A method of waste paper pulp-making is squeezed out using screw machine
Technical field
The present invention relates to waste paper recycling fields, and in particular to a method of waste paper pulp-making is squeezed out using screw machine.
Background technique
Waste paper is important renewable resource, and China's paper industry is faced with that there is lack of raw materials, energy shortage and pollution at present
Serious to wait three big main problems, the three big main problems that China's paper industry faces that are recycled as solving of waste paper have provided
Effect approach.Have relevant information introduction, recycles waste paper with using compared with Resources, can saving water 50%, it is energy saving
60% to 70%.If needing 4 m3 to 5 m3 logs to produce 1 ton of chemical pulp using wood raw material, and wastepaper as raw material is utilized, 1.25 tons
Waste paper can produce 1 ton of regenerated paper pulp, be not required to boiling chemicals or reduce chemicals dosage, so as to reduce atmosphere pollution
60% to 70%, bod reduces 40%, and suspended matter reduces 25% in sewage, and recycling waste paper can greatly reduce project throwing
Money reduces operating cost, increases economic efficiency and competitiveness.
In recent years, each state in the whole world all pays high attention to the recycling and utilization of waste paper resources, the rate of recovery and utilization rate of waste paper
Rapid growth year by year handles the methods and techniques of waste paper also in quick improve and perfect.Global waste paper utilization in 2005
Amount and utilization rate are respectively 164,900,000 tons and 54.4%, it is contemplated that will be respectively reached to waste paper utilization amounts and utilization rate in 2025
287800000 tons and 64.1%.The waste paper utilization amount in China is also rising rapidly.The dosage of China's secondary stock in 2012 is 22,200,000
Ton, accounts for the 47% of paper making pulps total amount, it is contemplated that arrives the year two thousand twenty, the specific gravity of secondary stock dosage will be more than 55%.
Although the technology that waste paper recycles is mature, still there are many problem needs in waste paper recycling
We go to solve.Due to the secondary reuse of fiber, the intensity of fiber, binding ability decline, water filtering performance are bad, all paper feeding machine
Operation and final product quality cause very big influence;Simultaneously in the removal process of waste paper, life is also given in the presence of impurity and sicker
It produces and product quality brings more trouble.
Patent CN201310504684.4 discloses a kind of using ClO2The pulping process of high wet strength waste paper is handled, although
From the pulpability for improving high wet strength waste paper to a certain degree, the utilization rate of fibre resources is improved, but not fundamentally
Solve the problems, such as that high wet strength waste paper fibre discongests that discomposing effect is poor, fiber recovery utilization rate is low, and ClO2It will increase discharge
The load of the Adsorbable organic halogens such as chloroform, tetrachloroethanes in sewage.
Patent CN201610070083.0 and CN201610070422.5 disclose a kind of wet strong waste paper chemical machinery respectively
Pulping process and wet strong waste paper recycle pulping system, solve in repulping process under neutral or basic conditions, big portion
The problem for dividing wet strengthening resin not oxidized, but pulping process is too complicated, equipment price is too expensive and inefficient, to fiber
Harmful disadvantage.
Summary of the invention
In order to overcome the deficiencies in the prior art, the present invention provides a kind of method that screw machine squeezes out waste paper pulp-making,
Its outstanding feature is can scale, closure, quality stability waste paper pulp.
The present invention is achieved by the following technical solutions:
A kind of method that screw machine squeezes out waste paper pulp-making, pulping process the following steps are included:
(1) waste paper, water, complex enzyme, chemical assistant are added in batch mixer, adjusting pH value is 5 ~ 10, is stirred in heating
It mixes, is heated to 45 ~ 65 DEG C, 10 ~ 20min of constant temperature obtains mixed slurry;
(2) slurry that step (1) obtains is pumped into screw machine feed opening, the setting rotation conveying at screw machine feeding inlet
The field of force, it is 50 ~ 70 DEG C that temperature, which is arranged, and revolving speed is 70 ~ 100rpm, is rotating transmission process for filler, ink and the fibre in slurry
Dimension separation, ink, gluing auxiliary agent are continuously isolated at the top of screw machine;Filler, metal impurities are recycled by screw rod motor spindle;
The rotary compression field of force is set in the discharge port of screw machine, setting temperature is 70 ~ 85 DEG C, and revolving speed is 50 ~ 80rpm, and paper pulp is carried out
Compression filtering, high temperature heat partition, obtain the secondary stock of high concentration;The rotation conveying is set as conveying screw thread, conveys screw thread
Surface is welded with tapered thorn, by waste paper further tearing in rotation transmission process;The rotary compression field of force is set as compressing
Screw thread plays compression filtering, high temperature heat partition paper pulp.
In above scheme, the screw machine is single screw extrusion machine, and screw slenderness ratio is greater than 120:1;From Screw Extrusion
Machine feeding inlet top end starts, and an air vents are at least arranged in interval at the position that draw ratio is 5 ~ 20:1;From screw rod
Extruder feeding inlet top end starts, and a liquid substance recovery port is arranged at the position that draw ratio is 40 ~ 80:1, to return
Receive ink, gluing auxiliary agent etc.;Since screw extruder feeding inlet lower end, it is arranged at the position that draw ratio is 50 ~ 100:1
One settling tank, the settling tank is for recycling filler, metal impurities.
In above scheme, the heating condensing unit that at least one group is arranged in series in the screw machine, the heating
The quantity of condensing unit is no more than the quantity of the air vents on Screw Extrusion unit.
In above scheme, the complex enzyme is the combination of cellulase, amylase, lipase, zytase, additive amount
It is the 0.05 ~ 1% of waste paper weight.
In above scheme, the complex enzyme forms by weight, cellulase 12 ~ 35%, amylase 10 ~ 25%, lipase
15 ~ 43%, zytase 20 ~ 44%.
In above scheme, the activity of the complex enzyme is, 1500 ~ 2000U/g of cellulase, amylase 3000 ~
4000U/g, 90000 ~ 100000U/g of lipase, 40000 ~ 60000U/g of zytase.
In above scheme, the chemical assistant is the composition of polyethers, surfactant, propylene glycol, oxidant, addition
Amount is the 0.03 ~ 2% of waste paper weight.
In above scheme, the chemical assistant forms by weight, polyethers 10 ~ 20%, surfactant 35 ~ 50%, 10-
20% propylene glycol, 10 ~ 25% oxidants.
In above scheme, the surfactant is neopelex, in calgon, sodium tripolyphosphate
One kind.
In above scheme, the oxidant includes hydrogen peroxide.
A kind of method that screw machine squeezes out waste paper pulp-making, by being sent into screw machine, spiral shell after impregnating waste paper and water, auxiliary agent etc.
The nose threads of bar machine are conveying screw thread, and flank is covered with tapered thorn, by waste paper further tearing in rotation transmission process,
In filler, ink and fiber separation, ink, gluing auxiliary agent etc. continuously isolated by the top of screw machine, and filler, metal etc. are miscellaneous
Matter is recycled by the settling tank that screw machine lower part is arranged;In screw machine rear end, screw thread is set as compression screw thread, with conveying paper pulp quilt
Compression filtering, high temperature heat partition obtain high concentration old paper stock, and pulp quality is high, whiteness is high.Its outstanding feature realizes rule
Modelling, closure, serialization, quality stability waste paper pulp.Wherein, ink, the gluing separated at the top of screw machine helps layering point
The precipitation and separations such as filler metal, impurity from the sedimentation of, bottom, all separation, the liquids recoveries being press-filtered out are reused, are substantially dropped
The generation of low waste water.
The beneficial effects of the present invention are:
(1) the further tearing dispersion of screw machine and high speed extrusion, weaken the mechanical force between waste paper fibre, weaken
Co-crosslinking effect, is conducive to impurity in wastepaper as raw material, oil between the self-crosslinking and gluing auxiliary agent and fiber of paper fiber itself
The removal of ink, gluing auxiliary agent, improves the efficiency of mechanical force pulping, reduces energy consumption.
(2) maceration for passing through complex enzyme and chemical assistant, so that ink and gluing auxiliary agent are easily isolated in waste paper
It removes, and plays the bleaching catharsis to secondary stock;
(3) present invention improves the technique of waste paper pulp-making, the recycling property energy of fiber in secondary stock is improved, fibre is improved
The recovery utilization rate of dimension not only increases the efficiency of regenerated papermaking slurry, improves secondary stock quality, and waste water is greatly reduced
It generates, obtains the high concentration paper pulp that mass concentration is 30 ~ 35%, solve resource and ring in puzzlement China's Paper Industry Development
Border problem.
Specific embodiment
In the following, the present invention will be further described in detail by way of specific embodiments, but this should not be interpreted as to the present invention
Range be only limitted to example below.Without departing from the idea of the above method of the present invention, according to ordinary skill
The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
(1) chemical assistant of 10kg waste paper, excessive water, the complex enzyme of 0.05kg, 0.1kg are added in batch mixer,
Adjusting pH value is 8, heats while stirring, is heated to 45 ~ 65 DEG C, constant temperature 10min obtains mixed slurry;
The complex enzyme forms by weight, cellulase 30%, amylase 2 5%, lipase 25%, zytase 20%.
The chemical assistant forms by weight, polyethers 15%, neopelex 50%, 10% propylene glycol, 25% oxygen
Agent.
(2) slurry that step (1) obtains being pumped into screw machine feed opening, the screw machine is single screw extrusion machine,
Screw slenderness ratio is 150:1;Since screw extruder feeding inlet top end, draw ratio be 10:1 position at interval at least
One air vents is set;Since screw extruder feeding inlet top end, it is arranged one at the position that draw ratio is 40:1
A liquid substance recovery port, to recycle ink, gluing auxiliary agent etc.;Since screw extruder feeding inlet lower end, in major diameter
Than a settling tank is arranged at the position for 80:1, the settling tank is for recycling filler, metal impurities.Enter in screw machine
The setting rotation conveying field of force at material mouth, setting temperature are 50 ~ 70 DEG C, and revolving speed 70rpm, the rotation conveying is set as conveying
Screw thread, conveying thread surface are welded with tapered thorn, are rotating transmission process for filler, ink and the fiber separation in slurry, oil
Ink, gluing auxiliary agent are continuously isolated at the top of screw machine;The rotary compression field of force is set in the discharge port of screw machine, temperature is set
It is 70 ~ 85 DEG C, revolving speed 50rpm, the rotary compression field of force is set as compression screw thread, plays compression filtering, high temperature heat partition
The effect of paper pulp obtains the secondary stock of high concentration.
The secondary stock that embodiment obtains, screenings is few, and deinking efficiency is significant, and whiteness reaches 82.5%ISO, and pulp density is
30%。
Embodiment 2
(1) chemical assistant of 10kg waste paper, excessive water, the complex enzyme of 0.02kg, 0.1kg are added in batch mixer,
Adjusting pH value is 10, heats while stirring, is heated to 45 ~ 65 DEG C, constant temperature 15min obtains mixed slurry;
The complex enzyme forms by weight, cellulase 20%, amylase 2 0%, lipase 30%, zytase 30%.
The chemical assistant forms by weight, polyethers 20%, calgon 35%, 20% propylene glycol, 25% hydrogen peroxide.
(2) slurry that step (1) obtains being pumped into screw machine feed opening, the screw machine is single screw extrusion machine,
Screw slenderness ratio is 130:1;Since screw extruder feeding inlet top end, draw ratio be 20:1 position at interval at least
One air vents is set;Since screw extruder feeding inlet top end, it is arranged one at the position that draw ratio is 80:1
A liquid substance recovery port, to recycle ink, gluing auxiliary agent etc.;Since screw extruder feeding inlet lower end, in major diameter
Than a settling tank is arranged at the position for 100:1, the settling tank is for recycling filler, metal impurities.In screw machine
The setting rotation conveying field of force at feeding inlet, setting temperature are 50 ~ 70 DEG C, and revolving speed 100rpm, the rotation conveying is set as
Screw thread is conveyed, conveying thread surface is welded with tapered thorn, divides filler, ink and the fiber in slurry in rotation transmission process
From ink, gluing auxiliary agent are continuously isolated at the top of screw machine;In the discharge port of screw machine, the rotary compression field of force is set, if
Setting temperature is 70 ~ 85 DEG C, revolving speed 80rpm, and the rotary compression field of force is set as compression screw thread, plays compression filtering, high temperature
The effect of heat partition paper pulp obtains the secondary stock of high concentration.
The secondary stock that embodiment obtains, screenings is few, and deinking efficiency is significant, and whiteness reaches 80.5%ISO, and pulp density is
35%。
Embodiment 3
(1) chemical assistant of 10kg waste paper, excessive water, the complex enzyme of 0.03kg, 0.15kg are added in batch mixer,
Adjusting pH value is 7, heats while stirring, is heated to 45 ~ 65 DEG C, constant temperature 20min obtains mixed slurry;
The complex enzyme forms by weight, cellulase 35%, amylase 10%, lipase 25%, zytase 30%.
The chemical assistant forms by weight, polyethers 20%, sodium tripolyphosphate 50%, 10% propylene glycol, 15% hydrogen peroxide.
(2) slurry that step (1) obtains being pumped into screw machine feed opening, the screw machine is single screw extrusion machine,
Screw slenderness ratio is 135:1;Since screw extruder feeding inlet top end, draw ratio be 20:1 position at interval at least
One air vents is set;Since screw extruder feeding inlet top end, it is arranged one at the position that draw ratio is 50:1
A liquid substance recovery port, to recycle ink, gluing auxiliary agent etc.;Since screw extruder feeding inlet lower end, in major diameter
Than a settling tank is arranged at the position for 100:1, the settling tank is for recycling filler, metal impurities.In screw machine
The setting rotation conveying field of force at feeding inlet, setting temperature are 50 ~ 70 DEG C, and revolving speed 80rpm, the rotation conveying is set as defeated
Send screw thread, conveying thread surface is welded with tapered thorn, in rotation transmission process by filler, ink and the fiber separation in slurry,
Ink, gluing auxiliary agent are continuously isolated at the top of screw machine;In the discharge port of screw machine, the rotary compression field of force, setting temperature are set
Degree is 70 ~ 85 DEG C, revolving speed 80rpm, and the rotary compression field of force is set as compression screw thread, plays compression filtering, high warm point
The effect for dissipating paper pulp, obtains the secondary stock of high concentration.
The secondary stock that embodiment obtains, screenings is few, and deinking efficiency is significant, and whiteness reaches 82%ISO, pulp density 30%.
Embodiment 4
(1) chemical assistant of 10kg waste paper, excessive water, the complex enzyme of 0.05kg, 0.1kg are added in batch mixer,
Adjusting pH value is 10, heats while stirring, is heated to 45 ~ 65 DEG C, constant temperature 20min obtains mixed slurry;
The complex enzyme forms by weight, cellulase 15%, amylase 2 0%, lipase 25%, zytase 40%.
The chemical assistant forms by weight, polyethers 20%, calgon 40%, 10% propylene glycol, 30% hydrogen peroxide.
(2) slurry that step (1) obtains being pumped into screw machine feed opening, the screw machine is single screw extrusion machine,
Screw slenderness ratio is 140:1;Since screw extruder feeding inlet top end, draw ratio be 15:1 position at interval at least
One air vents is set;Since screw extruder feeding inlet top end, it is arranged one at the position that draw ratio is 60:1
A liquid substance recovery port, to recycle ink, gluing auxiliary agent etc.;Since screw extruder feeding inlet lower end, in major diameter
Than a settling tank is arranged at the position for 50 ~ 100:1, the settling tank is for recycling filler, metal impurities.In screw rod
The setting rotation conveying field of force at machine feeding inlet, setting temperature are 50 ~ 70 DEG C, and revolving speed 70rpm, the rotation conveying is set as
Screw thread is conveyed, conveying thread surface welds tapered thorn, in rotation transmission process by filler, ink and the fiber separation in slurry,
Ink, gluing auxiliary agent are continuously isolated at the top of screw machine;In the discharge port of screw machine, the rotary compression field of force, setting temperature are set
Degree is 70 ~ 85 DEG C, revolving speed 50rpm, and the rotary compression field of force is set as compression screw thread, plays compression filtering, high warm point
The effect for dissipating paper pulp, obtains the secondary stock of high concentration.
The secondary stock that embodiment obtains, screenings is few, and deinking efficiency is significant, and whiteness reaches 83%ISO, pulp density 35%.
Embodiment 5
(1) chemical assistant of 10kg waste paper, excessive water, the complex enzyme of 0.05kg, 0.1kg are added in batch mixer,
Adjusting pH value is 5, heats while stirring, is heated to 45 ~ 65 DEG C, constant temperature 20min obtains mixed slurry;
The complex enzyme forms by weight, cellulase 35%, amylase 2 5%, lipase 15%, zytase 25%.
The chemical assistant forms by weight, polyethers 20%, surfactant 35%, 20% propylene glycol, 25% hydrogen peroxide.
(2) slurry that step (1) obtains being pumped into screw machine feed opening, the screw machine is single screw extrusion machine,
Screw slenderness ratio is 160:1;Since screw extruder feeding inlet top end, draw ratio be 20:1 position at interval at least
One air vents is set;Since screw extruder feeding inlet top end, it is arranged one at the position that draw ratio is 80:1
A liquid substance recovery port, to recycle ink, gluing auxiliary agent etc.;Since screw extruder feeding inlet lower end, in major diameter
Than a settling tank is arranged at the position for 100:1, the settling tank is for recycling filler, metal impurities.In screw machine
The setting rotation conveying field of force at feeding inlet, setting temperature are 50 ~ 70 DEG C, and revolving speed 100rpm, the rotation conveying is set as
Screw thread is conveyed, conveying thread surface is welded with tapered thorn, divides filler, ink and the fiber in slurry in rotation transmission process
From ink, gluing auxiliary agent are continuously isolated at the top of screw machine;In the discharge port of screw machine, the rotary compression field of force is set, if
Setting temperature is 70 ~ 85 DEG C, revolving speed 50rpm, and the rotary compression field of force is set as compression screw thread, plays compression filtering, high temperature
The effect of heat partition paper pulp obtains the secondary stock of high concentration.
The secondary stock that embodiment obtains, screenings is few, and deinking efficiency is significant, and whiteness reaches 84.2%ISO, and pulp density is
30%。