CN107153227A - A kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight - Google Patents

A kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight Download PDF

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Publication number
CN107153227A
CN107153227A CN201710519123.XA CN201710519123A CN107153227A CN 107153227 A CN107153227 A CN 107153227A CN 201710519123 A CN201710519123 A CN 201710519123A CN 107153227 A CN107153227 A CN 107153227A
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CN
China
Prior art keywords
parts
eyeglass
antifouling
uvioresistant
matrix
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201710519123.XA
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Chinese (zh)
Inventor
杨晓燕
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Suzhou Xin River Mirror Co Ltd
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Suzhou Xin River Mirror Co Ltd
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Priority to CN201710519123.XA priority Critical patent/CN107153227A/en
Publication of CN107153227A publication Critical patent/CN107153227A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/16Optical coatings produced by application to, or surface treatment of, optical elements having an anti-static effect, e.g. electrically conducting coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/11Anti-reflection coatings
    • G02B1/113Anti-reflection coatings using inorganic layer materials only
    • G02B1/115Multilayers
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Optical Elements (AREA)

Abstract

The present invention provides a kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight, and the eyeglass includes:Eyeglass matrix;Wear-resisting stiffening layer, antireflective coating, UV-absorbing layer, X ray reflection film layer and the antifouling plated film film layer of the eyeglass matrix surface are coated on from the inside to the outside;The UV-absorbing layer is the film layer formed by ultra-violet absorber.The sunshading board eyeglass eyeglass matrix special by designing; the collocation of various film layers is coordinated to use; visual fatigue can effectively be mitigated, damage of the ultraviolet to human eye is reduced, reduce strong illumination; mitigate solar radiation damage; driver's eyes are protected, degree of getting a clear view is lifted, reduction dizziness is felt; protect eyes, lift drive safety.

Description

A kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight
Technical field
The invention belongs to automotive sunshade panel technical field, in particular it relates to a kind of antifouling uvioresistant automobile sun-shading of lightweight Plate eyeglass.
Background technology
Automotive sunshade panel, is just mounted in driver and copilot above-head, for preventing the plank that the eyes are affected by the sunlight. When can turn down come without when can up and down turn over, left and right is turned over, that is, xy axles.
With the continuous improvement that client is required sunshading board, material aspect:Plastics, EPP, PU foaming, cardboard etc., it is multi-functional Sunshading board, has with lamp, has with mirror.Conventional visor can not meet the demand of client.Though orthodox car sunshading board So can be with block sunlight, but occupy most of visual field of driver.With the development of science and technology, having occurred in that a kind of vapour at present Car liquid crystal sun shield, it is can be with the irradiation of block sunlight, again can not block vision.
Medical research shows that the strong light such as burning sun sunlight, vehicle body reflection and car light distance light can have a strong impact on the vision health of eyes And driving safety.In prolonged drive, eyes are as often by strong light stimulus, and easy dim eyesight causes kopiopia and spirit tight , and trigger the diseases such as high pressure blood, gastric ulcer, and eyeball is also also easy to produce and dries, swells and ache when lesion in itself.According to investigations, have near 36% driver suffers from different degrees of ophthalmology disease.
Therefore, sunshading board eyeglass arises at the historic moment, and the protection to driver's eyes can be achieved in the use of eyeglass.
For automotive sunshade panel eyeglass, the current country is primarily present following patent document:
China Patent Publication No.:CN206057621U, discloses a kind of energy anti-infrared, the welding eye protection shading composite mirrors of ultraviolet light Piece, its structure at least includes two layers:Eyeglass A and eyeglass B, wherein eyeglass A are black welding goggles piece, and eyeglass B is optical filtering Piece, the eyeglass A and eyeglass B form the complex optics of AB or BA structures by being superimposed or bonding;The filter glass is vacuum Metal-coated membrane glass, or nanocomposite optical filter is made by CR39 resins or KOC resins.This welding eye protection composite mirrors Piece, effectively can not only suppress to ultraviolet and infrared harmful light, and the parameter such as the thickness by adjusting film layer, can be with Inhibition level to the transmission region of product, light transmittance and for harmful light is adjusted, and can thus meet different fields The need for conjunction, it can more thoroughly stop injury of the ultraviolet and infrared harmful light to human eye, be the works such as steel-making, boiler and welding People and the preferable eye protection instrument of field man.However, the eye protection shading complex optics that the patent is provided, it is adaptable to weld The protection of strong light in termination process, rather than the protection during running to other side's car light and daylight.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of antifouling uvioresistant automobile sun-shading of lightweight Plate eyeglass, the sunshading board eyeglass eyeglass matrix special by designing coordinates the collocation of various film layers to use, can effectively mitigated Visual fatigue, reduces damage of the ultraviolet to human eye, reduces strong illumination, mitigates solar radiation damage, protects driver's eyes, Degree of getting a clear view is lifted, reduction dizziness feels that protect eyes lift drive safety.
To reach above-mentioned purpose, the technical scheme is that:
A kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight, the eyeglass includes:Eyeglass matrix;Institute is coated on from the inside to the outside State wear-resisting stiffening layer, antireflective coating, UV-absorbing layer, X ray reflection film layer and the antifouling plated film film layer of eyeglass matrix surface; The UV-absorbing layer is the film layer formed by ultra-violet absorber;The eyeglass matrix includes the composition of following parts by weight: Isothiocyanates matrix:10 ~ 20 parts, polymethyl methacrylate:10 ~ 20 parts, diethylene glycol bis-allyl carbonate:10 ~ 15 parts, Nano-cerium oxide:5 ~ 10 parts, methacryloxypropyl silane:10 ~ 15 parts, carboxymethyl cellulose:1 ~ 5 part, ultra-violet absorber: 1 ~ 5 part, initiator:1 ~ 5 part, antioxidant:1 ~ 5 part.
Further, the antifouling plated film film layer is fluoride layer.
Preferably, the X ray reflection film is indium tin oxide film layer.
Preferably, the antireflective coating includes silicon dioxide layer, titanium dioxide zirconium layer and the oxidation set gradually from the bottom to top Indium tin layer.
Preferably, the eyeglass matrix includes the composition of following parts by weight:Isothiocyanates matrix:10 ~ 15 parts, poly- methyl Methyl acrylate:15 ~ 20 parts, diethylene glycol bis-allyl carbonate:10 ~ 13 parts, nano-cerium oxide:6 ~ 10 parts, methacryl TMOS:12 ~ 15 parts, carboxymethyl cellulose:1 ~ 3 part, ultra-violet absorber:3 ~ 5 parts, initiator:1 ~ 4 part, antioxidant: 2 ~ 5 parts.
Preferably, the eyeglass matrix includes the composition of following parts by weight:Isothiocyanates matrix:15 parts, poly- methyl-prop E pioic acid methyl ester:15 parts, diethylene glycol bis-allyl carbonate:13 parts, nano-cerium oxide:7 parts, methacryloxypropyl silane:14 Part, carboxymethyl cellulose:2 parts, ultra-violet absorber:4 parts, initiator:3 parts, antioxidant:2 parts.
Preferably, the antioxidant is butylhydroxy anisole or 1,3,5- tri- (3,5- di-t-butyl -4- hydroxyl benzyls Base) isocyanuric acid.
Preferably, the initiator is azodiisobutyronitrile or di-isopropyl peroxydicarbonate IPP.
Preferably, the ultra-violet absorber is the 2-2 ˊ-ˊ of hydroxyl-5-aminomethyl phenyl.
Preferably, the eyeglass matrix preparation method comprises the following steps:Isothiocyanates matrix, poly- first are weighed in proportion Base methyl acrylate, diethylene glycol bis-allyl carbonate, nano-cerium oxide, methacryloxypropyl silane, carboxymethyl cellulose And ultra-violet absorber, it is well mixed, sealing is stirred under vacuum under the conditions of then adding antioxidant and initiator, 30 ~ 40 DEG C It is even, mould is poured into, eyeglass is made in thermoset forming, die sinking cleaning, then carries out 3 ~ 4 solidifications, is put in storage after the assay was approved.
The beneficial effects of the present invention are:
The sunshading board eyeglass eyeglass matrix special by designing, coordinates the collocation of various film layers to use, can effectively mitigate and regard Feel fatigue, reduce damage of the ultraviolet to human eye, reduce strong illumination, mitigate solar radiation damage, protect driver's eyes, carry Degree of getting a clear view is risen, reduction dizziness feels that protect eyes lift drive safety.
Brief description of the drawings
Fig. 1 is a kind of structural representation of the antifouling uvioresistant automotive sunshade panel eyeglass of lightweight provided by the present invention.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention Scope.
A kind of reference picture 1, antifouling uvioresistant automotive sunshade panel eyeglass of lightweight of the present invention, the eyeglass includes: Eyeglass matrix 1;The wear-resisting stiffening layer 2 on the surface of eyeglass matrix 1, antireflective coating 3, UV-absorbing layer are coated on from the inside to the outside 4th, X ray reflection film layer 5 and antifouling plated film film layer 6;The UV-absorbing layer 4 is the film layer formed by ultra-violet absorber; The eyeglass matrix 1 includes the composition of following parts by weight:Isothiocyanates matrix:10 ~ 20 parts, polymethyl methacrylate:10~ 20 parts, diethylene glycol bis-allyl carbonate:10 ~ 15 parts, nano-cerium oxide:5 ~ 10 parts, methacryloxypropyl silane:10~15 Part, carboxymethyl cellulose:1 ~ 5 part, ultra-violet absorber:1 ~ 5 part, initiator:1 ~ 5 part, antioxidant:1 ~ 5 part.
Further, the antifouling plated film film layer 6 is fluoride layer.
Preferably, the X ray reflection film 5 is indium tin oxide film layer.
Preferably, the antireflective coating 3 includes the silicon dioxide layer set gradually from the bottom to top(It is not shown), zirconium dioxide Layer(It is not shown)And indium tin oxide layer(It is not shown).
Preferably, the eyeglass matrix includes the composition of following parts by weight:Isothiocyanates matrix:10 ~ 15 parts, poly- methyl Methyl acrylate:15 ~ 20 parts, diethylene glycol bis-allyl carbonate:10 ~ 13 parts, nano-cerium oxide:6 ~ 10 parts, methacryl TMOS:12 ~ 15 parts, carboxymethyl cellulose:1 ~ 3 part, ultra-violet absorber:3 ~ 5 parts, initiator:1 ~ 4 part, antioxidant: 2 ~ 5 parts.
Preferably, the eyeglass matrix includes the composition of following parts by weight:Isothiocyanates matrix:15 parts, poly- methyl-prop E pioic acid methyl ester:15 parts, diethylene glycol bis-allyl carbonate:13 parts, nano-cerium oxide:7 parts, methacryloxypropyl silane:14 Part, carboxymethyl cellulose:2 parts, ultra-violet absorber:4 parts, initiator:3 parts, antioxidant:2 parts.
Preferably, the antioxidant is butylhydroxy anisole or 1,3,5- tri- (3,5- di-t-butyl -4- hydroxyl benzyls Base) isocyanuric acid.
Preferably, the initiator is azodiisobutyronitrile or di-isopropyl peroxydicarbonate IPP.
Preferably, the ultra-violet absorber is the 2-2 ˊ-ˊ of hydroxyl-5-aminomethyl phenyl.
Preferably, the eyeglass matrix preparation method comprises the following steps:Isothiocyanates matrix, poly- first are weighed in proportion Base methyl acrylate, diethylene glycol bis-allyl carbonate, nano-cerium oxide, methacryloxypropyl silane, carboxymethyl cellulose And ultra-violet absorber, it is well mixed, sealing is stirred under vacuum under the conditions of then adding antioxidant and initiator, 30 ~ 40 DEG C It is even, mould is poured into, eyeglass is made in thermoset forming, die sinking cleaning, then carries out 3 ~ 4 solidifications, is put in storage after the assay was approved.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention In sharp claimed range.

Claims (10)

1. a kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight, it is characterised in that the eyeglass includes:
Eyeglass matrix;
Wear-resisting stiffening layer, antireflective coating, UV-absorbing layer, the X-ray for being coated on the eyeglass matrix surface from the inside to the outside are anti- Penetrate film layer and antifouling plated film film layer;
The UV-absorbing layer is the film layer formed by ultra-violet absorber;
The eyeglass matrix includes the composition of following parts by weight:Isothiocyanates matrix:10 ~ 20 parts, polymethyl methacrylate: 10 ~ 20 parts, diethylene glycol bis-allyl carbonate:10 ~ 15 parts, nano-cerium oxide:5 ~ 10 parts, methacryloxypropyl silane:10~ 15 parts, carboxymethyl cellulose:1 ~ 5 part, ultra-violet absorber:1 ~ 5 part, initiator:1 ~ 5 part, antioxidant:1 ~ 5 part.
2. the antifouling uvioresistant automotive sunshade panel eyeglass of a kind of lightweight according to claim 1, it is characterised in that described anti- Dirty plated film film layer is fluoride layer.
3. a kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight according to claim 1, it is characterised in that the X Ray reflectance coating is indium tin oxide film layer.
4. a kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight according to claim 1, it is characterised in that the increasing Permeable membrane layer includes silicon dioxide layer, titanium dioxide zirconium layer and the indium tin oxide layer set gradually from the bottom to top.
5. a kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight according to claim 1, it is characterised in that the mirror Sheet matrix includes the composition of following parts by weight:Isothiocyanates matrix:10 ~ 15 parts, polymethyl methacrylate:15 ~ 20 parts, two Glycol diene propyl carbonate:10 ~ 13 parts, nano-cerium oxide:6 ~ 10 parts, methacryloxypropyl silane:12 ~ 15 parts, carboxylic first Base cellulose:1 ~ 3 part, ultra-violet absorber:3 ~ 5 parts, initiator:1 ~ 4 part, antioxidant:2 ~ 5 parts.
6. a kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight according to claim 1, it is characterised in that the mirror Sheet matrix includes the composition of following parts by weight:Isothiocyanates matrix:15 parts, polymethyl methacrylate:15 parts, diethylene glycol (DEG) is double Allyl carbonate:13 parts, nano-cerium oxide:7 parts, methacryloxypropyl silane:14 parts, carboxymethyl cellulose:It is 2 parts, purple Ultraviolet absorbers:4 parts, initiator:3 parts, antioxidant:2 parts.
7. the antifouling uvioresistant automotive sunshade panel eyeglass of a kind of lightweight according to claim 1 or 5 or 6, it is characterised in that The antioxidant is butylhydroxy anisole or 1,3,5- tri- (3,5- di-tert-butyl-4-hydroxyl benzyls) isocyanuric acid.
8. the antifouling uvioresistant automotive sunshade panel eyeglass of a kind of lightweight according to claim 1 or 5 or 6, it is characterised in that The initiator is azodiisobutyronitrile or di-isopropyl peroxydicarbonate IPP.
9. the antifouling uvioresistant automotive sunshade panel eyeglass of a kind of lightweight according to claim 1 or 5 or 6, it is characterised in that The ultra-violet absorber is the 2-2 ˊ-ˊ of hydroxyl-5-aminomethyl phenyl.
10. a kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight according to claim 1 or 5 or 6, its feature exists In the eyeglass matrix preparation method comprises the following steps:Isothiocyanates matrix, poly-methyl methacrylate are weighed in proportion Ester, diethylene glycol bis-allyl carbonate, nano-cerium oxide, methacryloxypropyl silane, carboxymethyl cellulose and ultraviolet are inhaled Agent is received, is well mixed, sealing vacuum stirring is uniform under the conditions of then adding antioxidant and initiator, 30 ~ 40 DEG C, is poured into mould Eyeglass is made in tool, thermoset forming, die sinking cleaning, then carries out 3 ~ 4 solidifications, is put in storage after the assay was approved.
CN201710519123.XA 2017-06-30 2017-06-30 A kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight Pending CN107153227A (en)

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CN201710519123.XA CN107153227A (en) 2017-06-30 2017-06-30 A kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight

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CN201710519123.XA CN107153227A (en) 2017-06-30 2017-06-30 A kind of antifouling uvioresistant automotive sunshade panel eyeglass of lightweight

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203995582U (en) * 2014-07-22 2014-12-10 李传领 Automobile anti-dazzle sunshade mirror
CN106483587A (en) * 2015-09-01 2017-03-08 江苏凯越眼镜有限公司 A kind of ultralight resin lens and preparation method thereof
CN106483585A (en) * 2015-08-26 2017-03-08 江苏凯越眼镜有限公司 A kind of novel resin lenses
CN106674852A (en) * 2016-12-23 2017-05-17 合肥炜烨光学科技有限公司 Blue-ray-proof lens and resin raw material thereof
CN106749800A (en) * 2016-12-13 2017-05-31 江苏康耐特光学有限公司 A kind of preparation method of resistant to thermal aging resin lens

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN203995582U (en) * 2014-07-22 2014-12-10 李传领 Automobile anti-dazzle sunshade mirror
CN106483585A (en) * 2015-08-26 2017-03-08 江苏凯越眼镜有限公司 A kind of novel resin lenses
CN106483587A (en) * 2015-09-01 2017-03-08 江苏凯越眼镜有限公司 A kind of ultralight resin lens and preparation method thereof
CN106749800A (en) * 2016-12-13 2017-05-31 江苏康耐特光学有限公司 A kind of preparation method of resistant to thermal aging resin lens
CN106674852A (en) * 2016-12-23 2017-05-17 合肥炜烨光学科技有限公司 Blue-ray-proof lens and resin raw material thereof

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Application publication date: 20170912