CN107229090B - A kind of eyeshield automotive sunshade panel eyeglass filtering out harmful light - Google Patents

A kind of eyeshield automotive sunshade panel eyeglass filtering out harmful light Download PDF

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Publication number
CN107229090B
CN107229090B CN201710519124.4A CN201710519124A CN107229090B CN 107229090 B CN107229090 B CN 107229090B CN 201710519124 A CN201710519124 A CN 201710519124A CN 107229090 B CN107229090 B CN 107229090B
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parts
eyeglass
matrix
layer
eyeshield
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CN107229090A (en
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杨晓燕
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Suzhou Xin River Mirror Co Ltd
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Suzhou Xin River Mirror Co Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/22Absorbing filters
    • G02B5/223Absorbing filters containing organic substances, e.g. dyes, inks or pigments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60JWINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J3/00Antiglare equipment associated with windows or windscreens; Sun visors for vehicles
    • B60J3/02Antiglare equipment associated with windows or windscreens; Sun visors for vehicles adjustable in position
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Optical Filters (AREA)
  • Eyeglasses (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention provides a kind of eyeshield automotive sunshade panel eyeglass that can filter out harmful light, and the eyeglass includes: eyeglass matrix;It is coated on wear-resisting stiffening layer, antireflective coating, UV-absorbing layer and the X ray reflection film layer of the eyeglass matrix surface from the inside to the outside;The eyeglass matrix includes the ingredient of following parts by weight: isothiocyanates matrix: 10 ~ 20 parts, polymethyl methacrylate: 10 ~ 20 parts, diethylene glycol bis-allyl carbonate: 10 ~ 15 parts, nano-cerium oxide: 5 ~ 10 parts, methacryloxypropyl silane: 10 ~ 15 parts, carboxymethyl cellulose: 1 ~ 5 part, ultraviolet absorbing agent: 1 ~ 5 part, initiator: 1 ~ 5 part, antioxidant: 1 ~ 5 part.The sunshading board eyeglass cooperates the collocation of various film layers to use, can effectively mitigate visual fatigue, reduce strong illumination by designing special eyeglass matrix; mitigate solar radiation damage, protect driver's eyes, promotes degree of getting a clear view; it reduces dizziness to feel, protects eyes, promote drive safety.

Description

A kind of eyeshield automotive sunshade panel eyeglass filtering out harmful light
Technical field
The invention belongs to automotive sunshade panel lens technology fields, and in particular, to one kind can filter out the eyeshield vapour of harmful light Vehicle sunshading board eyeglass.
Background technique
Automotive sunshade panel is just mounted in driver and copilot above-head, for preventing the plank that the eyes are affected by the sunlight.? When can turn down can turn over up and down when not in use, left and right is turned over, that is, xy axis.
With the continuous improvement that client requires sunshading board, material aspect: plastics, EPP, PU foaming, cardboard etc. are multi-functional Sunshading board has with lamp, has with mirror.Conventional visor can no longer meet the demand of client.Though orthodox car sunshading board So can be with block sunlight, but occupy most of visual field of driver.With the development of science and technology, having had already appeared a kind of vapour at present Vehicle liquid crystal sun shield, it can block sunlight irradiation, and can not block vision.
Medical research shows that the Qiang Guanghui such as burning sun sunlight, vehicle body reflection and car light distance light seriously affect the vision health of eyes And driving safety.In driving for a long time, eyes are as often by strong light stimulus, being easy dim eyesight, causing asthenopia and spirit tight , and cause the diseases such as high pressure blood, gastric ulcer, and eyeball itself is also also easy to produce dry, swelling and pain and waits until lesion.According to investigations, have close 36% driver suffers from different degrees of ophthalmology disease.
Therefore, sunshading board eyeglass comes into being, and the protection to driver's eyes can be achieved in the use of eyeglass.
For automotive sunshade panel eyeglass, the current country is primarily present following patent document:
China Patent Publication No.: CN105061794A discloses a kind of eyeshield automobile adhesive film and preparation method thereof, eyeshield vapour Traffic allowance film includes release base layer;Thermal insulation layer is coated on the outer surface of release base layer;Uvioresistant layer is coated on thermal insulation layer Surface;Anti-blue light layer is coated on the inner surface of release base layer, wherein anti-blue light layer is by acrylate adhesive, levulinic Ketone, nanometer cobalt oxide, o-phenylenediamine, benzoyl peroxide, hexamethylphosphoramide and isocyanate curing agent composition;Anti- purple Outer anti-infrared layer, is coated on the surface of anti-blue light layer;Wearing layer is coated on the surface of UV resistance anti-infrared layer;Protective film layer with And installation glue-line, protective film layer are separably adhered to uvioresistant layer surface by installing glue-line.However, the patent is provided Vehicle protection eye patch, be attached at vehicle glass surface, sunshading board can not be suitable for.
Summary of the invention
Above-mentioned to solve the problems, such as, the purpose of the present invention is to provide the eyeshield automobile screenings that one kind can filter out harmful light Positive plate eyeglass, the sunshading board eyeglass cooperate the collocation of various film layers to use, can effectively subtract by designing special eyeglass matrix Light visual fatigue reduces strong illumination, mitigates solar radiation damage, protects driver's eyes, promote degree of getting a clear view, reduces dizzy It is dizzy to feel, eyes are protected, drive safety is promoted.
In order to achieve the above objectives, the technical scheme is that
A kind of eyeshield automotive sunshade panel eyeglass filtering out harmful light, the eyeglass includes: eyeglass matrix;It applies from the inside to the outside It is overlying on wear-resisting stiffening layer, antireflective coating, UV-absorbing layer and the X ray reflection film layer of the eyeglass matrix surface;The mirror Sheet matrix includes the ingredient of following parts by weight: isothiocyanates matrix: 10 ~ 20 parts, polymethyl methacrylate: and 10 ~ 20 parts, two Glycol diene propyl carbonate: 10 ~ 15 parts, nano-cerium oxide: 5 ~ 10 parts, methacryloxypropyl silane: 10 ~ 15 parts, carboxylic first Base cellulose: 1 ~ 5 part, ultraviolet absorbing agent: 1 ~ 5 part, initiator: 1 ~ 5 part, antioxidant: 1 ~ 5 part.
Further, the UV-absorbing layer is the absorbing membranous layer formed by ultraviolet absorbing agent.
Preferably, the X ray reflection film layer is indium tin oxide film layer.
Preferably, the antireflective coating includes the silicon dioxide layer set gradually from the bottom to top, titanium dioxide zirconium layer and oxidation Indium tin layer.
Preferably, the eyeglass matrix includes the ingredient of following parts by weight: isothiocyanates matrix: 15 ~ 20 parts, poly- methyl Methyl acrylate: 10 ~ 15 parts, diethylene glycol bis-allyl carbonate: 13 ~ 15 parts, nano-cerium oxide: 5 ~ 8 parts, methacryloxypropyl Base silane: 14 ~ 15 parts, carboxymethyl cellulose: 1 ~ 3 part, ultraviolet absorbing agent: 2 ~ 5 parts, initiator: 1 ~ 4 part, antioxidant: 1 ~ 4 parts.
Preferably, the eyeglass matrix includes the ingredient of following parts by weight: isothiocyanates matrix: 15 parts, poly- methyl-prop E pioic acid methyl ester: 13 parts, diethylene glycol bis-allyl carbonate: 14 parts, nano-cerium oxide: 7 parts, methacryloxypropyl silane: 14 Part, carboxymethyl cellulose: 2 parts, ultraviolet absorbing agent: 3 parts, initiator: 4 parts, antioxidant: 2 parts.
Preferably, the antioxidant is butylhydroxy anisole or 1,3,5- tri- (3,5- di-t-butyl -4- hydroxyl benzyls Base) isocyanuric acid.
Preferably, the initiator is azodiisobutyronitrile or di-isopropyl peroxydicarbonate IPP.
Preferably, the ultraviolet absorbing agent is septichen phenyl ester, Ultraviolet Absorber UV-P, ultraviolet radiation absorption Agent UV-O, ultraviolet absorbing agent UV-9, ultraviolet absorbent UV-531, ultraviolet absorbing agent UV-327 or ultraviolet absorbing agent RMB。
Preferably, the eyeglass matrix preparation method includes the following steps: to weigh isothiocyanates matrix, poly- first in proportion Base methyl acrylate, diethylene glycol bis-allyl carbonate, vinyl phenyl silicone oil, methacryloxypropyl silane, carboxymethyl are fine Dimension element and ultraviolet absorbing agent, are uniformly mixed, and then add antioxidant and initiator, sealing vacuum is stirred under the conditions of 30 ~ 40 DEG C It mixes uniformly, is poured into mold, thermoset forming, eyeglass is made in die sinking cleaning, then carries out 3 ~ 4 solidifications, is put in storage after the assay was approved.
The beneficial effects of the present invention are:
The sunshading board eyeglass cooperates the collocation of various film layers to use, can effectively subtract by designing special eyeglass matrix Light visual fatigue reduces strong illumination, mitigates solar radiation damage, protects driver's eyes, promote degree of getting a clear view, reduces dizzy It is dizzy to feel, eyes are protected, drive safety is promoted.
Detailed description of the invention
Fig. 1 is the structural schematic diagram for the eyeshield automotive sunshade panel eyeglass that one kind provided by the present invention can filter out harmful light.
Specific embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit protection of the invention Range.
Referring to Fig.1, one kind of the present invention can filter out the eyeshield automotive sunshade panel eyeglass of harmful light, the eyeglass packet It includes: eyeglass matrix 1;The wear-resisting stiffening layer 2 coated on 1 surface of eyeglass matrix, antireflective coating 3, ultraviolet light are inhaled from the inside to the outside Receive layer 4 and X ray reflection film layer 5;The eyeglass matrix 1 includes the ingredient of following parts by weight: isothiocyanates matrix: 10 ~ 20 Part, polymethyl methacrylate: 10 ~ 20 parts, diethylene glycol bis-allyl carbonate: 10 ~ 15 parts, nano-cerium oxide: 5 ~ 10 parts, first Base acryloxy silane: 10 ~ 15 parts, carboxymethyl cellulose: 1 ~ 5 part, ultraviolet absorbing agent: 1 ~ 5 part, initiator: 1 ~ 5 part, Antioxidant: 1 ~ 5 part.
Further, the UV-absorbing layer 4 is the absorbing membranous layer formed by ultraviolet absorbing agent.
Preferably, the X ray reflection film layer 5 is indium tin oxide film layer.
Preferably, the antireflective coating 3 includes the silicon dioxide layer (not shown) set gradually from the bottom to top, zirconium dioxide Layer (not shown) and indium tin oxide layer (not shown).
Preferably, the eyeglass matrix 1 includes the ingredient of following parts by weight: isothiocyanates matrix: 15 ~ 20 parts, poly- first Base methyl acrylate: 10 ~ 15 parts, diethylene glycol bis-allyl carbonate: 13 ~ 15 parts, nano-cerium oxide: 5 ~ 8 parts, methacryl Oxysilane: 14 ~ 15 parts, carboxymethyl cellulose: 1 ~ 3 part, ultraviolet absorbing agent: 2 ~ 5 parts, initiator: 1 ~ 4 part, antioxidant: 1 ~ 4 part.
Preferably, the eyeglass matrix 1 includes the ingredient of following parts by weight: isothiocyanates matrix: 15 parts, poly- methyl-prop E pioic acid methyl ester: 13 parts, diethylene glycol bis-allyl carbonate: 14 parts, nano-cerium oxide: 7 parts, methacryloxypropyl silane: 14 Part, carboxymethyl cellulose: 2 parts, ultraviolet absorbing agent: 3 parts, initiator: 4 parts, antioxidant: 2 parts.
Preferably, the antioxidant is butylhydroxy anisole or 1,3,5- tri- (3,5- di-t-butyl -4- hydroxyl benzyls Base) isocyanuric acid.
Preferably, the initiator is azodiisobutyronitrile or di-isopropyl peroxydicarbonate IPP.
Preferably, the ultraviolet absorbing agent is septichen phenyl ester, Ultraviolet Absorber UV-P, ultraviolet radiation absorption Agent UV-O, ultraviolet absorbing agent UV-9, ultraviolet absorbent UV-531, ultraviolet absorbing agent UV-327 or ultraviolet absorbing agent RMB。
Preferably, the eyeglass matrix preparation method includes the following steps: to weigh isothiocyanates matrix, poly- first in proportion Base methyl acrylate, diethylene glycol bis-allyl carbonate, vinyl phenyl silicone oil, methacryloxypropyl silane, carboxymethyl are fine Dimension element and ultraviolet absorbing agent, are uniformly mixed, and then add antioxidant and initiator, sealing vacuum is stirred under the conditions of 30 ~ 40 DEG C It mixes uniformly, is poured into mold, thermoset forming, eyeglass is made in die sinking cleaning, then carries out 3 ~ 4 solidifications, is put in storage after the assay was approved.
It should be noted that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although referring to compared with Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to the technology of invention Scheme is modified or replaced equivalently, and without departing from the range of technical solution of the present invention, should all be covered in power of the invention In sharp claimed range.

Claims (7)

1. the eyeshield automotive sunshade panel eyeglass that one kind can filter out harmful light, which is characterized in that the eyeglass includes:
Eyeglass matrix;
The wear-resisting stiffening layer coated on the eyeglass matrix surface, antireflective coating, UV-absorbing layer and X-ray are anti-from the inside to the outside Penetrate film layer;
The eyeglass matrix includes the ingredient of following parts by weight: isothiocyanates matrix: 10 ~ 20 parts, polymethyl methacrylate: 10 ~ 20 parts, diethylene glycol bis-allyl carbonate: 10 ~ 15 parts, nano-cerium oxide: 5 ~ 10 parts, methacryloxypropyl silane: 10 ~ 15 parts, carboxymethyl cellulose: 1 ~ 5 part, ultraviolet absorbing agent: 1 ~ 5 part, initiator: 1 ~ 5 part, antioxidant: 1 ~ 5 part;
The UV-absorbing layer is the absorbing membranous layer formed by ultraviolet absorbing agent;
The X ray reflection film layer is indium tin oxide film layer;
The antireflective coating includes the silicon dioxide layer set gradually from the bottom to top, titanium dioxide zirconium layer and indium tin oxide layer.
2. the eyeshield automotive sunshade panel eyeglass that one kind according to claim 1 can filter out harmful light, which is characterized in that described Eyeglass matrix includes the ingredient of following parts by weight: isothiocyanates matrix: 15 ~ 20 parts, polymethyl methacrylate: and 10 ~ 15 parts, Diethylene glycol bis-allyl carbonate: 13 ~ 15 parts, nano-cerium oxide: 5 ~ 8 parts, methacryloxypropyl silane: 14 ~ 15 parts, carboxylic first Base cellulose: 1 ~ 3 part, ultraviolet absorbing agent: 2 ~ 5 parts, initiator: 1 ~ 4 part, antioxidant: 1 ~ 4 part.
3. the eyeshield automotive sunshade panel eyeglass that one kind according to claim 1 can filter out harmful light, which is characterized in that described Eyeglass matrix includes the ingredient of following parts by weight: isothiocyanates matrix: 15 parts, polymethyl methacrylate: and 13 parts, diethylene glycol (DEG) Diene propyl carbonate: 14 parts, nano-cerium oxide: 7 parts, methacryloxypropyl silane: 14 parts, carboxymethyl cellulose: 2 parts, Ultraviolet absorbing agent: 3 parts, initiator: 4 parts, antioxidant: 2 parts.
4. one kind according to claim 1 or 2 or 3 can filter out the eyeshield automotive sunshade panel eyeglass of harmful light, feature exists In the antioxidant is butylhydroxy anisole or 1,3,5- tri- (3,5- di-tert-butyl-4-hydroxyl benzyl) isocyanuric acids.
5. one kind according to claim 1 or 2 or 3 can filter out the eyeshield automotive sunshade panel eyeglass of harmful light, feature exists In the initiator is azodiisobutyronitrile or di-isopropyl peroxydicarbonate IPP.
6. one kind according to claim 1 or 2 or 3 can filter out the eyeshield automotive sunshade panel eyeglass of harmful light, feature exists In, the ultraviolet absorbing agent be septichen phenyl ester, it is Ultraviolet Absorber UV-P, ultraviolet absorbing agent UV-O, ultraviolet Light absorbers UV-9, ultraviolet absorbent UV-531, ultraviolet absorbing agent UV-327 or ultraviolet absorbing agent RMB.
7. one kind according to claim 1 or 2 or 3 can filter out the eyeshield automotive sunshade panel eyeglass of harmful light, feature exists In the eyeglass matrix preparation method includes the following steps: to weigh isothiocyanates matrix, poly-methyl methacrylate in proportion Ester, diethylene glycol bis-allyl carbonate, vinyl phenyl silicone oil, methacryloxypropyl silane, carboxymethyl cellulose and ultraviolet Light absorbers are uniformly mixed, and then add antioxidant and initiator, sealing is stirred under vacuum uniformly casting under the conditions of 30 ~ 40 DEG C Enter mold, thermoset forming, eyeglass is made in die sinking cleaning, then carries out 3 ~ 4 solidifications, is put in storage after the assay was approved.
CN201710519124.4A 2017-06-30 2017-06-30 A kind of eyeshield automotive sunshade panel eyeglass filtering out harmful light Active CN107229090B (en)

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CN113835141A (en) * 2021-11-08 2021-12-24 厦门谨德光电科技有限公司 Fade-proof ultraviolet-resistant sunglasses lens

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CN106483585A (en) * 2015-08-26 2017-03-08 江苏凯越眼镜有限公司 A kind of novel resin lenses
CN106483587A (en) * 2015-09-01 2017-03-08 江苏凯越眼镜有限公司 A kind of ultralight resin lens and preparation method thereof
CN106749800B (en) * 2016-12-13 2019-03-08 江苏康耐特光学有限公司 A kind of preparation method of resistant to thermal aging resin lens
CN106674852B (en) * 2016-12-23 2019-03-15 合肥炜烨光学科技有限公司 A kind of anti-blue light eyeglass and its resin raw material

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