CN207169421U - A kind of regenerative system for flue gas desulfurization device line - Google Patents

A kind of regenerative system for flue gas desulfurization device line Download PDF

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Publication number
CN207169421U
CN207169421U CN201720785451.XU CN201720785451U CN207169421U CN 207169421 U CN207169421 U CN 207169421U CN 201720785451 U CN201720785451 U CN 201720785451U CN 207169421 U CN207169421 U CN 207169421U
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China
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sulfuric acid
pond body
support
tower body
liquid
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CN201720785451.XU
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麻强
王维江
王怀金
李立松
荀鹏
王平
廖玉珍
陈杰
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Chengdu Guo Hua Environmental Protection Technology Co Ltd
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Chengdu Guo Hua Environmental Protection Technology Co Ltd
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Abstract

The application is related to environmental protection industry (epi) technical field of atmospheric pollution control, more particularly to a kind of regenerative system for flue gas desulfurization device line, including pickling tube and at least one first pump unit, first pump unit is also connected with desulfurizing tower water inlet pipe, and first pump unit is pumped to the water inlet pipe for the independent sulfuric acid by each first pond body unit.Start the regenerative system of the application, the sulfuric acid adhered on a catalyst is rinsed using water, the sulfuric acid of formation is run down into pickling tube, realize the regeneration of catalyst, sulfuric acid is rinsed repeatedly to the catalyst layer in desulfurizing tower, on the one hand it is to improve the cleanliness factor that catalyst is rinsed, on the other hand can also improves the sulfuric acid concentration in pickling tube, improve the recovery value of sulfuric acid.

Description

A kind of regenerative system for flue gas desulfurization device line
Technical field
The application is related to environmental protection industry (epi) technical field of atmospheric pollution control, and in particular to one kind is used for flue gas desulfurization device line Regenerative system.
Background technology
Other are major pollutants in air to sulfur dioxide, there is very big harm to link and health, while It is the main reason for producing acid rain.With rapid development of economy, the discharge capacity of China's sulfur dioxide has occupied first place in the world, All there is acid rain to some extent in various regions, turn into the acid rain seriously polluted area after Europe, North America.Therefore, industrial discharge flue gas In, the removing improvement of sulfur dioxide is the important topic in Environmental Protection in China field.
Administered for the sulfur dioxide removal of industrial smoke, usual mode is using desulphurization plant line in industrial smoke Sulfur dioxide is handled, and current desulphurization plant line mainly includes gas supply assembly and desulfurization module, in real work, is supplied Industrial smoke is sent into desulfurization module by pneumatic module, and desulfurization module is usually desulfurizing tower, and desulfurizing tower takes off the sulfur dioxide in flue gas Remove, so realize the control to flue gas.
Adopt in manner just described, not only can significantly reduce the content of sulfur dioxide in industrial smoke, reduce industrial cigarette Pollution of the gas to environment, meanwhile, in the case of conditional, the sulfur dioxide of removing can also be collected and sharp again With.
With going deep into for research, inventor has found that above-mentioned desulphurization plant line still also there are deficiency, and concrete reason exists In:
In current Structure of Flue Gas Desulfuration Absorbing, desulfurization method is usually dry desulfurization or wet desulphurization, is carrying out desulfurization work When making, industrial smoke is by entering in tower body below tower body, and corresponding desulfurization agent, and then realizes the removing of sulfur dioxide, However, it is found by the inventors that in current desulfurization method, flue gas is not high with desulfurization agent efficiency, causes the use of desulfurizing agent And it is insufficient, the waste of desulfurizing agent is caused, the problem of also easily causing the removal efficiency of sulfur dioxide in flue gas low.
The content of the invention
The purpose of the application is:For sulfur dioxide removal rate in current desulphurization plant line it is not high the problem of, there is provided one Kind can improve the desulphurization plant of sulfur dioxide removal rate.
In order to realize foregoing invention purpose, this application provides following technical scheme:
A kind of filtering layer component for desulfurizing tower, the filtering layer component be located at desulfurizing tower gas approach and exhanst gas outlet it Between, after flue gas is first passed through the filtering layer component, then to be discharged by the exhanst gas outlet, the filtering layer component includes filter layer, Some exhaust gases passes passed through for flue gas are there are in the filter layer.
The filtering layer component of the application, there is some passages passed through for flue gas in filter layer, and the flue gas into tower body passes through These passages are discharged by exhanst gas outlet again, are adopted in such a way, can greatly improve sulfur dioxide in flue gas and desulfurizing agent Contacting efficiency, and then improve the removal efficiency of sulfur dioxide in flue gas, the desulfurizing agent in the application can be can and sulfur dioxide Occur to chemically react and then realize the chemicals of sulfur dioxide removal or for being catalyzed sulfur dioxide and other materials Occur to chemically react and then realize the catalyst of sulfur dioxide removal.
Preferably, the filter layer by some granular filter elements the shape in a manner of accumulating or lay Into formed with gap between adjacent filtration member, to be connected with each other either independently of each other or part connects between each gap Mode form some exhaust gases passes passed through for flue gas.
In this scenario, the exhaust gases passes passed through for flue gas are formed using aforesaid way, these exhaust gases passes shapes are random Property high, or bending or tortuous, be flue gas by providing longer path, can further improve connecing for flue gas and desulfurizing agent Touch efficiency, and then the further removal efficiency for improving sulfur dioxide.
Preferably, the filter element is spherical, ellipsoid or column.
Using the filter element of above-mentioned shape and specification, in accumulation or laying, facilitate the formation of exhaust gases passes, and The exhaust gases passes formed also have more suitably sized, that is, ensure that flue gas and desulfurizing agent have higher contacting efficiency, together When have and avoid the formation of excessive resistance, facilitate passing through for flue gas.
It is further preferred that the filter element is cylindric, a diameter of 3-10mm.
It is further preferred that the filter element is cylindric, a diameter of 4-6mm.
In actual design and in use, inventor's discovery, is arranged to above-mentioned size by filter element, makes its each filter element Between form size suitable gap, while ensureing that flue gas circulation is smooth, it is ensured that the gap inside filter layer has foot Enough big areas, ensure the removal efficiency of sulfur dioxide.
As one of which preferred scheme, the filter element is made using desulfurization catalyst agent material, the desulfurization catalyst Agent is used to make sulfur dioxide and oxygen generate sulfur trioxide.
In this programme, filter element is made using desulfurization catalyst agent material, that is to say, that make flue gas by filtering During exhaust gases passes between unit, under the catalytic action of catalyst material, sulfur dioxide is formed with the oxygen reaction in flue gas Sulfur trioxide, after sulfur trioxide is formed, because itself also has certain steam or water droplet in flue gas, so, worn in flue gas When crossing catalyst material, after sulfur trioxide is formed, sulfuric acid liquid is combined to form with steam or water droplet, is attached on filter element, And then the removing to sulfur dioxide in flue gas is realized, moreover, carrying out the removing of sulfur dioxide, catalyst by the way of catalyst Itself and free of losses, so, in actual use, using filter element made from desulfurization catalyst agent material can be repeatedly make With being on the one hand to have saved desulphurization cost, on the other hand also avoid the generation of new waste material or pollutant.
As another preferred scheme, the filter element is including the matrix as skeleton and is attached in described matrix Desulphurization catalyst, described matrix are activated carbon.
In this programme, using activated carbon as matrix, desulphurization catalyst is adhered on matrix, in sweetening process, two Sulfur oxide and oxygen form sulfur trioxide under desulphurization catalyst effect, and sulfur trioxide, which with water combines to form sulfuric acid and is attached to, urges In agent, and then the removing of sulfur dioxide is realized, further, in this programme, because matrix uses activated carbon, activated carbon table Face and inside all have compared with concrete dynamic modulus, are on the one hand matrix is adhered to more desulphurization catalysts, further improve dioxy Change the removal efficiency of sulphur, on the other hand, the exhaust gases passes shape formed is also more tortuous various, is more beneficial for flue gas and passed through While filtering layer, the removing of sulfur dioxide is more favorable to.
As another preferred scheme, the filter element is made using sulphur dioxide absorbent, when flue gas is described in During filtering layer, the sulfur dioxide in flue gas chemically reacts with the sulphur dioxide absorbent, realizes the absorption to sulfur dioxide.
In this scenario, sulphur dioxide absorbent is the alkali compounds that can be chemically reacted with sulfur dioxide, example Such as can be calcium, sodium, magnesium, ammonium compound, using this kind of mode, when flue gas passes through filtering layer, sulfur dioxide and filtering layer material Chemically react, and then also achieve the removing of sulfur dioxide in flue gas.
As another preferred scheme, the filter element is made using inert material, and the inert material is in dioxy Change the stable material of the chemical properties not chemically reacted in sulphur subtractive process.
In this programme, filter element is made using inert material, was used as example with stainless steel or activated carbon Unit is filtered, in wet desulphurization mode, under desulfurizing agent sprays above filter layer, by entering below filter layer, desulfurizing agent falls flue gas When on to filter layer, in sprinkling state, some fine drops and liquid mist are formed, are then proceeded to toward filter layer flowing underneath, at this During, flue gas is able to sufficiently be contacted with desulfurizing agent, in this way, greatly improving contact of the sulfur dioxide with desulfurizing agent Rate, and then significantly improve the removal efficiency of sulfur dioxide.
Preferably, the filtering layer component also includes the first silk screen, and the filter element accumulates or be layed in described first On twine, described first edge is engaged with the inwall of the tower body.By setting the first silk screen, branch is played to filter element While support, the smooth of flue gas circulation also ensure that.
Preferably, first silk screen is stainless steel cloth.Ensure that the first silk screen has good durability.
Preferably, the filtering layer component also includes the first iso-saddle ring layer, and the first iso-saddle ring layer includes some One iso-saddle ring, first iso-saddle ring are laid side by side below first silk screen.By setting the first iso-saddle ring layer, due to different Saddle ring structure has the characteristics that macroporosity and high flux, so, it is different by some first side by side in the scheme of the application Saddle ring forms the supporting construction of the first silk screen, while the first silk screen is ensured by secure support, also improves flue gas and enters filtering The uniformity of layer, improve the removal efficiency of sulfur dioxide.
It is further preferred that the filtering layer component also includes the second iso-saddle ring layer, the second iso-saddle ring layer includes Some second iso-saddle rings, second iso-saddle ring are laid side by side on the first iso-saddle ring layer, the knot of second iso-saddle ring Structure size is less than the physical dimension of first iso-saddle ring, also, the physical dimension of second iso-saddle ring ensures it not from the Fallen in the hole of one iso-saddle ring.
In such scheme, by setting the different iso-saddle ring of double-layer structure size, pass through the less second different saddle of size Circular layer supports the first silk screen, further ensure that the planarization that the first silk screen is supported, and different by larger-size first Saddle ring layer supports the second iso-saddle ring layer, not only ensure that the smooth of flue gas circulation, while also reduce the paving of the first iso-saddle ring layer If difficulty.
It is further preferred that the filtering layer component also includes the second silk screen, edge and the tower of second silk screen The inwall of body is engaged, and the first iso-saddle ring layer is layed on second silk screen.
Disclosed herein as well is a kind of catalyst support component for desulfurizing tower, the support component is arranged on desulfurizing tower Tower body in, the support component is located at below the filtering layer component, and the support component is used to support the filtering layer component, makes The bottom of the filtering layer component and the tower body separates.
In this scenario, by support component, filtering layer component and tower body bottom are separated, are on the one hand to facilitate flue gas to have Enough spaces riddle the underlying space of filtering layer component, avoid flue gas from only being passed through from the filtering layer close to smoke inlet part, and then Ensure the filter efficiency of the sulfur dioxide of filtering layer.
Preferably, the support component includes Turbogrid plates, and the inwall at the edge of the Turbogrid plates and the tower body matches Close, the second silk screen of the filtering layer component is layed on the Turbogrid plates.
Filtering layer component is supported using Turbogrid plates, can effectively ensure that filtering layer component has good planarization, and then ensure Filtering layer each several part can access good utilization, and be additionally, since Turbogrid plates has some holes in itself, is playing to filtering layer While component excellent support, the smooth of flue gas circulation also ensure that.
Preferably, the support component also includes some support beams, and the support beam is used to support the grid Panel, some support beams are arranged side by side, adjacent supports crossbeam it is be spaced apart, the both ends of the support beam with it is described The inwall of tower body is engaged, and the Turbogrid plates are located in the support beam.
The reliability that Turbogrid plates are supported ensure that come propping bar panel by some support beams in such scheme, Also the reliability that filtering layer component is supported is ensured that, is spaced apart between support beam, ensures the smooth of flue gas circulation.
Preferably, it is connected with the support ring of ring-type between the end of adjacent supports crossbeam, the support ring is along the tower body Inwall arrangement, the both ends of the support ring be connecteds with adjacent supports crossbeam respectively, the outer rim of the support ring and the tower body Inwall be engaged.
In such scheme, by setting ring-type to be on the one hand so that, the edge of flase floor can be reliable in support ring Support, be further ensured that the reliability that support component supports to filter assemblies;On the other hand, due to being connected between support beam Connect, also strengthen the stability of support beam to a certain extent;Another further aspect, because tower body is usually thin-walled tubular structure, In this application, using the combination of support ring and support beam, while layer assembly is filtered in support, also correspond in tower body Inwall forms a circle and strengthens ring structure, so also improving the structural strength of tower body, can significantly reduce the risk of tower body deformation, Enable the holding design form that tower body is good.
Preferably, the support beam is I-steel, upper side and the grid of the upper side wing edge of the support beam It is engaged on the downside of plate.
Preferably, the support ring is tabular, the both ends of the support ring upper side wing edge with adjacent supports crossbeam respectively It is relative to connect.
Preferably, the upper side of the upper side of the support ring and the upper side wing edge of the support beam is generally aligned in the same plane It is interior.
Pass through the setting of such scheme so that, the upper side and support ring upper side of support beam form support platform, with Turbogrid plates have larger mating surface, further ensure that the reliability that filter layer is supported.
Preferably, the first reinforcement is also associated between the web of the support ring and the support beam.Pass through setting First reinforcement increases the bonding strength between support ring and support beam.
Preferably, be additionally provided with some support posts below each support beam, the support post it is upper End is connected with the support beam, and the lower end of the support post is connected with the bottom plate of the tower body.
Preferably, the support post of support beam described in same root is is spaced apart.Adjacent upright posts are to be spaced apart, in guarantee pair It is also convenient to ensure the smooth of flue gas circulation while support beam secure support.
Preferably, the support post upper end and/or lower end are connected with backing plate.By setting backing plate to ensure the reliable of connection Property.
Preferably, the support post is steel pipe.
Preferably, some support tubes are also associated between adjacent supports crossbeam.Support tube, support beam are vertical with, support Post and tower body, the frame structure mutually supported is formed by connecting, is on the one hand that ensure that filtering layer component is reliably supported, On the other hand the structural strength of tower body is also significantly added.
Preferably, the junction of support tube and the support beam is located above the support post.That is, column Connected with the same place position of support tube and support beam, beneficial to the transmission of each member stress, further improve support component Structural stability.
Disclosed herein as well is a kind of tower body for desulfurizing tower,
Gas approach and exhanst gas outlet are provided with the tower body, is connected with smoke-intake pipe at the gas approach, it is described enter One end of smoke pipe is stretched into inside the tower body, in the vertical direction, the smoke-intake pipe inside the tower body, any of its inwall It all there are and block above position.
In this programme, all there are and block above any position of tower body inwall, in this way, avoid top liquid or Unclassified stores drops into smoke-intake pipe and influences flue gas conveying, in this law scheme, in the vertical direction, inside tower body Smoke-intake pipe, any position top of its inwall, which all there are, is blocked, and this is blocked, and can be obliquely installed smoke-intake pipe, be made into cigarette The port of pipe is oblique, and then makes at the port, and part above forms blocking for section below;Can also will enter cigarette Port of the pipe inside tower body is arranged to inclined opening structure;It can also be and port the latter half is cut out, make top half Form blocking for the latter half;Also it can also be and set independent barrier structure to block the port of smoke-intake pipe.
Preferably, the port that the smoke-intake pipe is located inside the tower body is angle.Inclined opening structure is set, is on the one hand to protect Card smoke-intake pipe can realize above-mentioned effect, meanwhile, also convenient processing, material is saved, manufacturing cost can be effectively reduced.
Preferably, the gas approach is arranged in the side wall of the tower body, the smoke-intake pipe by the tower body side wall Enter in the tower body.Smoke-intake pipe enters tower body by tower body side wall, is on the one hand a simplified the structure of tower body bottom, facilitates tower The mounting arrangements of body, the processing and manufacture being on the other hand also convenient for.
Preferably, the smoke-intake pipe is located at port inside the tower body and the bottom plate of the tower body has separated distance.Enter One step avoids liquid or unclassified stores in tower body from entering in smoke-intake pipe.
Preferably, be also associated with some first support members on the outer wall of the tower body bottom plate, first support member it Between for the setting that is parallel to each other, be spaced apart of adjacent first support member have distance.
As another preferable scheme, radial direction of first support member along the tower body is set.
The first some support members is set on tower body bottom plate described above, is on the one hand installation and the cloth for facilitating tower body Put, on the other hand, the first support member also acts as the effect for strengthening tower body bottom plate, improves the structural strength of tower body.
As another preferred scheme, first support member is corresponding with the support post of support component, the support Part is located at the underface of the support post.In the scheme of the application, support post is used to support filtering layer component, the first support Part is located at the underface of support post, in this way, be on the one hand to ensure that support post has excellent support intensity and stability of strutting system, On the other hand, can also reduce tower body bottom plate because conduct oneself with dignity and the pressure granted of support post and caused by deformation, further carry The high reliability of tower body structure.
Preferably, first support member is I-steel, channel-section steel or rectangular steel pipe.Using I-steel, channel-section steel or square Shape steel pipe or other section bars, on the one hand, use these section bars to facilitate market to buy for standard component, processing can be saved Cost, on the other hand, section bar has groove or opening in itself, so, be also convenient for the first support member and other support members it Between connection.
Disclosed herein as well is another tower body structure, the tower body structure can be combined with above-mentioned tower body structure, Tower body can also be separately formed:
A kind of tower body for desulfurizing tower,
Some spray heads are provided with the inside of the top plate of the tower body, each described spray head is connected with water inlet pipe.
In the scheme of the application, by setting spray head, the desulfurization with sulfur dioxide reaction can be sprayed in spray head Agent, the cleaning fluid for rinsing filtering layer component, guarantee filtering layer unit clean or recovery catalyst activity can also be sprayed, such as Clear water, make filtering layer component can be with Reusability, and ensure good filtration result.
Preferably, spray head is uniform around the exhanst gas outlet.
Preferably, at least one first partition is additionally provided with the tower body, the first partition is located at support component Above Turbogrid plates, the tower body inner space above the Turbogrid plates is divided at least two fillings for being used to load filter element Chamber.
By setting first partition, the tower body inner space above filtering layer component is split, convenient respectively to respectively filling out The filter element for filling intracavitary is controlled, such as is filled or changed respectively respectively, facilitates the control to filter element.
Preferably, the top plate inwall of the first partition upper end and tower body separates, and makes each filled cavity and the cigarette Gas outlet is connected.In this way, so the shared exhanst gas outlet of filled cavity, further simplifies right tower body structure.
Preferably, manhole is both provided with the tower body top plate corresponding to each described filled cavity, filled out described in each Fill the discharge port being both provided with corresponding to chamber in the tower body side wall for taking out filter element, on the manhole and discharge port all Removably it is connected with capping.Manhole passes in and out available for worker, can be used for the filling of filter element, in this way, convenient filtering The filling and replacing of unit.
Preferably, the top plate outer wall of the tower body is additionally provided with some second support members, between second support member For the setting being parallel to each other, be spaced apart of adjacent second support member has distance.
As another preferable scheme, radial direction of second support member along the tower body is set.
The second some support members is set on tower body top plate described above, is on the one hand installation and the cloth for facilitating tower body Put, on the other hand, the second support member also acts as the effect for strengthening tower body top plate, improves the structural strength of tower body.
Preferably, second support member aligns with the first support member on tower body bottom plate.Second support member and first The alignment of support member, further facilitate the arrangement of tower body external connection component.
Preferably, the tower body periphery is additionally provided with some the 3rd support members being vertically arranged, positioned at same vertical First support member and the second support member are connected with the 3rd support member.By this kind of mode, first, tower body can facilitate By the 3rd supports support, such as support to suitable height, in actual use, can be by multiple tower bodies same perpendicular Nogata carries out overlapping upwards, saves floor occupying area, and on the other hand, passes through the 3rd support member and connects the first support member and the second support Part, mutually supported between the first support member, the second support member and the 3rd support member, further increase tower body supported it is steady Qualitative and reliability, also further improve the strength and stiffness of tower body structure.
Preferably, the nozzle for thermometer for placing thermometer, the nozzle for thermometer are connected with the tower body top plate Connected with the inner space of the tower body.By nozzle for thermometer is set, it is necessary to when, can be by setting thermometer, further Facilitate use.
Preferably, a thermometer is both provided with the tower body top plate corresponding to each described filled cavity to connect Pipe.The convenient grasp to regional temperature.
Liquid device is returned for desulfurizing tower disclosed herein as well is a kind of,
Including the first liquid back pipe being arranged on tower body bottom plate, described first liquid back pipe one end and the tower body inner space Connect, the other end is connected with wastewater treatment equipment or regeneration of sulfuric acid system, first liquid back pipe and sky inside the tower body Between the end connected without departing from the bottom plate inwall.By setting the first liquid back pipe, the liquid in tower body is drawn, first time Liquid pipe and inwall of the end that tower body inner space is connected without departing from bottom plate, it can effectively ensure that liquid can be as far as possible more in tower body Outflow.
Preferably, first liquid back pipe includes the first bend pipe and the second bend pipe, described first bend pipe one end with it is described The inner space of tower body is connected, and the other end is connected with second bend pipe, and first bending pipe tool has downwardly convex first curved Portion, the first turn of bilge interior energy convergence liquid form the fluid-tight for blocking first liquid back pipe.In the scheme of the application, pass through The turn of bilge of first liquid back pipe itself forms fluid-tight, is to ensure when needed to block the first liquid back pipe first, avoids flue gas from the One liquid back pipe is discharged;Further, also with simple in construction, convenient the advantages that processing and manufacturing;On the other hand, due to titanium dioxide Sulphur, sulfuric acid etc. have aggressive, so, for more traditional valve mechanism, the first liquid back pipe is realized using fluid-tight Block, durability is more preferable, and structural behaviour is more reliable and more stable.
It is further preferred that second bending pipe tool has the second turn of bilge to raise up, first turn of bilge is less than described Second turn of bilge, the level height of first turn of bilge are less than the level height of second turn of bilge.In this way, realize the shape of fluid-tight Into.
Preferably, first bend pipe and the second bend pipe dock to form inverted S-shaped.Further convenient processing and system Make.
Preferably, the level height of the second bend pipe inner flow passage described in the level height of the first bend pipe inner flow passage is low In the level height of the tower body plate inner wall.Ensure that the liquid in tower body smoothly can flow out from the first liquid back pipe.
Preferably, downtake pipe, the downtake pipe lower end and institute are additionally provided with the top of second turn of bilge The inner flow passage for stating the second turn of bilge is connected, the downtake pipe that upper end connects with outside atmosphere.By setting downtake pipe, enter The outflow for facilitating liquid in tower body of one step, meanwhile, also ensure that the liquid for blocking the first liquid back pipe can be formed in the first bend pipe Envelope.
Preferably, the level height of the downtake pipe upper end is likely to be breached highest order higher than liquid in the tower body Put.The liquid in tower body is avoided to be overflowed from downtake pipe.
Preferably, the downtake pipe tip portion is bent downwards, makes the downtake pipe opening down.Can have Effect avoids exterior space debris and/or rainwater from entering in downtake pipe.
Disclosed herein as well is a kind of desulfurizing tower, including above-mentioned filtering layer component.The desulfurizing tower of the application, as a result of Above-mentioned filtering layer component, the contacting efficiency of sulfur dioxide in flue gas and desulfurizing agent can be greatly improved, and then improved two in flue gas The removal efficiency of sulfur oxide, the desulfurizing agent in the application can occur to chemically react and then realize titanium dioxide with sulfur dioxide The chemicals or occur to chemically react and then realize titanium dioxide for being catalyzed sulfur dioxide and other materials that sulphur removes The catalyst of sulphur removing.
Preferably, in addition to above-mentioned catalyst support component.Further, also adopted in the Structure of Flue Gas Desulfuration Absorbing of the application With above-mentioned catalyst support component, good support effect can be played to filtering layer in desulfurizing tower.
Preferably, in addition to above-mentioned tower body, the tower body of the application, can be above two tower body any one, It can be the combination of above two tower body.
Disclosed herein as well is a kind of pickling tube for desulphurization plant line, the pickling tube includes the first pond body, described At least one second partition is provided with first pond body, the space in first pond body is divided at least by the second partition Two are used for independent the first pond body unit for collecting sulfuric acid, and first with desulfurizing tower is both provided with each first pond body unit The first pipeline that liquid back pipe all connects, valve is both provided with first pipeline.
Preferably, the second partition is at least two, and the second partition separates the space in first pond body For at least three first pond body units.
The pickling tube of the application, by setting second partition, it is independent that the inner space of pickling tube is divided at least two The first pond body unit of sulfuric acid is collected, when being rinsed to desulfurizing tower inside, liquid pump is for independent by each first pond body Sulfuric acid in unit is pumped to the water inlet pipe of desulfurizing tower, can pass through the cooperation between the first pond body unit, i.e. will wherein Sulfuric acid is pumped to the flushing work of progress catalyst in desulfurizing tower in one the first pond body unit, and the sulfuric acid after flushing is flowed into separately In one the first pond body unit, so repeatedly, the catalyst layer in desulfurizing tower is rinsed repeatedly, is on the one hand to improve catalysis The cleanliness factor that agent is rinsed, the sulfuric acid concentration in pickling tube on the other hand can be also improved, improve the recovery value of sulfuric acid.
In this programme, when the first pond body unit be at least three, carry out catalyst layer flushing work when, expand The coordination scope carried out between first pond body unit, using the teaching of the invention it is possible to provide more optimal washing form;Particularly to multiple In the desulphurization plant line of desulfurizing tower, flush efficiency can not only be greatly improved, and the concentration of sulfuric acid can also be greatly improved;It is another Aspect, desulfurizing tower be two and more than, when carrying out catalyst regeneration, it is ensured that at least one desulfurizing tower is work shape State, so ensure the uninterrupted of fume treatment;
Further, because the first pond body unit is at least three, because sulfuric acid is Reusability, in each first pond body list Sulfuric acid concentration in member is different, and in actual flushing process, first rinse is carried out to catalyst layer using the sulfuric acid of high concentration, then Using gradually adopt concentration of taking second place sulfuric acid carry out subsequent rinse, in this way, constantly improve a portion sulfuric acid concentration, when After the sulfuric acid of best concentration reaches recovery requirement, recovery is extracted out, the sulfuric acid of remaining concentration repeats above-mentioned flushing work, such as This, the further recovery value for improving sulfuric acid.
Preferably, above-mentioned first pond body upper end is additionally provided with the first shrouding for closing the first pond body upper end open, institute The first pipeline is stated to connect with the inner space of the first pond body unit through first shrouding.By setting the first shrouding, Prevent sulfuric acid from trickling down outside pickling tube.
Preferably, it is both provided with second exhaust pipe corresponding to each first pond body unit on the first shrouding, described second Blast pipe lower end is stretched into the first pond body unit through first shrouding, and upper end is in open state.By setting second row Tracheae, the gas in the first pond body unit is discharged, ensures the smooth of sulphuric acid stream.
Preferably, the second exhaust pipe upper part is bent downwards, makes the upper end mouth down of the second exhaust pipe.Can To avoid outside debris or rainwater from dropping into pickling tube.
Preferably, the bottom of each the first pond body unit is both provided with blowoff valve.It is convenient to keep in pickling tube Cleaning, and then ensure sulfuric acid cleaning.
Preferably, the liquid level gauge for detecting inside liquid level is both provided with each described first pond body unit.It is easy to To the control of liquid level in pickling tube.
Preferably, some 4th support members, the 4th support member and the described 3rd are also associated with first pond body Support member is engaged.In this programme, by setting the 4th support member, during actual use, the pickling tube of the application can be set Put on the 3rd support member below desulfurizing tower, be on the one hand so that desulphurization plant line takes smaller area, on the other hand, Improve the globality between each equipment.
Disclosed herein as well is a kind of oil interceptor for flue gas desulfurization device line, including the second pond body, second pond At least one 3rd dividing plate and at least one 4th dividing plate are provided with vivo, obtain the side of the 3rd dividing plate and four dividing plate vertical directions The inwall closing of edge and second pond body connects, formed with first flow in the second pond body above the 3rd dividing plate, Formed with second flow channel in the second pond body below the 4th dividing plate, connect between the first flow and the second flow channel Third flow channel is connected with, the oil removal part for filtered tar is provided with the third flow channel.
In flue gas desulfurization process is carried out, rinse in the sulfuric acid that catalyst is formed and there are a large amount of tar, using the application Oil interceptor, the sulfuric acid with more tar content is passed through into oil interceptor, sulfuric acid is when through oil removal part, oil removal part in tar Stop, and then reduce the tar content in sulfuric acid, pass through the sulfuric acid of oil interceptor, when concentration, which reaches recovery, to be required, Ke Yizhi Capable recovery is tapped into, due to relatively low tar content, and then facilitates the recovery operation of sulfuric acid, it is dense by the sulfuric acid of oil interceptor When spending relatively low, it can be made to be again introduced into pickling tube work is rinsed to the catalyst in desulfurizing tower, due to tar content Reduce, catalyst flush can be obtained more clean.
Preferably, the lower edge of the 3rd dividing plate is connected with the bottom lock of second pond body, upper limb and described second The upper end of pond body separates to form the first flow.
Preferably, the upper limb of the 4th dividing plate is concordant with the second pond body upper end, lower edge and the second pond body bottom Portion separates to form second flow channel.
It is described above to set so that sulfuric acid is the flowing of relief form, beneficial to oil removal part mistake when through oil removal part The tar come in sulfuric acid.
Preferably, oil removal part includes some web plates being connected between the 3rd dividing plate and the 4th dividing plate, the net Plate is encircled into the cavity of closure with the 3rd dividing plate and the 4th dividing plate, in the cavity, filled with granular filler.It is logical Web plate is crossed to coat filler, ensures that sulfuric acid passes through oil removal portion.
Preferably, the filler is quartz sand.Quartz sand has stable chemical property and physical property, and can be anti- It is multiple to use, while guarantee has good oil removal effect, also save use cost.
Preferably, the second pond body upper end is provided with the second shrouding for closing the second pond body.By setting second Shrouding, avoid sulfuric acid from trickling down to outside the second pond body, also foreign matter can be avoided to enter in the second pond body.
Preferably, include in second pond body into liquid pool and filtrate liquor pool, it is described enter liquid pool connected with the second flow channel, The filtrate liquor pool connects with the first flow, it is described enter be additionally provided with corresponding to liquid pool in second pond body for detect into The liquid level gauge of liquid pool inside liquid level.
Preferably, it is additionally provided with corresponding to the filtrate liquor pool in second pond body for detecting filtrate liquor pool inside liquid level Liquid level gauge.
By the setting of liquid level, facilitate the assurance to liquid level in oil interceptor, another, can be by comparing into liquid pool The reading of liquid level gauge and the liquid level gauge reading of filtrate liquor pool, determine the tar content in oil removal portion, when reading difference is larger, you can Substantial amounts of tar is there are in specification oil removal portion, and then can contemplate the filler changed or cleaned in oil removal portion.
Preferably, the 3rd blast pipe, the 3rd exhaust are additionally provided with corresponding to the filtrate liquor pool on second shrouding The filtrate liquor pool is stretched into one end of pipe, and concordant with the inwall of second shrouding.
Preferably, some reinforcements are provided with second shrouding.
Preferably, it is described enter liquid pool and filtrate liquor pool bottom be both provided with blowoff valve.Easily it can ensure inside oil interceptor Cleaning.
Disclosed herein as well is a kind of regenerative system for flue gas desulfurization device line,
Including above-mentioned pickling tube and at least one first pump unit, first pump unit is also intake with desulfurizing tower Pipe connects, and first pump unit is pumped to the water inlet pipe for the independent sulfuric acid by each first pond body unit.
For desulfurizing tower of the filtering layer component using catalyst, with continuing for desulfurization work, the sulfuric acid formed is attached The amount on a catalyst is more and more, is on the one hand catalyst is reduced sulfur dioxide from good and smoke contacts Removal effect, on the other hand, also it is unfavorable for the circulation of flue gas, reduces the desulfuration efficiency of desulfurizing tower;
So after desulfurizing tower runs certain time, start the regenerative system of the application, using water to being attached to catalyst On sulfuric acid be rinsed, the sulfuric acid of formation is run down into pickling tube, realizes the regeneration of catalyst, in this programme, flow into acid The sulfuric acid of wash pool is required, using the pickling of the application by repeatedly for rinsing catalyst layer until sulfuric acid concentration reaches to reclaim Pond, by setting second partition, the inner space of pickling tube is divided at least two independent the first pond body lists for collecting sulfuric acid Member, when being rinsed to desulfurizing tower inside, liquid pump is pumped to de- for the independent sulfuric acid by each first pond body unit The water inlet pipe of sulphur tower, the cooperation between the first pond body unit can be passed through, i.e. by sulphur in one of them first pond body unit Acid is pumped to the flushing work of progress catalyst in desulfurizing tower, and the sulfuric acid after flushing is flowed into another the first pond body unit, So repeatedly, the catalyst layer in desulfurizing tower is rinsed repeatedly, is on the one hand to improve the cleanliness factor that catalyst is rinsed, separately On the one hand the sulfuric acid concentration in pickling tube can be also improved, improves the recovery value of sulfuric acid.
In this programme, when the first pond body unit be at least three, carry out catalyst layer flushing work when, expand The coordination scope carried out between first pond body unit, using the teaching of the invention it is possible to provide more optimal washing form;Particularly to multiple In the desulphurization plant line of desulfurizing tower, flush efficiency can not only be greatly improved, and the concentration of sulfuric acid can also be greatly improved;It is another Aspect, desulfurizing tower be two and more than, when carrying out catalyst regeneration, it is ensured that at least one desulfurizing tower is work shape State, so ensure the uninterrupted of fume treatment;
Further, because the first pond body unit is at least three, because sulfuric acid is Reusability, in each first pond body list Sulfuric acid concentration in member is different, and in actual flushing process, first rinse is carried out to catalyst layer using the sulfuric acid of high concentration, then Using gradually adopt concentration of taking second place sulfuric acid carry out subsequent rinse, in this way, constantly improve a portion sulfuric acid concentration, when After the sulfuric acid of best concentration reaches recovery requirement, recovery is extracted out, the sulfuric acid of remaining concentration repeats above-mentioned flushing work, such as This, the further recovery value for improving sulfuric acid.
Preferably, first pump unit is at least two.By setting at least two pump units, can make multiple The flushing work of desulfurizing tower is carried out simultaneously, improves flush efficiency;On the other hand, can also be by one of them or several pump units As standby, ensure the reliability service of equipment.
Preferably, the regenerative system also include back liquid supervisor, the first liquid back pipe of each desulfurizing tower with Described time liquid supervisor's connection, the pickling tube are connected by described time liquid supervisor with first liquid back pipe.
Disclosed herein as well is a kind of retrieval of sulfuric acid equipment line, including above-mentioned oil interceptor and regenerative system, the regeneration The liquid supervisor that returns of system also connect with the liquid pool that enters of the oil interceptor, described time liquid be responsible for and it is described enter liquid pool between pipeline On be provided with valve, the pickling tube of the filtrate liquor pool of the oil interceptor also with the regenerative system connects, in the filtrate liquor pool and acid Valve is provided with the pipeline connected between wash pool.
The retrieval of sulfuric acid equipment line of the application, when desulphurization plant line carries out catalyst flush work, as Jiao in sulfuric acid When oil content is higher, sulfuric acid is transported to the entering in liquid pool of oil interceptor, the tar in sulfuric acid is filtered, then again will filtering Sulfuric acid afterwards is transported to pickling punching and continues the flushing work of catalyst, in this way, on the one hand due in sulfuric acid tar filtered, Allow catalyst to be rinsed cleaner, on the other hand, sulfuric acid can also be enable more frequently to rinse catalyst, such as This, significantly improves sulfuric acid concentration, improves the recovery value of sulfuric acid.
Preferably, filter and the pump housing are also included, the import of the pump housing connects with the filtrate liquor pool of the oil interceptor, institute State outlet and the inlet communication of the filter of the pump housing.It is after oil removal, to pass through when the sulfuric acid lane in oil interceptor is sufficiently high The pump housing pumps sulfuric acid into filter in the sulfuric acid for being further filtrated to get cleaning, in this way, realizing the recovery of sulfuric acid.
Preferably, the outlet of the filter is also associated with the finished acid pond for collecting sulfuric acid.
Preferably, the pump housing is membrane filtration pump.Using membrane filtration pump, further sulfuric acid can also be filtered, entered The cleannes of the raising sulfuric acid of one step.
Preferably, the pump housing is two, and two pump housings are connected in parallel between the filtrate liquor pool and the filter inlet.Its In pump housing be standby, include the reliability service of equipment.
Preferably, the filtering includes filter cylinder, some filter membrane components is provided with the filter cylinder, the filter membrane component is used for Filter the sulfuric acid that the pump housing is pumped into.
Preferably, flushing pipe is additionally provided with the filter cylinder, described flushing pipe one end is stretched into the filter cylinder, another End connects with exterior clean water source.When impurity is excessive on filter membrane component, filter membrane component is rinsed by flushing pipe, made Filter membrane component keeps good filter effect.
Preferably, blowing line is additionally provided with the filter cylinder, described blowing line one end is stretched into the filter cylinder, another End is connected with air-blast device.After being rinsed to filter membrane component, high velocity air is blasted using air-blast device, by the inside of filter cylinder Space dries up, and avoids the cleaning solution dilution of residual or pollution sulfuric acid in filter cylinder.
Disclosed herein as well is a kind of fluid-tight system for desulphurization plant line, include U-tube and for containing fluid-tight The smoke-intake pipe road of the fluid-tight pond of liquid, described U-tube one end and the pipeline communication of conveying untreated flue gas, the other end and desulfurizing tower Connection, is provided with the second pump unit between the U-tube and the fluid-tight pond, and second pump unit is used for by described in In fluid-tight liquid pumping to the U-tube in fluid-tight pond.Using the fluid-tight system of the application, the break-make on smoke-intake pipe road is realized, As previously described, it is not only simple in structure, and there is more preferable durability and reliability.
Preferably, second pump unit is two groups.One of which is standby, ensures the reliability that equipment uses.
Preferably, the U-tube bottom is also associated with the second liquid back pipe, second liquid back pipe and catalyst regeneration system Pickling tube connection, be provided with valve on the pipeline that second liquid back pipe connects with pickling tube.Desulfurizing tower is carried out at flue gas During reason, the fluid-tight liquid in U-tube is put into pickling tube, the regeneration for carrying out remaining desulfurizing tower catalyst is rinsed, and has saved sulphur Acid and use cost.
Preferably, the fluid-tight bottom of pond portion is additionally provided with blowoff valve.
Disclosed herein as well is a kind of flue gas desulfurization device line, the desulphurization plant line includes at least one above-mentioned desulfurization Tower.
The desulphurization plant line of the application, as a result of above-mentioned desulfurizing tower, sulfur dioxide in flue gas can be greatly improved With the contacting efficiency of desulfurizing agent, and then the removal efficiency of sulfur dioxide in flue gas is improved, the desulfurizing agent in the application can be energy Occur to chemically react with sulfur dioxide and then realize the chemicals of sulfur dioxide removal or for being catalyzed sulfur dioxide Occur to chemically react and then realize the catalyst of sulfur dioxide removal with other materials
Preferably, in addition to above-mentioned fluid-tight system.As a result of above-mentioned fluid-tight system, the logical of smoke-intake pipe road is realized It is disconnected, as previously described, it is not only simple in structure, and there is more preferable durability and reliability
Preferably, in addition to above-mentioned retrieval of sulfuric acid equipment line.
Compared with prior art, the beneficial effect of the application:
In flue gas desulfurization process is carried out, rinse in the sulfuric acid that catalyst is formed and there are a large amount of tar, using the application Oil interceptor, the sulfuric acid with more tar content is passed through into oil interceptor, sulfuric acid is when through oil removal part, oil removal part in tar Stop, and then reduce the tar content in sulfuric acid, pass through the sulfuric acid of oil interceptor, when concentration, which reaches recovery, to be required, Ke Yizhi Capable recovery is tapped into, due to relatively low tar content, and then facilitates the recovery operation of sulfuric acid, it is dense by the sulfuric acid of oil interceptor When spending relatively low, it can be made to be again introduced into pickling tube work is rinsed to the catalyst in desulfurizing tower, due to tar content Reduce, catalyst flush can be obtained more clean.
Brief description of the drawings:
Fig. 1 is the structural representation of filtering layer component arrangement inside desulfurizing tower;
Fig. 2 is the partial structural diagram that filter component coordinates with support component;
Fig. 3 is the structural representation that support beam coordinates with support ring;
Fig. 4 is the partial structural diagram that support post coordinates with support beam;
Fig. 5 is the schematic diagram of support tube in desulfurizing tower, the first support member and the 3rd support member arrangement;
Fig. 6 is the top view of desulfurizing tower tower body;
The structural representation that Fig. 7 desulfurizing towers are returned at liquid device;
The structural representation of Fig. 8 pickling tubes;
Fig. 9 is the structural representation of oil interceptor
Figure 10 is the partial structural diagram in oil removal portion;
Figure 11 is that the equipment of regenerative system arranges schematic diagram;
Figure 12 is to arrange schematic diagram using the equipment of flue gas desulfurization device line during a desulfurizing tower;
Figure 13 is to arrange schematic diagram using the equipment of flue gas desulfurization device line during a desulfurizing tower,
Indicated in figure in 1-13:100- tower bodies, 101- gas approach, 102- exhanst gas outlets, 103- filtering layer components, 104- One silk screen, 105- the first iso-saddle ring layers, 106- the second iso-saddle ring layers, the silk screens of 107- second,
108- Turbogrid plates, 109- support beams, 110- support rings, the reinforcements of 111- first, 112- support posts, 113- pads Plate, 114- support tubes,
115- smoke-intake pipes, 116- bottom plates, the support members of 117- first, 118- spray heads, 119- water inlet pipes, 120- first every Plate, 121- top plates, 122- manholes, 123- discharge ports, the support members of 124- second, the support members of 125- the 3rd, 126- nozzle for thermometer, The bend pipes of 127- first, the bend pipes of 128- second, the turn of bilges of 129- first, the turn of bilges of 130- second, 131- downtake pipes, 132- filterings Layer,
The pond bodies of 133- first, 134- second partitions, 135- the first pond body units, the pipelines of 136- first, the shroudings of 137- first, 138- second exhaust pipes, the support members of 139- the 4th,
The pond bodies of 140- second, the dividing plates of 141- the 3rd, the dividing plates of 142- the 4th, 143- oil removal parts, 144- web plates, 145- second Shrouding, 146- enter liquid pool, 147- filtrate liquor pools, the blast pipes of 148- the 3rd, 149- liquid level gauges, 150- reinforcements,
The pump units of 151- first, 152- return liquid and are responsible for, the liquid back pipes of 153- first, 154- filters, the 155- pump housings, and 156 - finished acid pond, 157- filter cylinders, 158- flushing pipes, 159- blowing lines, 160- filter membrane components, 161- fluid-tights pond, 162- second Pump unit, the liquid back pipes of 163- second.
Embodiment
The application is described in further detail with reference to test example and embodiment.But this should not be understood Following embodiment is only limitted to for the scope of the above-mentioned theme of the application, it is all that this is belonged to based on the technology that teachings herein is realized The scope of application.
Embodiment 1, as shown in figures 1-13:
A kind of filtering layer component for desulfurizing tower, the filtering layer component 103 is located at desulfurizing tower gas approach 101 and flue gas goes out Between mouthfuls 102, after flue gas is first passed through the filtering layer component 103, then discharged by the exhanst gas outlet 102, the filtering layer component 103 include filter layer 132, and some exhaust gases passes passed through for flue gas are there are in the filter layer 132.
The filtering layer component 103 of the application, there are some passages passed through for flue gas in filter layer 132, into tower body 100 Flue gas is discharged by exhanst gas outlet 102 again by these passages, is adopted in such a way, can greatly improve sulfur dioxide in flue gas With the contacting efficiency of desulfurizing agent, and then the removal efficiency of sulfur dioxide in flue gas is improved, the desulfurizing agent in the application can be energy Occur to chemically react with sulfur dioxide and then realize the chemicals of sulfur dioxide removal or for being catalyzed sulfur dioxide Occur to chemically react and then realize the catalyst of sulfur dioxide removal with other materials.
Preferably, the filter layer 132 by some granular filter elements in a manner of accumulating or lay Formed, formed with gap between adjacent filtration member, to be connected with each other either independently of each other or part connects between each gap The mode connect forms some exhaust gases passes passed through for flue gas.
In this scenario, the exhaust gases passes passed through for flue gas are formed using aforesaid way, these exhaust gases passes shapes are random Property high, or bending or tortuous, be flue gas by providing longer path, can further improve connecing for flue gas and desulfurizing agent Touch efficiency, and then the further removal efficiency for improving sulfur dioxide.
Preferably, the filter element is spherical, ellipsoid or column.
Using the filter element of above-mentioned shape and specification, in accumulation or laying, facilitate the formation of exhaust gases passes, and The exhaust gases passes formed also have more suitably sized, that is, ensure that flue gas and desulfurizing agent have higher contacting efficiency, together When have and avoid the formation of excessive resistance, facilitate passing through for flue gas.
It is further preferred that the filter element is cylindric, a diameter of 3-10mm.
It is further preferred that the filter element is cylindric, a diameter of 4-6mm.
In actual design and in use, inventor's discovery, is arranged to above-mentioned size by filter element, makes its each filter element Between form size suitable gap, while ensureing that flue gas circulation is smooth, it is ensured that the gap inside filter layer 132 has Sufficiently large area, ensure the removal efficiency of sulfur dioxide.
As one of which preferred scheme, the filter element is made using desulfurization catalyst agent material, the desulfurization catalyst Agent is used to make sulfur dioxide and oxygen generate sulfur trioxide.
In this programme, filter element is made using desulfurization catalyst agent material, that is to say, that make flue gas by filtering During exhaust gases passes between unit, under the catalytic action of catalyst material, sulfur dioxide is formed with the oxygen reaction in flue gas Sulfur trioxide, after sulfur trioxide is formed, because itself also has certain steam or water droplet in flue gas, so, worn in flue gas When crossing catalyst material, after sulfur trioxide is formed, sulfuric acid liquid is combined to form with steam or water droplet, is attached on filter element, And then the removing to sulfur dioxide in flue gas is realized, moreover, carrying out the removing of sulfur dioxide, catalyst by the way of catalyst Itself and free of losses, so, in actual use, using filter element made from desulfurization catalyst agent material can be repeatedly make With being on the one hand to have saved desulphurization cost, on the other hand also avoid the generation of new waste material or pollutant.
As another preferred scheme, the filter element is including the matrix as skeleton and is attached in described matrix Desulphurization catalyst, described matrix are activated carbon.
In this programme, using activated carbon as matrix, desulphurization catalyst is adhered on matrix, in sweetening process, two Sulfur oxide and oxygen form sulfur trioxide under desulphurization catalyst effect, and sulfur trioxide, which with water combines to form sulfuric acid and is attached to, urges In agent, and then the removing of sulfur dioxide is realized, further, in this programme, because matrix uses activated carbon, activated carbon table Face and inside all have compared with concrete dynamic modulus, are on the one hand matrix is adhered to more desulphurization catalysts, further improve dioxy Change the removal efficiency of sulphur, on the other hand, the exhaust gases passes shape formed is also more tortuous various, is more beneficial for flue gas and passed through While filtering layer 132, the removing of sulfur dioxide is more favorable to.
As another preferred scheme, the filter element is made using sulphur dioxide absorbent, when flue gas is described in During filtering layer, the sulfur dioxide in flue gas chemically reacts with the sulphur dioxide absorbent, realizes the absorption to sulfur dioxide.
In this scenario, sulphur dioxide absorbent is the alkali compounds that can be chemically reacted with sulfur dioxide, example Such as can be calcium, sodium, magnesium, ammonium compound, using this kind of mode, when flue gas passes through filtering layer 132, sulfur dioxide and filtering layer material Material chemically reacts, and then also achieves the removing of sulfur dioxide in flue gas.
As another preferred scheme, the filter element is made using inert material, and the inert material is in dioxy Change the stable material of the chemical properties not chemically reacted in sulphur subtractive process.
In this programme, filter element is made using inert material, was used as example with stainless steel or activated carbon Unit is filtered, in wet desulphurization mode, under desulfurizing agent sprays above filter layer 132, flue gas is entered by the lower section of filter layer 132, is taken off When sulphur agent is fallen on filter layer 132, in sprinkling state, some fine drops and liquid mist are formed, are then proceeded to toward under filter layer 132 Fang Liudong, in this process, flue gas are able to sufficiently be contacted with desulfurizing agent, in this way, greatly improve sulfur dioxide with The contact rate of desulfurizing agent, and then significantly improve the removal efficiency of sulfur dioxide.
Preferably, the filtering layer component 103 also includes the first silk screen 104, and institute is accumulated or be layed in the filter element State on the first twine, described first edge is engaged with the inwall of the tower body 100.By setting the first silk screen 104, to mistake While filter unit plays support, the smooth of flue gas circulation also ensure that.
Preferably, first silk screen 104 is stainless steel cloth.Ensure that the first silk screen 104 has good durability.
Preferably, the filtering layer component 103 also includes the first iso-saddle ring layer 105, and the first iso-saddle ring layer 105 includes There are some first iso-saddle rings, first iso-saddle ring is laid side by side below first silk screen 104.By setting the first different saddle Circular layer 105, because iso-saddle ring structure has the characteristics that macroporosity and high flux, so, in the scheme of the application, by simultaneously Some first iso-saddle rings of row form the supporting construction of the first silk screen 104, are ensureing the first silk screen 104 by the same of secure support When, the uniformity that flue gas enters filter layer 132 is also improved, improves the removal efficiency of sulfur dioxide.
It is further preferred that the filtering layer component 103 also includes the second iso-saddle ring layer 106, the second iso-saddle ring layer 106 include some second iso-saddle rings, and second iso-saddle ring is laid side by side on the first iso-saddle ring layer 105, and described The physical dimension of two iso-saddle rings is less than the physical dimension of first iso-saddle ring, also, the physical dimension of second iso-saddle ring Ensure that it does not fall from the hole of the first iso-saddle ring.
In such scheme, by setting the different iso-saddle ring of double-layer structure size, pass through the less second different saddle of size Circular layer 106 supports the first silk screen 104, further ensure that the planarization that the first silk screen 104 is supported, and larger by size The first iso-saddle ring layer 105 support the second iso-saddle ring layer 106, not only ensure that the smooth of flue gas circulation, while also reduce the The laying difficulty of one iso-saddle ring layer 105.
It is further preferred that the filtering layer component 103 also includes the second silk screen 107, the edge of second silk screen 107 It is engaged with the inwall of the tower body 100, the first iso-saddle ring layer 105 is layed on second silk screen 107.
Embodiment 2, as shown in figures 1-13:
A kind of catalyst support component for desulfurizing tower, the support component are arranged in the tower body 100 of desulfurizing tower, institute State support component to be used to support the filtering layer component 103 positioned at the lower section of filtering layer component 103, the support component, make described The bottom of filtering layer component 103 and the tower body 100 separates.
In this scenario, by support component, filtering layer component 103 and the bottom of tower body 100 is separated, are on the one hand to facilitate cigarette Gas has the underlying space that enough spaces riddle filtering layer component 103, avoids flue gas only from the filtering layer close to smoke inlet part Pass through, and then ensure the filter efficiency of the sulfur dioxide of filtering layer.
Preferably, the support component includes Turbogrid plates 108, the edge of the Turbogrid plates 108 and the tower body 100 Inwall is engaged, and the second silk screen 107 of the filtering layer component 103 is layed on the Turbogrid plates 108.
Filtering layer component 103 is supported using Turbogrid plates 108, can effectively ensure that filtering layer component 103 has good planarization, And then ensure that filtering layer each several part can access good utilization, being additionally, since Turbogrid plates 108 itself has some holes, While playing to filtering layer 103 excellent support of component, the smooth of flue gas circulation also ensure that.
Preferably, the support component also includes some support beams 109, and the support beam 109 is used to support The Turbogrid plates 108, some support beams 109 are arranged side by side, and adjacent supports crossbeam 109 is to be spaced apart, the support The both ends of crossbeam 109 are engaged with the inwall of the tower body 100, and the Turbogrid plates 108 are located in the support beam 109.
It ensure that Turbogrid plates 108 are supported by some support beams 109 come propping bar panel 108 in such scheme Reliability, also ensure that the reliability that filtering layer component 103 is supported, be spaced apart between support beam 109, ensure flue gas That circulates is smooth.
Preferably, the support ring 110 of ring-type, the edge of support ring 110 are connected between the end of adjacent supports crossbeam 109 The inwall arrangement of the tower body 100, the both ends of the support ring 110 are connected with adjacent supports crossbeam 109 respectively, the support ring 110 outer rim is engaged with the inwall of the tower body 100.
In such scheme, by setting ring-type to be on the one hand so that in support ring 110, the edge of flase floor can be by It is reliable to support, it is further ensured that the reliability that support component supports to filter assemblies;On the other hand, due to support beam 109 Between be connected, also strengthen the stability of support beam 109 to a certain extent;Another further aspect, because tower body 100 is usually Thin-walled tubular structure, in this application, using the combination of support ring 110 and support beam 109, layer assembly 103 is filtered in support While, the inwall also corresponded in tower body 100 forms a circle reinforcement ring structure, so the structure for also improving tower body 100 is strong Degree, it can significantly reduce the risk of the deformation of tower body 100, enable the holding design form that tower body 100 is good.
Preferably, the support beam 109 is I-steel, the upper side of the upper side wing edge of the support beam 109 and institute The downside for stating Turbogrid plates 108 is engaged.
Preferably, the support ring 110 is tabular, the both ends of the support ring 110 respectively with adjacent supports crossbeam 109 Upper side wing edge is relative to be connect.
Preferably, the upper side of the upper side of the support ring 110 and the upper side wing edge of the support beam 109 is located at same In one plane.
Pass through the setting of such scheme so that, the upper side and the upper side of support ring 110 of support beam 109 form support Platform, there is larger mating surface with Turbogrid plates 108, further ensure that the reliability that filter layer 132 is supported.
Preferably, it is also associated with the first reinforcement 111 between the web of the support ring 110 and the support beam 109. By setting the first reinforcement 111 to increase the bonding strength between support ring 110 and support beam 109.
Preferably, each lower section of support beam 109 is additionally provided with some support posts 112, and the support is vertical The upper end of post 112 is connected with the support beam 109, the lower end of the support post 112 and the bottom plate 116 of the tower body 100 Connection.
Preferably, the support post 112 of support beam 109 described in same root is is spaced apart.Adjacent upright posts are to be spaced apart, It is also convenient to ensure the smooth of flue gas circulation while guarantee to 109 secure support of support beam.
Preferably, the upper end of support post 112 and/or lower end are connected with backing plate 113.By setting backing plate 113 to ensure The reliability of connection.
Preferably, the support post 112 is steel pipe.
Preferably, some support tubes 114 are also associated between adjacent supports crossbeam 109.Support tube 114, support beam 109, with, support post 112 and tower body 100, form the frame structure mutually supported by connecting, are on the one hand that ensure that filter Layer assembly 103 is reliably supported, and on the other hand also significantly adds the structural strength of tower body 100.
Preferably, the junction of support tube 114 and the support beam 109 is located at the top of support post 112.Also It is to say, column and support tube 114 are connected with the same place position of support beam 109, beneficial to the transmission of each member stress, further Improve the structural stability of support component.
Embodiment 3, as shown in figures 1-13:
Disclosed herein as well is a kind of tower body for desulfurizing tower,
Smoke-intake pipe 115 is connected with the gas approach 101, one end of the smoke-intake pipe 115 is stretched into the tower body 100 Portion, in the vertical direction, the smoke-intake pipe 115 inside the tower body 100, any position top of its inwall all there are screening Gear.
In this programme, it all there are and block above any position of the inwall of tower body 100, in this way, avoiding the liquid of top Or unclassified stores drops into smoke-intake pipe 115 and influences flue gas conveying, in this law scheme, in the vertical direction, positioned at tower Smoke-intake pipe 115 inside body 100, any position top of its inwall, which all there are, is blocked, and this is blocked, and can be by smoke-intake pipe 115 are obliquely installed, and make the port of smoke-intake pipe 115 oblique, and then make at the port, and part above forms section below Block;Can also be that the port that smoke-intake pipe 115 is located inside tower body 100 is arranged to inclined opening structure;It can also be to port The latter half is cut out, and top half is formed blocking for the latter half;Also it can also be and independent barrier structure pair be set Blocked the port of smoke-intake pipe 115.
Preferably, the port that the smoke-intake pipe 115 is located inside the tower body 100 is angle.Inclined opening structure, a side are set Face is to ensure that smoke-intake pipe 115 can realize above-mentioned effect, meanwhile, also convenient processing, material is saved, manufacture can be effectively reduced Cost.
Preferably, the gas approach 101 is arranged in the side wall of the tower body 100, and the smoke-intake pipe 115 is by the tower The side wall of body 100 is entered in the tower body 100.Smoke-intake pipe 115 enters tower body 100 by the side wall of tower body 100, is on the one hand simplified The structure of the bottom of tower body 100, facilitate the mounting arrangements of tower body 100, the processing and manufacture being on the other hand also convenient for.
Preferably, the smoke-intake pipe 115 be located at the bottom plate 116 of port inside the tower body 100 and the tower body 100 every It is provided with distance.Further liquid or unclassified stores in tower body 100 is avoided to enter in smoke-intake pipe 115.
Preferably, it is also associated with some first support members 117 on the outer wall of the bottom plate 116 of tower body 100, described first It is the setting being parallel to each other between support member 117, be spaced apart of adjacent first support member 117 has distance.
As another preferable scheme, radial direction of first support member 117 along the tower body 100 is set.
The first some support members 117 is set on the bottom plate 116 of tower body 100 described above, is on the one hand to facilitate tower body 100 installation and arrangement, on the other hand, the first support member 117 also act as the effect for strengthening the bottom plate 116 of tower body 100, improve tower body 100 structural strength.
As another preferred scheme, first support member 117 is corresponding with the support post 112 of support component, institute State the underface that support member is located at the support post 112.In the scheme of the application, support post 112 is used to support filtering layer Component 103, the first support member 117 are located at the underface of support post 112, in this way, being on the one hand to ensure that support post 112 has Excellent support intensity and stability of strutting system, on the other hand, it can also reduce the bottom plate 116 of tower body 100 because of deadweight and support post 112 The pressure granted and caused deformation, further improve the reliability of structure of tower body 100.
Preferably, first support member 117 is I-steel, channel-section steel or rectangular steel pipe.Using I-steel, channel-section steel or Rectangular steel pipe or other section bars, on the one hand, use these section bars to facilitate market to buy for standard component, can save and add Work cost, on the other hand, section bar have groove or opening in itself, so, it has been also convenient for the first support member 117 and other supports Connection between part.
Embodiment 4, as shown in figures 1-13:
A kind of tower body 100 for desulfurizing tower is also disclosed in the application,
The inner side of top plate 121 of the tower body 100 is provided with some spray heads 118, and each described spray head 118 connects It is connected to water inlet pipe 119.
In the scheme of the application, by setting spray head 118, it can spray in spray head 118 and be reacted with sulfur dioxide Desulfurizing agent, can also spray for rinsing filtering layer component 103, ensure that filtering layer component 103 cleans or recovers catalyst activity Cleaning fluid, such as clear water makes filtering layer component 103 can be with Reusability, and ensure good filtration result.
Preferably, spray head 118 is uniform around the exhanst gas outlet 102.
Preferably, at least one first partition 120 is additionally provided with the tower body 100, the first partition 120 is positioned at branch The top of Turbogrid plates 108 of support component, the inner space of tower body 100 of the top of Turbogrid plates 108 is divided at least two and is used for Load the filled cavity of filter element.
By setting first partition 120, the inner space of tower body 100 above filtering layer component 103 is split, convenient point The other filter element in each filled cavity is controlled, such as is filled or changed respectively respectively, is facilitated to filter element Control.
Preferably, the upper end of first partition 120 and the inwall of top plate 121 of tower body 100 separate, and make each filled cavity Connected with the exhanst gas outlet 102.In this way, so filled cavity shares an exhanst gas outlet 102, it is right further to simplify The structure of tower body 100.
Preferably, manhole 122 is both provided with the top plate 121 of tower body 100 corresponding to each described filled cavity, it is each The discharge port 123 for taking out filter element, the people are both provided with corresponding to the individual filled cavity in the side wall of tower body 100 Capping is all removably connected with hole 122 and discharge port 123.Manhole 122 passes in and out available for worker, and it is single to can be used for filtering The filling of member, in this way, facilitating the filling and replacing of filter element.
Preferably, the outer wall of top plate 121 of the tower body 100 is additionally provided with some second support members 124, described second It is the setting being parallel to each other between support member 124, be spaced apart of adjacent second support member 124 has distance.
As another preferable scheme, radial direction of second support member 124 along the tower body 100 is set.
The second some support members 124 is set on the top plate 121 of tower body 100 described above, is on the one hand to facilitate tower body 100 installation and arrangement, on the other hand, the second support member 124 also act as the effect for strengthening the top plate 121 of tower body 100, improve tower body 100 structural strength.
Preferably, second support member 124 aligns with the first support member 117 on the bottom plate 116 of tower body 100.Second Support member 124 is alignd with the first support member 117, further facilitates the arrangement of the external connection component of tower body 100.
Preferably, the periphery of tower body 100 is additionally provided with some the 3rd support members 125 being vertically arranged, positioned at same Vertical the first support member 117 and the second support member 124 is connected with the 3rd support member 125.It is first by this kind of mode First, tower body 100 can be supported easily by the 3rd support member 125, such as support to suitable height, in actual use, Multiple tower bodies 100 can be carried out on same vertical direction overlapping, saved floor occupying area, on the other hand, pass through the 3rd support Part 125 connects the first support member 117 and the second support member 124, the first support member 117, the second support member 124 and the 3rd support Mutually supported between part 125, further increase stability and reliability that tower body 100 is supported, also further improve The strength and stiffness of the structure of tower body 100.
Preferably, the nozzle for thermometer 126 for placing thermometer, the temperature are connected with the top plate 121 of tower body 100 Degree meter adapter 126 and the inner space of the tower body 100 are connected.By nozzle for thermometer 126 is set, it is necessary to when, can pass through Thermometer is set, has further facilitated use.
Preferably, it is both provided with a temperature on the top plate 121 of tower body 100 corresponding to each described filled cavity Count adapter 126.The convenient grasp to regional temperature.
Embodiment 5, as shown in figures 1-13:
Liquid device is returned for desulfurizing tower disclosed herein as well is a kind of,
Including the first liquid back pipe 153 being arranged on the bottom plate 116 of tower body 100, described one end of first liquid back pipe 153 with it is described The inner space of tower body 100 is connected, and the other end is connected with wastewater treatment equipment or regeneration of sulfuric acid system, first liquid back pipe 153 with the inner space of tower body 100 connect end without departing from the bottom plate 116 inwall.By setting the first liquid back pipe 153, the liquid in tower body 100 is drawn, the end that the first liquid back pipe 153 is connected with the inner space of tower body 100 is without departing from bottom plate 116 inwall, it can effectively ensure that liquid in tower body 100 being capable of more outflow as far as possible.
Preferably, first liquid back pipe 153 includes the first bend pipe 127 and the second bend pipe 128, first bend pipe 127 one end and the inner space of the tower body 100 are connected, and the other end is connected with second bend pipe 128, first bend pipe 127 have the first downwardly convex turn of bilge 129, and the interior energy of the first turn of bilge 129 convergence liquid, which is formed, blocks the first time liquid The fluid-tight of pipe 153.In the scheme of the application, fluid-tight is formed by the turn of bilge of the first liquid back pipe 153 itself, is to ensure first The first liquid back pipe 153 is blocked when needing, avoids flue gas from being discharged from the first liquid back pipe 153;Further, also with structure letter It is single, convenient the advantages that processing and manufacturing;On the other hand, because sulfur dioxide, sulfuric acid etc. have aggressive, so, relatively pass For the valve mechanism of system, the blocking of the first liquid back pipe 153 is realized using fluid-tight, durability is more preferable, and structural behaviour is more steady It is fixed reliable.
It is further preferred that second bend pipe 128 has the second turn of bilge 130 to raise up, first turn of bilge 129 Less than second turn of bilge 130, the level height of first turn of bilge 129 is less than the level height of second turn of bilge 130.Such as This, realizes the formation of fluid-tight.
Preferably, the bend pipe 128 of the first bend pipe 127 and second docking forms inverted S-shaped.Further convenient processing And manufacture.
Preferably, the level of the inner flow passage of the second bend pipe 128 described in the level height of the inner flow passage of the first bend pipe 127 Highly it is less than the level height of the inwall of 100 bottom plate of tower body 116.Ensure that the liquid in tower body 100 can be smoothly from first Liquid back pipe 153 flows out.
Preferably, downtake pipe 131, the downtake pipe 131 are additionally provided with the top of second turn of bilge 130 Lower end and the inner flow passage of second turn of bilge 130 are connected, the downtake pipe 131 that upper end connects with outside atmosphere.By setting Downtake pipe 131 is put, further facilitates the outflow of liquid in tower body 100, meanwhile, also ensure the energy in the first bend pipe 127 It is enough to form the fluid-tight for blocking the first liquid back pipe 153.
Preferably, the level height of the upper end of downtake pipe 131 is likely to be breached most higher than liquid in the tower body 100 High position.The liquid in tower body 100 is avoided to be overflowed from downtake pipe 131.
Preferably, the tip portion of downtake pipe 131 is bent downwards, makes the downtake pipe 131 opening down. Exterior space debris and/or rainwater can be effectively avoided to enter in downtake pipe 131.
Embodiment 6, as shown in figures 1-13:
Disclosed herein as well is a kind of desulfurizing tower, including above-mentioned filtering layer component 103.The desulfurizing tower of the application, due to adopting With above-mentioned filtering layer component 103, the contacting efficiency of sulfur dioxide in flue gas and desulfurizing agent can be greatly improved, and then improves cigarette The removal efficiency of sulfur dioxide in gas, the desulfurizing agent in the application can be occurred to chemically react with sulfur dioxide and then realize The chemicals of sulfur dioxide removal or occur to chemically react and then realize for being catalyzed sulfur dioxide and other materials The catalyst of sulfur dioxide removal.
Preferably, in addition to above-mentioned catalyst support component.Further, also adopted in the Structure of Flue Gas Desulfuration Absorbing of the application With above-mentioned catalyst support component, good support effect can be played to filtering layer in desulfurizing tower.
Preferably, in addition to above-mentioned tower body 100.
Embodiment 7, as shown in figures 1-13:
Disclosed herein as well is a kind of pickling tube for desulphurization plant line, the pickling tube includes the first pond body 133, institute State and at least one second partition 134 is provided with the first pond body 133, the second partition 134 is by first pond body 133 Space is divided at least two the first pond body units 135 for being used for independent collection sulfuric acid, on each first pond body unit 135 The first pipeline 136 all connected with the first liquid back pipe 153 of desulfurizing tower is provided with, valve is both provided with first pipeline 136 Door.
Preferably, the second partition 134 is at least two, and the second partition 134 is by first pond body 133 Space is divided at least three first pond body units 135.
The pickling tube of the application, by setting second partition 134, it is only that the inner space of pickling tube is divided at least two Vertical the first pond body unit 135 for collecting sulfuric acid, when being rinsed to desulfurizing tower inside, liquid pump is for independent by each first Sulfuric acid in pond body unit 135 is pumped to the water inlet pipe 119 of desulfurizing tower, can pass through the coordination between the first pond body unit 135 Coordinate, i.e. pump sulfuric acid in one of them first pond body unit 135 to the flushing work of progress catalyst in desulfurizing tower, punching Sulfuric acid after washing is flowed into another the first pond body unit 135, and so repeatedly, the catalyst layer in desulfurizing tower is carried out repeatedly Rinse, be on the one hand to improve the cleanliness factor that catalyst is rinsed, on the other hand can also improve the sulfuric acid concentration in pickling tube, carry The recovery value of high sulfuric acid.
In this programme, when the first pond body unit 135 be at least three, carry out catalyst layer flushing work when, expand The coordination scope carried out between big first pond body unit 135, using the teaching of the invention it is possible to provide more optimal washing form;Particularly to tool Have in the desulphurization plant line of multiple desulfurizing towers, flush efficiency can not only be greatly improved, and the dense of sulfuric acid can also be greatly improved Degree;On the other hand, desulfurizing tower be two and more than, when carrying out catalyst regeneration, it is ensured that at least one desulfurizing tower is Working condition, so ensure the uninterrupted of fume treatment;
Further, because the first pond body unit 135 is at least three, because sulfuric acid is Reusability, in each first pond Sulfuric acid concentration in body unit 135 is different, and in actual flushing process, catalyst layer is carried out first using the sulfuric acid of high concentration Rinse, then using gradually adopting the sulfuric acid for concentration of taking second place to carry out subsequent rinse, in this way, constantly improving the sulfuric acid of a portion Concentration, after the sulfuric acid of best concentration, which reaches recovery, to be required, extract recovery out, the sulfuric acid of remaining concentration repeats above-mentioned flushing work Make, in this way, further improving the recovery value of sulfuric acid.
Preferably, the above-mentioned upper end of first pond body 133 is additionally provided with the first envelope for closing the upper end open of the first pond body 133 Plate 137, first pipeline 136 connect through first shrouding 137 with the inner space of the first pond body unit 135. By setting the first shrouding 137, prevent sulfuric acid from trickling down outside pickling tube.
Preferably, second exhaust pipe 138 is both provided with first shrouding 137 corresponding to each first pond body unit 135, The lower end of second exhaust pipe 138 is stretched into the first pond body unit 135 through first shrouding 137, and upper end is in unlimited Shape.By setting second exhaust pipe 138, the gas in the first pond body unit 135 is discharged, ensures the smooth of sulphuric acid stream.
Preferably, the upper part of second exhaust pipe 138 is bent downwards, makes the upper port of the second exhaust pipe 138 Down.Outside debris or rainwater can be avoided to drop into pickling tube.
Preferably, the bottom of each the first pond body unit 135 is both provided with blowoff valve.It is convenient to keep pickling tube Interior cleaning, and then ensure the cleaning of sulfuric acid.
Preferably, the liquid level gauge for detecting inside liquid level is both provided with each described first pond body unit 135 149.It is easy to the control to liquid level in pickling tube.
Preferably, be also associated with some 4th support members 139 in first pond body 133, the 4th support member 139 with 3rd support member 125 is engaged.,, can be by this during actual use by setting the 4th support member 139 in this programme The pickling tube of application is arranged on the 3rd support member 125 below desulfurizing tower, and it is smaller to be on the one hand so that desulphurization plant line takes Area, on the other hand, also improve the globality between each equipment.
Embodiment 8, as shown in figures 1-13:
Disclosed herein as well is a kind of oil interceptor for flue gas desulfurization device line, including the second pond body 140, described second At least one 3rd dividing plate 141 and at least one 4th dividing plate 142 are provided with pond body 140, obtain the 3rd dividing plate 141 and four every The lateral margin of plate vertical direction and the inwall closing of second pond body 140 connect, the second pond above the 3rd dividing plate 141 It is described formed with second flow channel in the second pond body 140 below the 4th dividing plate 142 formed with first flow in body 140 Third flow channel is communicated between first flow and the second flow channel, be provided with the third flow channel for filtered tar every Oily 143, portion.
In flue gas desulfurization process is carried out, rinse in the sulfuric acid that catalyst is formed and there are a large amount of tar, using the application Oil interceptor, the sulfuric acid with more tar content is passed through into oil interceptor, sulfuric acid is when through 143, oil removal portion, oil removal in tar 143, portion stop, and then reduce the tar content in sulfuric acid, by the sulfuric acid of oil interceptor, when concentration, which reaches recovery, to be required, It can directly be reclaimed, due to relatively low tar content, and then facilitate the recovery operation of sulfuric acid, pass through oil interceptor When sulfuric acid concentration is relatively low, it can be made to be again introduced into pickling tube work is rinsed to the catalyst in desulfurizing tower, due to Jiao The reduction of oil mass, catalyst flush can be obtained more clean.
Preferably, the lower edge of the 3rd dividing plate 141 is connected with the bottom lock of second pond body 140, upper limb and institute The upper end for stating the second pond body 140 separates to form the first flow.
Preferably, the upper limb of the 4th dividing plate 142 is concordant with the upper end of the second pond body 140, lower edge and described second The bottom of pond body 140 separates to form second flow channel.
It is described above to set so that sulfuric acid is the flowing of relief form, beneficial to oil removal portion when through 143, oil removal portion Tar in 143 sulfuric acid that come.
Preferably, 143, oil removal portion includes some nets being connected between the 3rd dividing plate 141 and the 4th dividing plate 142 Plate 144, the web plate 144 is encircled into the cavity of closure with the 3rd dividing plate 141 and the 4th dividing plate 142, in the cavity, Filled with granular filler.Filler is coated by web plate 144, ensures that sulfuric acid passes through oil removal portion 143.
Preferably, the filler is quartz sand.Quartz sand has stable chemical property and physical property, and can be anti- It is multiple to use, while guarantee has good oil removal effect, also save use cost.
Preferably, the upper end of the second pond body 140 is provided with the second shrouding 145 for closing the second pond body 140.Pass through Second shrouding 145 is set, avoids sulfuric acid from trickling down to outside the second pond body 140, also foreign matter can be avoided to enter the second pond body In 140.
Preferably, include in second pond body 140 into liquid pool 146 and filtrate liquor pool 147, it is described enter liquid pool 146 with it is described Second flow channel connects, and the filtrate liquor pool 147 connects with the first flow, it is described enter second pond body corresponding to liquid pool 146 It is additionally provided with 140 for detecting the liquid level gauge 149 into the inside liquid level of liquid pool 146.
Preferably, it is additionally provided with second pond body 140 corresponding to the filtrate liquor pool 147 for detecting filtrate liquor pool 147 The liquid level gauge 149 of inside liquid level.
By the setting of liquid level, facilitate the assurance to liquid level in oil interceptor, another, can be by comparing into liquid pool The reading of 146 liquid level gauges 149 and the reading of liquid level gauge 149 of filtrate liquor pool 147, determine the tar content in oil removal portion 143, work as reading When difference is larger, you can substantial amounts of tar is there are in specification oil removal portion 143, and then can contemplate and change or clean oil removal Filler in portion 143.
Preferably, the 3rd blast pipe 148 is additionally provided with second shrouding 145 corresponding to the filtrate liquor pool 147, it is described The filtrate liquor pool 147 is stretched into one end of 3rd blast pipe 148, and concordant with the inwall of second shrouding 145.
Preferably, some reinforcements 150 are provided with second shrouding 145.
Preferably, it is described enter liquid pool 146 and the bottom of filtrate liquor pool 147 be both provided with blowoff valve.Oil removal can easily be ensured Cleaning inside pond.
Embodiment 9, as shown in figures 1-13:
Disclosed herein as well is a kind of regenerative system for flue gas desulfurization device line,
Including above-mentioned pickling tube and at least one first pump unit 151, first pump unit 151 is gone back and desulfurization Tower water inlet pipe 119 connects, and first pump unit 151 is used for the independent sulfuric acid pump by each first pond body unit 135 Deliver to the water inlet pipe 119.
For desulfurizing tower of the filtering layer component 103 using catalyst, with continuing for desulfurization work, the sulfuric acid formed The amount of attachment on a catalyst is more and more, is on the one hand catalyst is reduced sulfur dioxide from good and smoke contacts Removal effect, on the other hand, be also unfavorable for the circulation of flue gas, reduce the desulfuration efficiency of desulfurizing tower;
So after desulfurizing tower runs certain time, start the regenerative system of the application, using water to being attached to catalyst On sulfuric acid be rinsed, the sulfuric acid of formation is run down into pickling tube, realizes the regeneration of catalyst, in this programme, flow into acid The sulfuric acid of wash pool is required, using the pickling of the application by repeatedly for rinsing catalyst layer until sulfuric acid concentration reaches to reclaim Pond, by setting second partition 134, the inner space of pickling tube is divided at least two independent the first pond bodies for collecting sulfuric acid Unit 135, when being rinsed to desulfurizing tower inside, liquid pump is used for the independent sulfuric acid by each first pond body unit 135 Be pumped to the water inlet pipe 119 of desulfurizing tower, the cooperation between the first pond body unit 135 can be passed through, i.e. by one of them Sulfuric acid is pumped to the flushing work of progress catalyst in desulfurizing tower in one pond body unit 135, and the sulfuric acid after flushing is flowed into another In individual first pond body unit 135, so repeatedly, the catalyst layer in desulfurizing tower is rinsed repeatedly, is on the one hand to improve to urge The cleanliness factor that agent is rinsed, the sulfuric acid concentration in pickling tube on the other hand can be also improved, improve the recovery value of sulfuric acid.
In this programme, when the first pond body unit 135 be at least three, carry out catalyst layer flushing work when, expand The coordination scope carried out between big first pond body unit 135, using the teaching of the invention it is possible to provide more optimal washing form;Particularly to tool Have in the desulphurization plant line of multiple desulfurizing towers, flush efficiency can not only be greatly improved, and the dense of sulfuric acid can also be greatly improved Degree;On the other hand, desulfurizing tower be two and more than, when carrying out catalyst regeneration, it is ensured that at least one desulfurizing tower is Working condition, so ensure the uninterrupted of fume treatment;
Further, because the first pond body unit 135 is at least three, because sulfuric acid is Reusability, in each first pond Sulfuric acid concentration in body unit 135 is different, and in actual flushing process, catalyst layer is carried out first using the sulfuric acid of high concentration Rinse, then using gradually adopting the sulfuric acid for concentration of taking second place to carry out subsequent rinse, in this way, constantly improving the sulfuric acid of a portion Concentration, after the sulfuric acid of best concentration, which reaches recovery, to be required, extract recovery out, the sulfuric acid of remaining concentration repeats above-mentioned flushing work Make, in this way, further improving the recovery value of sulfuric acid.
Preferably, first pump unit 151 is at least two.By setting at least two pump units, can make The flushing work of multiple desulfurizing towers is carried out simultaneously, improves flush efficiency;On the other hand, can also be by one of them or several liquid pumps Component ensures the reliability service of equipment as standby.
Preferably, the regenerative system also includes back liquid supervisor 152, the first liquid back pipe of each desulfurizing tower 153 are all connected with described time liquid supervisor 152, and the pickling tube is responsible for 152 by described time liquid and connected with first liquid back pipe 153 It is logical.
Embodiment 10, as shown in figures 1-13:
Disclosed herein as well is a kind of retrieval of sulfuric acid equipment line, including above-mentioned oil interceptor and regenerative system, the regeneration The liquid supervisor that returns of system 152 also connects with the liquid pool 146 that enters of the oil interceptor, described time liquid supervisor 152 with it is described enter liquid pool It is provided with valve on pipeline between 146, the pickling tube of the filtrate liquor pool 147 of the oil interceptor also with the regenerative system connects, Valve is provided with the pipeline connected between the filtrate liquor pool 147 and pickling tube.
The retrieval of sulfuric acid equipment line of the application, when desulphurization plant line carries out catalyst flush work, as Jiao in sulfuric acid When oil content is higher, sulfuric acid is transported to the entering in liquid pool 146 of oil interceptor, the tar in sulfuric acid is filtered, then again will Sulfuric acid after filtering is transported to the flushing work that pickling punching continues catalyst, in this way, on the one hand due to tar quilt in sulfuric acid Filtering so that catalyst can be rinsed cleaner, on the other hand, sulfuric acid can also be enable more frequently to rinse catalysis Agent, in this way, significantly improving sulfuric acid concentration, improve the recovery value of sulfuric acid.
Preferably, filter 154 and the pump housing 155 are also included, the import of the pump housing 155 goes out liquid with the oil interceptor Pond 147 connects, the outlet of the pump housing 155 and the inlet communication of the filter 154.When the sulfuric acid in oil interceptor does individual enough Gao Shi, after oil removal, sulfuric acid is pumped to the sulfuric acid that cleaning is further filtrated to get into filter 154 by the pump housing 155, such as This, realizes the recovery of sulfuric acid.
Preferably, the outlet of the filter 154 is also associated with the finished acid pond 156 for collecting sulfuric acid.
Preferably, the pump housing 155 is membrane filtration pump.Using membrane filtration pump, also further sulfuric acid can be filtered, The further cleannes for improving sulfuric acid.
Preferably, the pump housing 155 is two, and two pump housings 155 are connected in parallel on the filtrate liquor pool 147 and the filter Between 154 imports.One of pump housing 155 is standby, includes the reliability service of equipment.
Preferably, the filtering includes filter cylinder 157, and some filter membrane components 160, the filter are provided with the filter cylinder 157 Membrane module 160 is used to filter the sulfuric acid that the pump housing 155 is pumped into.
Preferably, flushing pipe 158 is additionally provided with the filter cylinder 157, the filter is stretched into described one end of flushing pipe 158 In cylinder 157, the other end connects with exterior clean water source.It is right by flushing pipe 158 when impurity is excessive on filter membrane component 160 Filter membrane component 160 is rinsed, and filter membrane component 160 is kept good filter effect.
Preferably, blowing line 159 is additionally provided with the filter cylinder 157, the filter is stretched into described one end of blowing line 159 In cylinder 157, the other end is connected with air-blast device.After being rinsed to filter membrane component 160, high speed gas is blasted using air-blast device Stream, the inner space of filter cylinder 157 is dried up, avoid the cleaning solution dilution of residual or pollution sulfuric acid in filter cylinder 157.
Embodiment 11, as shown in figures 1-13:
Disclosed herein as well is a kind of fluid-tight system for desulphurization plant line, include U-tube and for containing fluid-tight The fluid-tight pond 161 of liquid, described U-tube one end and the pipeline communication of conveying untreated flue gas, the other end and desulfurizing tower enter cigarette Pipe 115 is connected, and the second pump unit 162, second liquid pump are provided between the U-tube and the fluid-tight pond 161 Component 162 is used in the fluid-tight liquid pumping in the fluid-tight pond 161 to the U-tube.Using the fluid-tight system of the application, The break-make on the tunnel of smoke-intake pipe 115 is realized, as previously described, is not only simple in structure, and there is more preferable durability and reliability.
Preferably, second pump unit 162 is two groups.One of which is standby, ensures the reliability that equipment uses.
Preferably, the U-tube bottom is also associated with the second liquid back pipe 163, and second liquid back pipe 163 and catalyst are again The pickling tube connection of raw system, valve is provided with the pipeline that second liquid back pipe 163 connects with pickling tube.Desulfurizing tower enters During row fume treatment, the fluid-tight liquid in U-tube is put into pickling tube, the regeneration for carrying out remaining desulfurizing tower catalyst is rinsed, Sulfuric acid and use cost are saved.
Preferably, the bottom of fluid-tight pond 161 is additionally provided with blowoff valve.
Embodiment 12, as shown in figures 1-13:
Disclosed herein as well is a kind of flue gas desulfurization device line, the desulphurization plant line includes at least one above-mentioned desulfurization Tower.
The desulphurization plant line of the application, as a result of above-mentioned desulfurizing tower, sulfur dioxide in flue gas can be greatly improved With the contacting efficiency of desulfurizing agent, and then the removal efficiency of sulfur dioxide in flue gas is improved, the desulfurizing agent in the application can be energy Occur to chemically react with sulfur dioxide and then realize the chemicals of sulfur dioxide removal or for being catalyzed sulfur dioxide Occur to chemically react and then realize the catalyst of sulfur dioxide removal with other materials.
Desulfurization reclaimer line in this example, exemplified by including one and four desulfurizing towers.
Preferably, in addition to above-mentioned fluid-tight system.As a result of above-mentioned fluid-tight system, the tunnel of smoke-intake pipe 115 is realized Break-make, as previously described, be not only simple in structure, and there is more preferable durability and reliability
Preferably, in addition to above-mentioned retrieval of sulfuric acid equipment line.
The desulphurization plant line of the application, as a result of above-mentioned retrieval of sulfuric acid equipment line, urged in desulphurization plant line During agent flushing work, when the tar content in sulfuric acid is higher, sulfuric acid is transported to the entering in liquid pool 146 of oil interceptor, to sulphur Tar in acid is filtered, and the sulfuric acid after filtering then is transported into pickling punching again continues the flushing work of catalyst, In this way, on the one hand due in sulfuric acid tar filtered so that catalyst can be rinsed cleaner, on the other hand, also may be used So that sulfuric acid can more frequently rinse catalyst, in this way, significantly improving sulfuric acid concentration, the recovery value of sulfuric acid is improved.
Above example only not limits technical scheme described herein to illustrate the application, although this explanation Book has been carried out being described in detail with reference to above-mentioned each embodiment to the application, but the application is not limited to above-mentioned specific implementation Mode, therefore any the application is modified or equivalent substitution;And the technical side of all spirit and scope for not departing from invention Case and its improvement, it all should cover among claims hereof scope.

Claims (10)

  1. A kind of 1. regenerative system for flue gas desulfurization device line, it is characterised in that:Including pickling tube and at least one first liquid Pump group part, first pump unit are also connected with desulfurizing tower water inlet pipe, and first pump unit will be each for independent Sulfuric acid in first pond body unit is pumped to the water inlet pipe.
  2. 2. regenerative system according to claim 1, it is characterised in that:First pump unit is at least two.
  3. 3. regenerative system according to claim 2, it is characterised in that:The regenerative system also includes back liquid supervisor, often First liquid back pipe of one desulfurizing tower all connects with described time liquid supervisor, and the pickling tube is responsible for by described time liquid and institute State the connection of the first liquid back pipe.
  4. 4. regenerative system according to claim 3, it is characterised in that:The pickling tube includes the first pond body, and described first At least one second partition is provided with pond body, the space in first pond body is divided at least two by the second partition For independent the first pond body unit for collecting sulfuric acid, the first time liquid with desulfurizing tower is both provided with each first pond body unit The first pipeline all connected is managed, valve is both provided with first pipeline.
  5. 5. regenerative system according to claim 4, it is characterised in that:The second partition is at least two, described second Space in first pond body is divided at least three first pond body units by dividing plate.
  6. 6. regenerative system according to claim 5, it is characterised in that:The first pond body upper end is additionally provided with for closing First shrouding of the first pond body upper end open, first pipeline are interior through first shrouding and the first pond body unit Portion space connects.
  7. 7. regenerative system according to claim 6, it is characterised in that:First shrouding corresponding to each first pond body unit On be both provided with second exhaust pipe, the first pond body unit is stretched into the second exhaust pipe lower end through first shrouding Interior, upper end is in open state.
  8. 8. regenerative system according to claim 7, it is characterised in that:The second exhaust pipe upper part is bent downwards, Make the upper end mouth down of the second exhaust pipe.
  9. 9. regenerative system according to claim 8, it is characterised in that:The bottom of each the first pond body unit is set It is equipped with blowoff valve.
  10. 10. regenerative system according to claim 9, it is characterised in that:Set on each described first pond body unit There is the liquid level gauge for detecting inside liquid level.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107126837A (en) * 2017-07-01 2017-09-05 成都国化环保科技有限公司 A kind of regenerative system for flue gas desulfurization device line

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107126837A (en) * 2017-07-01 2017-09-05 成都国化环保科技有限公司 A kind of regenerative system for flue gas desulfurization device line

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