CN107227558A - The manufacture method of sheeted film substrates, laminar film and sheeted film substrates - Google Patents
The manufacture method of sheeted film substrates, laminar film and sheeted film substrates Download PDFInfo
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- CN107227558A CN107227558A CN201610685875.9A CN201610685875A CN107227558A CN 107227558 A CN107227558 A CN 107227558A CN 201610685875 A CN201610685875 A CN 201610685875A CN 107227558 A CN107227558 A CN 107227558A
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- layers
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- sheeted
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- nanofibers
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
- D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Textile Engineering (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dermatology (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Nonwoven Fabrics (AREA)
Abstract
It is an object of the invention to provide the manufacture method of sheeted film substrates, laminar film and sheeted film substrates, the sheeted film substrates result in higher cosmetic result, and can obtain higher spiritual satisfaction.With the layers of nanofibers (20) formed by nanofiber (22), evaporation has golden (24) in layers of nanofibers (20).In addition, layers of nanofibers (20) formation is in the one side of flake reinforcement material layer (10), golden (24) are in the state on covering nanofiber (22) surface.In addition, the thickness of golden (24) is preferably in 1nm~100nm scope, nanofiber (22) is preferably formed by hydrophilic polymer.
Description
Technical field
The present invention relates to the manufacture method of a kind of laminar film (pack) base material, laminar film and sheeted film substrates.
Background technology
Conventionally, there is known the laminar film (for example, facial mask) with layers of reinforcement and layers of nanofibers is (for example, with reference to special
Sharp document 1 is Japanese Unexamined Patent Publication 2007-070347 publications).
Figure 12 is the figure in order to illustrate conventional laminar film 900 and represent.Figure 12 (a) is conventional laminar film 900
Side cross-sectional view, Figure 12 (b) is the enlarged drawing of the part surrounded in Figure 12 (a) by dotted line A.
As shown in figure 12, conventional laminar film 900 has in the base material (layers of reinforcement) formed by hydrophilic fibre 912
The structure of the layers of nanofibers 920 formed by Hydrophilic Nanofibrous 922 is formed with 910 one side.In conventional laminar film
In 900, contain in layers of nanofibers 920 and be soaked with skin lotion or beautifying liquid.
Therefore, can by by conventional laminar film 900 such as applying in face on using obtaining higher cosmetic result.
That is, conventional laminar film 900 is small due to the fibre diameter of nanofiber 922, therefore the readily permeable skin that arrives of nanofiber 922
In microflute, and it is excellent with the close property of skin.Thus, it is easy containing the skin lotion or beautifying liquid being immersed in layers of nanofibers 920
In being penetrated to the skin by nanofiber appearance.
In addition, conventional laminar film 900 is small due to the fibre diameter of nanofiber 922, therefore the shape between nanofiber
Into hole spatial volume it is big.Therefore, it is possible to be easy in the hole keep skin lotion or beautifying liquid, and it can make big
The toner or beautifying liquid of amount, which contain, to be immersed in layers of nanofibers.As a result, conventional laminar film 90 can keep beauty for a long time
Effect and moistening effect, are derived from higher cosmetic result.
Patent document
Patent document 1：Japanese Laid-Open Patent JP 2007-70347 publications
The content of the invention
Problem to be solved
For this laminar film, it is important that not only to obtain higher cosmetic result, also to obtain spiritual
Satisfaction.Therefore it is required that a kind of result in the cosmetic result higher than conventional laminar film, and it can obtain spiritual full
The laminar film of foot sense.
The present invention is to propose in view of the foregoing, the purpose is to provide a kind of sheeted film substrates, the sheeted film substrates
It can manufacture and result in higher cosmetic result compared with conventional laminar film, and the piece of spiritual satisfaction can be obtained
Shape film.Moreover, it is an object that a kind of laminar film, the laminar film is manufactured using the sheeted film substrates of the present invention
, therefore, it is possible to obtain higher cosmetic result compared with conventional laminar film, and spiritual satisfaction can be obtained.This
Outside, it is an object of the invention to provide a kind of manufacture method of sheeted film substrates, this method can effectively manufacture the piece of the present invention
Shape film base material.
The method for solving problem
[1] sheeted film substrates of the invention are characterised by, described to receive with the layers of nanofibers formed by nanofiber
Rice fibrous layer includes gold.
In addition, the gold used in the present invention is preferably high-purity (for example, more than 99.99%) gold.
[2] in the sheeted film substrates of the present invention, the layers of nanofibers is preferably formed in the one of flake reinforcement material layer
On face.
[3] in the sheeted film substrates of the present invention, the flake reinforcement material layer is preferably more than described receive by fibre diameter
The fiber of the fibre diameter of rice fiber is formed.
Therefore, it is possible to improve the intensity of sheeted film substrates.Thereby, it is possible to easily operated sheeted film substrates, and in manufacture
When (mould processing etc.) is processed during laminar film, processing is readily able to, and can effectively manufacture laminar film.
[4] in the sheeted film substrates of the present invention, the gold is preferably in the state on the surface for covering the nanofiber.
[5] in the sheeted film substrates of the present invention, the gold is preferably deposited with the state being comprised in the nanofiber
.
In this way, due to while gold is present in inside nanofiber to exist exposed to the state of nanofiber surface, when
The laminar film manufactured by the sheeted film substrates is applied in skin, the close property of gold and skin, golden composition pair can be more improved
The permeability of skin becomes good, improves effect of the gold to skin.
[6] in the sheeted film substrates of the present invention, the nanofiber is preferably formed by hydrophilic polymer.
By forming nanofiber by hydrophilic polymer, the laminar film manufactured using the sheeted film substrates, which is easy to contain, to macerate
Adornment water or beautifying liquid etc..
[7] laminar film of the invention is characterised by, using the sheeted film substrates described in any one of [1]~[6] come
Manufacture.
[8] in the film of the sheet of the present invention, the laminar film is preferably to apply the surface application laminar film using on the face.
In this way, because laminar film is to apply the surface application laminar film using on the face, therefore for beautifying face effect,
Higher cosmetic result compared with conventional laminar film is resulted in, and then is gilded because being tightened in face, is resulted in mentally
Satisfaction.
[9] manufacture method of sheeted film substrates of the invention, it is characterised in that formed for manufacturing by nanofiber
The sheeted film substrates of gold are included in layers of nanofibers, including：Prepare the work of the polymer solution as the nanofiber raw material
Sequence；By the electrostatic spinning process that the layers of nanofibers is formed to polymer solution progress electrostatic spinning；And institute
State the gold evaporation process of gold evaporation in layers of nanofibers.
According to the manufacture method of the sheeted film substrates of the present invention, the sheeted film substrates described in [1] can be manufactured.
[10] manufacture method of sheeted film substrates of the invention, for manufacturing in the layers of nanofibers formed by nanofiber
In comprising gold sheeted film substrates, it is characterised in that including：Prepare in the polymer solution as the nanofiber raw material
It is dispersed with the process of the golden dispersing polymer solution of gold particle；And by carrying out electrostatic spinning to the golden dispersing polymer solution
And form the electrostatic spinning process of the layers of nanofibers.
According to the manufacture method of the sheeted film substrates of the present invention, the sheeted film substrates described in [1] can be also manufactured.
Invention effect
According to the sheeted film substrates of the present invention, due to including gold in layers of nanofibers, therefore by using the present invention's
Sheeted film substrates, can produce and result in higher cosmetic result compared with conventional laminar film and result in mentally
Satisfaction laminar film.
Due to there is layers of reinforcement in the sheeted film substrates of the present invention, therefore with a certain degree of thickness and by force
Degree., can therefore, it is possible to easily operated sheeted film substrates, and when being processed (mould processing etc.) when manufacturing laminar film
It is easy to process, and can effectively manufacture laminar film.
Further, since state of the gold in covering nanofiber surface, when the laminar film that will be manufactured by the sheeted film substrates
When applying on skin, the close property of gold and skin can be more improved, golden composition becomes good to the permeability of skin, improve gold
To the effect of skin.
According to the laminar film of the present invention, used by the way that the laminar film is applied in skin etc., golden composition is penetrated to the skin
In, therefore higher cosmetic result compared with conventional laminar film can not only be obtained, and result in spiritual satisfaction
Sense.That is, in beauty treatment fields, the efficiency of gold was emphasized in many ways always in the past.If for example, it is believed that golden composition infiltration
In skin, with regard to Skin Cell can be activated, thus promote the metabolism of Skin Cell, moisturizing and elastic force are assigned to skin, and
The function that the waste that will be generated on subcutaneous cell or corium is discharged to outside can be improved.Moreover it is possible to bring because that will cover
The sheeted film substrates for having gold apply on skin and obtained the effect of spiritual satisfaction etc..
Brief description of the drawings
Fig. 1 is the figure in order to illustrate the sheeted film substrates 1A of embodiment 1 and represent；
Fig. 2 is the flow chart in order to illustrate the sheeted film substrates 1A of embodiment 1 manufacturing process and represent；
Fig. 3 is the figure for schematically showing electrostatic spinning process S2 and gold evaporation process S3 in each operation shown in Fig. 2；
Fig. 4 is the figure for the sheeted film substrates manufacture device 100A structures for schematically showing embodiment 1；
Fig. 5 is the figure in order to illustrate one of the laminar film 50 of embodiment 1 and represent；
Fig. 6 is the figure of the variation for the sheeted film substrates manufacture device 100A for schematically showing embodiment 1；
Fig. 7 is the figure in order to illustrate the sheeted film substrates 1B of embodiment 2 and represent；
Fig. 8 is the flow chart in order to illustrate the sheeted film substrates 1B of embodiment 2 manufacturing process and represent；
Fig. 9 is the figure for the sheeted film substrates manufacture device 100B structures for schematically showing embodiment 2；
Figure 10 is the flow chart in order to illustrate the sheeted film substrates 1C of embodiment 3 manufacturing process and represent；
Figure 11 is the figure for the sheeted film substrates manufacture device 100C structures for schematically showing embodiment 3；
Figure 12 is the figure in order to illustrate conventional laminar film 900 and represent.
Description of reference numerals
1A, 1B, 1C... piece state film base material
10... layers of reinforcement
12... fiber
20... layers of nanofibers
22... nanofiber
24... it is golden
30... layered product
50... laminar film
51... (eye) opening portion
52... (mouth) opening portion
53... otch
100A, 100B, 100C... sheeted film substrates manufacture device
110A, 110B... electrostatic spinning apparatus
111... polymer solution
111a... gold dispersing polymer solutions
112... head tank
113rd, 121... feed rollers
114... valve
115... nozzle
116... collector
117... high voltage power supply
118th, 125,135... takers-ins
119th, 126,136... conveying rollers
120A, 120B... gold evaporation coating device
122nd, 132... vacuum evaporations room
123rd, 133... vacuum deposition apparatus
124th, 134... chill rolls
127... vapor deposition treatment room
128... golden steam
129... barricade
200a... the first gold medal deposition units
200b... the second gold medal deposition units
Embodiment
Below, embodiments of the present invention are illustrated.
[embodiment 1]
Fig. 1 is the figure in order to illustrate the sheeted film substrates 1A of embodiment 1 and represent.Fig. 1 (a) is the piece of embodiment 1
Shape film base material 1A side cross-sectional view, Fig. 1 (b) be Fig. 1 (a) in by the dotted line A parts surrounded enlarged drawing, Fig. 1 (c) be Fig. 1 (b)
A-a line sectional views.
As shown in figure 1, the sheeted film substrates 1A of embodiment 1 has in the flake reinforcement material formed by hydrophilic fibre 12
The structure of the layers of nanofibers 20 formed by Hydrophilic Nanofibrous 22 is formed with the one side of the bed of material 10.In addition, embodiment 1
Sheeted film substrates 1A in layers of nanofibers 20 comprising gold 24.In addition, by the increasing in the sheeted film substrates 1A of embodiment 1
The state that layers of nanofibers 20 is formed with the one side of strong material layer 10 is referred to as " layered product 30 ".
In the sheeted film substrates 1A so constituted, formed the fiber 12 of layers of reinforcement 10 by fibre diameter be 1 μm~
100 μm of hydrophilic fibre is formed, formed the nanofiber 22 of layers of nanofibers 20 by fibre diameter receiving for 50nm~300nm
Rice fiber is formed, and layers of reinforcement 10 and layers of nanofibers 20 take non-woven fabrics form respectively.In addition, the thickness of layers of nanofibers 20
Degree for example can be in 1 μm~100 μm of scope.
In addition, in the sheeted film substrates 1A of embodiment 1, by layers of nanofibers 20 gold evaporation 24 manufacture
The sheeted film substrates 1A of gold 24 is included in layers of nanofibers 20.By the gold evaporation 24 in layers of nanofibers 20, so that as shape
State covered with gold on into the surface of each nanofiber 22 of layers of nanofibers 20.In addition, in Fig. 1 (a), layers of nanofibers
20 display grey are that the state for having gold 24 is deposited.In addition, gold 24 preferably has high-purity (for example, more than 99.99%).
Fig. 2 is to illustrate the sheeted film substrates 1A of embodiment 1 manufacturing process's (sheeted film substrates of embodiment 1
Manufacture method) and represent flow chart.As shown in Fig. 2 the manufacture method of the sheeted film substrates of embodiment 1 includes：Prepare
It is used as process (preparatory process of polymer solution) S1 of the polymer solution of the raw material of nanofiber 22；Polymer solution is carried out
Electrostatic spinning and the electrostatic spinning process S2 for forming layers of nanofibers；And process is deposited in the gold of gold evaporation in layers of nanofibers 20
S3。
Fig. 3 is the figure for schematically showing electrostatic spinning process S2 and gold evaporation process S3 in each operation shown in Fig. 2.
First, electrostatic spinning is carried out to the polymer solution of the preparatory process S1 preparations by polymer solution, so that with flexibility
Flake reinforcement material layer 10 one side on form layers of nanofibers 20.It can so manufacture as Fig. 3 (a) in reinforcing material
The layered product 30 of layers of nanofibers 20 is formed with the one side of layer 10.Next, the table of the layers of nanofibers 20 in layered product 30
Gold evaporation 24 on surface side.The sheeted film substrates for including gold in layers of nanofibers 20 as Fig. 3 (b) can so be manufactured
1A.In addition, Fig. 3 (b) is identical with Fig. 1 (a).
Fig. 4 is the figure for the sheeted film substrates manufacture device 100A structures for schematically showing embodiment 1.Embodiment 1
Sheeted film substrates manufacture device 100A be made up of electrostatic spinning apparatus 110A and gold evaporation coating device 120A.
Electrostatic spinning apparatus 110A is manufactured by increasing by forming layers of nanofibers 20 in the one side of layers of reinforcement 10
The layered product 30 that strong material layer 10 and layers of nanofibers 20 are constituted.Golden evaporation coating device 120A is passing through electrostatic spinning apparatus 110A
Come gold evaporation in the layers of nanofibers 20 of the layered product 30 manufactured.
As shown in figure 4, electrostatic spinning apparatus 110A has for storing the head tank 112 of polymer solution 111, being wound with
Feed roller 113 with flexible flake reinforcement material layer 10, for adjusting the polymer solution being stored in head tank 112
The valve 114 of 111 emitted dose, the nozzle 115 of polymer solution 111 for being ejected through valve 114, for nozzle
Apply the high voltage power supply 117 of predetermined voltage between 115 and collector 116, for the lamination by layers of nanofibers 20 is formed with
Takers-in 118 that body 30 is batched and the multiple conveying rollers 119 being arranged in transport path.
By using this electrostatic spinning apparatus 110A, it can manufacture and be made up of layers of reinforcement 10 and layers of nanofibers 20
Layered product 30.Below, the process for manufacturing layered product 30 is illustrated.
First, supplied to head tank 112 be dissolved with a solvent nanofiber 22 the raw material i.e. polymer of polymer it is molten
Liquid 111.Polyvinyl alcohol preferably can be used in polymer as the raw material of nanofiber 22, but hydrophily in addition can also be used
At the hydrophily of polyurethane, hydrophilicity kynoar, polyamide, silk, PLA, PCL etc. and process hydrophiling
Material of reason etc..
Next, untiing layers of reinforcement 10 from the feed roller 113 for being wound with layers of reinforcement 10.Then, enhancing is worked as
When material layer 10 is passed through above collector 116 by conveying roller 119, to applying high electricity between nozzle 115 and collector 116
In the state of pressure, valve 114 is opened, from nozzle 115 towards the spraying polymer solution 111 of layers of reinforcement 10.So as in enhancing
Layers of nanofibers 20 is formed on the surface of material layer 10.
In addition, the solvent comprising polymer solution 111 can be in polymer solution 111 from nozzle 115 towards layers of reinforcement
Evaporated in 10 way.Further, since collector 116 is in heated state because heater is (not shown), even if therefore residual
There is solvent, solvent can also evaporate because of the heat of heater.It is derived from being made up of layers of reinforcement 10 and layers of nanofibers 20
Long sheet layered product 30.Afterwards, layered product 30 is taken up by being wrapped in after conveying roller 119 on takers-in 118.
In this way, electrostatic spinning apparatus 110A forms nanofiber by method of electrostatic spinning on the surface of layers of reinforcement 10
Layer 20, using this electrostatic spinning apparatus 110A, can manufacture the lamination being made up of layers of reinforcement 10 and layers of nanofibers 20
Body 30 (referring to Fig. 3 (a)).
In addition, gold evaporation coating device 120B possesses：The layered product 30 for being wound with by electrostatic spinning apparatus 110A to manufacture
Feed roller 121, vacuum evaporation room 122, it is arranged in the vacuum evaporation room 122 and for layers of nanofibers in layered product 30
The vacuum deposition apparatus 123 of gold evaporation on 20, for the layered product 30 that evaporation has gold is cooled down chill roll 124, be used for
Winding passes through the takers-in 125 of the layered product 30 (being in this step sheeted film substrates 1A) of chill roll 124 and is arranged on fortune
Send multiple conveying rollers 126 on path.These each structural elements are arranged in vapor deposition treatment room 127.
In addition, in vacuum evaporation room 122, layers of nanofibers 20 is exposed to what is produced by vacuum deposition apparatus 123
After in the steam (being referred to as golden steam) 128 of gold, cooled roller 124 is cooled down, and the surface as each nanofiber 22 is covered with gold
State.In addition, barricade 129 is provided with vacuum evaporation room 122, because the barricade 129 suppresses the expansion of golden steam 128
Dissipate, therefore, it is possible to the effectively gold evaporation steam 128 of layers of nanofibers 20.
Using this golden evaporation coating device 120A, gold can be covered on each nanofiber 22 for constituting layers of nanofibers 20
24.By covering gold so on the surface of each nanofiber 22 of layers of nanofibers 20, sheet as shown in Figure 1 can be manufactured
Film base material 1A.In addition, manufactured sheeted film substrates 1A is wound on takers-in 125.
Further, since Fig. 1 (c) is schematic diagram, thus while showing that gold 24 is thick with identical around nanofiber 22
The state of covering is spent, but due to the gold evaporation in the face side of layers of nanofibers 20, therefore be naturally not limited to receive in formation
Gold 24 is covered around nanofiber 22 with uniform thickness on each nanofiber 22 of rice fibrous layer 20.Embodiment 1
Sheeted film substrates 1A is used to manufacture laminar film (for example, with reference to Fig. 5) using sheeted film substrates 1A, and it is to apply on skin
Mode is used.Therefore, if equably existing on whole sheeted film substrates 1A surface (surface of the side of layers of nanofibers 20)
Gold, how much uneven the thickness of gold 24 is around each nanofiber 22, the problem of there will not be special.
Next, being illustrated to the laminar film 50 of embodiment 1.
Fig. 5 is the figure in order to illustrate one of the laminar film 50 of embodiment 1 and represent.In addition, Fig. 5 is embodiment 1
Laminar film 50 deployed condition under top view.The laminar film 50 of embodiment 1 is manufactured using sheeted film substrates 1A.
The laminar film 50 of embodiment 1 is also known as facial mask, and it is used by applying in the way of on the face.Therefore, as shown in figure 5,
The laminar film 50 of embodiment 1, which is formed with, can expose the eye opening portion 51 of eyes, can expose the mouth opening portion 52 of mouth and along nose
The general profile of son is cut on the position of nose so as to cover the otch 53 of nose.
The laminar film 50 of this embodiment 1 can be carried out mould processing by the sheeted film substrates 1A to embodiment 1 and be added
Work is manufactured.In addition, although do not represent in Figure 5, preferably in 1 laminar film 50, layers of nanofibers 20 is being constituted
Each nanofiber 22 on covered with 24 (referring to Fig. 1 (c)) of gold.
In this way, the laminar film 50 of embodiment 1 carries out mould processing to make by the sheeted film substrates 1A to embodiment 1
Make, but due to there is layers of reinforcement 10 in the sheeted film substrates 1A of embodiment 1, therefore the thickness with some degree and strong
Degree.Therefore, it is possible to easily operated sheeted film substrates 1A, and processing is also readily susceptible to when carrying out mould processing, and can be effectively
Manufacture laminar film 50.
Further, since the laminar film 50 manufactured using the sheeted film substrates 1A of embodiment 1 is easily operated, therefore user
It is easy to apply the laminar film 50 on the face.And then, the laminar film that also sale is only made up of goldleaf in the past, but be only made up of goldleaf
Laminar film is very thin, and intensity is also very weak, therefore is easy to pleat, bending and corrugation, and ought produce pleat, bending and rise
It is difficult reinflated during wrinkle, but the laminar film 50 of embodiment 1 is the problem of be not in as described above, and it is easy to use.
Here, the application method to the laminar film 50 of embodiment 1 is illustrated.First, embodiment 1 is being applied on the face
Laminar film 50 the side of layers of nanofibers 20 surface.Now, right and left eyes are corresponded respectively to the eye opening portion 51 of laminar film 50
Eyeball, mouth opening portion 52 corresponds to mouth, and the otch 53 of nose applies laminar film 50 in face substantially conforming to the mode of nose profile
On.
In addition, it is also possible to which toner, beautifying liquid or water etc., which drench, to be applied after the laminar film 50 of embodiment 1 on the face,
The laminar film 50 of embodiment 1 can be applied on the face in the state of coating toner or beautifying liquid etc. on the face.In addition, also may be used
In the state of laminar film 50 is applied on the face, toner or beautifying liquid etc. are sprayed on laminar film 50.
In this way, the laminar film 50 in embodiment 1 is applied in the state of on the face, it is close to finger on skin.Thus, it is real
The gold 24 covered on each nanofiber 22 for applying the laminar film 50 of mode 1 is close on the face.Now, gold 24 is due to straight in fiber
Skin is close to be covered on the nanofiber 22 of 50nm~300nm scopes with the thickness of 1nm~100nm scopes in footpath
Property it is higher, the permeability of golden 24 pairs of skins is excellent, can further improve the effect that golden 24 pairs of skin is played.
In addition, when using the laminar film 50, the shape for having toner or beautifying liquid etc. can be also permeated in laminar film 50
Applied under state on the face.Due to being formed with appropriate space between each nanofiber 22 in layers of nanofibers 20, therefore protect fluidity
It is excellent, it can further improve the effect of skin lotion or beautifying liquid to skin.
In this way, can be applied by permeating to have in laminar film 50 on the face in the state of toner or beautifying liquid etc., so that
The effect of toner or beautifying liquid etc. can not only be brought to skin, moreover it is possible to the effect for bringing gold to have.In addition, Jin Weikang
With other metal phases metal higher than stability while oxidation material, therefore known its is not likely to produce allergy etc..
According to the laminar film 50 of embodiment 1, because evaporation has gold 24 in layers of nanofibers 20, if therefore by the sheet
Film 50 is applied on the face, gold 24 composition together with skin lotion or beautifying liquid skin permeation, so as to activate Skin Cell.Therefore,
The metabolism of Skin Cell can be promoted, moisturizing and elastic force are assigned to skin, and raising will be on subcutaneous cell and corium
The function that the waste of generation is discharged to outside.Therefore, the laminar film 50 of embodiment 1 results in higher cosmetic result.This
Outside, moreover it is possible to obtain because in the spiritual satisfaction for applying the laminar film 50 covered with gold 24 on the face and bringing.
[the sheeted film substrates manufacture device 100A of embodiment 1 variation]
On the sheeted film substrates manufacture device 100A of embodiment 1, exemplify electrostatic spinning apparatus 110A and gold is deposited
Device 120A is the situation of independent device, but is alternatively the knot that electrostatic spinning apparatus 110A is connected with gold evaporation coating device 120A
Structure.
Fig. 6 is the figure in order to illustrate the sheeted film substrates manufacture device 100A of embodiment 1 variation and represent.As schemed
Shown in 6, the sheeted film substrates manufacture device 100A of embodiment 1 variation (is referred to as " sheeted film substrates manufacture device
100A' ") it is the structure that electrostatic spinning apparatus 110A is connected with gold evaporation coating device 120A.
In the electrostatic spinning apparatus 110A and golden evaporation coating device of sheeted film substrates manufacture device 100A' shown in pie graph 6
In 120A each structural element, pair with the electrostatic spinning apparatus 110A shown in Fig. 4 and golden evaporation coating device 120A each structural element
Identical part marks identical reference.
In addition, sheeted film substrates manufacture device 100A' is due to being electrostatic spinning apparatus 110A and golden evaporation coating device 120A phases
The structure of connection, therefore the takers-in that batches the layered product 30 manufactured need not be used in electrostatic spinning apparatus 110A, and
And the conveying roller that conveys layered product 30 need not be used in golden evaporation coating device 120A.In addition, in electrostatic spinning apparatus 110A
It is provided with the conveying roller 119 conveyed for the layered product 30 that will have been manufactured to golden evaporation coating device 120A.
According to the sheeted film substrates manufacture device 100A' so constituted, it can be carried out continuously and utilize electrostatic spinning apparatus
The manufacturing process of 110A layered product 30 and the gold evaporation process using golden evaporation coating device 120A, therefore, it is possible to effectively manufacture
The sheeted film substrates 1A illustrated in embodiment 1 (referring to Fig. 1).
[embodiment 2]
Fig. 7 is the figure in order to illustrate the sheeted film substrates 1B of embodiment 2 and represent.Fig. 7 (a) is the piece of embodiment 2
Shape film base material 1B side cross-sectional view, Fig. 7 (b) is the enlarged drawing in Fig. 7 (a) with the dotted line A parts surrounded, and Fig. 7 (c) is Fig. 7 (b)
B-b line sectional views.
The sheeted film substrates 1B of embodiment 2 not only in layers of nanofibers 20, is still deposited in layers of reinforcement 10
There is gold 24, it is different from the sheeted film substrates 1A of embodiment 1 in this.
In the sheeted film substrates 1B of embodiment 2, because also evaporation has gold 24, therefore formed in layers of reinforcement 10
The surface of each fiber 12 of layers of reinforcement 10 is also at the state covered with gold 24.In addition, in Fig. 7 (a), layers of reinforcement
10 display grey are that the state for having gold 24 is deposited.
Fig. 8 is to illustrate the sheeted film substrates 1B of embodiment 2 manufacturing process's (sheeted film substrates of embodiment 2
Manufacture method) and represent flow chart.As shown in figure 8, the manufacture method of the sheeted film substrates of embodiment 2 includes：Prepare
It is used as process (preparatory process of polymer solution) S11 of the polymer solution of the raw material of nanofiber 22；Pass through method of electrostatic spinning
The electrostatic spinning process S12 of layers of nanofibers 20 is formed by polymer solution；The nanometer of gold evaporation 24 in layers of nanofibers 20
The gold evaporation process S13 of fibrous layer；And process S14 is deposited in the gold of the layers of reinforcement of gold evaporation 24 in layers of reinforcement 10.
It is deposited as shown in fig. 7, can be manufactured by this process in layers of nanofibers 20 while having gold in layers of reinforcement 10
Also evaporation has the sheeted film substrates 1B of gold 24.In addition, the preparatory process S11 of polymer solution, electrostatic spinning process S12 and nanometer
Process S13 is deposited in the gold of fibrous layer
Sequence S3 identical processes.
Laminar film 50 as shown in Figure 5 can be also manufactured using the sheeted film substrates 1B so manufactured.By sheeted film substrates
1B is not only being applied on surface (be referred to as face and be close to face) on the face in the state covered with gold 24 come the laminar film 50 manufactured, is gone back
Also turn into the state covered with gold 24 on the surface (surface of the side of layers of reinforcement 10) with the face side that to be close to face opposite.Cause
This, when user sees the face of oneself for applying the state of laminar film 50 by mirror, almost whole face turns into the shape covered with gold
State.Thus, user can experience the atmosphere of noble quality, further improve spiritual satisfaction.
Fig. 9 is the figure for the sheeted film substrates manufacture device 100B structures for schematically showing embodiment 2.Embodiment 2
Sheeted film substrates manufacture device 100B total not only have embodiment 1 sheeted film substrates manufacture device 100A
(referring to Fig. 4), also (is referred to as that " gold is deposited with electrostatic spinning apparatus (be referred to as " electrostatic spinning apparatus 110B ") and golden evaporation coating device
Device 120B ").The sheeted film substrates manufacture device 100B of embodiment 2 electrostatic spinning apparatus 110B can be and embodiment 1
Sheeted film substrates manufacture device 100A electrostatic spinning apparatus 110A identical structures, therefore illustrate golden evaporation coating device herein
120B。
Golden evaporation coating device 120B has the first gold medal deposition unit 200a and use for being used for the gold evaporation in layers of nanofibers 20
In the second gold medal deposition unit 200b of the gold evaporation in layers of reinforcement 10.First gold medal deposition unit 200a with representing in Fig. 4
Golden evaporation coating device 120A it is identical, pair with represented in Fig. 4 golden evaporation coating device 120A identicals structural element mark identical it is attached
Icon is remembered.
Second gold medal deposition unit 200b structure is also substantially identical with the golden evaporation coating device 120A represented in Fig. 4.That is,
Two gold medal deposition unit 200b have vacuum evaporation room 132, are arranged in the vacuum evaporation room 132 and in layers of nanofibers 20
Upper evaporation have the vacuum deposition apparatus 133 of gold evaporation on the sheeted film substrates 1A of the gold side of layers of reinforcement 10, chill roll 134,
For batching by the sheeted film substrates 1B of chill roll 134 takers-in 135 and the multiple conveyings being arranged in transport path
Roller 136.
, can be in layers of nanofibers 20 while gold evaporation 24 according to the golden evaporation coating device 120B so constituted, moreover it is possible to
The gold evaporation 24 in layers of reinforcement 10.Therefore, some gold 24 are also included on sheeted film substrates 1B thickness direction.That is, exist
Only in the case of gold evaporation, on the thickness direction of layers of nanofibers 20, have and increase on the surface of the side of layers of nanofibers 20
The situation of the amount of gold 24 is nearby reduced on the border of strong material layer 10 compared with surface, but due to the surface in the side of layers of reinforcement 10
On also gold evaporation, therefore can also increase near the border of layers of reinforcement 10 and layers of nanofibers 20 gold 24 of some degree
Amount.
In addition, the sheeted film substrates manufacture device 100A of embodiment 1 as shown in Figure 6 variation (sheeted film substrates
Manufacture device 100A') like that, the sheeted film substrates manufacture device 100B of embodiment 2 be alternatively electrostatic spinning apparatus 110B and
The structure that golden evaporation coating device 120B is connected.
[embodiment 3]
In above-mentioned embodiment 1, by layers of nanofibers 20 gold evaporation come produce in layers of nanofibers 20 wrap
Sheeted film substrates 1A containing gold 24, but in embodiment 3, by the polymer solution in the raw material as nanofiber 22
In be dispersed with gold particle " golden dispersing polymer solution " carry out electrostatic spinning come manufacture in layers of nanofibers 20 comprising gold 24
Sheeted film substrates 1C (not shown).
Figure 10 is to illustrate the sheeted film substrates 1C of embodiment 3 manufacturing process's (sheeted film substrates of embodiment 3
Manufacture method) and represent flow chart.As shown in Figure 10, the sheeted film substrates 1C of embodiment 3 manufacture method includes：It is accurate
The preparatory process S21 of the golden dispersing polymer solution of standby gold dispersing polymer solution；With by entering to golden dispersing polymer solution
Row electrostatic spinning forms the electrostatic spinning process S22 of layers of nanofibers 20.
By carrying out this process, the sheeted film substrates 1C that gold is included in layers of nanofibers 20 can be manufactured.Now, though
Diagram is so omitted, gold 24 exists with the state being comprised in each nanofiber 22 to form layers of nanofibers 20.In addition, also having
Situation of the gold 24 in the state of exposure on the surface of layers of nanofibers 20.In addition, the goldc grains mixed in a polymer solution
The size (particle diameter) of son can hundreds of nm~several μm scope.By the way that the size (particle diameter) of gold particle is set into this scope, respectively
Nanofiber 22 can carry gold particle.For example, when the fibre diameter of nanofiber 22 is 300nm~500nm degree, this is received
Rice fiber 22 can carry (5 μm) Zuo You of particle diameter 5000nm gold particle.
In addition, when the fibre diameter of nanofiber 22 is smaller (such as 50nm or so), if by the particle diameter of gold 24 also with this
For example hundreds of nm or so are correspondingly set to, then the nanofiber 22 can also carry the particle of gold 24.
In this way, in the sheeted film substrates 1C of embodiment 3 manufacture method, by being carried out to golden dispersing polymer solution
The state that electrostatic spinning includes gold 24 turn into layers of nanofibers 20.Therefore, be not required to y will in layers of nanofibers 20 gold evaporation
Process.
Figure 11 is the figure for the sheeted film substrates manufacture device 100C structures for schematically showing embodiment 3.Such as Figure 11 institutes
Show, the sheeted film substrates manufacture device 100C of embodiment 3 need not be used for the gold evaporation of the gold evaporation in layers of nanofibers 20
Device (the golden evaporation coating device 120A in Fig. 4).That is, the structure of the sheeted film substrates manufacture device 100C of embodiment 3 can be with Fig. 4
In electrostatic spinning apparatus 110A it is identical.
In addition, in the sheeted film substrates manufacture device 100C of embodiment 3, head tank 112 is used to being stored in as receiving
" the golden dispersing polymer solution 111a " of golden 24 particle is dispersed with the polymer solution of the raw material of rice fiber.Also, it can pass through
The laminar film base that gold 24 is included in layers of nanofibers 20 is manufactured to golden dispersing polymer solution 111a progress electrostatic spinnings
Material 1C.The laminar film 50 such as Fig. 5 can be also manufactured using this sheeted film substrates 1C.
In addition, the invention is not limited in above-mentioned embodiment, a variety of changes can be carried out in scope of the invention not departing from
Shape is implemented.For example, can also carry out following deformation implementation.
(1) in the respective embodiments described above, the situation for the laminar film for almost covering whole face is exemplified to laminar film 50, but
Or the laminar film used on the specific part (for example, the part in so-called T areas etc.) from forehead to nose of face.In addition,
Or the laminar film used on other positions beyond face.
(2) sheeted film substrates (1A, 1B and 1C) of the respective embodiments described above are with layers of reinforcement 10 and nanofiber
The structure of layer 20, but if only also can obtain sufficient intensity by layers of nanofibers 20 and not hinder operationally, not necessarily forms increasing
Strong material layer 10.
(3) although not referring in the respective embodiments described above, also cosmetic can be soaked with by containing in advance in laminar film 50
The laminar film of water or beautifying liquid is sold as commodity.
(4) in the respective embodiments described above, layers of reinforcement (reinforcing material) is non-woven fabrics, but is not limited to nonwoven
Cloth, such as being alternatively piece official form for filing a lawsuit.Now, easily it can be peeled off preferably when user uses laminar film from layers of nanofibers 20
Piece official form for filing a lawsuit.
Claims (10)
1. a kind of sheeted film substrates, it is characterised in that with the layers of nanofibers formed by nanofiber, the layers of nanofibers
Include gold.
2. sheeted film substrates according to claim 1, it is characterised in that enhancing of the layers of nanofibers formation in sheet
In the one side of material layer.
3. sheeted film substrates according to claim 2, it is characterised in that the layers of reinforcement is more than institute by fibre diameter
The fiber for stating the fibre diameter of nanofiber is formed.
4. the sheeted film substrates according to any one of claims 1 to 3, it is characterised in that the gold is in covering institute
State the state on the surface of nanofiber.
5. the sheeted film substrates according to any one of claims 1 to 3, it is characterised in that the gold is to be comprised in
State in the nanofiber is present.
6. the sheeted film substrates according to any one of Claims 1 to 5, it is characterised in that the nanofiber is by parent
Waterborne polymeric is formed.
7. a kind of laminar film, it is characterised in that manufactured using the sheeted film substrates described in any one of claim 1~6.
8. laminar film according to claim 7, it is characterised in that the laminar film is to apply the surface application piece using on the face
Shape film.
9. a kind of manufacture method of sheeted film substrates, it is characterised in that for manufacturing in the nanofiber formed by nanofiber
The sheeted film substrates of gold are included on layer, including：
Prepare the process of the polymer solution as the nanofiber raw material；
By the electrostatic spinning process that the layers of nanofibers is formed to polymer solution progress electrostatic spinning；And
The gold evaporation process of gold evaporation in the layers of nanofibers.
10. a kind of manufacture method of sheeted film substrates, it is characterised in that for manufacturing in the nanofiber formed by nanofiber
The sheeted film substrates of gold are included in layer, including：
Preparation is dispersed with the golden dispersing polymer solution of gold particle in the polymer solution as the nanofiber raw material
Process；And
By the electrostatic spinning process that the layers of nanofibers is formed to the golden dispersing polymer solution progress electrostatic spinning.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016-059886 | 2016-03-24 | ||
| JP2016059886A JP2017171614A (en) | 2016-03-24 | 2016-03-24 | Sheet-like pack base materials, sheet-like pack, and production methods of sheet-like pack base materials |
| KR1020160075069A KR20170114222A (en) | 2016-03-24 | 2016-06-16 | The sheet phase pack material, pack of sheet phase, and the manufacturing method for pack material being sheet phase |
| KR10-2016-0075069 | 2016-06-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107227558A true CN107227558A (en) | 2017-10-03 |
Family
ID=59932002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610685875.9A Pending CN107227558A (en) | 2016-03-24 | 2016-08-18 | The manufacture method of sheeted film substrates, laminar film and sheeted film substrates |
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| Country | Link |
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| CN (1) | CN107227558A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114846188A (en) * | 2019-12-23 | 2022-08-02 | 花王株式会社 | Method for producing colored nonwoven fabric |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008060675A2 (en) * | 2006-06-01 | 2008-05-22 | Invista Technologies S.A R.L. | Coaxial polycarbonate/polyurethane composite nanofibers |
| CN102560896A (en) * | 2012-02-13 | 2012-07-11 | 东华大学 | Method and device for preparation of composite functional membrane with nanofiber layer |
| CN102851877A (en) * | 2012-09-11 | 2013-01-02 | 中国科学技术大学 | Method for assembling gold and silver one-dimensional nano-material by adopting electrostatic spinning technology and application thereof |
| CN104372525A (en) * | 2014-12-03 | 2015-02-25 | 北京航空航天大学 | High-transparent flexible hollow metal nanofiber membrane and manufacturing method thereof |
-
2016
- 2016-08-18 CN CN201610685875.9A patent/CN107227558A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008060675A2 (en) * | 2006-06-01 | 2008-05-22 | Invista Technologies S.A R.L. | Coaxial polycarbonate/polyurethane composite nanofibers |
| CN102560896A (en) * | 2012-02-13 | 2012-07-11 | 东华大学 | Method and device for preparation of composite functional membrane with nanofiber layer |
| CN102851877A (en) * | 2012-09-11 | 2013-01-02 | 中国科学技术大学 | Method for assembling gold and silver one-dimensional nano-material by adopting electrostatic spinning technology and application thereof |
| CN104372525A (en) * | 2014-12-03 | 2015-02-25 | 北京航空航天大学 | High-transparent flexible hollow metal nanofiber membrane and manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114846188A (en) * | 2019-12-23 | 2022-08-02 | 花王株式会社 | Method for producing colored nonwoven fabric |
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Application publication date: 20171003 |