CN107214432A - A kind of welding point high intensity cracking resistance aluminium alloy welding wire - Google Patents

A kind of welding point high intensity cracking resistance aluminium alloy welding wire Download PDF

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Publication number
CN107214432A
CN107214432A CN201710329496.0A CN201710329496A CN107214432A CN 107214432 A CN107214432 A CN 107214432A CN 201710329496 A CN201710329496 A CN 201710329496A CN 107214432 A CN107214432 A CN 107214432A
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China
Prior art keywords
welding
aluminium alloy
high intensity
cracking resistance
welding wire
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CN201710329496.0A
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Chinese (zh)
Inventor
卢齐元
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Anhui Welding Industry Ltd By Share Ltd
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Anhui Welding Industry Ltd By Share Ltd
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Priority to CN201710329496.0A priority Critical patent/CN107214432A/en
Publication of CN107214432A publication Critical patent/CN107214432A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/28Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
    • B23K35/286Al as the principal constituent
    • B23K35/288Al as the principal constituent with Sn or Zn

Abstract

The invention discloses a kind of welding point high intensity cracking resistance aluminium alloy welding wire, it includes following components by mass fraction:Mg, B, Li, Cu, Si, Ti, Cr, Mn, Fe, V, Sr, Na, Zr, Nb, Mo, Pr, Ce, Nd, remaining is Al and inevitable impurity.A kind of welding point proposed by the present invention high intensity cracking resistance aluminium alloy welding wire, its component is reasonable, splashed during welding small, deposited metal dense structure, pore-free occurs with crackle, welding point has high intensity, splitting resistance good, with mother metal bond strength it is big the advantages of, improve hardware overall performance.

Description

A kind of welding point high intensity cracking resistance aluminium alloy welding wire
Technical field
The present invention relates to welding wire technology field, more particularly to a kind of welding point high intensity cracking resistance aluminium alloy welding wire.
Background technology
Aluminium alloy has good specific strength, corrosion resistance and electrical and thermal conductivity, while having excellent formability And weldability, in fields such as space flight and aviation, ship automobile, machine-building, military chemical industry by extensive use.With life and state People's economy is continued to develop, and the demand to aluminum alloy welding connection member is increasing, and the selection to material is continued to optimize, butt welding silk quality The requirement of amount is more and more stricter, and the quality of welding quality, the height of welding efficiency are determined by welding material, welding procedure, Quality inside aluminium alloy welding wire is heavily dependent on the quality of primary aluminum material, and current aluminium alloy welding wire also has component not Rationally, splash big during welding, stomata easily occurs in deposited metal, and strength of welded joint is small, splitting resistance and corrosion-resistant, influence The normal of hardware is used.
The content of the invention
The technical problem existed based on background technology, the present invention is proposed a kind of welding point high intensity cracking resistance aluminium and closed Gold solder silk, its component rationally, is splashed small during welding, and deposited metal dense structure, pore-free occurs with crackle, and welding point has High intensity, splitting resistance are good, with mother metal bond strength it is big the advantages of, improve hardware overall performance.
The present invention proposes a kind of welding point high intensity cracking resistance aluminium alloy welding wire, and it is included following by mass fraction Component:Mg:2-3%, B:0.15-0.25%, Li:0.1-0.2%, Cu:0.2-0.35%, Si:0.25-0.4%, Ti:0.2- 0.3%th, Cr:0.12-0.22%, Mn:0.25-0.4%, Fe:0.15-0.25%, V:0.2-0.3%, Sr:0.1-0.2%, Na:0.15-0.25%, Zr:0.05-0.15%, Nb:0.02-0.1%, Mo:0.15-0.25%, Pr:0.06-0.12%, Ce: 0.15-0.25%, Nd:0.05-0.12%, remaining is Al and inevitable impurity.
In specific embodiment, Mg mass fraction can also for 2.1%, 2.3%, 2.5%, 2.6%, 2.8%, B matter Amount fraction can also be 0.17%, 0.19%, 0.2%, 0.22%, 0.24%, Li mass fraction can also be 0.11%, 0.13%th, 0.15%, 0.17%, 0.19%, Cu mass fraction can also for 0.22%, 0.25%, 0.28%, 0.3%, 0.32%, Si mass fraction can also may be used also for 0.28%, 0.3%, 0.32%, 0.35%, 0.38%, Ti mass fraction Think 0.22%, 0.24%, 0.25%, 0.26%, 0.28%, Cr mass fraction can also for 0.14%, 0.16%, 0.18%th, 0.2%, Mn mass fraction can also for 0.28%, 0.3%, 0.32%, 0.35%, 0.38%, Fe quality point Number can also be 0.17%, 0.19%, 0.2%, 0.22%, 0.24%, V mass fraction can also be 0.21%, 0.23%, 0.25%th, 0.27%, 0.29%, Sr mass fraction can also be 0.12%, 0.14%, 0.15%, 0.16%, 0.18%, Na mass fraction can also for 0.17%, 0.19%, 0.2%, 0.22%, 0.24%, Zr mass fraction can also be 0.06%th, 0.08%, 0.1%, 0.12%, 0.14%, Nb mass fraction can also for 0.03%, 0.04%, 0.06%, 0.07%th, 0.09%, Mo mass fraction can also for 0.17%, 0.19%, 0.2%, 0.22%, 0.24%, Pr quality Fraction can also be 0.07%, 0.08%, 0.09%, 0.1%, 0.11%, Ce mass fraction can also be 0.17%, 0.19%th, 0.2%, 0.22%, 0.24%, Nd mass fraction can also for 0.07%, 0.08%, 0.09%, 0.1%, 0.11%, remaining is Al and inevitable impurity.
Preferably, the mass fraction of B, Li, Ti in aluminium alloy welding wire meets relationship below:1.4%≤(B+Li)/Ti ≤ 2%.
Preferably, Sr, Na weight ratio are 1:1.5-2.
Preferably, the mass fraction of Cu, Cr, Mn, V, Mo in aluminium alloy welding wire meets relationship below:0.8%≤Cr+ Mn+V+Mo≤1.1%.
Preferably, it includes following components by mass fraction:Mg:2.2-2.8%, B:0.18-0.22%, Li:0.12- 0.18%th, Cu:0.25-0.3%, Si:0.3-0.35%, Ti:0.22-0.28%, Cr:0.14-0.2%, Mn:0.3- 0.35%th, Fe:0.18-0.22%, V:0.22-0.28%, Sr:0.12-0.18%, Na:0.18-0.22%, Zr:0.08- 0.12%th, Nb:0.04-0.08%, Mo:0.18-0.22%, Pr:0.08-0.1%, Ce:0.18-0.22%, Nd:0.08- 0.1%, remaining is Al and inevitable impurity.
Preferably, welding condition is as follows:Gas flow is 17-18.5L/min, and weldingvoltage is 22-25V, welding Electric current is 190-210A, and wire feed rate is 11-12.5m/min, and speed of welding is 0.65-0.8m/min.
Preferably, welding condition is as follows:Gas flow is 17.5-18L/min, and weldingvoltage is 23-24V, welding Electric current is 195-205A, and wire feed rate is 11.5-12m/min, and speed of welding is 0.7-0.75m/min.
The present invention is made using conventional fabrication process.
Have well for deposited metal by adjusting the content of Cu, Cr, Mn, V and Mo in aluminium alloy welding wire in the present invention The mechanical properties such as tensile strength, yield strength, hardness and toughness are laid a good foundation, while improving the weldability of aluminium alloy welding wire Energy;By adjusting B, Li, Ti content, because the density of B, Li, Ti three are different, the diffusion velocity in welding fluid is different, by The difference of oxidational losses situation, to ensure deposited metal by quick effective and permanent modification effect, it is to avoid Li, B are rotten easy Decline, it is to avoid the longer shortcoming of Ti deterioration latency stages is used alone, controls B, Li, Ti content, makes to meet function between three Relational expression:1.4%≤(B+Li)/Ti≤2%, B, Li, Ti three coordinate, and deteriorating time is long, and modification effect substantially, promotes heterogeneous The formation of forming core core, prevents the growth and aggregation of tiny crystal grains, promotes cenotype nucleation, makes the overall crystal grain refinement of deposited metal, And the hardening constituent Al of generation3Ti、Al3Li、TiB2It is evenly distributed in α-Al matrixes, as forming core substrate in α-Al matrixes, shows The crystal grain in refinement seam organization is write, recrystallization temperature in deposited metal is improved, dislocation movement by slip is hindered, effectively mitigates the danger of impurity Evil, makes Copper component in deposited metal less and more tiny, while the thick gill shape β phases of appearance are prevented effectively from, so as to improve welding The corrosion resistance and tensile strength of joint, coordinate with Sr, Na, and Sr, Na weight ratio meet 1:1.5-2, further enhance molten The modification effect of metallisation, improves tissue morphology in welding point, reduces the generation of primary silicon and Eutectic Silicon in Al-Si Cast Alloys in deposited metal, makes Tissue in weld seam is presented hypoeutectic state, and pin hole rate reaches minimum in weld seam, and Tissue distribution is more uniform in welding point, There is segregation phenomena in suppression, and the toughness of welding point is also significantly improved while strength of welded joint and hardness is improved, is resisted Creep properties, corrosion resistance, effectively prevent that welding point is cracking, metaboly.A kind of welding point proposed by the present invention is used High intensity cracking resistance aluminium alloy welding wire, its component rationally, is splashed small during welding, deposited metal dense structure, pore-free and crackle Occur, welding point has high intensity, splitting resistance good, with mother metal bond strength it is big the advantages of, improve the entirety of hardware Performance.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of welding point proposed by the present invention high intensity cracking resistance aluminium alloy welding wire, it is included following by mass fraction Component:Mg:2%th, B:0.25%th, Li:0.1%th, Cu:0.35%th, Si:0.25%th, Ti:0.3%th, Cr:0.12%th, Mn: 0.4%th, Fe:0.15%th, V:0.3%th, Sr:0.1%th, Na:0.25%th, Zr:0.05%th, Nb:0.1%th, Mo:0.15%th, Pr: 0.12%th, Ce:0.15%th, Nd:0.12%, remaining is Al and inevitable impurity.
Embodiment 2
A kind of welding point proposed by the present invention high intensity cracking resistance aluminium alloy welding wire, it is included following by mass fraction Component:Mg:3%th, B:0.15%th, Li:0.2%th, Cu:0.2%th, Si:0.4%th, Ti:0.2%th, Cr:0.22%th, Mn:0.25%th, Fe:0.25%th, V:0.2%th, Sr:0.2%th, Na:0.15%th, Zr:0.15%th, Nb:0.02%th, Mo:0.25%th, Pr:0.06%th, Ce:0.25%th, Nd:0.05%, remaining is Al and inevitable impurity.
Embodiment 3
A kind of welding point proposed by the present invention high intensity cracking resistance aluminium alloy welding wire, it is included following by mass fraction Component:Mg:2.5%th, B:0.2%th, Li:0.15%th, Cu:0.28%th, Si:0.32%th, Ti:0.25%th, Cr:0.16%th, Mn: 0.32%th, Fe:0.2%th, V:0.25%th, Sr:0.15%th, Na:0.2%th, Zr:0.1%th, Nb:0.06%th, Mo:0.2%th, Pr: 0.09%th, Ce:0.2%th, Nd:0.09%, remaining is Al and inevitable impurity.
Wherein, welding condition is as follows:Gas flow is 18L/min, and weldingvoltage is 24V, and welding current is 200A, Wire feed rate is 12m/min, and speed of welding is 0.75m/min.
Embodiment 4
A kind of welding point proposed by the present invention high intensity cracking resistance aluminium alloy welding wire, it is included following by mass fraction Component:Mg:2.2%th, B:0.22%th, Li:0.12%th, Cu:0.3%th, Si:0.3%th, Ti:0.28%th, Cr:0.14%th, Mn: 0.35%th, Fe:0.18%th, V:0.28%th, Sr:0.12%th, Na:0.22%th, Zr:0.08%th, Nb:0.08%th, Mo:0.18%th, Pr:0.1%th, Ce:0.18%th, Nd:0.1%, remaining is Al and inevitable impurity.
Wherein, welding condition is as follows:Gas flow is 17L/min, and weldingvoltage is 22V, and welding current is 210A, Wire feed rate is 11m/min, and speed of welding is 0.65m/min.
Embodiment 5
A kind of welding point proposed by the present invention high intensity cracking resistance aluminium alloy welding wire, it is included following by mass fraction Component:Mg:2.8%th, B:0.18%th, Li:0.18%th, Cu:0.25%th, Si:0.35%th, Ti:0.22%th, Cr:0.2%th, Mn: 0.3%th, Fe:0.22%th, V:0.22%th, Sr:0.18%th, Na:0.18%th, Zr:0.12%th, Nb:0.04%th, Mo:0.22%th, Pr:0.08%th, Ce:0.22%th, Nd:0.08%, remaining is Al and inevitable impurity.
Wherein, welding condition is as follows:Gas flow is 18.5L/min, and weldingvoltage is 25V, and welding current is 190A, wire feed rate is 12.5m/min, and speed of welding is 0.8m/min.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (7)

1. a kind of welding point high intensity cracking resistance aluminium alloy welding wire, it is characterised in that it is included with the following group by mass fraction Point:Mg:2-3%, B:0.15-0.25%, Li:0.1-0.2%, Cu:0.2-0.35%, Si:0.25-0.4%, Ti:0.2- 0.3%th, Cr:0.12-0.22%, Mn:0.25-0.4%, Fe:0.15-0.25%, V:0.2-0.3%, Sr:0.1-0.2%, Na:0.15-0.25%, Zr:0.05-0.15%, Nb:0.02-0.1%, Mo:0.15-0.25%, Pr:0.06-0.12%, Ce: 0.15-0.25%, Nd:0.05-0.12%, remaining is Al and inevitable impurity.
2. welding point high intensity cracking resistance aluminium alloy welding wire according to claim 1, it is characterised in that B, Li, Ti exist Mass fraction in aluminium alloy welding wire meets relationship below:1.4%≤(B+Li)/Ti≤2%.
3. welding point high intensity cracking resistance aluminium alloy welding wire according to claim 1, it is characterised in that Sr, Na weight Amount is than being 1:1.5-2.
4. welding point high intensity cracking resistance aluminium alloy welding wire according to claim 1, it is characterised in that Cu, Cr, Mn, The mass fraction of V, Mo in aluminium alloy welding wire meets relationship below:0.8%≤Cr+Mn+V+Mo≤1.1%.
5. welding point high intensity cracking resistance aluminium alloy welding wire according to claim 1, it is characterised in that it is by quality point Number includes following components:Mg:2.2-2.8%, B:0.18-0.22%, Li:0.12-0.18%, Cu:0.25-0.3%, Si: 0.3-0.35%, Ti:0.22-0.28%, Cr:0.14-0.2%, Mn:0.3-0.35%, Fe:0.18-0.22%, V:0.22- 0.28%th, Sr:0.12-0.18%, Na:0.18-0.22%, Zr:0.08-0.12%, Nb:0.04-0.08%, Mo:0.18- 0.22%th, Pr:0.08-0.1%, Ce:0.18-0.22%, Nd:0.08-0.1%, remaining is Al and inevitable impurity.
6. the welding point high intensity cracking resistance aluminium alloy welding wire according to any one of claim 1 or 2-5, its feature exists In welding condition is as follows:Gas flow is 17-18.5L/min, and weldingvoltage is 22-25V, and welding current is 190- 210A, wire feed rate is 11-12.5m/min, and speed of welding is 0.65-0.8m/min.
7. welding point high intensity cracking resistance aluminium alloy welding wire according to claim 6, it is characterised in that welding procedure is joined Number is as follows:Gas flow is 17.5-18L/min, and weldingvoltage is 23-24V, and welding current is 195-205A, and wire feed rate is 11.5-12m/min, speed of welding is 0.7-0.75m/min.
CN201710329496.0A 2017-05-11 2017-05-11 A kind of welding point high intensity cracking resistance aluminium alloy welding wire Withdrawn CN107214432A (en)

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN110181192A (en) * 2019-06-14 2019-08-30 新乡市和光科技有限公司 A kind of arc-welding increasing material manufacturing Al alloy powder core filaments
US11958140B2 (en) 2019-05-10 2024-04-16 General Cable Technologies Corporation Aluminum welding alloys with improved performance

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11958140B2 (en) 2019-05-10 2024-04-16 General Cable Technologies Corporation Aluminum welding alloys with improved performance
CN110181192A (en) * 2019-06-14 2019-08-30 新乡市和光科技有限公司 A kind of arc-welding increasing material manufacturing Al alloy powder core filaments

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Application publication date: 20170929