CN107237165A - A kind of silane coating polyolefin leatheroid of damage resistant - Google Patents
A kind of silane coating polyolefin leatheroid of damage resistant Download PDFInfo
- Publication number
- CN107237165A CN107237165A CN201610175950.7A CN201610175950A CN107237165A CN 107237165 A CN107237165 A CN 107237165A CN 201610175950 A CN201610175950 A CN 201610175950A CN 107237165 A CN107237165 A CN 107237165A
- Authority
- CN
- China
- Prior art keywords
- silane
- silane coating
- damage resistant
- leatheroid
- polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
- D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Paints Or Removers (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Abstract
It is to cover with paint, lacquer, colour wash, etc. one layer of silane coating material in polyolefine substrate surfaces and solidify, silane coating material is to blend the silane that one or more are not pre-condensed or part is pre-condensed with reactant the present invention relates to a kind of silane of damage resistant coating polyolefin leatheroid.The molecular weight of silane is more than 200.Silane has in organic side chain suitably forms hydrogen bridge bond polarity group.After polyolefin leatheroid surface is protected through silane coating material, make polyolefin leatheroid that there is more preferable scratch-resistant Flaw characterization, improve the use quality of polyolefin leatheroid.
Description
Technical field
The invention belongs to polyolefin leatheroid technical field, and in particular to a kind of polyolefin leatheroid of the silane coating of damage resistant.
Background technology
Artificial leather is a kind of outward appearance, feel like leather and can replace its plastic products that use.Generally using fabric as base, coating synthetic resin and the addition of various plastics are made.Last century the eighties, expensive fur clothing cladding common people can not consume, and in response to the market demand, the artificial leather of counterfeit leather once came into vogue, and be widely used in clothing, system bag.
The silane coating of silicones production is known, by constantly development, it should which silane coating can improve the use quality of artificial leather as the protective layer of artificial leather.
The content of the invention
Polyolefin leatheroid is coated with it is an object of the invention to provide a kind of silane of damage resistant.
The present invention the used technical scheme that solves the above problems is：A kind of silane of damage resistant is coated with polyolefin leatheroid, is to cover with paint, lacquer, colour wash, etc. one layer of silane coating material in polyolefine substrate surfaces and solidify, the silane coating material is to blend the silane that one or more are not pre-condensed or part is pre-condensed with reactant.
According to the present invention, the molecular weight of the silane is more than 200, more preferably greater than 300, especially greater than 500, and most preferably greater than 1000.
In scope of the invention, the silane has in organic side chain suitably forms hydrogen bridge bond polarity group.
Relatively rational set is, before the solidification, and organic cross-linking reaction is carried out by the silane of the silane and homology or non-homology or with organic monomer, oligomer or polymer.
The improvement of the present invention is that solvent is added in silane coating material, including alcohol, acetate, ether or reaction diluent.
Further, to wet-chemical silane coating coating material on polyolefin-based bottom, including spraying, dipping, flow coat, roller coat, smearing, extrusion, centrifugal coating, blade coating or vacuum evaporation.
Compared with prior art, the advantage of the invention is that：The polyolefin leatheroid being coated with there is provided a kind of silane, after the silane coating material protection by the present invention, makes polyolefin preferably damage resistant, improves the use quality of polyolefin leatheroid.
Embodiment
The present invention is described in further detail with reference to embodiments.
Embodiment 1
By 11.8g hexylene glycols and 49.5g isocyanatopropyl triethoxysilanes（ICTES）It is heated with stirring to 50 DEG C and is mixed into 0.1g dibutyl tin laurates disastrously.Further stirred 30 minutes at 50 DEG C, room temperature is cooled to afterwards.
The above-mentioned material dissolutions of 5g in 10g1- methoxy-2-propanols and are blended into 0.2g aluminium acetylacetonates.
The silane coating material obtained is covered with paint, lacquer, colour wash, etc. by the way of flow coat and arrives polyolefin leatheroid surface, is solidified 50 minutes in draft furnace at 120 DEG C afterwards.
Polyolefin leatheroid obtained by the present embodiment has good scratch-resistant Flaw characterization.
Embodiment 2
By 30.0gDesmophen1145 and 4.3g isocyanatopropyl triethoxysilanes（ICTES）It is heated with stirring to 50 DEG C and is mixed into 0.15g dibutyl tin laurates disastrously.Further stirred 60 minutes at 50 DEG C, room temperature is cooled to afterwards.
The above-mentioned material dissolutions of 10g in 8g1- methoxy-2-propanols and are blended into 0.1g aluminium acetylacetonates.
The silane coating material obtained is covered with paint, lacquer, colour wash, etc. by the way of spraying and arrives polyolefin leatheroid surface, is solidified 60 minutes in draft furnace at 150 DEG C afterwards.
Polyolefin leatheroid obtained by the present embodiment has good scratch-resistant Flaw characterization.
Embodiment 3
22.1g aminopropyltriethoxywerene werenes and 27.8g glycidoxypropyls triethoxysilane are stirred and put at such a temperature at 45 DEG C and is stayed 45 minutes.
10g reactant mixtures are dissolved in 12g isopropanols and 0.3g acetylacetone,2,4-pentanediones are blended into.
Flow coat is to polyolefin leatheroid surface again, by coating in solidifying 20 minutes in draft furnace at 120 DEG C.
Polyolefin leatheroid obtained by the present embodiment has good scratch-resistant Flaw characterization.
Claims (6)
1. a kind of silane coating polyolefin leatheroid of damage resistant, it is characterised in that：It is to cover with paint, lacquer, colour wash, etc. one layer of silane coating material in polyolefine substrate surfaces and solidify, the silane coating material is to blend the silane that one or more are not pre-condensed or part is pre-condensed with reactant.
2. the silane coating polyolefin leatheroid of damage resistant according to claim 1, it is characterised in that：The molecular weight of the silane is more than 200.
3. the silane coating polyolefin leatheroid of damage resistant according to claim 2, it is characterised in that：The silane has in organic side chain suitably forms hydrogen bridge bond polarity group.
4. the silane coating polyolefin leatheroid of damage resistant according to claim 1, it is characterised in that：Before the solidification, organic cross-linking reaction is carried out by the silane of the silane and homology or non-homology or with organic monomer, oligomer or polymer.
5. the silane coating polyolefin leatheroid of damage resistant according to claim 1, it is characterised in that：Solvent, including alcohol, acetate, ether or reaction diluent are added in silane coating material.
6. the silane coating polyolefin leatheroid of damage resistant according to claim 1, it is characterised in that：Wet-chemical silane coating coating material on to polyolefin-based bottom, including spraying, dipping, flow coat, roller coat, smearing, extrusion, centrifugal coating, blade coating or vacuum evaporation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610175950.7A CN107237165A (en) | 2016-03-28 | 2016-03-28 | A kind of silane coating polyolefin leatheroid of damage resistant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610175950.7A CN107237165A (en) | 2016-03-28 | 2016-03-28 | A kind of silane coating polyolefin leatheroid of damage resistant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107237165A true CN107237165A (en) | 2017-10-10 |
Family
ID=59982610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610175950.7A Pending CN107237165A (en) | 2016-03-28 | 2016-03-28 | A kind of silane coating polyolefin leatheroid of damage resistant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107237165A (en) |
-
2016
- 2016-03-28 CN CN201610175950.7A patent/CN107237165A/en active Pending
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171010 |