CN102745974A - Environment-friendly building material and preparation method thereof - Google Patents

Environment-friendly building material and preparation method thereof Download PDF

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Publication number
CN102745974A
CN102745974A CN201210262970XA CN201210262970A CN102745974A CN 102745974 A CN102745974 A CN 102745974A CN 201210262970X A CN201210262970X A CN 201210262970XA CN 201210262970 A CN201210262970 A CN 201210262970A CN 102745974 A CN102745974 A CN 102745974A
Authority
CN
China
Prior art keywords
sawdust
preparation
building materials
parts
magnesium chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201210262970XA
Other languages
Chinese (zh)
Inventor
黄东明
陈亚川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUJIAN ZHUOLONG BUILDING MATERIALS TECHNOLOGY Co Ltd
Original Assignee
FUJIAN ZHUOLONG BUILDING MATERIALS TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUJIAN ZHUOLONG BUILDING MATERIALS TECHNOLOGY Co Ltd filed Critical FUJIAN ZHUOLONG BUILDING MATERIALS TECHNOLOGY Co Ltd
Priority to CN201210262970XA priority Critical patent/CN102745974A/en
Publication of CN102745974A publication Critical patent/CN102745974A/en
Priority to PCT/CN2013/080141 priority patent/WO2014015818A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

The invention discloses an environment-friendly building material and a preparation method thereof. The building material mainly comprises, by weight, 70-90 parts of sawdust, 10-15 parts of magnesium oxide, 5-10 parts of magnesium chloride, 1-2 parts of over 85% of concentrated sulphuric acid and 1-2 parts of paraffin. The preparation method includes sorting, hot grinding, drying, mixing, pavement and hot forming. The environment-friendly building material can replace materials such as medium density fiberboards and three-ply boards and has superior performance.

Description

A kind of environmental protection building material and preparation method thereof
Technical field
The present invention relates to building material field, relate to a kind of environmental protection building material and preparation method thereof particularly.
Background technology
MDF is that density board is a kind of, is raw material with wood fibre or other plant fiber, through smash, fiber separation, dry after-applied urea-formaldehyde resin or other tackiness agent that is suitable for, a kind of artificial board of after hot pressing, processing again.Generally in 0.5-0.8 grams per cubic centimter scope, thickness is generally the 3-30 millimeter to its density.The wad homogeneous microstructure, interfibrous bonding strength is high, so its MOR, plane tensile strength, modulus of elasticity are good.It is strong to hold screw power geometric ratio shaving board; The wad surfacing, smooth, be convenient to finishing materials such as gluing plane system veneer and tissue paper, and be convenient to cover with paint, lacquer, colour wash, etc. and practice thrift coating; Medium density fibre board (MDF) can produce from several millimeters to tens mm thick sheet materials, can replace plank, the square bar of any thickness, and have the favorable mechanical processing characteristics.Therefore, MDF has obtained using widely.Yet the dependence formaldehyde of part MDF is bonding, though can eliminate formaldehyde through hanging sheet material later, the content of the formaldehyde of some products is still very high, and is also very big to people's health harm.In addition, wear into fiber, changed the structure of timber fully, so moisture absorption, water absorbing properties, thickness swelling are higher because MDF is a log.Therefore, its environment for use has restriction.
The plate of mainly making by inorganic materials; Glass magnesium plate for example, its staple is Natural manganese dioxide and magnesium chloride (more than at least 60%), when atmospheric moisture is big; The surface of plate absorbs airborne moisture and produces surface moisture; And then overwork the globule, even the globule occurs and join together and form trickling phenomenon, phenomenon that Here it is so-called " returning halogen "; When the atmospheric moisture step-down, product surface moisture correspondingly evaporates, and staying full of stains or spots white mark is so-called scum.Return halogen, scum is the great mass defect of magnesian product, can cause and reduce intensity and waterproof moisture-proof characteristic; Influence decorate properties, cause finishing material to come off; Influence outward appearance.
Summary of the invention
The object of the present invention is to provide a kind of building materials, to solve the problems referred to above that exist in the prior art.
Technical scheme provided by the invention is following:
A kind of building materials, by weight, mainly be prepared from following composition:
Sawdust 70-90 part; Natural manganese dioxide 10-15 part;
Magnesium chloride 5-10 part; Vitriol oil 1-2 part more than 85%; And
Paraffin 1-2 part.
In preferred embodiment of the present invention, the water ratio of said sawdust is lower than 10%.
In preferred embodiment of the present invention, the water ratio of said sawdust is 8-10%.
A kind of preparation method of building materials comprises the steps:
(1) sawdust is selected materials;
(2) defibrator process;
(3) drying: adopt dryer that the water cut of sawdust is reduced to water cut and be lower than 10%;
(4) mix: dried sawdust 70-90 part; Natural manganese dioxide 10-15 part; Magnesium chloride 5-10 part; Add concentration vitriol oil 1-2 part more than 85%, the vitriol oil mixes earlier with Natural manganese dioxide and magnesium chloride, mixes with sawdust again, adds paraffin 1-2 part again, and mixer mixing stirs;
(5) mat formation;
(6) hot-forming.
In preferred embodiment of the present invention, the mixing tank rotating speed of step (4) is 1000-5000r.
In preferred embodiment of the present invention, the mixing temperature of step (4) is controlled at 15-35 degree.
In preferred embodiment of the present invention, the hot-forming temperature of step (6) is 180-200 ℃, and pressure is that pressure is 1500-2300T.
Sawdust of the present invention can be from Furniture Factory's tankage, wood-working factory etc.
In the present invention, sawdust is a base-material; Natural manganese dioxide and magnesium chloride be as the gummed effect, replaces tackiness agent such as formaldehyde and have anti-fire action; Sulfuric acid can prevent " returning halogen " phenomenon; Paraffin plays waterproof action.After comprehensive, product do not have " returning halogen ", " scum " phenomenon, waterproof, fire prevention, anticorrosion, mothproof, formaldehydeless volatilization, heat insulation, soundproof effect is strong, resistance to compression is resisting and is surpassing national standard.Product of the present invention can replace materials such as MDF, three-ply-wood, can be used as building materials such as timber floor, partition plate, window frame, door-plate and furniture and uses plate.Product can bore, can follow closely, be prone to that cutting, surface layer can be painted, the veneer performance is good.
Embodiment
Embodiment 1
80 parts in sawdust; 12 parts in Natural manganese dioxide;
8 parts in magnesium chloride; 1.5 parts of the vitriol oils more than 85%; And
1.5 parts in paraffin.
(1) selects materials: sawdust
(2) defibrator process: adopt defibrator to carry out, be current techique, operate identical with MDF;
(3) drying: sawdust is dried to the about 8-10% of water cut;
(4) mix: the vitriol oil mixes earlier with Natural manganese dioxide and magnesium chloride, stirs; With sawdust, paraffin, be that 3500r, blade radius are 80 centimeters super mixer mixing again, stir that temperature is controlled at 15-35 degree through rotating speed;
(5) mat formation;
(6) hot-forming, temperature 180-200 ℃, pressure 1500T.
Embodiment 2
90 parts in sawdust; 10 parts in Natural manganese dioxide;
10 parts in magnesium chloride; 2 parts of the vitriol oils more than 85%; And
2 parts in paraffin.
Except that above proportioning difference, all the other operations are identical with embodiment 1.
Embodiment 3
70 parts in sawdust; 15 parts in Natural manganese dioxide;
5 parts in magnesium chloride; 1 part of the vitriol oil more than 85%; And
1 part in paraffin.
Except that above proportioning difference, all the other operations are identical with embodiment 1.
The comparative example
The MDF of commercial certain brand was placed on flame following 10 minutes, and MDF is directly lighted by fire; After the fire extinguishing, product surface deepens black comprehensively; It is inserted in 100 ℃ of boiling water again and boil 5h, this MDF feels like jelly, and fracture.
Under the equal conditions, get the plate of the embodiment of the invention 1, be placed on flame following 10 minutes, plate is not on fire; The only local blackout of product surface, and degree is more shallow; It is inserted in 100 ℃ of boiling water again and boil 5h, this plate does not feel like jelly except that darkening, and the form that is kept perfectly.
Above-mentionedly be merely a specific embodiment of the present invention, but design concept of the present invention is not limited thereto, allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.

Claims (7)

1. building materials, by weight, mainly be prepared from following composition:
Sawdust 70-90 part; Natural manganese dioxide 10-15 part;
Magnesium chloride 5-10 part; Vitriol oil 1-2 part more than 85%; And
Paraffin 1-2 part.
2. a kind of building materials as claimed in claim 1 is characterized in that: the water ratio of said sawdust is lower than 10%.
3. a kind of building materials as claimed in claim 2 is characterized in that: the water ratio of said sawdust is 8-10%.
4. the preparation method of building materials comprises the steps:
(1) sawdust is selected materials;
(2) defibrator process;
(3) drying: adopt dryer that the water cut of sawdust is reduced to water cut and be lower than 10%;
(4) mix: dried sawdust 70-90 part; Natural manganese dioxide 10-15 part; Magnesium chloride 5-10 part; Add concentration vitriol oil 1-2 part more than 85%, the vitriol oil mixes earlier with Natural manganese dioxide and magnesium chloride, mixes with sawdust again, adds paraffin 1-2 part again, and mixer mixing stirs;
(5) mat formation;
(6) hot-forming.
5. the preparation method of a kind of building materials as claimed in claim 4, it is characterized in that: the mixing tank rotating speed of step (4) is 1000-5000r.
6. the preparation method of a kind of building materials as claimed in claim 1 is characterized in that: the mixing temperature of step (4) is controlled at 15-35 degree.
7. the preparation method of a kind of building materials as claimed in claim 1, it is characterized in that: the hot-forming temperature of step (6) is 180-200 ℃, pressure is 1500-2300T.
CN201210262970XA 2012-07-26 2012-07-26 Environment-friendly building material and preparation method thereof Pending CN102745974A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201210262970XA CN102745974A (en) 2012-07-26 2012-07-26 Environment-friendly building material and preparation method thereof
PCT/CN2013/080141 WO2014015818A1 (en) 2012-07-26 2013-07-25 Environmentally friendly building material and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210262970XA CN102745974A (en) 2012-07-26 2012-07-26 Environment-friendly building material and preparation method thereof

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WO (1) WO2014015818A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014015818A1 (en) * 2012-07-26 2014-01-30 福建省卓隆建材科技有限公司 Environmentally friendly building material and manufacturing method thereof
CN104016655A (en) * 2014-04-19 2014-09-03 徐高强 Magnesium oxide board and preparation method thereof
CN105330188A (en) * 2015-10-13 2016-02-17 山东省建筑科学研究院 Magnesium oxysulfate gelling material early strength agent, and applications thereof
CN110790562A (en) * 2019-10-10 2020-02-14 陈发江 Dustproof and odor-free solid wood flowerpot and preparation method and application thereof
CN112724470A (en) * 2019-10-29 2021-04-30 株式会社特肯斯 Release-resistant rigid moisture absorbent compositions and absorbent articles comprising the same
US11400431B2 (en) 2019-10-29 2022-08-02 Tkens, Co., Ltd. Composition for soft anti-release moisture absorbent

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630917B (en) * 2016-09-22 2019-09-24 佛山市东鹏陶瓷有限公司 A kind of preparation method and prepared adobe of magnesite adobe
CN114103300A (en) * 2022-01-25 2022-03-01 矩匠(北京)科技有限公司 Novel glass magnesium board composite board preparation method and composite board

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1225345A (en) * 1998-11-30 1999-08-11 韩敏芳 Artificial stone products
CN1294094A (en) * 1999-10-29 2001-05-09 赵连春 Composite rice straw board and its making technology

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102745974A (en) * 2012-07-26 2012-10-24 福建省卓隆建材科技有限公司 Environment-friendly building material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1225345A (en) * 1998-11-30 1999-08-11 韩敏芳 Artificial stone products
CN1294094A (en) * 1999-10-29 2001-05-09 赵连春 Composite rice straw board and its making technology

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
陈献梅等: "对解决菱镁材料耐水性差等问题途径的探讨", 《湖南化工》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014015818A1 (en) * 2012-07-26 2014-01-30 福建省卓隆建材科技有限公司 Environmentally friendly building material and manufacturing method thereof
CN104016655A (en) * 2014-04-19 2014-09-03 徐高强 Magnesium oxide board and preparation method thereof
CN105330188A (en) * 2015-10-13 2016-02-17 山东省建筑科学研究院 Magnesium oxysulfate gelling material early strength agent, and applications thereof
CN110790562A (en) * 2019-10-10 2020-02-14 陈发江 Dustproof and odor-free solid wood flowerpot and preparation method and application thereof
CN112724470A (en) * 2019-10-29 2021-04-30 株式会社特肯斯 Release-resistant rigid moisture absorbent compositions and absorbent articles comprising the same
US11400431B2 (en) 2019-10-29 2022-08-02 Tkens, Co., Ltd. Composition for soft anti-release moisture absorbent

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Legal Events

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PB01 Publication
C53 Correction of patent of invention or patent application
CB03 Change of inventor or designer information

Inventor after: Huang Dongming

Inventor before: Huang Dongming

Inventor before: Chen Yachuan

COR Change of bibliographic data

Free format text: CORRECT: INVENTOR; FROM: HUANG DONGMING CHEN YACHUAN TO: HUANG DONGMING

C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20121024