CN107224941A - A kind of low pressure drop high stability distributor and reactor - Google Patents

A kind of low pressure drop high stability distributor and reactor Download PDF

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Publication number
CN107224941A
CN107224941A CN201710494882.5A CN201710494882A CN107224941A CN 107224941 A CN107224941 A CN 107224941A CN 201710494882 A CN201710494882 A CN 201710494882A CN 107224941 A CN107224941 A CN 107224941A
Authority
CN
China
Prior art keywords
guider
distributor
venthole
reacting gas
openend
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710494882.5A
Other languages
Chinese (zh)
Inventor
张晨曦
魏飞
骞伟中
朱畅
钱成伟
付晓添
孙晓超
徐丰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Liaoning Gem Chemical Equipment Co Ltd
Tsinghua University
Original Assignee
Liaoning Gem Chemical Equipment Co Ltd
Tsinghua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Liaoning Gem Chemical Equipment Co Ltd, Tsinghua University filed Critical Liaoning Gem Chemical Equipment Co Ltd
Priority to CN201710494882.5A priority Critical patent/CN107224941A/en
Publication of CN107224941A publication Critical patent/CN107224941A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818Feeding of the fluidising gas
    • B01J8/1827Feeding of the fluidising gas the fluidising gas being a reactant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1872Details of the fluidised bed reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention provides a kind of low pressure drop high stability distributor and reactor, the distributor includes:Distributor body and at least one guider;The guider is the tubular structure that one end is closed, and is provided with tube wall at least one through hole;At least one venthole is provided with the distributor body;The openend of each guider is connected with a venthole on the distributor body, and the different venthole of the different guider correspondences;The distributor body, the reacting gas for receiving external reactors air inlet port transmission, and the reacting gas is transferred to by each guider by venthole each described;Each described guider, for passing through at least one through hole described in included, the reacting gas rotating jet that connected venthole transmission is come is to the catalytic reaction zone of the reactor, therefore this programme can ensure jet uniformly and depth under relatively low distribution grid pressure reduction conditions.

Description

A kind of low pressure drop high stability distributor and reactor
Technical field
The present invention relates to technical field of petrochemical industry, more particularly to a kind of low pressure drop high stability distributor and reactor.
Background technology
Fluidized-bed reactor has good heat transfer property and is easy to the features such as continuous catalyst regenerating is circulated, extensive Be applied to the field such as petrochemical industry.Wherein, distributor can be uniformly distributed the gas entered inside fluidized-bed reactor, It is to directly affect one of key component of fluidized-bed reactor reaction effect and reaction efficiency.
Current distributor is porous tabular, and reacting gas directly passes through the outlet in distributor when using distributor The catalytic reaction zone that hole is entered in fluidized-bed reactor, so that catalytic reaction zone is in contact with reacting gas, reaches reaction Purpose.
Existing distributor is directed to, during distributor use, each venthole that reacting gas passes through distributor When being directly entered catalytic reaction zone, most of kinetic energy of reacting gas itself is expended in distribution anode drop.So in order that logical The reaction gas flow for crossing each venthole is stable, and in order to obtain the Jet Penetration Depth of reaction requirement, it is necessary to using high pressure drop Gas distributor.Therefore, existing distributor needs just to can guarantee that jet is uniform and deep under higher distribution grid pressure reduction conditions Degree.
The content of the invention
, can be in relatively low distribution grid pressure reduction conditions the invention provides a kind of low pressure drop high stability distributor and reactor Lower guarantee jet is uniform and depth.
In a first aspect, the invention provides a kind of low pressure drop high stability distributor, the distributor includes:Distributor body With at least one guider;
The guider is the tubular structure that one end is closed, and is provided with tube wall at least one through hole;
At least one venthole is provided with the distributor body;
The openend of each guider is connected with a venthole on the distributor body, and not The different venthole with guider correspondence;
The distributor body, the reacting gas for receiving external reactors air inlet port transmission, and by described in each The reacting gas is transferred to each guider by venthole;
Each described guider, for by least one through hole described in included, the venthole that will be connected The reacting gas that transmission comes is transmitted in the way of rotating jet to the catalytic reaction zone of the external reactors.
Preferably,
The distributor body, including:Pipe distributor or board-like distributor;
Wherein, the pipe distributor includes being provided with least one at least one airway tube, each airway tube The venthole, and the airway tube is connected with the reactor air inlet;The board-like distributor is platy structure, the plate At least one described venthole is provided with shape structure, and the board-like distributor is connected with the reactor air inlet.
Preferably,
When the distributor body includes pipe distributor,
The blind end of the guider towards the catalytic reaction zone top layer, by the through hole with the side of rotating jet Formula transmits the reacting gas to the catalytic reaction zone;
When the distributor body includes board-like distributor,
The blind end of the guider towards the catalytic reaction zone bottom, by the through hole with the side of rotating jet Formula transmits the reacting gas to the catalytic reaction zone.
Preferably,
The blind end of the guider is cone structure.
Preferably,
The surface of each guider is enclosed with wear-resisting lining.
Preferably,
The openend of the guider passes through the welding manner venthole phase corresponding with the distributor body Even.
Preferably,
The openend of the guider passes through the snap fit venthole phase corresponding with the distributor body Even.
Preferably,
It is provided with the openend of the guider on flange, and the flange and is provided with least one bolt hole;
At least one corresponding with venthole each described respectively bolt hole is provided with the distributor body;
Each described guider, it is corresponding at least using at least one bolt hole and the venthole on the flange One bolt hole, the mode being bolted is connected with the corresponding venthole.
Preferably,
Each described guider is round tube shape structure, and the openend is provided with pin thread;
Negative thread is provided with the corresponding venthole of each described guider;
Each described guider, using the negative thread in the pin thread on the openend and the venthole, passes through The mode of threaded connection is connected with the corresponding venthole.
Preferably,
Each described guider is round tube shape structure, and the openend is provided with negative thread;
Pin thread is provided with the corresponding venthole of each described guider;
Each described guider, using the pin thread outside the negative thread on the openend and the venthole, passes through The mode of threaded connection is connected with the corresponding venthole.
Preferably,
The external diameter of the openend of each guider is less than the external diameter of blind end.
Second aspect, the invention provides a kind of reactor, the reactor includes:Housing, air inlet, catalytic reaction zone with And any of the above-described described distributor;
The housing, for fixing the distributor;
The air inlet, for reacting gas to be transferred into the distributor, so that the distributor is with rotating jet Mode transmits the reacting gas to the catalytic reaction zone;
The catalytic reaction zone, the reacting gas for receiving the distributor transmission.
The invention provides a kind of low pressure drop high stability distributor and reactor, the distributor includes:Distributor body With at least one guider, wherein, the openend of each guider is connected with a venthole on distributor body, when point When cloth device body receives the reacting gas of external reactors air inlet port transmission, reacting gas is passed by each venthole of itself It is defeated by each coupled guider.Then each guider is by the through hole included by itself, by connected venthole The reacting gas that transmission comes is transmitted in the way of rotating jet to the catalytic reaction zone of external reactors.Can by said process Know, in this programme after venthole of the reacting gas by distributor body, do not enter directly into catalytic reaction zone, but enter Into the guider being connected with venthole so that reacting gas is changed into rotational flow gas and transmitted in the way of rotating jet to outer The catalytic reaction zone of portion's reactor.Because the jet that the extra circular rector stability that rotational flow gas has can improve reacting gas is equal Cloth stability and depth.Therefore the scheme that the present invention is provided can ensure that jet is uniform and deep under relatively low distribution grid pressure reduction conditions Degree.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are the present invention Some embodiments, for those of ordinary skill in the art, on the premise of not paying creative work, can also basis These accompanying drawings obtain other accompanying drawings.
Fig. 1 is a kind of structural representation for low pressure drop high stability distributor that one embodiment of the invention is provided;
Fig. 2 is a kind of top view for pipe distributor that one embodiment of the invention is provided;
Fig. 3 is a kind of top view for board-like distributor that one embodiment of the invention is provided;
Fig. 4 is a kind of front view for guider that one embodiment of the invention is provided;
Fig. 5 is the low pressure drop high stability that a kind of distributor body that one embodiment of the invention is provided is pipe distributor The structural representation of reactor where distributor;
Fig. 6 is the low pressure drop high stability that a kind of distributor body that one embodiment of the invention is provided is board-like distributor The structural representation of reactor where distributor;
Fig. 7 is a kind of front view for guider including flange that one embodiment of the invention is provided;
Fig. 8 is a kind of structural representation for reactor that one embodiment of the invention is provided;
Fig. 9 is a kind of flow of the application method for low pressure drop high stability distributor that one embodiment of the invention is provided Figure.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is A part of embodiment of the present invention, rather than whole embodiments, based on the embodiment in the present invention, those of ordinary skill in the art The every other embodiment obtained on the premise of creative work is not made, belongs to the scope of protection of the invention.
As shown in figure 1, the embodiments of the invention provide a kind of low pressure drop high stability distributor, the distributor includes:Point Cloth device body 101 and at least one guider 102;
The guider 102 is the tubular structure that one end is closed, and is provided with tube wall at least one through hole 1021;
At least one venthole 1011 is provided with the distributor body 101;
The openend of each guider 102 with a venthole on the distributor body 101 1011 are connected, and the different venthole 1011 of the different guiders 102 correspondence;
The distributor body 101, the reacting gas for receiving external reactors air inlet port transmission, and pass through each institute State venthole 1011 and the reacting gas is transferred to each guider 102;
Each described guider 102, for by least one through hole 1021 described in included, described in being connected The reacting gas that venthole transmission comes is transmitted in the way of rotating jet to the catalytic reaction zone of the external reactors.
According to embodiment as shown in Figure 1, the distributor includes:Distributor body and at least one guider, wherein, often The openend of one guider is connected with a venthole on distributor body, enters when distributor body receives external reactors During the reacting gas of gas port transmission, reacting gas is transferred to each coupled guiding by each venthole of itself Device.Then connected venthole is transmitted next reacting gas to rotate by each guider by the through hole included by itself The mode of jet is transmitted to the catalytic reaction zone of external reactors.By said process, reacting gas passes through in this programme After the venthole of distributor body, catalytic reaction zone is not entered directly into, and is into the guider being connected with venthole In so that reacting gas is changed into rotational flow gas and transmitted in the way of rotating jet to the catalytic reaction zone of external reactors. The uniform stability of jet and depth that reacting gas can be improved due to the extra circular rector stability that rotational flow gas has.Therefore originally Invention provide embodiment can ensure under relatively low distribution grid pressure reduction conditions jet uniformly and depth.
In an embodiment of the invention, the distributor body in the structural representation shown in Fig. 1 can be tubular type distribution Device or board-like distributor;
When distributor body is pipe distributor, as shown in Fig. 2 pipe distributor 201 includes at least one airway tube 2011, be provided with least one described venthole 2012 on each airway tube 2011, and the airway tube 2011 with it is described Reactor air inlet is connected;
When distributor body is board-like distributor, as shown in figure 3, board-like distributor 301 is platy structure, the tabular At least one described venthole 3011 is provided with structure, and the board-like distributor 301 is connected with the reactor air inlet.
In the present embodiment, pipe distributor includes the quantity of airway tube and the shape of airway tube can want according to business The quantity of the venthole set in determination, and each airway tube, the shape of venthole and venthole are asked on airway tube Distribution situation can be determined according to business need.But it should be noted that the shape of venthole will be with the openend of guider Shape matches, so that guider can be connected with venthole.
In the top view for pipe distributor shown in Fig. 2, this figure pipe distributor include annular airway tube 2011a and Annular airway tube 2011b, wherein annular airway tube 2011a and annular airway tube 2011b pass through airway tube respectively 2011c1, airway tube 2011c2, airway tube 2011c3, airway tube 2011c4, airway tube 2011c5, airway tube 2011c6, air guide Pipe 2011c7 and airway tube 2011c8 connections.Annular airway tube 2011a is connected with reactor air inlet A.When reactor enters When gas port A is to circular airway tube 2011a transmission reaction gas Gs, reaction gas G can be connected with circular airway tube 2011a Each air guide Bottomhole pressure, and flow in each guider being connected with venthole in each airway tube.
In the present embodiment, the quantity of venthole, the shape of venthole and the venthole set on board-like distributor Distribution situation can be determined according to business need.Such as, for large-scale reactor, distributor body can use corrugated Cross section Design, the bed quality for carrying fluid bed.Should further be noted that the shape of venthole will be opened with guider The shape at mouth end matches, so that guider can be connected with venthole.
Board-like distributor is a circular plate-like shape structure in the top view for board-like distributor shown in Fig. 3, this figure, and is wrapped The venthole included is circular venthole.When reactor air inlet transmits reacting gas to board-like distributor, reacting gas leads to Each venthole is crossed to flow in each guider being connected with venthole.In addition, board-like distributor surrounding be evenly arranged to A few bolt hole 302, board-like distributor is fixed by these bolts hole and reactor shell.
In the present embodiment, what is no matter selected is the number of board-like distributor or pipe distributor, venthole and guider Magnitude relation at least may have following two situations:
Situation one:Each venthole on distributor body corresponds to one guider of connection.Such as, board-like distributor In be provided with 100 ventholes, then each venthole in 100 ventholes corresponds to one guider of connection.
Situation two:There was only venthole correspondence one guider of connection in part in all ventholes on distributor body. Such as, 100 ventholes are provided with board-like distributor, then only have 50 outlet pore size distribution correspondences to connect in 100 ventholes Connect a guider.It is noted herein that the distribution situation of the venthole of connection guider can be true according to business need It is fixed, such as can be with distributor body horizontal center line as boundary, the venthole on the upside of horizontal center line corresponds to connection one Individual guider, and the venthole on the downside of horizontal center line is not connected to guider.
According to above-described embodiment, distributor body can include pipe distributor or board-like distributor, can be according to difference Business need choose the type of distributor body, therefore improve the application flexibility of distributor body.
In an embodiment of the invention, the guider in structural representation as shown in Figure 1 is the pipe that one end is closed Shape structure, and it is provided with tube wall at least one through hole.
In the present embodiment, the concrete shape of tubular structure can be determined according to business need, such as can be square tube Shape structure can also be round tube shape structure.Shape, size and the depth of cavity can be according to business in other tubular structure It is required that determining, such as the cylindrical cavity from a diameter of 5 millimeters.
In the present embodiment, the number and shape of the through hole set on the tube wall of tubular structure can also be wanted according to business Ask determination.It should be noted that set location of the through hole on tube wall is relevant with the quantity of through hole, and can at least exist following Two kinds of situations:
Situation one:When the quantity of through hole is one, a through hole can be arranged on the optional position on tube wall;
Situation two:When the quantity of through hole is at least two, at least two through holes are equally distributed to be arranged on tube wall.
In addition, the perforate direction of through hole can towards the openend of guider, can also towards guider blind end.Its The perforate direction of middle through hole towards the openend of guider be a kind of preferred perforate direction.The position of opening of through hole is to guider The distance of openend can also be determined according to business need.
In the present embodiment, when reacting gas enters the body in guider tubular structure, the envelope of tubular structure Closed end turns back the reacting gas of entrance, and is emitted into by the through hole on tubular structure tube wall the catalytic reaction zone of reactor. When the blind end of tubular structure turns back the reacting gas of entrance, the energy that script can dissipate on distributor body is changed into For the rotation function of reacting gas.Reacting gas with rotation function can maintain larger Jet Penetration Depth, make reacting gas Bubble will not become big rapidly, keep minute bubbles high-frequency, so as to increase residence time of the reacting gas in catalytic reaction zone, reach To the purpose for improving fluidization quality.
The guider 401 being illustrated in figure 4 in the front view of guider, figure is the circular tube shaped that a diameter c is 24 millimeters Structure.Include the through hole that 4 diameter a are 2.5 millimeters on tube wall, and 4 through holes are evenly distributed on tube wall.Each through hole Center line B2 and guider vertical axial center line B1 angle k be 44 °, and through hole position of opening to distributor body Apart from b be 9 millimeters.The cavity diameter h of guider tubular structure is 5 millimeters of cylindrical cavity.
According to above-described embodiment, when entering the body in guider tubular structure due to reacting gas, tubular structure Blind end turns back the reacting gas of entrance., can be by originally and the blind end of tubular structure is when the reacting gas of entrance is turned back The energy dissipated on distributor body transforms into the rotation function of reacting gas, anti-in catalytic reaction zone due to entering Gas is answered to carry rotation function, so improving residence time of the reacting gas in catalytic reaction zone.
In an embodiment of the invention, such as, guider is used for the reactor that hydrogenation of chloronitrobenzene prepares the 1wt/a of aniline In, the Jet Penetration Depth of reacting gas wherein is increased due to having used guider in the preparation process, so that passing through distribution The reaction gas flow of device is uniform so that reacting gas can carry out uniform violent reaction with catalyst, to reach effectively Suppress catalyst defluidization or react the carbon distribution caused excessively.So that in crude benzol amine product after reactor is converted, nitrobenzene Content is steady in a long-term in below 10mg/kg, so that catalyst regeneration cycle extended to 7-10 by original 3-4 months Month.
According to above-described embodiment, due to reactor by guider after, the reaction gas with rotation function can be converted to Body, increases the Jet Penetration Depth of reacting gas, so that uniform by the reaction gas flow of distributor so that reacting gas Uniform violent reaction can be carried out with catalyst, to reach effectively suppression catalyst defluidization or react the carbon distribution caused excessively. So as to extend the regeneration period of catalyst.
In an embodiment of the invention, as shown in figure 5, when distributor body be pipe distributor 501 when,
The blind end 5021 of the guider 502 towards the catalytic reaction zone top layer, by the through hole to rotate The mode of jet transmits the reacting gas to the catalytic reaction zone.
In the present embodiment, Fig. 5 is that the low pressure drop high stability distributor that distributor body is pipe distributor is reacting Position view in device 50, the guider being connected in figure with venthole in pipe distributor is a kind of signal.It is low in figure Pressure drop high stability distributor need by the catalytic reaction zone in reactor according to the track L1 shown in figure in reactor Bottom is circulated to the top of reactor.Therefore the through hole direction in the guider that will be connected with venthole on pipe distributor is needed The top layer D1 of catalytic reaction zone, to make through hole transmit reacting gas to the top layer D1 of catalytic reaction zone in the way of rotating jet. Reacting gas can drive catalyst to be flowed according to the track L1 shown in figure.
According to above-described embodiment, when distributor body is using pipe distributor, the blind end direction catalysis of guider The top layer of reaction zone, and reacting gas is transmitted to catalytic reaction zone by way of included through hole is with rotating jet, so that Reacting gas can promote catalyst to flow, so as to improve the mobility of catalyst.
In an embodiment of the invention, as shown in fig. 6, distributor body use board-like distributor 601 when,
The blind end 6021 of the guider 602 towards the catalytic reaction zone bottom, by the through hole to rotate The mode of jet transmits the reacting gas to the catalytic reaction zone.
In the present embodiment, Fig. 6 is that the low pressure drop high stability distributor that distributor body is board-like distributor is reacting Position view in device 60, with the guider that venthole is connected in board-like distributor is a kind of signal in figure.It is low in figure Pressure drop high stability distributor 601 need by the catalytic reaction zone in reactor according to the track L2 shown in figure in reactor Bottom be circulated to the top of reactor, it is therefore desirable to by with the through hole court in the guider that venthole is connected on board-like distributor Reacting gas is discharged to the bottom D2 of catalytic reaction zone, to make bottom D2 of the through hole to catalytic reaction zone in the way of rotating jet Transmit reacting gas.Reacting gas can drive catalyst to be flowed according to the track L2 shown in figure.
According to above-described embodiment, when distributor body is using board-like distributor, the blind end direction catalysis of guider Reaction zone bottom, and reacting gas is transmitted to catalytic reaction zone by way of included through hole is with rotating jet, so that instead Answer gas catalyst can be promoted to flow, so as to improve the mobility of catalyst.
In an embodiment of the invention, as shown in figure 4, the blind end of the guider 401 is cone structure 403.
In the present embodiment, the shape and size of the blind end of guider can be determined according to business need, due to working as The blind end of guider be cone structure, the stress when blind end that can reduce guider is in contact with catalytic reaction zone, because This cone structure is a kind of preferred structure.
As shown in figure 4, the guider shown in figure, it is 13 millimeters to include height d, and diameter c is 24 millimeters of taper knot Structure, and be 20 millimeters apart from e.
According to above-described embodiment, when the blind end of guider is cone structure, the blind end and catalytic reaction of guider When area is in contact, it is possible to reduce the stress that guider is born, so as to reduce the probability that guider is deformed.
In an embodiment of the invention, as shown in figure 4, the surface of each guider 401 be enclosed with it is wear-resisting Lining 404.
In the present embodiment, during reactor is run, there are the feelings being in contact in guider with the catalyst flowed Condition.When being in contact, catalyst can produce certain abrasion to guider, therefore in order to reduce the abrasion condition of guider, often The surface of one guider is required to be enclosed with wear-resisting lining.
The material and thickness of wear-resisting lining can be determined according to business need, such as can be 0.5 millimeter from thickness Ceramic wear-resisting is served as a contrast or corundum wear-resisting lining.
As shown in figure 4, it 404 is just wear-resisting lining that the thickness in figure, which is 0.5 millimeter,.
According to above-described embodiment, the surface of each guider is enclosed with wear-resisting lining.Connect in catalyst with guider When touching, it is possible to reduce the scuffing of guider, so as to effectively improve the service life of guider.
In an embodiment of the invention, as shown in figure 4, the openend 405 of the guider 401 by welding manner with The corresponding venthole 4021 is connected on the distributor body 402.
In the present embodiment, the openend for being oriented to gas can be by the welding manners such as electric welding or argon arc welding and distributor body Upper corresponding gas outlet is connected.It should be noted that need to make openend be in concentric with venthole in welding, with Reacting gas is set to circulate unobstructed.
According to above-described embodiment, the openend of guider passes through the welding manner venthole corresponding with distributor body It is connected.Because welding manner is that guider can be made to be firmly fixed on distributor body, therefore guider is in distributor sheet Steadiness on body is higher.
In an embodiment of the invention, as shown in figure 4, the openend 405 of the guider 401 by snap fit with The corresponding venthole 4021 is connected on the distributor body 402.
In the present embodiment, the openend of guider can be provided with least one buckle, in going out for distributor body At least one bayonet socket corresponding with least one buckle is provided with stomata.When guider openend by snap fit with When corresponding venthole is connected on distributor body, the buckle set by openend bayonet socket corresponding with venthole matches Close, guider is fixed on corresponding venthole.
According to above-described embodiment, the openend of guider passes through the snap fit venthole phase corresponding with distributor Even.Due to using clamping connected mode, guider convenient disassembly, therefore maintenance and changing the convenience height of guider.
In an embodiment of the invention, as shown in fig. 7, being provided with flange on the openend 705 of the guider 701 At least one bolt hole 7031 is provided with 703, and the flange 703;
At least one corresponding with venthole each described 7021 respectively is provided with the distributor body 702 Bolt hole 7022;
Each described guider 701, utilizes at least one bolt hole 7031 and the venthole on the flange 703 7021 at least one corresponding bolt hole 7022, are connected by way of bolt 704 is connected with the corresponding venthole 7021.
In the present embodiment, when guider openend uses flange, the outlet being connected on distribution body with guider Hole surrounding need to be provided with the bolt hole corresponding with the number of bolt hole of flange and position, to allow to be directed to device by bolt The flange of openend is connected with corresponding venthole.
In the present embodiment, the flange specification and material of guider openend can be determined according to business need.
Include as shown in fig. 7, guider openend includes on titanium, 600 pounds and a diameter of 40 millimeters of flange, flange Have 4 bolts hole being evenly arranged, then the venthole surrounding in corresponding distribution body body be provided with size it is identical and The bolt hole being evenly arranged.The flange for being directed to device openend by 4 bolts is connected with corresponding venthole.P1 in figure, P2 and P3 length can determine according to business need, it should be noted that P2 length be greater than guider blind end most Broadly square width, to there is enough operating spaces, can be such that bolt is screwed into bolt hole.
According to above-described embodiment, flange is provided with the openend of guider, and is provided with flange at least one spiral shell Keyhole, when guider is connected with venthole, using the corresponding bolt hole of bolt hole and venthole on flange in guider, leads to Bolted mode is crossed with venthole to be connected.Due to using bolt connecting mode, guider convenient disassembly, therefore maintenance It is high with the convenience for changing guider.
In an embodiment of the invention, as shown in figure 4, each described guider 401 is round tube shape structure, and it is described Openend 405 is provided with pin thread;
Negative thread is provided with the corresponding venthole 4021 of each described guider 401;
Each described guider 401, utilizes the moon in the pin thread on the openend 405 and the venthole 4021 Screw thread, the mode being connected through a screw thread is connected with the corresponding venthole 4021;
In the present embodiment, the specification and size of the negative thread in the pin thread and venthole of guider openend To be determined according to business need.It should be noted that the negative thread in the pin thread and venthole of guider openend should be pair The specification and size answered, so that guider and venthole can be connected.
According to above-described embodiment, when guider is connected with the venthole on distributor body, it is possible to use guider is opened Negative thread in the pin thread and venthole at mouth end, the mode being connected through a screw thread makes guider be connected with corresponding venthole, Due to using thread connecting mode, guider convenient disassembly, therefore maintenance and changing the convenience height of guider.
In an embodiment of the invention, as shown in figure 4, each described guider 401 is round tube shape structure, and it is described Openend 405 is provided with negative thread;
Pin thread is provided with the corresponding venthole 4021 of each described guider 401;
Each described guider 401, utilizes the sun outside the negative thread on the openend 405 and the venthole 4021 Screw thread, the mode being connected through a screw thread is connected with the corresponding venthole 4021.
In the present embodiment, the specification and size of the pin thread in the negative thread and venthole of guider openend To be determined according to business need.It should be noted that the pin thread in the negative thread and venthole of guider openend should be pair The specification and size answered, so that guider and venthole can be connected.
According to above-described embodiment, when guider is connected with the venthole on distributor body, it is possible to use guider is opened Pin thread in the negative thread and venthole at mouth end, the mode being connected through a screw thread makes guider be connected with corresponding venthole, Due to using thread connecting mode, guider convenient disassembly, therefore maintenance and changing the convenience height of guider.
In an embodiment of the invention, as shown in figure 4, the external diameter of the openend 405 of each guider 401 is small In the external diameter of blind end 403.
In the present embodiment, the external diameter of the openend of guider is less than the external diameter of blind end, can so reduce distributor The size of venthole in body, so as to increase the percent opening of distributor body.In addition, the external diameter of the openend of guider is less than envelope During the external diameter of closed end, not only install more convenient, and the material used in generation guider can be reduced.
As shown in figure 4, the diameter i of the openend of guider is 14, the diameter c of blind end is 24.And openend 405 with When venthole in distributor body is connected, the top of blind end and distributor body has apart from the spacing that f is 2 millimeters.
According to above-described embodiment, the external diameter of the openend of each guider is less than the external diameter of blind end, due to openend The size with the venthole on distributor body is needed to match, when the external diameter that the external diameter of openend is less than blind end can increase The percent opening of distributor body.
As shown in figure 8, the embodiments of the invention provide a kind of reactor, the reactor includes:Housing 801, air inlet 802, catalytic reaction zone 803 and any of the above-described described distributor 804;
The housing 801, for fixing the distributor 804;
The air inlet 802, for reacting gas to be transferred into the distributor 804, so that the distributor 804 is with rotation The mode for turning jet transmits the reacting gas to the catalytic reaction zone 803;
The catalytic reaction zone 803, for receiving the reacting gas that the distributor 804 is transmitted.
According to embodiment as shown in Figure 8, the reactor includes:Housing, air inlet, catalytic reaction zone and distributor, Wherein, the reacting gas of air inlet port transmission is discharged into catalytic reaction zone by distributor, due to including guider in the distributor, After venthole of the reacting gas of air inlet port transmission by distributor body, catalytic reaction zone is not entered directly into, but enter Enter into the guider being connected with venthole, then again will by way of the through hole included by each guider is with rotating jet The reacting gas is transmitted to the catalytic reaction zone of reactor, therefore the embodiment of the present invention can be in relatively low distribution grid pressure reduction conditions Lower guarantee jet is uniform and depth.
As shown in figure 9, the embodiments of the invention provide a kind of application method of low pressure drop high stability distributor, reactor The 1200t/a productions of p-Cyanochlorobenzene are prepared for parachlorotoluene gas phase ammonoxidation, the use of distributor body are pipe distributor Low pressure drop high stability distributor, venthole connection in pipe distributor for the guider shown in Fig. 4, this method can be with Including:
Step 901:Each guider, utilizes the moon in the venthole in the pin thread and pipe distributor on openend Screw thread, the mode being connected through a screw thread is connected with corresponding venthole.
, it is necessary to which venthole whole in pipe distributor is all connected with into guider in the present embodiment.Such as, the tubular type used Distributor includes 100 ventholes being evenly arranged, and each venthole is provided with negative thread.The guider used Openend is provided with pin thread, by each guider in 100 guiders, utilizes the pin thread on openend and tubular type point The negative thread in venthole in cloth device, the mode being connected through a screw thread is connected with corresponding venthole.
Step 902:The pipe distributor for being connected to guider is fixed on the housing of reactor, and with reactor air inlet Mouth is connected.
In this step, the bolt hole being evenly arranged using pipe distributor surrounding, guider will be connected to by bolt Pipe distributor be fixed on the housing of reactor, and be connected with reactor air inlet, so that air inlet port transmission can be received Air.
Step 903:Reacting gas is transferred to pipe distributor by the air inlet of reactor.
In this step, air is transferred to pipe distributor by the air inlet of reactor.
Step 904:Pipe distributor receives the reacting gas of reactor air inlet port transmission, and will be anti-by each venthole Gas transport is answered to each guider.
In this step, pipe distributor receives the reaction gas including ammonia and parachlorotoluene of reactor air inlet port transmission Body, and air is transferred to by each guider by each venthole.
Step 905:Each guider transmits connected venthole by way of included through hole is with rotating jet The reacting gas come is transmitted to the catalytic reaction zone of reactor.
In this step, when air enters the body in guider tubular structure, the blind end of tubular structure will The air of entrance is turned back, and is emitted into by the through hole on tubular structure tube wall the catalytic reaction zone of reactor.Tubular structure When blind end turns back the air of entrance, the rotation that the energy that script can dissipate on distributor body transforms into air is moved Can, and the air with rotation function is transmitted in the way of rotating jet to the catalytic reaction zone of reactor.
Step 906:Catalytic reaction zone receives the reacting gas of each guider transmission, anti-to be carried out using reacting gas Should, and flowed under the drive of reacting gas.
In this step, after air enters catalytic reaction zone, ammonia and parachlorotoluene and air contacted with catalyst into Row ammoxidation reaction.Wherein, the mol ratio of parachlorotoluene and ammonia is 1:The mol ratio of 4-8, parachlorotoluene and oxygen is 1:9 to 1:5, Catalyst emulsion zone reaction temperature is at 430 DEG C, and the actual gas velocity of catalyst emulsion zone is 0.3m/s.When being reacted, due to sky Gas carries rotation function, air-spray depth is increased, so that uniform by the air mass flow of distributor so that air energy Enough and catalyst carries out uniform violent reaction, to reach effectively suppression catalyst defluidization or react the carbon distribution caused excessively.Cause Parachlorotoluene conversion ratio can reach 99% in this reaction, can selectively reach 95%.
In summary, each embodiment of the invention can at least realize following beneficial effect:
1st, in embodiments of the present invention, the distributor includes:Distributor body and at least one guider, wherein, it is each The openend of individual guider is connected with a venthole on distributor body, when distributor body receives external reactors air inlet During the reacting gas of port transmission, reacting gas is transferred to each coupled guider by each venthole of itself. Then connected venthole is transmitted the reacting gas come with rotating jet by each guider by the through hole included by itself Mode transmit to the catalytic reaction zone of external reactors.By said process, reacting gas passes through distribution in this programme After the venthole of device body, catalytic reaction zone is not entered directly into, and is into the guider being connected with venthole, is made Reacting gas is obtained to be changed into rotational flow gas and transmit in the way of rotating jet to the catalytic reaction zone of external reactors.Due to rotation The uniform stability of jet and depth that the extra circular rector stability that gas body has can improve reacting gas.Therefore the present invention is carried The embodiment of confession can ensure that jet is uniform and depth under relatively low distribution grid pressure reduction conditions.
2nd, in embodiments of the present invention, distributor body can include pipe distributor or board-like distributor, can basis Different business needs chooses the type of distributor body, therefore improves the application flexibility of distributor body.
3rd, in embodiments of the present invention, when entering the body in guider tubular structure due to reacting gas, tubulose knot The blind end of structure turns back the reacting gas of entrance., can be by and the blind end of tubular structure is when the reacting gas of entrance is turned back Originally the energy dissipated on distributor body transforms into the rotation function of reacting gas, due to entering in catalytic reaction zone Reacting gas carry rotation function, so improving residence time of the reacting gas in catalytic reaction zone.
4th, in embodiments of the present invention, due to reactor by guider after, can be converted to the anti-of rotation function Gas is answered, the Jet Penetration Depth of reacting gas is increased, so that uniform by the reaction gas flow of distributor so that reaction Gas can carry out uniform violent reaction with catalyst, to reach effectively suppression catalyst defluidization or react the product caused excessively Carbon.So as to extend the regeneration period of catalyst.
5th, in embodiments of the present invention, when distributor body is using pipe distributor, the blind end direction of guider The top layer of catalytic reaction zone, and reacting gas is transmitted to catalytic reaction zone by way of included through hole is with rotating jet, So that reacting gas can promote catalyst to flow, so as to improve the mobility of catalyst.
6th, in embodiments of the present invention, when distributor body is using board-like distributor, the blind end direction of guider Catalytic reaction zone bottom, and reacting gas is transmitted to catalytic reaction zone by way of included through hole is with rotating jet, with Reacting gas is set to promote catalyst to flow, so as to improve the mobility of catalyst.
7th, in embodiments of the present invention, when the blind end of guider is cone structure, the blind end of guider and catalysis When reaction zone is in contact, it is possible to reduce the stress that guider is born, so as to reduce the probability that guider is deformed.
8th, in embodiments of the present invention, the surface of each guider is enclosed with wear-resisting lining.In catalyst and guider When being in contact, it is possible to reduce the scuffing of guider, so as to effectively improve the service life of guider.
9th, in embodiments of the present invention, the openend of guider goes out by the way that welding manner is corresponding with distributor body Stomata is connected.Because welding manner is that guider can be made to be firmly fixed on distributor body, therefore guider is in distribution Steadiness on device body is higher.
10th, in embodiments of the present invention, the openend of guider passes through the snap fit outlet corresponding with distributor Hole is connected.Due to using clamping connected mode, guider convenient disassembly, therefore maintenance and the convenience for changing guider It is high.
11st, in embodiments of the present invention, flange is provided with the openend of guider, and is provided with flange at least one Individual bolt hole, when guider is connected with venthole, utilizes the corresponding bolt of bolt hole and venthole on flange in guider Hole, the mode being bolted is connected with venthole.Due to using bolt connecting mode, guider convenient disassembly, because This maintenance and the convenience height for changing guider.
12nd, in embodiments of the present invention, when guider is connected with the venthole on distributor body, it is possible to use be oriented to Negative thread in the pin thread and venthole of device openend, the mode being connected through a screw thread makes guider and corresponding venthole phase Even, due to using thread connecting mode, guider convenient disassembly, therefore maintenance and changing the convenience height of guider.
13rd, in embodiments of the present invention, when guider is connected with the venthole on distributor body, it is possible to use be oriented to Pin thread in the negative thread and venthole of device openend, the mode being connected through a screw thread makes guider and corresponding venthole phase Even, due to using thread connecting mode, guider convenient disassembly, therefore maintenance and changing the convenience height of guider.
14th, in embodiments of the present invention, the external diameter of the openend of each guider is less than the external diameter of blind end, due to opening Mouthful end needs the size with the venthole on distributor body to match, when the external diameter of openend can be with less than the external diameter of blind end Increase the percent opening of distributor body.
15th, in embodiments of the present invention, the reactor includes:Housing, air inlet, catalytic reaction zone and distributor, its In, the reacting gas of air inlet port transmission is discharged into catalytic reaction zone by distributor, due to including guider in the distributor, is entered After venthole of the reacting gas of gas port transmission by distributor body, catalytic reaction zone is not entered directly into, but enter Into the guider being connected with venthole, then again by way of the through hole included by each guider is with rotating jet by institute Reacting gas is stated to transmit to the catalytic reaction zone of reactor, therefore the embodiment of the present invention can be under relatively low distribution grid pressure reduction conditions Ensure that jet is uniform and depth.
16th, in embodiments of the present invention, connect due to changing jet front end with solid catalyst particle in catalytic reaction zone The mode of touching, therefore the abrasion of solid catalyst particle can be reduced, so as to extend the service life of solid catalyst, reach Cost-effective purpose.And due to reducing the abrasion of solid catalyst particle, reduce the solid after solid catalyst abrasion The discharge capacity of grain fine powder.
It should be noted that herein, such as first and second etc relational terms are used merely to an entity Or operation makes a distinction with another entity or operation, and not necessarily require or imply exist between these entities or operation Any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant be intended to it is non- It is exclusive to include, so that process, method, article or equipment including a series of key elements not only include those key elements, But also other key elements including being not expressly set out, or also include solid by this process, method, article or equipment Some key elements.In the absence of more restrictions, the key element limited by sentence " including one ", is not arranged Except also there is other identical factor in the process including the key element, method, article or equipment.
It is last it should be noted that:Presently preferred embodiments of the present invention is the foregoing is only, the skill of the present invention is merely to illustrate Art scheme, is not intended to limit the scope of the present invention.Any modification for being made within the spirit and principles of the invention, Equivalent substitution, improvement etc., are all contained in protection scope of the present invention.

Claims (10)

1. a kind of low pressure drop high stability distributor, it is characterised in that including:Distributor body and at least one guider;
The guider is the tubular structure that one end is closed, and is provided with tube wall at least one through hole;
At least one venthole is provided with the distributor body;
The openend of each guider is connected with a venthole on the distributor body, and different institutes State the different venthole of guider correspondence;
The distributor body, the reacting gas for receiving external reactors air inlet port transmission, and pass through outlet each described The reacting gas is transferred to each guider by hole;
Each described guider, for by least one through hole described in included, the connected venthole to be transmitted The reacting gas come is transmitted in the way of rotating jet to the catalytic reaction zone of the external reactors.
2. distributor according to claim 1, it is characterised in that
The distributor body, including:Pipe distributor or board-like distributor;
Wherein, the pipe distributor includes being provided with described at least one at least one airway tube, each airway tube Venthole, and the airway tube is connected with the reactor air inlet;The board-like distributor is platy structure, the tabular knot At least one described venthole is provided with structure, and the board-like distributor is connected with the reactor air inlet.
3. distributor according to claim 2, it is characterised in that
When the distributor body includes pipe distributor,
The blind end of the guider towards the catalytic reaction zone top layer, by way of the through hole is with rotating jet to Transmit the reacting gas in the catalytic reaction zone;
When the distributor body includes board-like distributor,
The blind end of the guider towards the catalytic reaction zone bottom, by way of the through hole is with rotating jet to Transmit the reacting gas in the catalytic reaction zone.
4. distributor according to claim 1, it is characterised in that
The blind end of the guider is cone structure.
5. distributor according to claim 4, it is characterised in that
The surface of each guider is enclosed with wear-resisting lining.
6. distributor according to claim 1, it is characterised in that
The openend of the guider is connected by the welding manner venthole corresponding with the distributor body;
Or,
The openend of the guider is connected by the snap fit venthole corresponding with the distributor body.
7. distributor according to claim 1, it is characterised in that
It is provided with the openend of the guider on flange, and the flange and is provided with least one bolt hole;
At least one corresponding with venthole each described respectively bolt hole is provided with the distributor body;
Each described guider, using at least one bolt hole and the venthole on the flange it is corresponding at least one Bolt hole, the mode being bolted is connected with the corresponding venthole.
8. distributor according to claim 1, it is characterised in that
Each described guider is round tube shape structure, and the openend is provided with pin thread;
Negative thread is provided with the corresponding venthole of each described guider;
Each described guider, using the negative thread in the pin thread on the openend and the venthole, passes through screw thread The mode of connection is connected with the corresponding venthole;
Or,
Each described guider is round tube shape structure, and the openend is provided with negative thread;
Pin thread is provided with the corresponding venthole of each described guider;
Each described guider, using the pin thread outside the negative thread on the openend and the venthole, passes through screw thread The mode of connection is connected with the corresponding venthole.
9. distributor according to claim 6, it is characterised in that
The external diameter of the openend of each guider is less than the external diameter of blind end.
10. a kind of reactor, it is characterised in that including:Housing, air inlet, catalytic reaction zone and claim 1 to 9 are any Described distributor;
The housing, for fixing the distributor;
The air inlet, for reacting gas to be transferred into the distributor, to make the distributor in the way of rotating jet The reacting gas is transmitted to the catalytic reaction zone;
The catalytic reaction zone, the reacting gas for receiving the distributor transmission.
CN201710494882.5A 2017-06-26 2017-06-26 A kind of low pressure drop high stability distributor and reactor Pending CN107224941A (en)

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1481930A (en) * 2002-12-17 2004-03-17 中国石油化工股份有限公司 Fluidized bed reactor gases distributing plate
CN1583237A (en) * 2004-06-05 2005-02-23 石油大学(华东) Hood gad distributing board
CN201605166U (en) * 2009-11-27 2010-10-13 上海森和投资有限公司 Hydrogenation silicon tetrachloride boiling bed reactor
CN105289424A (en) * 2015-11-25 2016-02-03 苏州天沃科技股份有限公司 Fluidized bed reactor apparatus blast cap and distribution plate assembling structure
CN205550237U (en) * 2016-03-11 2016-09-07 湖北兴瑞化工有限公司 Organosilicon fluidized bed reactor gas distribution arrangement
US20160257626A1 (en) * 2013-10-31 2016-09-08 Shell Oil Company Process for converting oxygenates to olefins
CN206853645U (en) * 2017-06-26 2018-01-09 辽宁加宝石化设备有限公司 A kind of low pressure drop high stability distributor and reactor

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1481930A (en) * 2002-12-17 2004-03-17 中国石油化工股份有限公司 Fluidized bed reactor gases distributing plate
CN1583237A (en) * 2004-06-05 2005-02-23 石油大学(华东) Hood gad distributing board
CN201605166U (en) * 2009-11-27 2010-10-13 上海森和投资有限公司 Hydrogenation silicon tetrachloride boiling bed reactor
US20160257626A1 (en) * 2013-10-31 2016-09-08 Shell Oil Company Process for converting oxygenates to olefins
CN105289424A (en) * 2015-11-25 2016-02-03 苏州天沃科技股份有限公司 Fluidized bed reactor apparatus blast cap and distribution plate assembling structure
CN205550237U (en) * 2016-03-11 2016-09-07 湖北兴瑞化工有限公司 Organosilicon fluidized bed reactor gas distribution arrangement
CN206853645U (en) * 2017-06-26 2018-01-09 辽宁加宝石化设备有限公司 A kind of low pressure drop high stability distributor and reactor

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Application publication date: 20171003