CN107236313A - A kind of asphaltic liquid repaired for asphalt pavement crack and preparation method thereof - Google Patents

A kind of asphaltic liquid repaired for asphalt pavement crack and preparation method thereof Download PDF

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Publication number
CN107236313A
CN107236313A CN201710618712.3A CN201710618712A CN107236313A CN 107236313 A CN107236313 A CN 107236313A CN 201710618712 A CN201710618712 A CN 201710618712A CN 107236313 A CN107236313 A CN 107236313A
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CN
China
Prior art keywords
component
agent
accelerator
antistripping
asphalt
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Pending
Application number
CN201710618712.3A
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Chinese (zh)
Inventor
王志祥
许新权
吴传海
李善强
肖春发
方杨
刘锋
荣垂强
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HUALU TRAFFIC SCIENCE-TECHNOLOGY Co Ltd GUANGDONG
Changan University
Original Assignee
HUALU TRAFFIC SCIENCE-TECHNOLOGY Co Ltd GUANGDONG
Changan University
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Application filed by HUALU TRAFFIC SCIENCE-TECHNOLOGY Co Ltd GUANGDONG, Changan University filed Critical HUALU TRAFFIC SCIENCE-TECHNOLOGY Co Ltd GUANGDONG
Priority to CN201710618712.3A priority Critical patent/CN107236313A/en
Publication of CN107236313A publication Critical patent/CN107236313A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The invention discloses a kind of asphaltic liquid repaired for asphalt pavement crack, the component A, B component, the mass ratio of curing agent are 100:(3~5):(6~10);The component A is that polyurethane is formed with asphalt compounding, or resin is formed with asphalt compounding;The B component is the mixture of diluent, accelerator, coupling agent, reinforcing agent and antistripping agent composition, diluent, accelerator, coupling agent, reinforcing agent and antistripping agent.Component A is fast with curing agent reaction speed in the asphaltic liquid of the present invention, and curing time is short, without heating in whipping process, and construction is simple, and operating performance is good;Reinforcing agent and antistripping agent significantly improve the adhesiveness and reinforcing effect of pitch in B component, the mobility of pitch can be significantly improved by diluent, make with preferable viscosity and mobility, viscosity is up to 2.5Pa.s, mobility reaches 14mm, reaction speed can be accelerated using accelerator and coupling agent, predetermined strength is reached.

Description

A kind of asphaltic liquid repaired for asphalt pavement crack and preparation method thereof
Technical field
The present invention relates to pavement crack repair Material Field, and in particular to a kind of pitch repaired for asphalt pavement crack Liquid and preparation method thereof.
Background technology
With developing rapidly for China paving and deck paving technology, bituminous concrete with its function admirable, construction it is simple, Be easily recycled, low cost and other advantages and be widely used and promote, but the mat formation crack of bitumen layer of the thing followed is asked Topic is always the focus and difficult point of road circle concern.China's economy is developed rapidly, and the volume of traffic and load-carrying are continuously increased, and pave-load layer exists About it is to produce than more serious crack disease, particularly damp and hot height in 1~2 year year of open to traffic under the repeated action of heavy duty Warm area, Rotating fields of mating formation produce serious cracking destruction quickly;Semi-rigid type base that China's expressway surface is used mostly and not The defect of the disconnected Steel Bridge Deck mechanical property promoted also exacerbates pave-load layer structural damage.Paving structure Crack failure not only influences The comfortableness of driving and road surface it is attractive in appearance, more had a strong impact on its structural mechanical property and durability;If the microcrack of early stage If without repairing in time, road table water has an opportunity to enter inside pavement structure, or even in roadbed, produces roadbed uneven Deformation, to roadbed output destroy, influence roadbed service behaviour;Under the influence of traffic load and periodicity environment, crack Further development then produces the diseases such as the peeling of aggregate or fritter bituminous concrete, loose, pit, ultimately result in big transverse joint, The appearance of longitudinal joint, check crack.
Handled mostly using filling technology fracture at present, crack treatment material is roughly divided into three classes, a class is heat Filling formula rubber asphalt, it is cheap, but heating is needed, viscosity is low, and construction technology is relatively complicated;One class is resin, and viscosity is big, Crack should not be fully infiltrated into, and high are required to execution conditions, expensive, benefit is low;Another kind of is that cold-penetration formula emulsified asphalt is filled out Sewing, it is few to be restricted condition, is not required to heating, but preparation technology is cumbersome, and expensive, service life is shorter, poor-performing.
Therefore be badly in need of a kind of asphalt pavement repairing asphaltic liquid of research and development, with viscosity is strong, good fluidity, operability it is excellent, The characteristics of service life is long, constructs at normal temperatures while have again, economizes on resources, easily stored, effect is high, reduction maintenance cost Advantage.
The content of the invention
In view of the above-mentioned problems, the present invention is intended to provide a kind of preparation method is simple, component is stable, be easily mixed the use of solidification Asphaltic liquid repaired in asphalt pavement crack and preparation method thereof.
To realize the technical purpose, the solution of the present invention is:A kind of asphaltic liquid repaired for asphalt pavement crack, including Component A, B component, curing agent, the component A, B component, the mass ratio of curing agent are 100:(3~5):(6~10);
The component A is that polyurethane is formed with asphalt compounding, or resin is formed with asphalt compounding, described The mass ratio of compounding is (20~30):100;
The B component be diluent, accelerator, coupling agent, reinforcing agent and antistripping agent composition mixture, diluent, Accelerator, coupling agent, the mass ratio of reinforcing agent and antistripping agent are:(30~40):(20~30):(20~28):(12~19): (3~5).
Preferably, polyurethane is aqueous, two-component type, polyether-type, casting type or acrylic acid in described component A One kind in class polyurethane;
Unsaturated-resin is one kind in polyurethane metaphenylene, bisphenol A-type or metaphenylene resin in described component A;
Asphalt in the component A is 90# bi tumenf orr oads or 110# bi tumenf orr oads or 130# One kind in bi tumenf orr oad.
Preferably, the curing agent is cyclohexanone peroxide, dibenzoyl peroxide, methyl ethyl ketone peroxide or mistake Aoxidize one kind in t-butyl perbenzoate.
Preferably, the diluent in the B component is acetone, ethanol, maleic anhydride, gasoline, styrene, insatiable hunger With one or more mixtures in polyester resin;
Accelerator in the B component is sour cobalt class, amine, one or more kinds of mixtures of ethers accelerator;
Coupling agent in the B component is the one of vinyl, methacryloxy and the one type of silane coupling agent of epoxy radicals 3 Kind;
Reinforcing agent in the B component is one kind in wollastonite in powder, cement;
Antistripping agent in the B component uses LT-B types antistripping agent, AR-68 types antistripping agent or the anti-stripping of HT-09 types Fall one kind in agent.
Preferably, the sour cobalt class accelerator is cobalt naphthenate, the mixture of cobalt octoate one or two kinds of;
The amine type accelerator is dimethylaniline, diethylaniline, OTAC, hexa-methylene four One or more kinds of mixtures in amine;
The ethers accelerator be AEO, diethylene glycol ether, ethylene glycol ethyl ether in one kind or A variety of mixtures.
A kind of preparation method for the asphaltic liquid repaired for asphalt pavement crack, is comprised the following steps that:
The first step, be according to mass ratio by the diluent of B component, accelerator, coupling agent, reinforcing agent and antistripping agent:(30 ~40):(20~30):(20~28):(12~19):The ratio mixing of (3~5), 2~3min of hand operated mixing, it is ensured that each composition It is well mixed, do not isolate;
Second step, is 100 according to the mass ratio of component A, B component, curing agent:(3~5):The ratio of (6~10), first will Quantitative B component is added in component A, 1~2min of hand operated mixing;
3rd step, then quantitative curing agent component is added in above-mentioned mixed solution, with electric blender stirring 3~ 5min, 1000~2000r/min of mixing speed, are made pavement patching asphaltic liquid.
Component A is fast with curing agent reaction speed in beneficial effects of the present invention, asphaltic liquid of the invention, can be completed in 5h Curing reaction, curing time is short, without heating in whipping process, and construction is simple, and operating performance is good, is handed over without long-time closing Lead to, while being capable of the effectively save energy;Reinforcing agent and antistripping agent significantly improve the adhesiveness and reinforcement effect of pitch in B component Really, the mobility of pitch can be significantly improved by diluent, is made with preferable viscosity and mobility, viscosity is reachable 2.5Pa.s, mobility reaches 14mm, can accelerate reaction speed using accelerator and coupling agent, reach predetermined strength;The application's B component performance is stable, has excellent storage stability, performance change will not occur during long term storage, volatilization in 3 days only causes 0.22% Mass loss;Asphaltic liquid produced by the present invention specific preferably construction workability, caking property, low temperature flexibility, weather-proof, resistance to ag(e)ing Energy;While cost is low, effect is fast;Preparation method is simple, required time is shorter, specific application prospect well.
Embodiment
The present invention is described in further details with reference to specific embodiment.
Specific embodiment of the present invention is used for the asphaltic liquid that asphalt pavement crack is repaired, including component A, B to be a kind of Component, curing agent, the component A, B component, the mass ratio of curing agent are 100:(3~5):(6~10);
The component A is that polyurethane is formed with asphalt compounding, or resin is formed with asphalt compounding, described The mass ratio of compounding is (20~30):100;
The B component be diluent, accelerator, coupling agent, reinforcing agent and antistripping agent composition mixture, diluent, Accelerator, coupling agent, the mass ratio of reinforcing agent and antistripping agent are:(30~40):(20~30):(20~28):(12~19): (3~5).
Polyurethane is in aqueous, two-component type, polyether-type, casting type or acrylic compounds polyurethane in described component A One kind;Unsaturated-resin is one kind in polyurethane metaphenylene, bisphenol A-type or metaphenylene resin in described component A; Asphalt in the component A is 90# bi tumenf orr oads or 110# bi tumenf orr oads or 130# road oil One kind in pitch.
The curing agent is cyclohexanone peroxide, dibenzoyl peroxide, methyl ethyl ketone peroxide or perbenzoic acid One kind in the tert-butyl ester.
Diluent in the B component is acetone, ethanol, maleic anhydride, gasoline, styrene, unsaturated polyester (UP) tree One or more mixtures in fat;Accelerator in the B component be sour cobalt class, amine, one kind of ethers accelerator or The a variety of mixture of person;Coupling agent in the B component is vinyl, methacryloxy and the one type of silane of epoxy radicals 3 are coupled One kind of agent;Reinforcing agent in the B component is one kind in wollastonite in powder, cement;Antistripping agent in the B component is used One kind in LT-B types antistripping agent, AR-68 types antistripping agent or HT-09 type antistripping agents.
The sour cobalt class accelerator is cobalt naphthenate, the mixture of cobalt octoate one or two kinds of;The amine type accelerator To be one or more kinds of mixed in dimethylaniline, diethylaniline, OTAC, hexa Compound;The ethers accelerator is the one or more in AEO, diethylene glycol ether, ethylene glycol ethyl ether Mixture.
A kind of preparation method for the asphaltic liquid repaired for asphalt pavement crack, is comprised the following steps that:The first step, by B groups Point diluent, accelerator, coupling agent, reinforcing agent and antistripping agent be according to mass ratio:(30~40):(20~30):(20~ 28):(12~19):The ratio mixing of (3~5), 2~3min of hand operated mixing, it is ensured that each composition is well mixed, and is not isolated;Second Step, is 100 according to the mass ratio of component A, B component, curing agent:(3~5):The ratio of (6~10), first adds quantitative B component Enter into component A, 1~2min of hand operated mixing;3rd step, then quantitative curing agent component is added in above-mentioned mixed solution, 3~5min, 1000~2000r/min of mixing speed are stirred with electric blender, pavement patching asphaltic liquid is made.Road surface of the present invention Repairing asphaltic liquid need to meet the technical indicator of table 1.
The asphaltic liquid technical indicator of table 1
Embodiment 1:Component A, B component, the mass ratio of curing agent are 100:8:5
Wherein component A is the mixture of aqueous polyurethane and 110# asphalt, and mass ratio is 25:100;Curing agent was Aoxidize t-butyl perbenzoate;Diluent is acetone in B component, and accelerator is cobalt naphthenate, and coupling agent is, methacryloxy Silane, reinforcing agent is wollastonite in powder, and antistripping agent selects LT-B types, and its mass ratio is:35:25:23:13:4.
Then according to following operation preparation asphaltic liquid:(1) first by each composition hand operated mixing 2.5min of B component, it is ensured that Each composition is well mixed, and is not isolated;
(2) quantitative B component is added in component A, hand operated mixing 1.5min, obtains uncured asphaltic liquid;
(3) quantitative curing agent is added in above-mentioned uncured asphaltic liquid again, stirs 4min with electric blender, stir Speed 1500r/min is mixed, pavement patching asphaltic liquid is made.
This example pavement patching asphaltic liquid performance detection technical indicator such as table 2.
The asphaltic liquid performance detection technical indicator of table 2
Embodiment 2:Component A, B component, the mass ratio of curing agent are 100:4:7
Wherein component A is the mixture with 130# asphalt using polyurethane metaphenylene unsaturated-resin, and mass ratio is 27:100;Curing agent is peroxidized t-butyl perbenzoate;Diluent is ethanol in B component, and accelerator is dimethylaniline, coupling Agent is, methacryloxypropyl silane, and reinforcing agent is wollastonite in powder, and antistripping agent selects AR-68 types, and its mass ratio is:35:25: 23:13:4.
Then according to following operation preparation asphaltic liquid:(1) first by each composition hand operated mixing 2.8min of B component, it is ensured that Each composition is well mixed, and is not isolated;(2) quantitative B component is added in component A, hand operated mixing 1.3min, obtained uncured Asphaltic liquid;(3) quantitative curing agent is added in above-mentioned uncured asphaltic liquid again, 5min is stirred with electric blender, Mixing speed 1500r/min, is made pavement patching asphaltic liquid.
This example pavement patching asphaltic liquid performance detection technical indicator such as table 3.
The asphaltic liquid performance detection technical indicator of table 3
Component A is fast with curing agent reaction speed in the asphaltic liquid of the present invention, and curing reaction, curing time can be completed in 5h Short, without heating in whipping process, construction is simple, and operating performance is good, without long-time close traffic etc., while can be effective Save the energy;Reinforcing agent and antistripping agent significantly improve the adhesiveness and reinforcing effect of pitch in B component, can be shown by diluent Writing improves the mobility of pitch, makes with preferable viscosity and mobility, viscosity reaches 14mm up to 2.5Pa.s, mobility, Reaction speed can be accelerated using accelerator and coupling agent, predetermined strength is reached;The B component performance of the application is stable, stable storing Property it is excellent, will not occur performance change during long term storage, volatilization in 3 days only causes 0.22% mass loss;It is produced by the present invention Asphaltic liquid specific preferably construction workability, caking property, low temperature flexibility, weather-proof, ageing-resistant performance;While cost is low, effect is fast; Preparation method is simple, required time is shorter, specific application prospect well.
Described above, only presently preferred embodiments of the present invention is not intended to limit the invention, every skill according to the present invention Any trickle amendment, equivalent substitution and improvement that art is substantially made to above example, should be included in technical solution of the present invention Protection domain within.

Claims (6)

1. a kind of asphaltic liquid repaired for asphalt pavement crack, it is characterised in that:It is described including component A, B component, curing agent Component A, B component, the mass ratio of curing agent are 100:(3~5):(6~10);
The component A is that polyurethane is formed with asphalt compounding, or resin is formed with asphalt compounding, described compounding Mass ratio be (20~30):100;
The B component is the mixture of diluent, accelerator, coupling agent, reinforcing agent and antistripping agent composition, diluent, promotion Agent, coupling agent, the mass ratio of reinforcing agent and antistripping agent are:(30~40):(20~30):(20~28):(12~19):(3~ 5)。
2. the asphaltic liquid according to claim 1 repaired for asphalt pavement crack, it is characterised in that:Described component A Middle polyurethane is one kind in aqueous, two-component type, polyether-type, casting type or acrylic compounds polyurethane;
Unsaturated-resin is one kind in polyurethane metaphenylene, bisphenol A-type or metaphenylene resin in described component A;
Asphalt in the component A is 90# bi tumenf orr oads or 110# bi tumenf orr oads or 130# roads One kind in asphalt.
3. the asphaltic liquid according to claim 1 repaired for asphalt pavement crack, it is characterised in that:The curing agent is One kind in cyclohexanone peroxide, dibenzoyl peroxide, methyl ethyl ketone peroxide or peroxidized t-butyl perbenzoate.
4. the asphaltic liquid according to claim 1 repaired for asphalt pavement crack, it is characterised in that:In the B component Diluent be one or more mixed in acetone, ethanol, maleic anhydride, gasoline, styrene, unsaturated polyester resin Compound;
Accelerator in the B component is sour cobalt class, amine, one or more kinds of mixtures of ethers accelerator;
Coupling agent in the B component is one kind of vinyl, methacryloxy and the one type of silane coupling agent of epoxy radicals 3;
Reinforcing agent in the B component is one kind in wollastonite in powder, cement;
Antistripping agent in the B component uses LT-B types antistripping agent, AR-68 types antistripping agent or HT-09 type antistripping agents In one kind.
5. the asphaltic liquid according to claim 4 repaired for asphalt pavement crack, it is characterised in that:The sour cobalt class promotees Enter agent for cobalt naphthenate, the mixture of cobalt octoate one or two kinds of;
The amine type accelerator is in dimethylaniline, diethylaniline, OTAC, hexa One or more kinds of mixtures;
The ethers accelerator is the one or more in AEO, diethylene glycol ether, ethylene glycol ethyl ether Mixture.
6. a kind of preparation method of asphaltic liquid for any asphalt pavement crack repairings of claim 1-5, it is characterised in that:Tool Body step is as follows:
The first step, be according to mass ratio by the diluent of B component, accelerator, coupling agent, reinforcing agent and antistripping agent:(30~ 40):(20~30):(20~28):(12~19):The ratio mixing of (3~5), 2~3min of hand operated mixing, it is ensured that each composition is mixed Close uniform, do not isolate;
Second step, is 100 according to the mass ratio of component A, B component, curing agent:(3~5):The ratio of (6~10), first will be quantitative B component be added in component A, 1~2min of hand operated mixing;
3rd step, then quantitative curing agent component is added in above-mentioned mixed solution, 3~5min is stirred with electric blender, 1000~2000r/min of mixing speed, is made pavement patching asphaltic liquid.
CN201710618712.3A 2017-07-26 2017-07-26 A kind of asphaltic liquid repaired for asphalt pavement crack and preparation method thereof Pending CN107236313A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110092643A (en) * 2019-05-16 2019-08-06 武汉钢铁有限公司 A kind of combined blown converter furnace bottom material for repairing
CN110903665A (en) * 2019-12-13 2020-03-24 西安建筑科技大学 Double-component polyurethane modified asphalt and preparation method thereof
CN113062167A (en) * 2021-04-02 2021-07-02 常州市建筑科学研究院集团股份有限公司 Smearing type asphalt-based road crack repairing glue
CN114250058A (en) * 2020-12-31 2022-03-29 山西省交通科技研发有限公司 Double-component pouring sealant for repairing cracks of asphalt concrete pavement and preparation method thereof
CN114250058B (en) * 2020-12-31 2024-04-19 山西省交通科技研发有限公司 Double-component pouring sealant for repairing cracks of asphalt concrete pavement and preparation method thereof

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CN103044935A (en) * 2013-01-04 2013-04-17 陈永红 Modified cold-stirred and cold-spread room temperature bitumen and preparation method thereof
CN104693783A (en) * 2015-03-30 2015-06-10 河南省路嘉路桥股份有限公司 Two-component normal-temperature curing crack pouring material for bituminous pavement
CN105348827A (en) * 2015-11-09 2016-02-24 长安大学 Solvent-type cold-patch asphalt liquid and preparation technology therefor

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JP3133378B2 (en) * 1991-06-17 2001-02-05 昭博 森吉 Asphalt mixture
CN1385469A (en) * 2001-05-15 2002-12-18 中国科学院成都有机化学研究所 Asphalt liquefying agent
KR100982734B1 (en) * 2009-11-26 2010-09-16 주식회사 화신 Constructing method using an aqueous asphalt repair agent
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110092643A (en) * 2019-05-16 2019-08-06 武汉钢铁有限公司 A kind of combined blown converter furnace bottom material for repairing
CN110903665A (en) * 2019-12-13 2020-03-24 西安建筑科技大学 Double-component polyurethane modified asphalt and preparation method thereof
CN114250058A (en) * 2020-12-31 2022-03-29 山西省交通科技研发有限公司 Double-component pouring sealant for repairing cracks of asphalt concrete pavement and preparation method thereof
CN114250058B (en) * 2020-12-31 2024-04-19 山西省交通科技研发有限公司 Double-component pouring sealant for repairing cracks of asphalt concrete pavement and preparation method thereof
CN113062167A (en) * 2021-04-02 2021-07-02 常州市建筑科学研究院集团股份有限公司 Smearing type asphalt-based road crack repairing glue

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