CN107216662A - A kind of high temperature polymeric materialses - Google Patents
A kind of high temperature polymeric materialses Download PDFInfo
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- CN107216662A CN107216662A CN201710461248.1A CN201710461248A CN107216662A CN 107216662 A CN107216662 A CN 107216662A CN 201710461248 A CN201710461248 A CN 201710461248A CN 107216662 A CN107216662 A CN 107216662A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2248—Oxides; Hydroxides of metals of copper
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
- C08K2003/3063—Magnesium sulfate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of high temperature polymeric materialses, it is prepared from the following raw materials in parts by weight：20 60 parts of plastics；40 70 parts of pitch；15 25 parts of retarder thinner；5 10 parts of compatilizer；30 50 parts of vulcanized rubber powder；21 34 parts of cupric oxide；15 parts of magnesium sulfate；1 25 parts of corrosion-resistant agent；1 20 parts of anti-wear agent；22 67 parts of absolute ethyl alcohol；22 40 parts of lubricant；12 30 parts of Zirconium oxide fibre；Three 20 30 parts of silica.A kind of high temperature polymeric materialses that the present invention is provided, with Zirconium oxide fibre, its resistance to elevated temperatures is good, and with anti-wear performance, and service life is long.
Description
Technical field
The present invention relates to technical field of polymer materials, more particularly to a kind of high temperature polymeric materialses.
Background technology
Material is important substance composition indispensable in modern society's process.The macromolecule being made up of high-molecular compound
Material is a major class of most representative and development prospect at present.High polymer material abundant raw material, quality is light and handy, possesses excellent
Mechanical property and processing characteristics, thus people gradually use it to replace traditional metal material and inorganic non-metallic material, extensively
It is general to be applied to each science and technology and economic construction field.And in recent years, the high speed development pair of the high-end technical industry such as Aero-Space
New requirement, such as high temperature resistant are proposed in synthesis high polymer material, corrosion-resistant, high intensity, radiation hardness etc., therefore high temperature resistant corrosion resistant
The important research direction for being developed into Material Field of erosion high polymer material, and corrosion-and high-temp-resistant macromolecule material in the prior art
Material is adding the mechanical performance of material in itself, while improving heat resisting corrosion-proof performance, also in the presence of easy aging, brittle, resistance to
The shortcomings of grinding poor performance, have impact on the use life cycle of material.
The content of the invention
In order to solve the above problems, the invention provides a kind of process of high temperature polymeric materialses, with solution
State the problem of being proposed in background technology.
To solve the above problems, technical scheme proposed by the present invention is：
A kind of high temperature polymeric materialses, it is characterised in that be prepared from the following raw materials in parts by weight：20-60 parts of plastics；Pitch
40-70 parts；15-25 parts of retarder thinner；5-10 parts of compatilizer；30-50 parts of vulcanized rubber powder；Cupric oxide 21-34
Part；1-5 parts of magnesium sulfate；1-25 parts of corrosion-resistant agent；1-20 parts of anti-wear agent；22-67 parts of absolute ethyl alcohol；22-40 parts of lubricant；Oxygen
Change 12-30 parts of zirconium fiber；Three 20-30 parts of silica.
In some embodiments, it is prepared from the following raw materials in parts by weight：20-35 parts of plastics；40-50 parts of pitch；It is dilute
Release 15-22 parts of solvent；6-10 parts of compatilizer；30-45 parts of vulcanized rubber powder；21-34 parts of cupric oxide；Magnesium sulfate 1-5
Part；1-25 parts of corrosion-resistant agent；1-20 parts of anti-wear agent；22-67 parts of absolute ethyl alcohol；22-40 parts of lubricant；Zirconium oxide fibre 12-30
Part；Three 20-25 parts of silica.
In some embodiments, the plastics be polyethylene, polypropylene, polyvinyl chloride, polystyrene and propylene it is blue or green-
The one or more of butadiene-styrene copolymerized compound.
In some embodiments, the lubricant is fatty acid acyl amine, hydro carbons, fatty acid, esters, alcohols, gold
Belong to any one in soaps, compounded lubricant.
In some embodiments, the raw material that the anti-wear agent has following parts by weight is made：Epoxy natural rubber 12-35
Part, 11-15 parts of triethyl citrate, 10-20 parts of Cosan, 5-10 parts of magnesinm methacrylate, adipic acid propanediol polyester 2-10
Part, 13-23 parts of calcium-zinc composite stabilizing agent, 10-40 parts of titanium dioxide, 12-40 parts of Tissuemat E, 3-10 parts of methyl acrylate, plasticising
3-10 parts of agent, 2-16 parts of water.
In some embodiments, the raw material that the anti-wear agent has following parts by weight is made：Epoxy natural rubber 12-23
Part, 11-14 parts of triethyl citrate, 10-15 parts of Cosan, 5-8 parts of magnesinm methacrylate, 2-8 parts of adipic acid propanediol polyester,
13-23 parts of calcium-zinc composite stabilizing agent, 10-40 parts of titanium dioxide, 12-40 parts of Tissuemat E, 3-10 parts of methyl acrylate, plasticizer
3-10 parts, 2-16 parts of water.
A kind of high temperature polymeric materialses that the present invention is provided, with Zirconium oxide fibre, its resistance to elevated temperatures is good, with resistance to
Performance is ground, and service life is long.
Embodiment
Specific embodiment is described in further detail explanation to technical scheme below.
Embodiment 1：
A kind of high temperature polymeric materialses, it is characterised in that be prepared from the following raw materials in parts by weight：20-60 parts of plastics；Pitch
40-70 parts；15-25 parts of retarder thinner；5-10 parts of compatilizer；30-50 parts of vulcanized rubber powder；Cupric oxide 21-34
Part；1-5 parts of magnesium sulfate；1-25 parts of corrosion-resistant agent；1-20 parts of anti-wear agent；22-67 parts of absolute ethyl alcohol；22-40 parts of lubricant；Oxygen
Change 12-30 parts of zirconium fiber；Three 20-30 parts of silica.
Wherein, it is prepared from the following raw materials in parts by weight：26 parts of plastics；45 parts of pitch；17 parts of retarder thinner；Compatilizer 6
Part；33 parts of vulcanized rubber powder；32 parts of cupric oxide；4 parts of magnesium sulfate；22 parts of corrosion-resistant agent；5 parts of anti-wear agent；25 parts of absolute ethyl alcohol；
25 parts of lubricant；22 parts of Zirconium oxide fibre；Three 24 parts of silica.
Wherein, the plastics are polyethylene, polypropylene, polyvinyl chloride, polystyrene and propylene green grass or young crops-butadiene-benzene second
The one or more of alkene co-polymer.
Wherein, the lubricant is fatty acid acyl amine, hydro carbons, fatty acid, esters, alcohols, metal soap, compound profit
Any one in lubrication prescription.
Wherein, the raw material that the anti-wear agent has following parts by weight is made：12-35 parts of epoxy natural rubber, citric acid three
11-15 parts of ethyl ester, 10-20 parts of Cosan, 5-10 parts of magnesinm methacrylate, 2-10 parts of adipic acid propanediol polyester, Ca Zn composite
13-23 parts of stabilizer, 10-40 parts of titanium dioxide, 12-40 parts of Tissuemat E, 3-10 parts of methyl acrylate, 3-10 parts of plasticizer,
2-16 parts of water.
Wherein, the raw material that the anti-wear agent has following parts by weight is made：15 parts of epoxy natural rubber, triethyl citrate
13 parts, 12 parts of Cosan, 6 parts of magnesinm methacrylate, 6 parts of adipic acid propanediol polyester, 15 parts of calcium-zinc composite stabilizing agent, titanium dioxide
16 parts, 18 parts of Tissuemat E, 7 parts of methyl acrylate, 6 parts of plasticizer, 12 parts of water.
A kind of high temperature polymeric materialses that the present invention is provided, with Zirconium oxide fibre, its resistance to elevated temperatures is good, with resistance to
Performance is ground, and service life is long.
Embodiment 2：
A kind of high temperature polymeric materialses, it is characterised in that be prepared from the following raw materials in parts by weight：20-60 parts of plastics；Pitch
40-70 parts；15-25 parts of retarder thinner；5-10 parts of compatilizer；30-50 parts of vulcanized rubber powder；Cupric oxide 21-34
Part；1-5 parts of magnesium sulfate；1-25 parts of corrosion-resistant agent；1-20 parts of anti-wear agent；22-67 parts of absolute ethyl alcohol；22-40 parts of lubricant；Oxygen
Change 12-30 parts of zirconium fiber；Three 20-30 parts of silica.
Wherein, it is prepared from the following raw materials in parts by weight：26 parts of plastics；45 parts of pitch；17 parts of retarder thinner；Compatilizer 8
Part；33 parts of vulcanized rubber powder；32 parts of cupric oxide；4 parts of magnesium sulfate；22 parts of corrosion-resistant agent；5 parts of anti-wear agent；60 parts of absolute ethyl alcohol；
35 parts of lubricant；22 parts of Zirconium oxide fibre；Three 28 parts of silica.
Wherein, the plastics are polyethylene, polypropylene, polyvinyl chloride, polystyrene and propylene green grass or young crops-butadiene-benzene second
The one or more of alkene co-polymer.
Wherein, the lubricant is fatty acid acyl amine, hydro carbons, fatty acid, esters, alcohols, metal soap, compound profit
Any one in lubrication prescription.
Wherein, the raw material that the anti-wear agent has following parts by weight is made：12-35 parts of epoxy natural rubber, citric acid three
11-15 parts of ethyl ester, 10-20 parts of Cosan, 5-10 parts of magnesinm methacrylate, 2-10 parts of adipic acid propanediol polyester, Ca Zn composite
13-23 parts of stabilizer, 10-40 parts of titanium dioxide, 12-40 parts of Tissuemat E, 3-10 parts of methyl acrylate, 3-10 parts of plasticizer,
2-16 parts of water.
Wherein, the raw material that the anti-wear agent has following parts by weight is made：15 parts of epoxy natural rubber, triethyl citrate
14 parts, 18 parts of Cosan, 6 parts of magnesinm methacrylate, 6 parts of adipic acid propanediol polyester, 15 parts of calcium-zinc composite stabilizing agent, titanium dioxide
16 parts, 18 parts of Tissuemat E, 5 parts of methyl acrylate, 6 parts of plasticizer, 16 parts of water.
A kind of high temperature polymeric materialses that the present invention is provided, with Zirconium oxide fibre, its resistance to elevated temperatures is good, with resistance to
Performance is ground, and service life is long.
Described above is only the preferred embodiment for the present invention, it is noted that to those skilled in the art, is not being taken off
On the premise of from the invention design, some similar modification and improvement can also be made, these also should be regarded as the guarantor of invention
Within the scope of shield.
Claims (6)
1. a kind of high temperature polymeric materialses, it is characterised in that be prepared from the following raw materials in parts by weight：20-60 parts of plastics；
40-70 parts of pitch；15-25 parts of retarder thinner；5-10 parts of compatilizer；30-50 parts of vulcanized rubber powder；Cupric oxide 21-
34 parts；1-5 parts of magnesium sulfate；1-25 parts of corrosion-resistant agent；1-20 parts of anti-wear agent；22-67 parts of absolute ethyl alcohol；Lubricant 22-40
Part；12-30 parts of Zirconium oxide fibre；Three 20-30 parts of silica.
2. a kind of high temperature polymeric materialses according to claim 1, it is characterised in that by the raw material of following parts by weight
It is made：20-35 parts of plastics；40-50 parts of pitch；15-22 parts of retarder thinner；6-10 parts of compatilizer；Vulcanized rubber powder 30-
45 parts；21-34 parts of cupric oxide；1-5 parts of magnesium sulfate；1-25 parts of corrosion-resistant agent；1-20 parts of anti-wear agent；Absolute ethyl alcohol 22-67
Part；22-40 parts of lubricant；12-30 parts of Zirconium oxide fibre；Three 20-25 parts of silica.
3. a kind of high temperature polymeric materialses according to claim 1, it is characterised in that the plastics are polyethylene, gathered
Propylene, polyvinyl chloride, polystyrene and propylene green grass or young crops-butadiene-
The one or more of styrene copolymerized compound.
4. a kind of high temperature polymeric materialses according to claim 1, it is characterised in that the lubricant is fatty acid acyl
Any one in amine, hydro carbons, fatty acid, esters, alcohols, metal soap, compounded lubricant.
5. a kind of high temperature polymeric materialses according to claim 1, it is characterised in that the anti-wear agent has following weight
The raw material of part is made：12-35 parts of epoxy natural rubber, 11-15 parts of triethyl citrate, 10-20 parts of Cosan, metering system
Sour magnesium 5-10 parts, 2-10 parts of adipic acid propanediol polyester, 13-23 parts of calcium-zinc composite stabilizing agent, 10-40 parts of titanium dioxide, polyethylene
12-40 parts of wax, 3-10 parts of methyl acrylate, 3-10 parts of plasticizer, 2-16 parts of water.
6. a kind of high temperature polymeric materialses according to claim 5, it is characterised in that the anti-wear agent has following weight
The raw material of part is made：12-23 parts of epoxy natural rubber, 11-14 parts of triethyl citrate, 10-15 parts of Cosan, metering system
Sour magnesium 5-8 parts, 2-8 parts of adipic acid propanediol polyester, 13-23 parts of calcium-zinc composite stabilizing agent, 10-40 parts of titanium dioxide, Tissuemat E
12-40 parts, 3-10 parts of methyl acrylate, 3-10 parts of plasticizer, 2-16 parts of water.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710461248.1A CN107216662A (en) | 2017-06-19 | 2017-06-19 | A kind of high temperature polymeric materialses |
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| CN201710461248.1A CN107216662A (en) | 2017-06-19 | 2017-06-19 | A kind of high temperature polymeric materialses |
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| CN107216662A true CN107216662A (en) | 2017-09-29 |
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| CN201710461248.1A Pending CN107216662A (en) | 2017-06-19 | 2017-06-19 | A kind of high temperature polymeric materialses |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102924934A (en) * | 2012-10-26 | 2013-02-13 | 无锡中易薄膜科技有限公司 | High-temperature-resistant water-resistant high polymer material and preparation thereof |
| CN105348600A (en) * | 2015-11-09 | 2016-02-24 | 安徽冠泓塑业有限公司 | Wear-resisting agent of household cleaning gloves |
-
2017
- 2017-06-19 CN CN201710461248.1A patent/CN107216662A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102924934A (en) * | 2012-10-26 | 2013-02-13 | 无锡中易薄膜科技有限公司 | High-temperature-resistant water-resistant high polymer material and preparation thereof |
| CN105348600A (en) * | 2015-11-09 | 2016-02-24 | 安徽冠泓塑业有限公司 | Wear-resisting agent of household cleaning gloves |
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