CN107227474A - A kind of metal surface treatment process - Google Patents

A kind of metal surface treatment process Download PDF

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Publication number
CN107227474A
CN107227474A CN201710501588.2A CN201710501588A CN107227474A CN 107227474 A CN107227474 A CN 107227474A CN 201710501588 A CN201710501588 A CN 201710501588A CN 107227474 A CN107227474 A CN 107227474A
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China
Prior art keywords
solution
treatment
substrate
oil
metal
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CN201710501588.2A
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Chinese (zh)
Inventor
李德高
黄海新
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DONGGUANG NBC ELECTRONIC TECHNOLOGIES Co Ltd
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DONGGUANG NBC ELECTRONIC TECHNOLOGIES Co Ltd
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Priority to CN201710501588.2A priority Critical patent/CN107227474A/en
Publication of CN107227474A publication Critical patent/CN107227474A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10Electroplating with more than one layer of the same or of different metals
    • C25D5/12Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
    • C25D5/14Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/04Electroplating: Baths therefor from solutions of chromium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/12Electroplating: Baths therefor from solutions of nickel or cobalt
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/38Electroplating: Baths therefor from solutions of copper
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/36Pretreatment of metallic surfaces to be electroplated of iron or steel
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • C25D5/42Pretreatment of metallic surfaces to be electroplated of light metals
    • C25D5/44Aluminium
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces

Abstract

The present invention relates to metal working technical area, refer in particular to a kind of metal surface treatment process, substrate surface is first carried out paraffin removal, oil removing by the present invention, then activated, nickel plating, copper facing are carried out again in the substrate surface of activation, wire drawing is carried out on the surface of nickel plating, copper-plated base material, the substrate surface after wire drawing carries out nickel plating, chromium plating, finally carry out oil spout processing;Wire drawing makes plating film layer and substrate surface compactness higher, prevent film layer from dropping, increase the metal sense of substrate surface, plated film uses same plated film and wire-drawing equipment respectively twice, can economize on resources, and the present invention can deposit multiple layer metal or metallic compound in metallic surface, hardness, decay resistance, crocking resistance and the interior high-temperature behavior of substrate surface can be made all to be significantly improved, and compared with traditional method, the present invention use multiple plated film, make substrate surface more attractive in appearance with it is fine and smooth.

Description

A kind of metal surface treatment process
Technical field
The present invention relates to metal working technical area, a kind of metal surface treatment process is referred in particular to.
Background technology
Surface drawing process processing is exactly to be fabricated to line with wire drawing material to metal and stainless steel, aluminium material surface to play decoration Surface action, drawing process processing in surface is also a kind of surface treatment means.The current wire drawing in metal surface is simply by letter It is single by surface wire drawing process, wire-drawing surface is uneven, and metal surface reflectance is higher.
The content of the invention
The present invention provides that a kind of wire-drawing effect is good, the uniform and low metal of surface reflection degree for problem of the prior art Process of surface treatment.
In order to solve the above-mentioned technical problem, the present invention is adopted the following technical scheme that:
A kind of metal surface treatment process, comprises the following steps:
A. paraffin removal, oil removal treatment:Base material is put into supersonic generator and carries out removing Lasaxing Oilfield, the base material after paraffin removal is put into Oil removal treatment is carried out in motor-generator set;
B. activation process:The substrate surface of paraffin removal, oil removing is utilized into hydrochloric acid solution progress activation process;
C. nickel plating, copper plating treatment:Substrate surface first after activation process carries out nickel plating, is then carried out on the surface of nickel plating Electric coke-plated copper, finally carries out electroplating acid copper on the surface of coke-plated copper;
D. wire drawing process:Base material obtained by step C is subjected to surface wire drawing process;
E. paraffin removal, oil removal treatment:Base material after wire drawing process is subjected to paraffin removal, oil removal treatment again;
F. activation process:Substrate surface after paraffin removal, oil removal treatment is subjected to re-activation processing using hydrochloric acid solution;
G. nickel plating, chromium plating process:Nickel plating is carried out in the substrate surface of re-activation, then chromium plating is carried out on the surface of nickel plating;
H. oil spout:Under conditions of vacuum, oil spout processing is carried out to substrate surface;
I. product examination:The product of H steps is checked, it is qualified to check whether.
Preferably, during step C nickel plating using 60-120g/L hydrochloric acid solution and 60-120g/L nickel chloride solution The ratio between volume of mixed liquor, hydrochloric acid solution and nickel chloride solution is 1:1, copper facing uses 30-90g/L burnt copper solution and 250- The ratio between volume of the mixed liquor of 300g/L burnt potassium solution, burnt copper solution and burnt potassium solution is 1:1.
Preferably, chlorination of the solution used during step G nickel plating for 300-600g/L nickel sulfate solution, 30-60g/L Potassium solution, 30-60g/L boric acid solution are according to volume ratio 1:1:1 mixed liquor, the solution that chromium plating is used is 15-45g/L chromium Salting liquid, 15-45g/L conduction liquid, 15-45g/L stabiliser solutions are according to volume ratio 1:1:1 mixed liquor.
Preferably, the concrete technology of step C, G is:Mixed liquor will be added in the solution tank of motor-generator set, electric current is accessed, will Mixed liquor makes solution fully be contacted with substrate surface by rocking equipment, and plated film time can require to set according to membrane system and thickness.
Preferably, the concrete technology of step B, F is:Base material after oil removing, paraffin removal is put into mass concentration for 30- Activated in 50% hydrochloric acid, soak time is 30-90 seconds.
Preferably, the concrete technology of step A, E is:Base material is put into supersonic generator first, mass ratio is added Wax powder is removed for 3-5%, ultrasonic wavelength is set as 4-5Hz, the paraffin removal of 120-180 seconds is carried out, then by the base after paraffin removal Material carries out adding the degreasing powder that mass ratio is 2-3% in electrolytic degreasing, the solution of oil removing.
Preferably, the product after H steps is carried out into spray anti-fingerprint oil, then toasted, a length of 50-60 during baking Minute, baking temperature is 150-200 DEG C.
Preferably, the base material is stainless steel, copper, aluminium, iron.
Beneficial effects of the present invention:
As seen from the above technical solution provided by the invention:Substrate surface is first carried out paraffin removal, oil removing, Ran Houjin by the present invention Row activation, nickel plating, copper facing are carried out in the substrate surface of activation again, wire drawing are carried out on the surface of nickel plating, copper-plated base material, in wire drawing Substrate surface afterwards carries out nickel plating, chromium plating, finally carries out oil spout processing;Wire drawing makes plating film layer and substrate surface compactness more Height, prevents film layer from dropping, and increases the metal sense of substrate surface, and plated film uses same plated film and wire-drawing equipment respectively twice, can save About resource, of the invention to deposit multiple layer metal or metallic compound in metallic surface, can make hardness, the corrosion resistant of substrate surface Corrosion energy, crocking resistance and interior high-temperature behavior are all significantly improved, and compared with traditional method, the present invention is adopted Use multiple plated film, make substrate surface more attractive in appearance with it is fine and smooth.
Brief description of the drawings
Fig. 1 is process step figure of the invention.
Embodiment
For the ease of the understanding of those skilled in the art, the present invention is made further with reference to embodiment and accompanying drawing It is bright, the content that embodiment is referred to not limitation of the invention.The present invention is described in detail below in conjunction with accompanying drawing.
Embodiment one:
A kind of metal surface treatment process that the present invention that the present invention is provided is provided, comprises the following steps:
A. paraffin removal, oil removal treatment:Base material is put into supersonic generator and carries out removing Lasaxing Oilfield, the base material after paraffin removal is put into Oil removal treatment is carried out in motor-generator set;
B. activation process:The substrate surface of paraffin removal, oil removing is utilized into hydrochloric acid solution progress activation process;
C. nickel plating, copper plating treatment:Substrate surface first after activation process carries out nickel plating, is then carried out on the surface of nickel plating Electric coke-plated copper, finally carries out electroplating acid copper on the surface of coke-plated copper;
D. wire drawing process:Base material obtained by step C is subjected to surface wire drawing process;
E. paraffin removal, oil removal treatment:Base material after wire drawing process is subjected to paraffin removal, oil removal treatment again;
F. activation process:Substrate surface after paraffin removal, oil removal treatment is subjected to re-activation processing using hydrochloric acid solution;
G. nickel plating, chromium plating process:Nickel plating is carried out in the substrate surface of re-activation, then chromium plating is carried out on the surface of nickel plating;
H. oil spout:Under conditions of vacuum, oil spout processing is carried out to substrate surface;
I. product examination:The product of H steps is checked, it is qualified to check whether.
Substrate surface is first carried out paraffin removal, oil removing by the present invention, is then activated, is plated again in the substrate surface of activation Nickel, copper facing, wire drawing is carried out on the surface of nickel plating, copper-plated base material, and the substrate surface after wire drawing carries out nickel plating, chromium plating, most Oil spout processing is carried out afterwards;Wire drawing makes plating film layer and substrate surface compactness higher, prevents film layer from dropping, increase substrate surface Metal sense, twice plated film respectively use same plated film and wire-drawing equipment, can economize on resources, the present invention can be deposited in metallic surface Multiple layer metal or metallic compound, can make hardness, decay resistance, crocking resistance and the interior high-temperature behavior of substrate surface All be significantly improved, and compared with traditional method, the present invention uses multiple plated film, make substrate surface more attractive in appearance with It is fine and smooth.
In the present embodiment, during step C nickel plating using 60g/L hydrochloric acid solution and 60g/L nickel chloride solution mixed liquor, The ratio between volume of hydrochloric acid solution and nickel chloride solution is 1:1, copper facing uses 30g/L burnt copper solution and 250g/L burnt potassium solution Mixed liquor, the ratio between burnt copper solution and the volume of burnt potassium solution are 1:1.
In the present embodiment, the solution used during step G nickel plating is 300g/L nickel sulfate solution, 30g/L potassium chloride is molten Liquid, 30g/L boric acid solution are according to volume ratio 1:1:1 mixed liquor, the solution that chromium plating is used for 15g/L chromium salt solution, 15g/L conduction liquid, 15g/L stabiliser solutions are according to volume ratio 1:1:1 mixed liquor.
The metal surface treatment process of the present invention by strictly controlling the consumption, addition sequence and response parameter of each raw material, Make each raw material concerted reaction, whole reaction system in order, it is stable carry out, it is the hardness on the surface after processing, decay resistance, resistance to Frictional behaviour and interior high-temperature behavior are all significantly improved.
In the present embodiment, the concrete technology of step C, G is:Mixed liquor will be added in the solution tank of motor-generator set, electric current is accessed, Solution is set fully to be contacted with substrate surface by rocking equipment mixed liquor, plated film time can be set according to membrane system and thickness requirement It is fixed.
In the present embodiment, the concrete technology of step B, F is:Base material after oil removing, paraffin removal is put into concentration for 30% hydrochloric acid Middle to be activated, soak time is 30 seconds.
In the present embodiment, the concrete technology of step A, E is:Base material is put into supersonic generator first, quality is added Than for 3%, except wax powder, ultrasonic wavelength being set as into 4Hz, the paraffin removal of 120 seconds is carried out, then the base material after paraffin removal is carried out The degreasing powder that mass ratio is 2% is added in electrolytic degreasing, the solution of oil removing.
In the present embodiment, the product after H steps is subjected to spray anti-fingerprint oil, then toasted, a length of 50 during baking Minute, baking temperature is 150 DEG C.
In the present embodiment, the base material is stainless steel, copper, aluminium, iron.
In the present invention, boric acid is added in the solution that step G is used so that the nickel dam surface electroplated out shows pearl Color, and chromic salts uses the chromium of positive trivalent, and the substrate surface after being handled by this method can show strong wire-drawing effect, can The metal sense of enhancing base materials.
Embodiment two:
A kind of metal surface treatment process that the present invention that the present invention is provided is provided, comprises the following steps:
A. paraffin removal, oil removal treatment:Base material is put into supersonic generator and carries out removing Lasaxing Oilfield, the base material after paraffin removal is put into Oil removal treatment is carried out in motor-generator set;
B. activation process:The substrate surface of paraffin removal, oil removing is utilized into hydrochloric acid solution progress activation process;
C. nickel plating, copper plating treatment:Substrate surface first after activation process carries out nickel plating, is then carried out on the surface of nickel plating Electric coke-plated copper, finally carries out electroplating acid copper on the surface of coke-plated copper;
D. wire drawing process:Base material obtained by step C is subjected to surface wire drawing process;
E. paraffin removal, oil removal treatment:Base material after wire drawing process is subjected to paraffin removal, oil removal treatment again;
F. activation process:Substrate surface after paraffin removal, oil removal treatment is subjected to re-activation processing using hydrochloric acid solution;
G. nickel plating, chromium plating process:Nickel plating is carried out in the substrate surface of re-activation, then chromium plating is carried out on the surface of nickel plating;
H. oil spout:Under conditions of vacuum, oil spout processing is carried out to substrate surface;
I. product examination:The product of H steps is checked, it is qualified to check whether.
In the present embodiment, in the present embodiment, 120g/L hydrochloric acid solution and 120g/L nickel chloride are used during step C nickel plating The ratio between volume of the mixed liquor of solution, hydrochloric acid solution and nickel chloride solution is 1:1, copper facing using 90g/L burnt copper solution and The ratio between volume of the mixed liquor of 300g/L burnt potassium solution, burnt copper solution and burnt potassium solution is 1:1.
In the present embodiment, the solution used during step G nickel plating is 600g/L nickel sulfate solution, 60g/L potassium chloride is molten Liquid, 60g/L boric acid solution are according to volume ratio 1:1:1 mixed liquor, the solution that chromium plating is used for 45g/L chromium salt solution, 45g/L conduction liquid, 45g/L stabiliser solutions are according to volume ratio 1:1:1 mixed liquor.
In the present embodiment, the concrete technology of step C, G is:Mixed liquor will be added in the solution tank of motor-generator set, electric current is accessed, Solution is set fully to be contacted with substrate surface by rocking equipment mixed liquor, plated film time can be set according to membrane system and thickness requirement It is fixed.
In the present embodiment, the concrete technology of step B, F is:It is 50% that base material after oil removing, paraffin removal is put into mass concentration Activated in hydrochloric acid, soak time is 90 seconds.
In the present embodiment, the concrete technology of step A, E is:Base material is put into supersonic generator first, quality is added Than for 5%, except wax powder, ultrasonic wavelength being set as into 5Hz, the paraffin removal of 180 seconds is carried out, then the base material after paraffin removal is carried out The degreasing powder that mass ratio is 3% is added in electrolytic degreasing, the solution of oil removing.
In the present embodiment, the product after H steps is subjected to spray anti-fingerprint oil, then toasted, a length of 60 during baking Minute, baking temperature is 200 DEG C.
In the present embodiment, the base material is stainless steel, copper, aluminium, iron
It is described above, only it is present pre-ferred embodiments, any formal limitation not is made to the present invention, although this hair It is bright to be disclosed as above with preferred embodiment, but the present invention is not limited to, any those skilled in the art are not taking off In the range of technical solution of the present invention, when the technology contents using the disclosure above make a little change or are modified to equivalent variations Equivalent embodiment, as long as being, without departing from technical solution of the present invention content, to refer to make above example according to the technology of the present invention Any simple modification, equivalent variations and modification, belong in the range of technical solution of the present invention.

Claims (8)

1. a kind of metal surface treatment process, it is characterised in that comprise the following steps:
Paraffin removal, oil removal treatment:Base material is put into supersonic generator and carries out removing Lasaxing Oilfield, the base material after paraffin removal is put into whole Oil removal treatment is carried out in stream machine;
Activation process:The substrate surface of paraffin removal, oil removing is utilized into hydrochloric acid solution progress activation process;
Nickel plating, copper plating treatment:Substrate surface first after activation process carries out nickel plating, then carries out electricity on the surface of nickel plating Coke-plated copper, finally carries out electroplating acid copper on the surface of coke-plated copper;
Wire drawing process:Base material obtained by step C is subjected to surface wire drawing process;
Paraffin removal, oil removal treatment:Base material after wire drawing process is subjected to paraffin removal, oil removal treatment again;
Activation process:Substrate surface after paraffin removal, oil removal treatment is subjected to re-activation processing using hydrochloric acid solution;
Nickel plating, chromium plating process:Nickel plating is carried out in the substrate surface of re-activation, then chromium plating is carried out on the surface of nickel plating;
Oil spout:Under conditions of vacuum, oil spout processing is carried out to substrate surface;
Product examination:The product of H steps is checked, it is qualified to check whether.
2. a kind of metal surface treatment process according to claim 1, it is characterised in that:60- is used during step C nickel plating The volume of the mixed liquor of 120g/L hydrochloric acid solution and 60-120g/L nickel chloride solution, hydrochloric acid solution and nickel chloride solution it Than for 1:1, copper facing uses the mixed liquor of 30-90g/L burnt copper solution and 250-300g/L burnt potassium solution, burnt copper solution and Jiao The ratio between volume of potassium solution is 1:1.
3. a kind of metal surface treatment process according to claim 1, it is characterised in that:What is used during step G nickel plating is molten The nickel sulfate solution, 30-60g/L Klorvess Liquid, 30-60g/L boric acid solution that liquid is 300-600g/L are according to volume ratio 1:1:1 mixed liquor, the solution that chromium plating is used is steady for 15-45g/L chromium salt solution, 15-45g/L conduction liquid, 15-45g/L Agent solution is determined according to volume ratio 1:1:1 mixed liquor.
4. a kind of metal surface treatment process according to claim 1, it is characterised in that the concrete technology of step C, G is: Mixed liquor will be added in the solution tank of motor-generator set, electric current is accessed, solution is filled with substrate surface by rocking equipment mixed liquor Tap is touched, and plated film time can require to set according to membrane system and thickness.
5. a kind of metal surface treatment process according to claim 1, it is characterised in that the concrete technology of step B, F is: Base material after oil removing, paraffin removal is put into mass concentration to be activated in 30-50% hydrochloric acid, soak time is 30-90 seconds.
6. a kind of metal surface treatment process according to claim 5, it is characterised in that A, E concrete technology is:First Base material is put into supersonic generator, mass ratio is added and removes wax powder for 3-5%, ultrasonic wavelength is set as 4-5Hz, entered The row paraffin removal of 120-180 seconds, it is 2- then to carry out adding mass ratio in electrolytic degreasing, the solution of oil removing by the base material after paraffin removal 3% degreasing powder.
7. a kind of metal surface treatment process according to claim 1, it is characterised in that:Product after H steps is entered Row spray anti-fingerprint oil, is then toasted, and a length of 50-60 minutes during baking, baking temperature is 150-200 DEG C.
8. a kind of metal surface treatment process according to claim 1, it is characterised in that:The base material be stainless steel, copper, Aluminium, iron.
CN201710501588.2A 2017-06-27 2017-06-27 A kind of metal surface treatment process Pending CN107227474A (en)

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Cited By (5)

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CN109321902A (en) * 2018-09-30 2019-02-12 中国人民解放军第五七九工厂 A kind of method of powder metallurgy high-temperature alloy electrodeposited chromium
CN109338432A (en) * 2018-11-27 2019-02-15 东莞市慧泽凌化工科技有限公司 A kind of electroplating technology of stainless steel and aluminium alloy compound part
CN110093643A (en) * 2018-01-31 2019-08-06 佛山市诺诚化工有限公司 The pre-treatment and activation liquid and preprocess method of aluminium and plating on aluminium alloy
CN110539238A (en) * 2019-08-21 2019-12-06 福建捷思金属科技发展有限公司 Copper plate oxidation nickel plating disorder treatment method
CN111270279A (en) * 2020-03-03 2020-06-12 长沙岱勒新材料科技股份有限公司 Method for preventing yellow spot defect generated in appearance in diamond wire production process

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Application publication date: 20171003