CN107236375A - It is a kind of effectively to purify emulsion paint of air and preparation method thereof - Google Patents
It is a kind of effectively to purify emulsion paint of air and preparation method thereof Download PDFInfo
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- CN107236375A CN107236375A CN201710467732.5A CN201710467732A CN107236375A CN 107236375 A CN107236375 A CN 107236375A CN 201710467732 A CN201710467732 A CN 201710467732A CN 107236375 A CN107236375 A CN 107236375A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
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- C09D125/14—Copolymers of styrene with unsaturated esters
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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Abstract
The invention discloses a kind of emulsion paint that can effectively purify air and preparation method thereof, it is related to emulsion paint technical field, includes the raw material of following part meter：36 ~ 38 parts of 65 ~ 68 parts of styrene-acrylic emulsion, modified 45 ~ 55 parts of bamboo pulp fiber, 32 ~ 34 parts of particle of enhancing, 27 ~ 29 parts of citronella oil, 24 ~ 26 parts of castor oil acid, 22 ~ 23 parts of plant dehydration filament, 19 ~ 20 parts of auxiliary agent and water.Paint film appearance of the present invention is smooth, good without lump, good hand touch and glossiness, can effectively remove formaldehyde, other harmful organic volatiles.
Description
Technical field
The present invention relates to emulsion paint technical field, and in particular to a kind of effectively to purify emulsion paint and its preparation of air
Method.
Background technology
Formaldehyde is a kind of important Organic Ingredients, is mainly used in artificial synthesized adhesive, phenolic resin processed, Lauxite,
Synthetic fibers (such as synthesizing vinylon-polyvinyl formal), leather industry, medicine, dyestuff.Various artificial boards
Due to having used pollopas binder in (particieboard, fiberboard, glued board etc.), thus contain formaldehyde.New-type family
The making of tool, metope, the decoration laying on ground, will use adhesive.The place of every a large amount of use adhesives, always has first
Aldehyde discharges.A small amount of formaldehyde is often sucked, slow poisoning can be caused, serious causes leukaemia and vegetative nervous disorder etc..
At present, absorption method is often taken to remove formaldehyde and other harmful organic volatiles.The general principle of absorption method is,
Some are added in coating to contain more pore, have the natural or synthetic material of suction-operated, by formaldehyde absorbing in pore.
This method the disadvantage is that, infringement coating it is physical.Because reaching abundant absorption, it is necessary that the pore of porous material
Exposed to coating surface, such film can not be excessively fine and close, therefore its scrub performance is accordingly affected.Absorption method it is another
It is individual the disadvantage is that, during relatively low aerial content of formaldehyde, the formaldehyde of absorption can separate out, or gone out by other gas displacement
Come, the adsorption effect not reached, and the adsorption capacity of sorbing material is very limited, it is easy to reach saturation.Therefore it provides one
Kind itself without formaldehyde, other harmful volatile organic contents it is relatively low and can effectively remove formaldehyde, other are harmful organic
The emulsion paint of volatile matter, with realistic meaning.
The content of the invention
It is an object of the invention to provide a kind of emulsion paint that can effectively purify air and preparation method thereof, paint film appearance is put down
It is whole, good without lump, good hand touch and glossiness, it can effectively remove formaldehyde, other harmful organic volatiles.
The invention provides following technical scheme：It is a kind of effectively to purify the emulsion paint of air, including following part meter
Raw material：65 ~ 68 parts of styrene-acrylic emulsion, modified 45 ~ 55 parts of bamboo pulp fiber, 32 ~ 34 parts of particle of enhancing, 27 ~ 29 parts of citronella oil, castor-oil plant
36 ~ 38 parts of 24 ~ 26 parts of oleic acid, 22 ~ 23 parts of plant dehydration filament, 19 ~ 20 parts of auxiliary agent and water；
The auxiliary agent includes the raw material that following part is counted：7 ~ 8 parts of foaming agent, 5 ~ 7 parts of thickener, 3 ~ 5 parts of water-loss reducer, plasticizer 2 ~ 3
0.2 ~ 0.4 part of part, 1 ~ 2 part of antioxidant, 0.8 ~ 1.2 part of mould inhibitor and fire retardant；
The foaming agent includes the raw material that following part is counted：2 ~ 3 parts of glue class, 1 ~ 2 part of lauryl sodium sulfate, polyethers emulsion 0.8 ~
1.2 parts, 0.6 ~ 0.7 part of animal protein, 0.5 ~ 0.6 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.3 ~ 0.5 part of rosin, silicon ash 0.2
1 ~ 2 part of ~ 0.3 part, 0.1 ~ 0.2 part of silicones, 0.1 ~ 0.2 part of caustic soda and water.
Wherein, the modified bamboo pulp fiber includes the raw material that following part is counted：20 ~ 25 parts of bamboo pulp fiber, chitosan 15 ~ 17
10 ~ 12 parts of part, 12 ~ 13 parts of sericin, 12 ~ 13 parts of hydrogenperoxide steam generator and sodium periodate solution.
Wherein, the preparation method of the modified bamboo pulp fiber is：Bamboo pulp fiber is weighed to add in sodium periodate solution, with
200~300r/min rotating speed stirs 10~20min, then adds acid solution and adjusts to neutrality, sequentially adds chitosan, silk gum
Albumen and hydrogenperoxide steam generator, ultrasonically treated 1 ~ 2h, are filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo is obtained after drying
Pulp fibres.
Wherein, the thickener is algin or Arabic gum, and the water-loss reducer is carboxymethyl cellulose or hydroxyl second
Base cellulose, the plasticizer is in dibutyl phthalate, dioctyl phthalate and diisononyl phthalate
One or more, the antioxidant is the mixing of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine
Thing, the mould inhibitor is ZPT, and the fire retardant is magnesium hydroxide.
Wherein, the enhancing particle includes the raw material that following part is counted：10 ~ 12 parts of activated carbon, 7 ~ 8 parts of nano titanium oxide and
5 ~ 7 parts of nano zine oxide.
Wherein, the preparation method of the nano zine oxide is：Added into 200mL 0.1mol/L zinc nitrate solutions
100mL 0.4mol/L urea liquid, both are well mixed, then 4 ~ 5h of isothermal reaction at 60 ~ 70 DEG C, question response knot
Shu Hou, the product that reaction is obtained is filtered, and collects filter residue, and filter residue is first dried into 3 ~ 4h at 60 ~ 80 DEG C, then at 300 ~ 400 DEG C
Under the conditions of calcine 1 ~ 2h, obtain the nano zine oxide.
Wherein, the plant dehydration filament is Chinese herbal medicine dehydrated fiber silk.
The present invention provides a kind of preparation method for the emulsion paint that can effectively purify air, comprises the following steps：
（1）, prepare foaming agent
Glue class is weighed according to proportioning and animal protein is well mixed, is positioned in heating container, under 70~80 DEG C of temperature conditionss,
1~2h of water-bath, products therefrom is cooled down, filtered, material A is obtained；Lauryl sodium sulfate, polyethers breast are weighed according to proportioning
Liquid and water, are heated to after 90 ~ 100 DEG C adding afore-mentioned materials A, stir 10 ~ 20min with 100 ~ 200r/min rotating speed, obtain thing
Expect B；
Sodium sulfate of polyethenoxy ether of fatty alcohol, rosin, silicon ash, silicones and caustic soda are weighed according to proportioning, afore-mentioned materials B is added to
In, 1 ~ 2h is stirred with 250 ~ 300r/min rotating speed, the foaming agent is obtained, it is standby；
（2）, mashing
Surplus stock is weighed according to proportioning, is put into mixer, step is then added（1）Obtained foaming agent, with 200 ~ 300r/
Min rotating speed stirs 25 ~ 35min, is uniformly dispersed and obtains slurry；
（3）, be sanded
Scattered slurry is sanded, rotating speed is 800 ~ 1200r/min, the sand milling time is 30 ~ 60min；Water is used after sand milling
Slurry is cleaned, obtains described can effectively purifying the emulsion paint of air.
Beneficial effects of the present invention：Paint film appearance is smooth, good without lump, good hand touch and glossiness, can effectively remove first
Aldehyde, other harmful organic volatiles, it is specific as follows：
（1）, add activated carbon, nano titanium oxide and nano zine oxide in the feed in the present invention, three's synergy makes this
The emulsion paint of invention effectively can adsorb and decompose the harmful substances such as formaldehyde, benzene, ammonia, sulfide free in air, hence it is evident that
Air peculiar smell is reduced, indoor living environment can be improved with adjusting air humidity；Wherein, nano titanium oxide, its special point
Together with minor structure can also be closely fitted to each raw material, and the space filled up between each raw material so that emulsion paint is wear-resisting
It is smooth with top layer, reach toughened and reinforced effect；
（2）, add modified bamboo pulp fiber in the present invention, it is molten using chitosan, sericin, hydrogenperoxide steam generator and sodium metaperiodate
Liquid is modified to bamboo pulp fiber so that the surface of wall after emulsion paint coating is produced without thalline, antibacterial bacteriostatic, in addition, also carrying
High acoustical absorption heat preserving and waterproof and dampproof effect；Plant dehydration filament in the feed, after emulsion paint is used on metope, wall
Face face has the thread random stripe of filament generation, visually has a sense of hierarchy very much, improves aesthetics；
（3）, the present invention add foaming agent in the feed, using organic and inorganic composite foamed, the foam of generation is tiny, amount is big and
It is evenly distributed, improves foaming effect, by adding animal albuminoid and glue class etc., makes the foam of generation after expanding can be in bubble
Film forming on body wall, so that the separate closing of each foam, improves intensity and resist and open while improving heat-insulating property
Fragility energy；
（4）, the present invention emulsion paint by mashing, the technique such as be sanded and complete, preparation method is simple, pollution-free, VOC emission pole
It is low, with preferable abrasion resistance and stain resistance, it is used for a long time, dry linting phenomenon, good decorating effect, construction party will not be produced
Just；With stronger adhesive force, stabilization is combined with wall, the phenomenons such as lacquer painting peeling, explosion are not likely to produce.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
It is a kind of effectively to purify the emulsion paint of air, include the raw material of following part meter：65 parts of styrene-acrylic emulsion, modified bamboo pulp fiber
45 parts, 32 parts of particle of enhancing, 27 parts of citronella oil, 24 parts of castor oil acid, 22 parts of plant dehydration filament, 19 parts of auxiliary agent and water 36
Part；
The auxiliary agent includes the raw material that following part is counted：7 parts of foaming agent, 5 parts of thickener, 3 parts of water-loss reducer, 2 parts of plasticizer, antioxidant
0.2 part of 1 part, 0.8 part of mould inhibitor and fire retardant；
The foaming agent includes the raw material that following part is counted：2 parts of glue class, 1 part of lauryl sodium sulfate, 0.8 part of polyethers emulsion, animal
0.6 part of albumen, 0.5 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.3 part of rosin, 0.2 part of silicon ash, 0.1 part of silicones, caustic soda 0.1
1 part of part and water.
Wherein,
The modified bamboo pulp fiber includes the raw material that following part is counted：20 parts of bamboo pulp fiber, 15 parts of chitosan, 12 parts of sericin,
10 parts of 12 parts of hydrogenperoxide steam generator and sodium periodate solution.
The preparation method of the modified bamboo pulp fiber is：Weigh bamboo pulp fiber to add in sodium periodate solution, with 200r/
Min rotating speed stirring 10min, then adds acid solution and adjusts to neutrality, sequentially add chitosan, sericin and hydrogen peroxide
Solution, ultrasonically treated 1h, is filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo pulp fiber is obtained after drying.
The thickener is algin, and the water-loss reducer is carboxymethyl cellulose, and the plasticizer is phthalic acid two
Butyl ester, the antioxidant is the mixture of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine, described anti-
Mould dose is ZPT, and the fire retardant is magnesium hydroxide.
The enhancing particle includes the raw material that following part is counted：10 parts of activated carbon, 7 parts of nano titanium oxide and nano zine oxide
5 parts.
The preparation method of the nano zine oxide is：Add 100mL's into 200mL 0.1mol/L zinc nitrate solutions
0.4mol/L urea liquid, both are well mixed, then the isothermal reaction 4h at 60 DEG C, after question response terminates, will be reacted
Obtained product filtering, collects filter residue, and filter residue is first dried into 3h at 60 DEG C, then calcines 1h under the conditions of 300 DEG C, obtains described
Nano zine oxide.
The plant dehydration filament is Chinese herbal medicine dehydrated fiber silk.
A kind of preparation method for the emulsion paint that can effectively purify air is provided in the present embodiment, comprised the following steps：
（1）, prepare foaming agent
Glue class is weighed according to proportioning and animal protein is well mixed, is positioned in heating container, under 70 DEG C of temperature conditionss, water-bath
1h is reacted, products therefrom is cooled down, filtered, material A is obtained；Lauryl sodium sulfate, polyethers emulsion and water are weighed according to proportioning,
It is heated to after 90 DEG C adding afore-mentioned materials A, 10min is stirred with 100r/min rotating speed, material B is obtained；
Sodium sulfate of polyethenoxy ether of fatty alcohol, rosin, silicon ash, silicones and caustic soda are weighed according to proportioning, afore-mentioned materials B is added to
In, 1h is stirred with 250r/min rotating speed, the foaming agent is obtained, it is standby；
（2）, mashing
Surplus stock is weighed according to proportioning, is put into mixer, step is then added（1）Obtained foaming agent, with 200r/min
Rotating speed stirring 25min, be uniformly dispersed and obtain slurry；
（3）, be sanded
Scattered slurry is sanded, rotating speed is 800r/min, the sand milling time is 3min；Slurry is cleaned with water after sand milling,
Obtain described can effectively purifying the emulsion paint of air.
Embodiment 2
It is a kind of effectively to purify the emulsion paint of air, include the raw material of following part meter：68 parts of styrene-acrylic emulsion, modified bamboo pulp fiber
55 parts, 34 parts of particle of enhancing, 29 parts of citronella oil, 26 parts of castor oil acid, 23 parts of plant dehydration filament, 20 parts of auxiliary agent and water 38
Part；
The auxiliary agent includes the raw material that following part is counted：8 parts of foaming agent, 7 parts of thickener, 5 parts of water-loss reducer, 3 parts of plasticizer, antioxidant
0.4 part of 2 parts, 1.2 parts of mould inhibitor and fire retardant；
The foaming agent includes the raw material that following part is counted：3 parts of glue class, 2 parts of lauryl sodium sulfate, 1.2 parts of polyethers emulsion, animal
0.7 part of albumen, 0.6 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.5 part of rosin, 0.3 part of silicon ash, 0.2 part of silicones, caustic soda 0.2
2 parts of part and water.
Wherein,
The modified bamboo pulp fiber includes the raw material that following part is counted：25 parts of bamboo pulp fiber, 17 parts of chitosan, 13 parts of sericin,
12 parts of 13 parts of hydrogenperoxide steam generator and sodium periodate solution.
The preparation method of the modified bamboo pulp fiber is：Weigh bamboo pulp fiber to add in sodium periodate solution, with 300r/
Min rotating speed stirring 20min, then adds acid solution and adjusts to neutrality, sequentially add chitosan, sericin and hydrogen peroxide
Solution, ultrasonically treated 2h, is filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo pulp fiber is obtained after drying.
The thickener is Arabic gum, and the water-loss reducer is hydroxyethyl cellulose, and the plasticizer is phthalic acid
Dioctyl ester, the antioxidant is the mixture of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine, described
Mould inhibitor is ZPT, and the fire retardant is magnesium hydroxide.
The enhancing particle includes the raw material that following part is counted：12 parts of activated carbon, 8 parts of nano titanium oxide and nano zine oxide
7 parts.
The preparation method of the nano zine oxide is：Add 100mL's into 200mL 0.1mol/L zinc nitrate solutions
0.4mol/L urea liquid, both are well mixed, then the isothermal reaction 5h at 70 DEG C, after question response terminates, will be reacted
Obtained product filtering, collects filter residue, and filter residue is first dried into 4h at 80 DEG C, then calcines 2h under the conditions of 400 DEG C, obtains described
Nano zine oxide.
The plant dehydration filament is Chinese herbal medicine dehydrated fiber silk.
A kind of preparation method for the emulsion paint that can effectively purify air is provided in the present embodiment, comprised the following steps：
（1）, prepare foaming agent
Glue class is weighed according to proportioning and animal protein is well mixed, is positioned in heating container, under 80 DEG C of temperature conditionss, water-bath
2h is reacted, products therefrom is cooled down, filtered, material A is obtained；Lauryl sodium sulfate, polyethers emulsion and water are weighed according to proportioning,
It is heated to after 100 DEG C adding afore-mentioned materials A, 20min is stirred with 200r/min rotating speed, material B is obtained；
Sodium sulfate of polyethenoxy ether of fatty alcohol, rosin, silicon ash, silicones and caustic soda are weighed according to proportioning, afore-mentioned materials B is added to
In, 2h is stirred with 300r/min rotating speed, the foaming agent is obtained, it is standby；
（2）, mashing
Surplus stock is weighed according to proportioning, is put into mixer, step is then added（1）Obtained foaming agent, with 300r/min
Rotating speed stirring 35min, be uniformly dispersed and obtain slurry；
（3）, be sanded
Scattered slurry is sanded, rotating speed is 1200r/min, the sand milling time is 60min；Slurry is cleaned after sand milling with water
Material, obtains described can effectively purifying the emulsion paint of air.
Embodiment 3
It is a kind of effectively to purify the emulsion paint of air, include the raw material of following part meter：67.5 parts of styrene-acrylic emulsion, modified bamboo pulp are fine
Dimension 50 parts, enhancing 33 parts of particle, 28 parts of citronella oil, 25 parts of castor oil acid, 22.5 parts of plant dehydration filament, 19.5 parts of auxiliary agent and
37 parts of water；
The auxiliary agent includes the raw material that following part is counted：It is 7.5 parts of foaming agent, 6 parts of thickener, 4 parts of water-loss reducer, 2.5 parts of plasticizer, anti-
0.3 part of 1.5 parts of oxygen agent, 1 part of mould inhibitor and fire retardant；
The foaming agent includes the raw material that following part is counted：It is 2.5 parts of glue class, 1.5 parts of lauryl sodium sulfate, 1 part of polyethers emulsion, dynamic
0.65 part of thing albumen, 0.55 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.4 part of rosin, 0.25 part of silicon ash, 0.15 part of silicones,
1.5 parts of 0.15 part of caustic soda and water.
Wherein,
The modified bamboo pulp fiber includes the raw material that following part is counted：22.5 parts of bamboo pulp fiber, 16 parts of chitosan, sericin 12.5
11 parts of part, 12.5 parts of hydrogenperoxide steam generator and sodium periodate solution.
The preparation method of the modified bamboo pulp fiber is：Weigh bamboo pulp fiber to add in sodium periodate solution, with 250r/
Min rotating speed stirring 15min, then adds acid solution and adjusts to neutrality, sequentially add chitosan, sericin and hydrogen peroxide
Solution, ultrasonically treated 1.5h, is filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo pulp fiber is obtained after drying.
The thickener is algin, and the water-loss reducer is hydroxyethyl cellulose, and the plasticizer is phthalic acid two
Different nonyl ester, the antioxidant is the mixture of 2,4-DTBP, phosphorus trioxide, pentaerythritol ester and ethylenediamine, described
Mould inhibitor is ZPT, and the fire retardant is magnesium hydroxide.
The enhancing particle includes the raw material that following part is counted：11 parts of activated carbon, 7.5 parts of nano titanium oxide and nano oxidized
6 parts of zinc.
The preparation method of the nano zine oxide is：Add 100mL's into 200mL 0.1mol/L zinc nitrate solutions
0.4mol/L urea liquid, both are well mixed, then the isothermal reaction 4.5h at 65 DEG C, after question response terminates, will be anti-
The product filtering that should be obtained, collects filter residue, and filter residue is first dried into 3.5h at 70 DEG C, then calcines 1.5h under the conditions of 350 DEG C, obtains
To the nano zine oxide.
The plant dehydration filament is Chinese herbal medicine dehydrated fiber silk.
The present embodiment provides a kind of preparation method for the emulsion paint that can effectively purify air, comprises the following steps：
（1）, prepare foaming agent
Glue class is weighed according to proportioning and animal protein is well mixed, is positioned in heating container, under 75 DEG C of temperature conditionss, water-bath
1.5h is reacted, products therefrom is cooled down, filtered, material A is obtained；According to proportioning weigh lauryl sodium sulfate, polyethers emulsion and
Water, is heated to after 95 DEG C adding afore-mentioned materials A, stirs 15min with 150r/min rotating speed, obtain material B；
Sodium sulfate of polyethenoxy ether of fatty alcohol, rosin, silicon ash, silicones and caustic soda are weighed according to proportioning, afore-mentioned materials B is added to
In, 1.5h is stirred with 275r/min rotating speed, the foaming agent is obtained, it is standby；
（2）, mashing
Surplus stock is weighed according to proportioning, is put into mixer, step is then added（1）Obtained foaming agent, with 250r/min
Rotating speed stirring 30min, be uniformly dispersed and obtain slurry；
（3）, be sanded
Scattered slurry is sanded, rotating speed is 1000r/min, the sand milling time is 45min；Slurry is cleaned after sand milling with water
Material, obtains described can effectively purifying the emulsion paint of air.
The present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, its according to
The technical scheme described in foregoing embodiments can so be modified, or which part technical characteristic is equally replaced
Change.Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., should be included in the present invention
Protection domain within.
Claims (9)
1. a kind of can effectively purify the emulsion paint of air, it is characterised in that the raw material counted including following part：Styrene-acrylic emulsion 65 ~
68 parts, modified 45 ~ 55 parts of bamboo pulp fiber, 32 ~ 34 parts of particle of enhancing, 27 ~ 29 parts of citronella oil, 24 ~ 26 parts of castor oil acid, plant take off
36 ~ 38 parts of 22 ~ 23 parts of water cellulose silk, 19 ~ 20 parts of auxiliary agent and water；
The auxiliary agent includes the raw material that following part is counted：7 ~ 8 parts of foaming agent, 5 ~ 7 parts of thickener, 3 ~ 5 parts of water-loss reducer, plasticizer 2 ~ 3
0.2 ~ 0.4 part of part, 1 ~ 2 part of antioxidant, 0.8 ~ 1.2 part of mould inhibitor and fire retardant；
The foaming agent includes the raw material that following part is counted：2 ~ 3 parts of glue class, 1 ~ 2 part of lauryl sodium sulfate, polyethers emulsion 0.8 ~
1.2 parts, 0.6 ~ 0.7 part of animal protein, 0.5 ~ 0.6 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.3 ~ 0.5 part of rosin, silicon ash 0.2
1 ~ 2 part of ~ 0.3 part, 0.1 ~ 0.2 part of silicones, 0.1 ~ 0.2 part of caustic soda and water.
2. according to claim 1 can effectively purify the emulsion paint of air, it is characterised in that the original counted including following part
Material：67.5 parts of styrene-acrylic emulsion, modified 50 parts of bamboo pulp fiber, 33 parts of particle of enhancing, 28 parts of citronella oil, 25 parts of castor oil acid, plant
37 parts of 22.5 parts of dehydrated fiber silk, 19.5 parts of auxiliary agent and water；
The auxiliary agent includes the raw material that following part is counted：It is 7.5 parts of foaming agent, 6 parts of thickener, 4 parts of water-loss reducer, 2.5 parts of plasticizer, anti-
0.3 part of 1.5 parts of oxygen agent, 1 part of mould inhibitor and fire retardant；
The foaming agent includes the raw material that following part is counted：It is 2.5 parts of glue class, 1.5 parts of lauryl sodium sulfate, 1 part of polyethers emulsion, dynamic
0.65 part of thing albumen, 0.55 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 0.4 part of rosin, 0.25 part of silicon ash, 0.15 part of silicones,
1.5 parts of 0.15 part of caustic soda and water.
3. according to claim 1 can effectively purify the emulsion paint of air, it is characterised in that the modified bamboo pulp fiber
The raw material counted including following part：20 ~ 25 parts of bamboo pulp fiber, 15 ~ 17 parts of chitosan, 12 ~ 13 parts of sericin, hydrogenperoxide steam generator
12 ~ 13 parts and 10 ~ 12 parts of sodium periodate solution.
4. according to claim 3 can effectively purify the emulsion paint of air, it is characterised in that the modified bamboo pulp fiber
Preparation method be：Bamboo pulp fiber is weighed to add in sodium periodate solution, with 200~300r/min rotating speed stirring 10~
20min, then adds acid solution and adjusts to neutrality, sequentially add chitosan, sericin and hydrogenperoxide steam generator, ultrasonically treated
1 ~ 2h, is filtrated to get filter residue, and filter residue is put into baking oven, and the bamboo pulp fiber is obtained after drying.
5. according to claim 1 can effectively purify the emulsion paint of air, it is characterised in that the thickener is marine alga
Glue or Arabic gum, the water-loss reducer are carboxymethyl cellulose or hydroxyethyl cellulose, and the plasticizer is O-phthalic
One or more in dibutyl phthalate, dioctyl phthalate and diisononyl phthalate, the antioxidant is 2,4-
DI-tert-butylphenol compounds, phosphorus trioxide, the mixture of pentaerythritol ester and ethylenediamine, the mould inhibitor are ZPT, described
Fire retardant is magnesium hydroxide.
6. according to claim 1 can effectively purify the emulsion paint of air, it is characterised in that the enhancing particle includes
The raw material of following part meter：5 ~ 7 parts of 10 ~ 12 parts of activated carbon, 7 ~ 8 parts of nano titanium oxide and nano zine oxide.
7. according to claim 6 can effectively purify the emulsion paint of air, it is characterised in that the nano zine oxide
Preparation method is：100mL 0.4mol/L urea liquid is added into 200mL 0.1mol/L zinc nitrate solutions, incite somebody to action both
It is well mixed, then 4 ~ 5h of isothermal reaction at 60 ~ 70 DEG C, after question response terminates, the product that reaction is obtained is filtered, and collects filter
Slag, 3 ~ 4h is first dried by filter residue at 60 ~ 80 DEG C, then calcines 1 ~ 2h under the conditions of 300 ~ 400 DEG C, obtains described nano oxidized
Zinc.
8. according to claim 1 can effectively purify the emulsion paint of air, it is characterised in that the plant dehydration fiber
Silk is Chinese herbal medicine dehydrated fiber silk.
9. a kind of preparation method of emulsion paint that can effectively purify air according to any one of claim 1 ~ 8, it is special
Levy and be, comprise the following steps：
（1）, prepare foaming agent
Glue class is weighed according to proportioning and animal protein is well mixed, is positioned in heating container, under 70~80 DEG C of temperature conditionss,
1~2h of water-bath, products therefrom is cooled down, filtered, material A is obtained；Lauryl sodium sulfate, polyethers breast are weighed according to proportioning
Liquid and water, are heated to after 90 ~ 100 DEG C adding afore-mentioned materials A, stir 10 ~ 20min with 100 ~ 200r/min rotating speed, obtain thing
Expect B；
Sodium sulfate of polyethenoxy ether of fatty alcohol, rosin, silicon ash, silicones and caustic soda are weighed according to proportioning, afore-mentioned materials B is added to
In, 1 ~ 2h is stirred with 250 ~ 300r/min rotating speed, the foaming agent is obtained, it is standby；
（2）, mashing
Surplus stock is weighed according to proportioning, is put into mixer, step is then added（1）Obtained foaming agent, with 200 ~ 300r/
Min rotating speed stirs 25 ~ 35min, is uniformly dispersed and obtains slurry；
（3）, be sanded
Scattered slurry is sanded, rotating speed is 800 ~ 1200r/min, the sand milling time is 30 ~ 60min；Water is used after sand milling
Slurry is cleaned, obtains described can effectively purifying the emulsion paint of air.
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| CN107841224A (en) * | 2017-11-30 | 2018-03-27 | 明光市裕阳新材料有限公司 | A kind of antibiotic emulsion paint and preparation method thereof |
| CN108329765A (en) * | 2018-01-23 | 2018-07-27 | 合肥梵腾环保科技有限公司 | A kind of environment friendly emulsion paint and preparation method thereof |
| CN108384387A (en) * | 2018-03-12 | 2018-08-10 | 合肥同佑电子科技有限公司 | A kind of high-temperature resistant coating and preparation method thereof for solar energy equipment |
| CN110054955A (en) * | 2018-01-19 | 2019-07-26 | 天津天涂豪邦涂料有限公司 | A kind of emulsion paint and preparation method thereof of effective purification air |
| CN115124896A (en) * | 2022-08-27 | 2022-09-30 | 张鑫 | Wall coating for purifying formaldehyde, preparation method and use method thereof |
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