through the filter layer 132, the sulfur dioxide chemically reacts with the filter layer material, thereby further removing sulfur dioxide in the flue gas.

In the scheme, inert materials are adopted to manufacture the filtering unit, such as stainless steel or activated carbon is adopted as the filtering unit, in a wet desulfurization mode, a desulfurizing agent is sprayed from the upper part of the filtering layer 132, flue gas enters from the lower part of the filtering layer 132, when the desulfurizing agent falls onto the filtering layer 132, the flue gas is in a spraying state, a plurality of fine liquid drops and liquid mist are formed, and then the flue gas continuously flows to the lower part of the filtering layer 132, and in the process, the flue gas can be fully contacted with the desulfurizing agent, so that the contact rate of sulfur dioxide and the desulfurizing agent is greatly improved, and the removal rate of sulfur dioxide is greatly improved.

Preferably, the filter layer assembly 103 further includes a first wire mesh 104, the filter units are stacked or laid on the first wire mesh, and the first edge is matched with the inner wall of the tower body 100. By arranging the first silk screen 104, the filter unit is supported, and meanwhile, the smoothness of smoke circulation is ensured.

Preferably, the first wire mesh 104 is a stainless steel wire mesh. Ensuring good durability of the first wire mesh 104.

Preferably, the filter layer assembly 103 further includes a first saddle ring layer 105, and the first saddle ring layer 105 includes a plurality of first saddle rings, and the first saddle rings are laid side by side under the first wire mesh 104. Through setting up first different saddle ring layer 105, because different saddle ring structure has characteristics such as macroporosity and high flux, so, in the scheme of this application, through the bearing structure of a plurality of first different saddle ring formation first silk screen 104 side by side, when guaranteeing that first silk screen 104 is reliably supported, still improve the homogeneity that flue gas got into filter layer 132, improve sulfur dioxide's desorption efficiency.

Further preferably, the filter layer assembly 103 further includes a second saddle ring layer 106, the second saddle ring layer 106 includes a plurality of second saddle rings, the second saddle rings are laid on the first saddle ring layer 105 side by side, the structural size of the second saddle rings is smaller than that of the first saddle rings, and the structural size of the second saddle rings ensures that the second saddle rings do not fall from the pores of the first saddle rings.

In the above scheme, through setting up two-layer structure different in size's different saddle ring, support first silk screen 104 through the different saddle ring layer 106 of second that the size is less, further guaranteed the planarization that first silk screen 104 was supported, and support the different saddle ring layer 106 of second through the different saddle ring layer 105 of the great first of size, not only guaranteed the smoothness of flue gas circulation, also reduced the laying degree of difficulty on the different saddle ring layer 105 simultaneously.

Further preferably, the filter layer assembly 103 further includes a second wire mesh 107, an edge of the second wire mesh 107 is matched with an inner wall of the tower body 100, and the first saddle ring layer 105 is laid on the second wire mesh 107.

Example 2, as shown in fig. 1-13:

a catalyst support assembly for a desulfurizing tower, the support assembly being disposed within a tower body 100 of the desulfurizing tower, the support assembly being positioned below the filter layer assembly 103, the support assembly being configured to support the filter layer assembly 103 such that the filter layer assembly 103 is spaced from a bottom of the tower body 100.

In this scheme, through supporting component, separate filtering layer subassembly 103 and body of tower 100 bottom, on the one hand make things convenient for the flue gas to have sufficient space and be full of in filtering layer subassembly 103's below space, avoid the flue gas to pass from the filtering layer that is close to the inlet portion only, and then guarantee the filtration efficiency of the sulfur dioxide of filtering layer.

Preferably, the support assembly comprises a grid plate 108, an edge of the grid plate 108 is matched with an inner wall of the tower body 100, and the second wire mesh 107 of the filter layer assembly 103 is laid on the grid plate 108.

The grid plate 108 is used for supporting the filter layer assembly 103, so that the filter layer assembly 103 can be effectively guaranteed to have good flatness, and further all parts of the filter layer can be well utilized, and moreover, the grid plate 108 has a plurality of holes, so that the filter layer assembly 103 is well supported, and meanwhile, the smoothness of smoke circulation is guaranteed.

Preferably, the support assembly further comprises a plurality of support beams 109, the support beams 109 are used for supporting the grid plates 108, the plurality of support beams 109 are arranged side by side, adjacent support beams 109 are spaced apart, two ends of the support beams 109 are matched with the inner wall of the tower body 100, and the grid plates 108 are located on the support beams 109.

In the above scheme, the grid plate 108 is supported by the plurality of support beams 109, so that the reliability of the grid plate 108 being supported is ensured, the reliability of the filter layer assembly 103 being supported is also ensured, and the support beams 109 are arranged at intervals, so that the smoothness of smoke circulation is ensured.

Preferably, an annular supporting ring 110 is connected between the ends of the adjacent supporting beams 109, the supporting rings 110 are arranged along the inner wall of the tower body 100, two ends of each supporting ring 110 are respectively connected with the adjacent supporting beams 109, and the outer edge of each supporting ring 110 is matched with the inner wall of the tower body 100.

In the above-mentioned scheme, by arranging the ring-shaped supporting ring 110, on one hand, the edges of the grating plates can be reliably supported, and the reliability of the supporting component for supporting the filtering component is further ensured; on the other hand, since the support beams 109 are connected, the stability of the support beams 109 is also enhanced to some extent; on the other hand, since the tower body 100 is generally in a thin-walled tubular structure, in the present application, the combination of the support ring 110 and the support beam 109 is adopted, and the support of the filter layer assembly 103 is equivalent to forming a ring of reinforcing ring structure on the inner wall of the tower body 100, so that the structural strength of the tower body 100 is also improved, the risk of deformation of the tower body 100 can be greatly reduced, and the tower body 100 can well maintain the design form.

Preferably, the supporting beam 109 is i-steel, and the upper side of the upper flange of the supporting beam 109 is matched with the lower side of the grid plate 108.

Preferably, the supporting ring 110 is plate-shaped, and two ends of the supporting ring 110 are respectively abutted with upper side edges of adjacent supporting beams 109.

Preferably, the upper side of the support ring 110 is in the same plane as the upper side of the upper flange of the support beam 109.

By the arrangement of the scheme, the upper side surfaces of the supporting beams 109 and the upper side surfaces of the supporting rings 110 form a supporting platform, and the supporting platform and the grid plate 108 have larger matching surfaces, so that the reliability of the supporting of the filter layer 132 is further ensured.

Preferably, a first reinforcing rib 111 is further connected between the supporting ring 110 and the web of the supporting beam 109. The strength of the connection between the support ring 110 and the support beam 109 is increased by providing the first reinforcing ribs 111.

Preferably, a plurality of support columns 112 are further disposed below each support beam 109, the upper ends of the support columns 112 are connected with the support beams 109, and the lower ends of the support columns 112 are connected with the bottom plate 116 of the tower body 100.

Preferably, the support columns 112 of the same support beam 109 are spaced apart. The adjacent upright posts are separated, so that the reliable support of the support beam 109 is ensured, and the smooth smoke circulation is also conveniently ensured.

Preferably, the upper end and/or the lower end of the supporting upright post 112 is/are connected with a backing plate 113. The reliability of the connection is ensured by providing the pad 113.

Preferably, the support posts 112 are steel tubes.

Preferably, a plurality of support tubes 114 are also connected between adjacent support beams 109. The support pipes 114, the support beams 109, the support columns 112 and the tower body 100 form a mutually supported frame structure through connection, so that on one hand, the filter layer assembly 103 is reliably supported, and on the other hand, the structural strength of the tower body 100 is greatly improved.

Preferably, the connection between the support tube 114 and the support beam 109 is located above the support column 112. That is, the upright posts and the support tubes 114 are connected with the support beams 109 at the same position, so that the stress transmission of each component is facilitated, and the structural stability of the support assembly is further improved.

Example 3, as shown in fig. 1-13:

the application also discloses a tower body for the desulfurizing tower,

the smoke inlet 101 is connected with a smoke inlet pipe 115, one end of the smoke inlet pipe 115 extends into the tower body 100, and in the vertical direction, the smoke inlet pipe 115 positioned in the tower body 100 has a shielding part above any part of the inner wall of the smoke inlet pipe.

In the scheme, a shielding exists above any part of the inner wall of the tower body 100, so that the phenomenon that liquid or other materials above the tower body fall into the smoke inlet pipe 115 to influence the smoke gas transmission is avoided; the port of the smoke inlet pipe 115 positioned in the tower body 100 can be in a bevel structure; cutting the lower half part of the port to form the upper half part to cover the lower half part; or a separate shielding structure can be arranged to shield the port of the smoke inlet pipe 115.

Preferably, the port of the smoke inlet pipe 115 located inside the tower body 100 is a bevel. The inclined port structure is arranged, so that the smoke inlet pipe 115 can achieve the effect, meanwhile, the processing is convenient, the materials are saved, and the manufacturing cost can be effectively reduced.

Preferably, the flue gas inlet 101 is disposed on a side wall of the tower body 100, and the flue gas inlet pipe 115 enters the tower body 100 from the side wall of the tower body 100. The smoke inlet pipe 115 enters the tower body 100 from the side wall of the tower body 100, so that the structure of the bottom of the tower body 100 is simplified, the installation and arrangement of the tower body 100 are convenient, and the processing and the manufacturing are convenient.

Preferably, the port of the smoke inlet pipe 115 located inside the tower body 100 is spaced apart from the bottom plate 116 of the tower body 100. Further preventing liquids or other materials from entering the tower body 100 into the smoke inlet pipe 115.

Preferably, a plurality of first supporting members 117 are further connected to the outer wall of the bottom plate 116 of the tower body 100, the first supporting members 117 are disposed parallel to each other, and a distance is provided between adjacent first supporting members 117.

As another preferred aspect, the first supporting member 117 is disposed along a radial direction of the tower 100.

As described above, the plurality of first supporting members 117 are disposed on the bottom plate 116 of the tower body 100, which is convenient for installing and arranging the tower body 100 on one hand, and the first supporting members 117 also play a role of reinforcing the bottom plate 116 of the tower body 100, so as to improve the structural strength of the tower body 100 on the other hand.

As another preferred aspect, the first supporting member 117 corresponds to the supporting column 112 of the supporting assembly, and the supporting member is located directly under the supporting column 112. In the scheme of this application, support column 112 is used for supporting filtering layer subassembly 103, and first support 117 is located the support column 112 under, so, on the one hand guarantees that support column 112 has good support strength and support stability, on the other hand, also can reduce the deformation that tower body 100 bottom plate 116 produced because of dead weight and the pressure that support column 112 applyed, further improved the reliability of tower body 100 structure.

Preferably, the first supporting member 117 is i-steel, channel steel or rectangular steel pipe. The I-steel, the channel steel or the rectangular steel pipe can be adopted, and other sectional materials can be adopted, so that on one hand, the sectional materials are used as standard components, the market purchase is facilitated, the processing cost can be saved, and on the other hand, the sectional materials are provided with grooves or openings, and therefore the connection between the first supporting piece 117 and other supporting pieces is also facilitated.

Example 4, as shown in fig. 1-13:

the present application also discloses a tower body 100 for a desulfurizing tower,

a plurality of spray heads 118 are arranged on the inner side of a top plate 121 of the tower body 100, and each spray head 118 is connected with a water inlet pipe 119.

In the scheme of this application, through setting up shower head 118, can spout the desulfurizing agent that reacts with sulfur dioxide in the shower head 118, also can spout and be used for washing filtering layer assembly 103, guarantee that filtering layer assembly 103 is clean or resume the washing liquid of catalyst activity, for example clear water, make filtering layer assembly 103 can use repeatedly to guarantee good filtering effect.

Preferably, the showerhead 118 is uniformly distributed about the flue gas outlet 102.

Preferably, at least one first partition plate 120 is further disposed in the tower body 100, and the first partition plate 120 is located above the grid plate 108 of the support assembly, so as to divide the internal space of the tower body 100 above the grid plate 108 into at least two filling cavities for filling the filtering units.

By providing the first partition 120, the inner space of the tower body 100 above the filter layer assembly 103 is divided, so that the filter units in each filling cavity can be conveniently controlled, for example, the filter units can be respectively filled or respectively replaced, and the handle control of the filter units is convenient.

Preferably, the upper end of the first partition 120 is spaced from the inner wall of the top plate 121 of the tower body 100, so that each filling cavity is connected to the flue gas outlet 102. In this way, the filling cavity can share one smoke outlet 102, and the structure of the tower body 100 is further simplified.

Preferably, a manhole 122 is provided on the top plate 121 of the tower body 100 corresponding to each filling cavity, a discharge opening 123 for taking out the filtering unit is provided on the side wall of the tower body 100 corresponding to each filling cavity, and a sealing cover is detachably connected to the manhole 122 and the discharge opening 123. The manhole 122 may be used for both worker access and filling of the filter unit, thus facilitating filling and replacement of the filter unit.

Preferably, a plurality of second supporting members 124 are further disposed on the outer wall of the top plate 121 of the tower body 100, and the second supporting members 124 are disposed in parallel with each other, and a distance is provided between adjacent second supporting members 124.

As another preferred option, the second support 124 is disposed along a radial direction of the tower 100.

As described above, the plurality of second supporting members 124 are disposed on the top plate 121 of the tower body 100, which is convenient for installing and arranging the tower body 100 on one hand, and the second supporting members 124 also play a role in reinforcing the top plate 121 of the tower body 100, so as to improve the structural strength of the tower body 100 on the other hand.

Preferably, the second support 124 is aligned with the first support 117 on the floor 116 of the tower 100. Alignment of the second support 124 with the first support 117 further facilitates placement of the external connection assembly of the tower 100.

Preferably, a plurality of third supporting members 125 are further disposed on the periphery of the tower body 100, and the first supporting member 117 and the second supporting member 124 located in the same vertical direction are connected to one third supporting member 125. In this way, firstly, the tower body 100 can be conveniently supported by the third supporting member 125, for example, to a proper height, in practical use, a plurality of tower bodies 100 can be overlapped in the same vertical direction, so as to save the occupied area, on the other hand, the third supporting member 125 is used for connecting the first supporting member 117 and the second supporting member 124, and the first supporting member 117, the second supporting member 124 and the third supporting member 125 support each other, so that the stability and the reliability of the supported tower body 100 are further improved, and the strength and the rigidity of the structure of the tower body 100 are also further improved.

Preferably, a thermometer adapter 126 for placing a thermometer is connected to the top plate 121 of the tower body 100, and the thermometer adapter 126 is connected to the inner space of the tower body 100. By providing the thermometer nipple 126, the use may be further facilitated by providing a thermometer, if desired.

Preferably, one of the thermometer connecting pipes 126 is disposed on the top plate 121 of the tower body 100 corresponding to each of the filling cavities. The temperature of each area can be conveniently mastered.

Example 5, as shown in fig. 1-13:

the device comprises a first liquid return pipe 153 arranged on a bottom plate 116 of the tower body 100, wherein one end of the first liquid return pipe 153 is communicated with the inner space of the tower body 100, the other end of the first liquid return pipe 153 is connected with a wastewater treatment device or a sulfuric acid regeneration system, and the communicated end of the first liquid return pipe 153 and the inner space of the tower body 100 does not exceed the inner wall of the bottom plate 116. By arranging the first liquid return pipe 153, liquid in the tower body 100 is led out, and the end part of the first liquid return pipe 153, which is communicated with the inner space of the tower body 100, does not exceed the inner wall of the bottom plate 116, so that the liquid in the tower body 100 can be effectively ensured to flow out as much as possible.

Preferably, the first liquid return pipe 153 includes a first elbow 127 and a second elbow 128, one end of the first elbow 127 is connected to the inner space of the tower body 100, the other end of the first elbow 127 is connected to the second elbow 128, the first elbow 127 has a first elbow 129 protruding downward, and the first elbow 129 can collect liquid to form a liquid seal for blocking the first liquid return pipe 153. In the scheme of the application, the liquid seal is formed through the bent part of the first liquid return pipe 153, so that the first liquid return pipe 153 is blocked when needed, and the exhaust of the flue gas from the first liquid return pipe 153 is avoided; furthermore, the device has the advantages of simple structure, convenience in processing and manufacturing and the like; on the other hand, sulfur dioxide, sulfuric acid and the like have strong corrosiveness, so compared with the traditional valve structure, the blocking of the first liquid return pipe 153 is realized by adopting a liquid seal, the durability is better, and the structural performance is more stable and reliable.

Further preferably, the second bent pipe 128 has a second bent portion 130 protruding upward, the first bent portion 129 is lower than the second bent portion 130, and a horizontal height of the first bent portion 129 is smaller than a horizontal height of the second bent portion 130. In this way, the formation of a liquid seal is achieved.

Preferably, the first and second bends 127, 128 are butted to form an inverted S-shape. Further facilitating processing and manufacturing.

Preferably, the level of the internal flow channel of the first elbow 127 is lower than the level of the internal wall of the bottom 116 of the tower body 100, and the level of the internal flow channel of the second elbow 128 is lower than the level of the internal wall of the bottom 116. Ensuring that the liquid in the tower body 100 can smoothly flow out from the first liquid return pipe 153.

Preferably, a first exhaust pipe 131 is further disposed at the top of the second curved portion 130, the lower end of the first exhaust pipe 131 is connected to the internal flow channel of the second curved portion 130, and the upper end of the first exhaust pipe 131 is connected to the external atmosphere. By providing the first exhaust pipe 131, the outflow of the liquid in the tower body 100 is further facilitated, and at the same time, the liquid seal blocking the first liquid return pipe 153 can be ensured to be formed in the first bent pipe 127.

Preferably, the upper end of the first exhaust pipe 131 is higher than the highest possible position of the liquid in the tower body 100. Avoiding liquid in the tower 100 from escaping from the gauntlet.

Preferably, the top end portion of the first exhaust pipe 131 is bent downward, so that the opening of the first exhaust pipe 131 is downward. External space foreign matters and/or rainwater can be effectively prevented from entering the first exhaust pipe 131.

Example 6, as shown in fig. 1-13:

the application also discloses a desulfurizing tower, including foretell filtering layer subassembly 103. The desulfurizing tower of this application owing to adopted foretell filtering layer subassembly 103, can improve the contact efficiency of sulfur dioxide and desulfurizing agent in the flue gas by a wide margin, and then improve the desorption efficiency of sulfur dioxide in the flue gas, desulfurizing agent in this application can take place chemical reaction and then realize the chemical preparation of sulfur dioxide desorption with sulfur dioxide, also can be the catalyst that is used for catalyzing sulfur dioxide and other substances and takes place chemical reaction and then realize the sulfur dioxide desorption.

Preferably, the tower 100 is also included.

Example 7, as shown in fig. 1-13:

the application also discloses a pickling tank for desulfurization equipment line, the pickling tank includes first cell body 133, be provided with at least one second baffle 134 in the first cell body 133, second baffle 134 will the space in the first cell body 133 is cut apart into two at least first cell body units 135 that are used for independently collecting sulfuric acid, all is provided with the first pipeline 136 that all communicates with the first return pipe 153 of desulfurizing tower on every first cell body unit 135, all be provided with the valve on the first pipeline 136.

Preferably, the number of the second partitions 134 is at least two, and the second partitions 134 divide the space in the first tank 133 into at least three first tank units 135.

The pickling tank of this application cuts apart into two at least independent first cell body units 135 of collecting sulfuric acid through setting up second baffle 134 with the inner space of pickling tank, when washing the desulfurizing tower inside, the liquid pump is used for the independent inlet tube 119 that pumps the sulfuric acid in each first cell body unit 135 to the desulfurizing tower, can carry out the washing work of catalyst in pumping to the desulfurizing tower in one of them first cell body unit 135 through the coordination cooperation between the first cell body unit 135, sulfuric acid after the washing flows into another first cell body unit 135, so relapse, wash repeatedly the catalyst layer in the desulfurizing tower, on the one hand is the cleanliness factor that improves the catalyst and is washed, on the other hand also can improve the sulfuric acid concentration in the pickling tank, improve the recovery value of sulfuric acid.

In this scheme, when the number of the first tank units 135 is at least three, the coordination range between the first tank units 135 is enlarged when the flushing operation of the catalyst layer is performed, so that a more optimized flushing mode can be provided; particularly, in a desulfurization equipment line with a plurality of desulfurization towers, not only the flushing efficiency can be greatly improved, but also the concentration of sulfuric acid can be greatly improved; on the other hand, two or more desulfurizing towers can ensure that at least one desulfurizing tower is in a working state when the catalyst is regenerated, so that uninterrupted flue gas treatment is ensured;

Further, since the concentration of sulfuric acid in each first cell unit 135 is different due to the repeated use of at least three first cell units 135, in the actual washing process, the catalyst layer is washed for the first time by using sulfuric acid with high concentration, and then is washed for the subsequent time by using sulfuric acid with gradually low concentration, so that the concentration of sulfuric acid in one part is continuously increased, when the sulfuric acid with the best concentration reaches the recovery requirement, the sulfuric acid with the rest concentration is extracted and recovered, and the washing operation is repeated for the rest sulfuric acid with the above concentration, so that the recovery value of the sulfuric acid is further improved.

Preferably, a first sealing plate 137 for sealing an opening at the upper end of the first tank 133 is further disposed at the upper end of the first tank 133, and the first duct 136 passes through the first sealing plate 137 to communicate with the inner space of the first tank unit 135. By providing the first seal plate 137, sulfuric acid is prevented from spilling out of the pickling bath.

Preferably, a second exhaust pipe 138 is disposed on the first sealing plate 137 corresponding to each first tank unit 135, and the lower end of the second exhaust pipe 138 passes through the first sealing plate 137 and extends into the first tank unit 135, and the upper end is open. By providing the second exhaust pipe 138, the gas in the first cell unit 135 is exhausted, and the smooth flow of sulfuric acid is ensured.

Preferably, a drain valve is provided at the bottom of each of the first tank units 135. The cleaning in the pickling tank is conveniently kept, and the cleaning of sulfuric acid is further ensured.

Preferably, a level gauge 149 for detecting the internal liquid level is provided on each of the first tank units 135. Is convenient for controlling the liquid level height in the pickling tank.

Preferably, the first tank 133 is further connected with a plurality of fourth supporting members 139, and the fourth supporting members 139 are matched with the third supporting members 125. In this scheme, through setting up fourth support 139, during the in-service use, can set up the pickling tank of this application on the third support 125 of desulfurizing tower below, on the one hand make the desulfurizing equipment line occupy less area, on the other hand, also improved the wholeness between each equipment.

Example 8, as shown in fig. 1-13:

the application also discloses an oil removal pond for flue gas desulfurization equipment line, including second cell body 140, be provided with at least one third baffle 141 and at least one fourth baffle 142 in the second cell body 140, obtain the side reason of the vertical direction of third baffle 141 and four baffles with the inner wall of second cell body 140 is sealed to be connected be formed with first runner in the second cell body 140 of third baffle 141 top be formed with the second runner in the second cell body 140 of fourth baffle 142 below, first runner with the intercommunication has the third runner between the second runner, be provided with the oil removal portion 143 spare that is used for filtering the tar in the third runner.

In carrying out flue gas desulfurization process, there is a large amount of tar in the sulfuric acid that the flushing catalyst formed, adopt this application oil removal pond, will have the sulfuric acid of more tar content through the oil removal pond, when passing oil removal portion 143 piece, oil removal portion 143 piece blocks in the tar, and then the tar content in the sulfuric acid has been reduced, through the sulfuric acid of oil removal pond, when concentration reaches the recovery requirement, can directly retrieve, owing to have lower tar content, and then make things convenient for sulfuric acid's recovery work, when the sulfuric acid concentration through the oil removal pond is lower, can make it get into the pickling pond again and wash the work to the catalyst in the desulfurizing tower, owing to the reduction of tar volume, can wash the catalyst more clean.

Preferably, the lower edge of the third partition 141 is closely connected to the bottom of the second tank 140, and the upper edge of the third partition is spaced apart from the upper end of the second tank 140 to form the first flow channel.

Preferably, the upper edge of the fourth partition 142 is flush with the upper end of the second tank 140, and the lower edge of the fourth partition is spaced from the bottom of the second tank 140 to form a second flow channel.

The arrangement is that the sulfuric acid flows in a wave form when passing through the oil separation part 143, so that tar in the sulfuric acid is facilitated by the oil separation part 143.

Preferably, the oil separator 143 includes a plurality of mesh plates 144 connected between the third and fourth partitions 141 and 142, and the mesh plates 144 and the third and fourth partitions 141 and 142 define a closed cavity in which the granular packing is filled. The packing is covered by the mesh plate 144 to ensure that the sulfuric acid smoothly passes through the oil separation part 143.

Preferably, a second sealing plate 145 for sealing the second tank 140 is disposed at the upper end of the second tank 140. By providing the second sealing plate 145, the sulfuric acid is prevented from being spilled outside the second tank 140, and external impurities can be prevented from entering the second tank 140.

Preferably, the second tank body 140 includes a liquid inlet tank 146 and a liquid outlet tank 147, the liquid inlet tank 146 is communicated with the second flow channel, the liquid outlet tank 147 is communicated with the first flow channel, and a liquid level meter 149 for detecting the liquid level inside the liquid inlet tank 146 is further disposed on the second tank body 140 corresponding to the liquid inlet tank 146.

Preferably, a level gauge 149 for detecting the liquid level inside the liquid pool 147 is further disposed on the second pool body 140 corresponding to the liquid outlet pool 147.

Through the setting of liquid level, the convenience is to the grasp of oil removal inslot liquid level height, and another portion can be through comparing the reading of feed liquor pond 146 level gauge 149 and the level gauge 149 reading of play liquid pond 147, confirms the tar content in the oil removal portion 143, when the reading difference is great, can instruct that oil removal portion 143 has a large amount of tars to exist, and then can consider to change or clean the packing in the oil removal portion 143.

Preferably, a third exhaust pipe 148 is further disposed on the second sealing plate 145 corresponding to the liquid outlet tank 147, and one end of the third exhaust pipe 148 extends into the liquid outlet tank 147 and is flush with the inner wall of the second sealing plate 145.

Preferably, the second sealing plate 145 is provided with a plurality of reinforcing ribs 150.

Preferably, drain valves are arranged at the bottoms of the liquid inlet tank 146 and the liquid outlet tank 147. The cleaning of the inside of the oil separation tank can be conveniently ensured.

Example 9, as shown in fig. 1-13:

the pickling tank comprises the pickling tank and at least one first liquid pump assembly 151, wherein the first liquid pump assembly 151 is also connected with a desulfurizing tower water inlet pipe 119, and the first liquid pump assembly 151 is used for independently pumping sulfuric acid in each first tank unit 135 to the water inlet pipe 119.

For the desulfurizing tower with the catalyst adopted by the filter layer assembly 103, along with the continuous desulfurization work, the formed sulfuric acid is more and more adhered to the catalyst, so that the catalyst cannot be well contacted with flue gas to reduce the removal effect of sulfur dioxide, and the flow of flue gas is not facilitated to reduce the desulfurization efficiency of the desulfurizing tower;

therefore, after the desulfurizing tower operates for a certain time, the regeneration system of the present application is started, water is adopted to wash sulfuric acid attached to the catalyst, formed sulfuric acid flows down into the pickling tank, regeneration of the catalyst is achieved, in the scheme, sulfuric acid flowing into the pickling tank is repeatedly used for washing a catalyst layer until the sulfuric acid concentration reaches the recovery requirement, the pickling tank of the present application is adopted, the inner space of the pickling tank is divided into at least two first tank units 135 for independently collecting sulfuric acid through the arrangement of the second partition 134, when the inside of the desulfurizing tower is washed, the liquid pump is used for independently pumping sulfuric acid in each first tank unit 135 to the water inlet pipe 119 of the desulfurizing tower, namely, sulfuric acid in one first tank unit 135 is pumped into the desulfurizing tower to carry out washing work of the catalyst, the washed sulfuric acid flows into the other first tank unit 135, so the catalyst layer in the desulfurizing tower is repeatedly washed, on the one hand, the cleanliness of the catalyst layer in the desulfurizing tower is improved, on the other hand, the sulfuric acid concentration in the desulfurizing tank can also be improved, and the recovery value of the sulfuric acid in the desulfurizing tower can be improved.

Preferably, the number of the first liquid pump assemblies 151 is at least two. By arranging at least two liquid pump components, the flushing operation of a plurality of desulfurizing towers can be simultaneously carried out, and the flushing efficiency is improved; on the other hand, one or more liquid pump components can be used as spare, so that the reliable operation of the equipment is ensured.

Preferably, the regeneration system further comprises a liquid return main pipe 152, a first liquid return pipe 153 of each desulfurization tower is connected with the liquid return main pipe 152, and the pickling tank is communicated with the first liquid return pipe 153 through the liquid return main pipe 152.

Example 10, as shown in fig. 1-13:

the application also discloses a sulfuric acid recovery equipment line, including foretell oil removal pond and regeneration system, regeneration system's back liquid main pipe 152 still with the feed liquor pond 146 intercommunication of oil removal pond the back liquid main pipe 152 with be provided with the valve on the pipeline between the feed liquor pond 146, the play liquid pond 147 of oil removal pond still with regeneration system's pickling tank intercommunication be provided with the valve on the pipeline of intercommunication between play liquid pond 147 and the pickling tank.

The utility model provides a sulfuric acid recovery equipment line carries out catalyst flushing operation at the desulfurization equipment line, when the tar content in the sulfuric acid is higher, in carrying the feed liquor pond 146 of oil removal pond with the sulfuric acid, filter the tar in the sulfuric acid, then carry the pickling towards carrying out the flushing operation of catalyst with the sulfuric acid after filtering again, so, on the one hand because the tar is filtered in the sulfuric acid for the catalyst can be washed more the sensation, on the other hand, also can make the sulfuric acid wash the catalyst more times, so, improvement sulfuric acid concentration by a wide margin, the recovery value of improvement sulfuric acid.

Preferably, the filter 154 and the pump body 155 are further included, an inlet of the pump body 155 is communicated with the liquid outlet tank 147 of the oil separation tank, and an outlet of the pump body 155 is communicated with an inlet of the filter 154. When the sulfuric acid in the oil separation tank is sufficiently high, after oil separation, the sulfuric acid is pumped to the filter 154 by the pump body 155 for further filtration to obtain clean sulfuric acid, and thus, the recovery of the sulfuric acid is realized.

Preferably, the outlet of the filter 154 is also connected to a finished acid tank 156 for collecting sulfuric acid.

Preferably, the pump body 155 is a membrane filtration pump. The adoption of the membrane filter pump can further filter the sulfuric acid, so that the cleanliness of the sulfuric acid is further improved.

Preferably, two pump bodies 155 are provided, and the two pump bodies 155 are connected in parallel between the liquid outlet tank 147 and the inlet of the filter 154. One of the pumps 155 is ready for use, including reliable operation of the device.

Preferably, the filtering includes a filter cartridge 157, and a plurality of filter membrane assemblies 160 are disposed in the filter cartridge 157, and the filter membrane assemblies 160 are used for filtering the sulfuric acid pumped by the pump body 155.

Preferably, a flushing pipe 158 is further provided on the filter cartridge 157, one end of the flushing pipe 158 extends into the filter cartridge 157, and the other end is communicated with an external clean water source. When the impurities on the filter membrane assembly 160 are excessive, the filter membrane assembly 160 is washed through the washing pipeline 158, so that the filter membrane assembly 160 keeps a good filtering effect.

Preferably, a blast pipe 159 is further disposed on the filter cartridge 157, and one end of the blast pipe 159 extends into the filter cartridge 157, and the other end is connected with a blast device. After the filter membrane assembly 160 is washed, a high-speed air flow is blown in by a blower device to blow the inner space of the filter cartridge 157 dry, so that the residual cleaning liquid in the filter cartridge 157 is prevented from diluting or polluting sulfuric acid.

Example 11, as shown in fig. 1-13:

the application also discloses a liquid seal system for desulfurization equipment line, including U-shaped pipe and be used for adorning the liquid seal pond 161 of flourishing liquid seal liquid, U-shaped pipe one end and the pipeline intercommunication of carrying untreated flue gas, the other end and desulfurizing tower advance tobacco pipe 115 and say the intercommunication the U-shaped pipe with be provided with second liquid pump assembly 162 between the liquid seal pond 161, second liquid pump assembly 162 is used for with liquid seal liquid pump in the liquid seal pond 161 arrives in the U-shaped pipe. By adopting the liquid seal system, the on-off of the smoke inlet pipe 115 is realized, and as described above, the liquid seal system is simple in structure and has better durability and reliability.

Preferably, the second liquid pump assembly 162 is two sets. One group is standby, and the reliability of the equipment is ensured.

Preferably, the bottom of the U-shaped pipe is also connected with a second liquid return pipe 163, the second liquid return pipe 163 is communicated with a pickling tank of the catalyst regeneration system, and a valve is arranged on a pipeline for communicating the second liquid return pipe 163 with the pickling tank. When the desulfurization tower is used for flue gas treatment, the liquid seal liquid in the U-shaped pipe is put into the pickling tank for regeneration flushing of the rest of desulfurization tower catalysts, so that sulfuric acid and use cost are saved.

Preferably, a drain valve is further disposed at the bottom of the liquid sealing tank 161.

Example 12, as shown in fig. 1-13:

The desulfurizing equipment line of this application owing to adopted foretell desulfurizing tower, can improve the contact efficiency of sulfur dioxide and desulfurizing agent in the flue gas by a wide margin, and then improves the desorption efficiency of sulfur dioxide in the flue gas, desulfurizing agent in this application can take place chemical reaction and then realize the chemical preparation of sulfur dioxide desorption with sulfur dioxide, also can be the catalyst that is used for catalyzing sulfur dioxide and other material and takes place chemical reaction and then realize the sulfur dioxide desorption.

The desulfurization recovery apparatus line in this example is exemplified as including one and four desulfurization towers.

Preferably, the liquid sealing system is further included. Due to the adoption of the liquid sealing system, the on-off of the smoke inlet pipe 115 is realized, and as described above, the structure is simple, and the durability and the reliability are better

Preferably, the sulfuric acid recovery equipment line is further included.

The desulfurization equipment line of this application has owing to adopted foretell sulfuric acid recovery equipment line, when desulfurization equipment line carries out catalyst flushing operation, when the tar content in the sulfuric acid is higher, carry the feed liquor pond 146 of oil removal pond with the sulfuric acid in, filter the tar in the sulfuric acid, then carry the pickling towards with the sulfuric acid after filtering again and continue the flushing operation of catalyst, so, on the one hand because the tar is filtered in the sulfuric acid for the catalyst can be washed more the sensation, on the other hand also can make the sulfuric acid can more wash the catalyst, so, improvement sulfuric acid concentration by a wide margin, the recovery value of improvement sulfuric acid.

The foregoing examples are only for illustrating the present application and not for limiting the technical solutions described in the present application, and although the present application has been described in detail in this specification with reference to the foregoing examples, the present application is not limited to the foregoing detailed description, and thus any modifications or equivalent substitutions are made to the present application; all technical solutions and modifications thereof that do not depart from the spirit and scope of the invention are intended to be covered by the claims of this application.

Claims

1. A desulfurizing tower, characterized in that: the flue gas desulfurization device comprises a filter layer assembly, wherein the filter layer assembly is positioned between a flue gas inlet and a flue gas outlet of a desulfurization tower, so that flue gas passes through the filter layer assembly first and then is discharged from the flue gas outlet, the filter layer assembly comprises a filter layer, and a plurality of flue gas channels for the flue gas to pass through are formed in the filter layer; the filter layer is formed by stacking or paving a plurality of granular filter units, gaps are formed between every two adjacent filter units, and a plurality of flue gas channels for flue gas to pass through are formed between the gaps in a mutually connected or mutually independent or partially connected mode; the filter layer assembly comprises a first silk screen, a first saddle ring layer and a second saddle ring layer, the filter units are piled or laid on the first silk screen, the first saddle ring layer comprises a plurality of first saddle rings, the first saddle rings are laid below the first silk screen side by side, the second saddle ring layer comprises a plurality of second saddle rings, the second saddle rings are laid on the first saddle ring layer side by side, the structural size of the second saddle rings is smaller than that of the first saddle rings, and the structural size of the second saddle rings ensures that the second saddle rings do not fall from the holes of the first saddle rings; the desulfurization tower comprises a tower body, a filter layer assembly, a support assembly, a plurality of support beams, annular support rings, first reinforcing ribs and second reinforcing ribs, wherein the support assembly is arranged in the tower body of the desulfurization tower and is positioned below the filter layer assembly, the support assembly is used for supporting the filter layer assembly to enable the filter layer assembly to be separated from the bottom of the tower body, the annular support rings are connected between the end parts of the adjacent support beams and are arranged along the inner wall of the tower body, the two ends of each support ring are respectively connected with the adjacent support beams, the outer edges of each support ring are matched with the inner wall of the tower body, the two ends of each support ring are respectively butted with the upper side edges of the adjacent support beams, the upper side surfaces of the support rings and the upper side edges of the upper side flanges of the support beams are positioned in the same plane, and the first reinforcing ribs are connected between the support rings and the webs of the support beams; each support beam below still is provided with a plurality of support columns, the upper end of support column with the support beam is connected, the lower extreme of support column with the bottom plate of body of the tower is connected, same root separate between the support column of support beam, support column upper end and/or lower extreme are connected with the backing plate, still are connected with a plurality of stay tubes between the adjacent support beam, the stay tube with the junction of support beam is located the support column top.

2. The desulfurizing tower according to claim 1, wherein: the filter unit is spherical, ellipsoidal or columnar.

3. The desulfurizing tower according to claim 2, wherein: the filter unit is cylindrical and has a diameter of 3-10mm.

4. A desulfurizing tower according to any one of claims 1 to 3, wherein: the filtering unit is made of a desulfurization catalyst material, and the desulfurization catalyst is used for enabling sulfur dioxide and oxygen to generate sulfur trioxide.

5. A desulfurizing tower according to any one of claims 1 to 3, wherein: the filter unit comprises a matrix serving as a framework and a desulfurization catalyst attached to the matrix, wherein the matrix is activated carbon.

6. The desulfurizing tower according to claim 1, wherein: the support assembly comprises a grid plate, the edge of the grid plate is matched with the inner wall of the tower body, and the second silk screen of the filter layer assembly is laid on the grid plate.

7. The desulfurizing tower according to claim 6, wherein: the supporting beams are used for supporting the grid plates, a plurality of supporting beams are arranged side by side, adjacent supporting beams are separated, two ends of each supporting beam are matched with the inner wall of the tower body, and the grid plates are located on the supporting beams.