CN107268286A - A kind of silane coating semi-aromatic polyamide artificial leather of anti-radiation protection - Google Patents
A kind of silane coating semi-aromatic polyamide artificial leather of anti-radiation protection Download PDFInfo
- Publication number
- CN107268286A CN107268286A CN201610205690.3A CN201610205690A CN107268286A CN 107268286 A CN107268286 A CN 107268286A CN 201610205690 A CN201610205690 A CN 201610205690A CN 107268286 A CN107268286 A CN 107268286A
- Authority
- CN
- China
- Prior art keywords
- silane
- aromatic polyamide
- semi
- artificial leather
- radiation protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/125—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
- D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/065—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/066—Silicon polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/04—Properties of the materials having electrical or magnetic properties
- D06N2209/048—Electromagnetic interference shielding
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Abstract
Semi-aromatic polyamide artificial leather is coated with the present invention relates to a kind of silane of anti-radiation protection; it is to cover with paint, lacquer, colour wash, etc. one layer of silane coating material in semi-aromatic polyamide substrate surface and solidify, silane coating material is to blend the silane that one or more are not pre-condensed or part is pre-condensed with reactant.The molecular weight of silane is more than 200.Silane has in organic side chain suitably forms hydrogen bridge bond polarity group.After semi-aromatic polyamide artificial leather surface is protected through silane coating material, make semi-aromatic polyamide artificial leather that there is more preferable anti-radiation protection characteristic, improve the use quality of semi-aromatic polyamide artificial leather.
Description
Technical field
The invention belongs to semi-aromatic polyamide technical field of artificial leather, and in particular to a kind of semi-aromatic polyamide artificial leather of the silane coating of anti-radiation protection.
Background technology
Artificial leather is a kind of outward appearance, feel like leather and can replace its plastic products that use.Generally using fabric as base, coating synthetic resin and the addition of various plastics are made.Last century the eighties, expensive fur clothing cladding common people can not consume, and in response to the market demand, the artificial leather of counterfeit leather once came into vogue, and be widely used in clothing, system bag.
The silane coating of silicones production is known, by constantly development, it should which silane coating can improve the use quality of artificial leather as the protective layer of artificial leather.
The content of the invention
Semi-aromatic polyamide artificial leather is coated with it is an object of the invention to provide a kind of silane of anti-radiation protection.
The present invention the used technical scheme that solves the above problems is：A kind of silane coating semi-aromatic polyamide artificial leather of anti-radiation protection; it is to cover with paint, lacquer, colour wash, etc. one layer of silane coating material in semi-aromatic polyamide substrate surface and solidify; the silane coating material is that the silane that one or more are not pre-condensed or part is pre-condensed is blended with reactant, and zinc oxide is included in silane coating material.
According to the present invention, the molecular weight of the silane is more than 200, more preferably greater than 300, especially greater than 500, and most preferably greater than 1000.
In scope of the invention, the silane has in organic side chain suitably forms hydrogen bridge bond polarity group.
Relatively rational set is, before the solidification, and organic cross-linking reaction is carried out by the silane of the silane and homology or non-homology or with organic monomer, oligomer or polymer.
The improvement of the present invention is that solvent is added in silane coating material, including alcohol, acetate, ether or reaction diluent.
Further, to wet-chemical silane coating coating material in semi-aromatic polyamide substrate, including spraying, dipping, flow coat, roller coat, smearing, extrusion, centrifugal coating, blade coating or vacuum evaporation.
Compared with prior art, the advantage of the invention is that：The semi-aromatic polyamide artificial leather being coated with there is provided a kind of silane, after the silane coating material protection by the present invention, makes semi-aromatic polyamide have preferably anti-radiation protection characteristic, improves the use quality of semi-aromatic polyamide artificial leather.
Embodiment
The present invention is described in further detail with reference to embodiments.
Embodiment 1
By 11.8g hexylene glycols and 49.5g isocyanatopropyl triethoxysilanes（ICTES）It is heated with stirring to 50 DEG C and is mixed into 0.1g dibutyl tin laurates disastrously.Further stirred 30 minutes at 50 DEG C, room temperature is cooled to afterwards.
The above-mentioned material dissolutions of 5g in 10g1- methoxy-2-propanols and are blended into 0.2g aluminium acetylacetonates and 0.3g zinc oxide.
The silane coating material obtained is covered with paint, lacquer, colour wash, etc. by the way of flow coat and arrives semi-aromatic polyamide artificial leather surface, is solidified 50 minutes in draft furnace at 120 DEG C afterwards.
Semi-aromatic polyamide artificial leather obtained by the present embodiment has good anti-radiation protection characteristic.
Embodiment 2
By 30.0gDesmophen1145 and 4.3g isocyanatopropyl triethoxysilanes（ICTES）It is heated with stirring to 50 DEG C and is mixed into 0.15g dibutyl tin laurates disastrously.Further stirred 60 minutes at 50 DEG C, room temperature is cooled to afterwards.
The above-mentioned material dissolutions of 10g in 8g1- methoxy-2-propanols and are blended into 0.1g aluminium acetylacetonates and 0.2g zinc oxide.
The silane coating material obtained is covered with paint, lacquer, colour wash, etc. by the way of spraying and arrives semi-aromatic polyamide artificial leather surface, is solidified 60 minutes in draft furnace at 150 DEG C afterwards.
Semi-aromatic polyamide artificial leather obtained by the present embodiment has good anti-radiation protection characteristic.
Embodiment 3
22.1g aminopropyltriethoxywerene werenes and 27.8g glycidoxypropyls triethoxysilane are stirred and put at such a temperature at 45 DEG C and is stayed 45 minutes.
10g reactant mixtures are dissolved in 12g isopropanols and 0.3g acetylacetone,2,4-pentanediones and 0.2g zinc oxide is blended into.
Flow coat is to semi-aromatic polyamide artificial leather surface again, by coating in solidifying 20 minutes in draft furnace at 120 DEG C.
Semi-aromatic polyamide artificial leather obtained by the present embodiment has good anti-radiation protection characteristic.
Claims (6)
1. a kind of silane coating semi-aromatic polyamide artificial leather of anti-radiation protection, it is characterised in that：It is to cover with paint, lacquer, colour wash, etc. one layer of silane coating material in semi-aromatic polyamide substrate surface and solidify, the silane coating material is that the silane that one or more are not pre-condensed or part is pre-condensed is blended with reactant, and zinc oxide is included in silane coating material.
2. the silane coating semi-aromatic polyamide artificial leather of anti-radiation protection according to claim 1, it is characterised in that：The molecular weight of the silane is more than 200.
3. the silane coating semi-aromatic polyamide artificial leather of anti-radiation protection according to claim 2, it is characterised in that：The silane has in organic side chain suitably forms hydrogen bridge bond polarity group.
4. the silane coating semi-aromatic polyamide artificial leather of anti-radiation protection according to claim 1, it is characterised in that：Before the solidification, organic cross-linking reaction is carried out by the silane of the silane and homology or non-homology or with organic monomer, oligomer or polymer.
5. the silane coating semi-aromatic polyamide artificial leather of anti-radiation protection according to claim 1, it is characterised in that：Solvent, including alcohol, acetate, ether or reaction diluent are added in silane coating material.
6. the silane coating semi-aromatic polyamide artificial leather of anti-radiation protection according to claim 1, it is characterised in that：Wet-chemical silane coating coating material on to semi-aromatic polyamide substrate, including spraying, dipping, flow coat, roller coat, smearing, extrusion, centrifugal coating, blade coating or vacuum evaporation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610205690.3A CN107268286A (en) | 2016-04-06 | 2016-04-06 | A kind of silane coating semi-aromatic polyamide artificial leather of anti-radiation protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610205690.3A CN107268286A (en) | 2016-04-06 | 2016-04-06 | A kind of silane coating semi-aromatic polyamide artificial leather of anti-radiation protection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107268286A true CN107268286A (en) | 2017-10-20 |
Family
ID=60051679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610205690.3A Pending CN107268286A (en) | 2016-04-06 | 2016-04-06 | A kind of silane coating semi-aromatic polyamide artificial leather of anti-radiation protection |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107268286A (en) |
-
2016
- 2016-04-06 CN CN201610205690.3A patent/CN107268286A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171020 |