CN107213703B - Efficient desulfurizing tower - Google Patents

Efficient desulfurizing tower Download PDF

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Publication number
CN107213703B
CN107213703B CN201710661809.2A CN201710661809A CN107213703B CN 107213703 B CN107213703 B CN 107213703B CN 201710661809 A CN201710661809 A CN 201710661809A CN 107213703 B CN107213703 B CN 107213703B
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CN
China
Prior art keywords
demisting
desulfurizing tower
outlet flue
tower body
shell
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CN201710661809.2A
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Chinese (zh)
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CN107213703A (en
Inventor
李树春
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Shandong Hengke Environmental Protection Equipment Co
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Shandong Hengke Environmental Protection Equipment Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D45/00Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/12Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by centrifugal forces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • B01D50/40Combinations of devices covered by groups B01D45/00 and B01D47/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/78Liquid phase processes with gas-liquid contact

Abstract

The present invention relates to technical field of environment protection equipment, more particularly to a kind of efficient desulfurizing tower, including tower body, outlet flue is equipped at the top of tower body, multi-stage spray system is equipped in tower body, the lower part of every grade of spray system is equipped with multiple demisting dedusters, multiple demisting dedusters are arranged in parallel or series, a discharge mouth demisting deduster is additionally provided in tower body, outlet flue demisting deduster is arranged at outlet flue, demisting deduster and outlet flue demisting deduster include shell, shell upper end and bottom end are respectively equipped with spiral board, spiral board includes swirl vane, the direction of rotation of the swirl vane of two spiral boards is opposite, fume purifier is connected at the outlet flue.The configuration of the present invention is simple, water mist removal rate are high.

Description

Efficient desulfurizing tower
Technical field
The present invention relates to technical field of environment protection equipment, and in particular to a kind of efficient desulfurizing tower.
Background technique
Desulfurizing tower is the equipment for carrying out desulfurization process to industrial waste gas, is the important equipment in chemical industry equipment, desulfurizing tower is A kind of desulfuration efficiency is high, the desulphurization plant of the lower simultaneous energy dedusting of the pressure loss.
Desulfurizing tower passes through the improvement of many years, has evolved into spraying type, Venturi type, eddy flow template, eddy flow column type, floating ball Various types of desulfurizing towers, the equipment and technologies such as type, sieve plate type, Pneumatic emulsifying type reach its maturity.
The desulfurizing tower of spraying type is one of the most widely used desulfurizing tower type, using akaline liquid as carrier, by cigarette The harmful substances such as dirt, sulfur dioxide, hydrocarbon in gas separating treatment from flue gas absorbs sedimentation, finally reaches purification The purpose of flue gas.Spraying type desulfurizing tower has structure simple, and the reliable advantage of technical maturity is widely used in large power plant, in Small-sized low-sulfur smoke gas treatment;For high-sulfur smoke gas treatment, coloured industry is based on Pneumatic emulsifying desulfurizing tower, Multi-layer sprinkling tower etc..
Wherein, desulfurizing tower generates a large amount of droplets at runtime, goes back dust-laden particle in a large amount of water mists, influences in tower just Often operation.Demisting dust-extraction unit in the prior art mostly uses Open architecture, in use, the setting spray of demisting dust-extraction unit top Water drenching, shower water, which flows downward, influences defogging effect.
Gas flows up in desulfurizing tower, eventually arrives at the discharge of tower top position.For meet the requirement of environmental protection, needing will be in gas Solid particle or other magazines removal after, purification discharge.
In the prior art, baffle plate is mostly used to carry out gas purification, demisting, baffle plate purifying rate is low, and structure is complicated, Installation maintenance is inconvenient.
In addition, the liquid in desulfurizing tower after spray can gather together, collection device is flow to by circulating line, was sprayed Contain particles and other solid impurities such as a large amount of calcium carbonate, magnesium sulfate, calcium sulfate, recycle slurry liquid stream in loop slurry afterwards In dynamic process, above-mentioned particle and solid impurity can cause to scratch to pipeline inside, pipeline life be reduced, in addition, loop slurry In also contain a certain amount of sour gas, can be to pipeline by certain corrosiveness.Prior art majority using pipe lining modeling, The mode of lining rubber protects pipeline, but effect is not significant, and pipeline life is lower, increases using and safeguarding for desulfurizing tower Cost.
There are some sour gas inside desulfurizing tower, have the function of corrosion to the facility in spray column, reduce desulfurizing tower The service life of interior facility.Wherein, spray liquid pipeline is the equipment that setting is more in desulfurizing tower, and pipeline outer wall is easy by acid The corrosion of property substance.Liquid in spray liquid pipeline is circulating liquid, wherein there may be some solid impurity particles, liquid flow When dynamic, inner wall of the pipe can be caused to scratch, to influence the service life of pipeline.
The tower body of desulfurizing tower mostly uses glass flake, and the glass flake time has grown the phenomenon that being easy to happen cracking, falling off, right The use of desulfurizing tower generates adverse effect.In addition, there may be some solid impurity particles inside desulfurizing tower, when liquid flows, Desulfurizing tower tower body inner wall can be caused to scratch, to influence its service life.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of efficient desulfurizing tower, stabilized structure, long service life, and With good demisting, dust removing effects, purification efficiency is significantly improved.
The present invention adopts the following technical scheme:
A kind of efficient desulfurizing tower, including tower body, tower body top are equipped with outlet flue, are equipped with multi-stage spray system in tower body, often The lower part of grade spray system is equipped with multiple demisting dedusters, and multiple demisting dedusters are arranged in parallel or series.It is additionally provided in tower body One discharge mouth demisting deduster, outlet flue demisting deduster are arranged at outlet flue.
Demisting deduster and outlet flue demisting deduster include shell, and shell upper end and bottom end are respectively equipped with spiral board, Spiral board includes swirl vane, and the direction of rotation of the swirl vane of two spiral boards is on the contrary, the structure of phase reverse rotation can further promote Into eddy flow effect.Housing bottom side is equipped with water return outlet.Water mist rotates in shell to be flowed up, in rotary course, got rid of to Inner walls, water droplet are assembled on the inner wall of the housing, form water flow, flow to lower part water return outlet, entered in desulfurizing tower by water return outlet.
Case top is provided with top cover, and top cover upper surface is sphere curved surface, and sphere curved surface is to recessed.The setting of demisting deduster In spray head lower part, to prevent ejecting liquid from entering in shell, case top is provided with top cover, has between top cover and shell certain Gap, facilitate air to enter, equilibrium air pressure.Top cover upper surface is sphere curved surface, and to recessed, spherical surface can have sphere curved surface Effect is alleviated ejecting liquid and is splashed everywhere.
Fume purifier is connected at the outlet flue, fume purifier includes purifying tube, is equipped with multistage inside purifying tube Spiral board, purifying tube lower sides are equipped with ash hole.Gas is entered by purifying tube lower part, after spiral board, with rotating flow Form enters purifying tube, and the granule foreign and water mist in gas, which are got rid of due to the effect of rotating flow to purifying tube inner wall, to be assembled, and gathers Granule foreign and water mist after collection drop down onto purifying tube lower part, are flowed out by ash hole.
The top cover lower part is cone connection, and cone connection connects support column, and support column connects shell, taper connection The pyramidal structure in portion can be such that the gas sent out by top spiral board naturally sends out along tapered surface, guarantee eddy flow effect.
Water-blocking groove is equipped at shell nozzle between the shell and top cover of the demisting deduster, the shell at water-blocking groove is straight Diameter is less than lower case diameter, and water-blocking groove can prevent from entering shell by the ejecting liquid that top cover is fallen.Top cover upper surface is equipped with four A diversion trench, four diversion trenches are symmetrical two-by-two, and diversion trench flows down ejecting liquid received on top cover export.According to practical need It asks, the diversion trench is settable multiple.
Upper end is equipped with drip ring at the shell nozzle of the outlet flue demisting deduster, and the drip ring is circular ring shape.For It prevents the droplet in shell from splashing outflow, drip ring is set at shell nozzle.
Desulfurizing tower internal recycle pipeline is set in the tower body, and the tube wall of the internal recycle pipeline includes that ecto-entad is successively set Enhancement layer, corrosion-resistant coating, the wearing layer set.Enhancement layer is the main support structure of internal recycle pipeline;Corrosion-resistant coating prevents acidity The corrosiveness of gas inner loop pipeline;Wearing layer hardness is high, prevent the solid particles such as calcium carbonate, magnesium sulfate, calcium sulfate and The scratch of impurity inner loop pipeline.
The wearing layer selects silicon carbide or corundum to be made, and the hardness of above-mentioned material is all larger than calcium carbonate, magnesium sulfate, sulfuric acid The hardness of the particles such as calcium effectively prevent scratching inner wall of the pipe, improves the wearability of pipeline;Corrosion-resistant coating uses FRP material, FRP Material is glass reinforced plastic, and FRP material is light and handy, corrosion-resistant, anti-aging, high mechanical strength, and can prevent acid gas permeation from going out, Corrode outer reinforcing layer;Enhancement layer is made of stainless steel, and enhancement layer whole to pipeline effectively support, the structure for enhancing pipeline is steady Solidity.
The spray system includes bracket, spray head and spray liquid pipeline, and the tube wall of the spray liquid pipeline includes by outer The first erosion resistant coating, structure sheaf, the second erosion resistant coating and the wearing layer inwardly set gradually.First erosion resistant coating can prevent spray liquid pipeline Corrosiveness of the sour gas external, in desulfurizing tower to pipeline;Structure sheaf is the main support structure of spray liquid pipeline;Second Erosion resistant coating can prevent the acidic materials inside spray liquid pipeline to the corrosiveness of spray liquid pipeline;Wearing layer can prevent solid miscellaneous Scratch of the matter particle to spray liquid pipeline.
First erosion resistant coating and the second erosion resistant coating are FRP material, and wearing layer is silicon carbide material, and structure sheaf is stainless Steel material.
The spray liquid pipeline is supported by bracket, and spray liquid pipeline connects spray head, and spray head setting is in bracket lower part, spray The liquid that leaching head sprays avoids bracket, slows down the corrosion to bracket.
Priming coat, intermediate course, wearing layer are successively arranged on the inside of the tower wall of the tower body, intermediate course uses compound glass Fiber woven roving covers suitable glass flake plasticine on priming coat.
The wearing layer uses silicon carbide or corundum, and the intermediate course will be appropriate using 4-5 layers of glass fibre woven roving Glass flake plasticine cover on priming coat, the glass flake plasticine of the intermediate course includes vinylite, glass squama Piece.
It advantages of the present invention and has the beneficial effect that
The configuration of the present invention is simple, water mist removal rate are high.When operation test, water mist is formed using the water of 19.72KG, is sent into wind Speed is 14 meter per seconds, and after the processing of the utility model demisting deduster, the utility model collects the water of 14.474KG, that is, is gone The water of 14.474KG in desulfurizing tower is removed, removal rate reaches 73.4%;Under above-mentioned condition, when feeding wind speed is set as 8 meter per second, Water mist removal rate is greater than 80%.It can be seen that the working efficiency of desulfurizing tower can be improved in the utility model, and in the work of demisting In, play the role of dedusting.
In addition, in actual use, the water film thickness of measurement demisting shell of dust remover inner wall reaches 2mm, in the prior art water Film thickness basically reaches 1mm, it follows that the utility model structure is conducive to the collection of water mist.
Identical desulfurizing tower, using the demister of the prior art, desulfurizing tower needs to be arranged 17 layers of demister, is using this reality When with novel demisting deduster, 4 layers of demisting deduster need to be only used, the utility model can save space in desulfurizing tower, reduce Desulfurizing tower manufacturing cost.
The present invention can effectively prevent the corrosion of sour gas inner loop pipeline, tower body and spray system, and effectively anti- Only scratch of the solid particle to pipeline improves the service life of pipeline, reduces the use cost of desulfurizing tower interior conduit on the whole.
The service life of desulfurizing tower can be improved in the present invention, extends the service life of desulfurizing tower to 6 years or more.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention;
Fig. 2 is the structural schematic diagram figure of demisting deduster;
Fig. 3 is the cross section view of Fig. 2;
Fig. 4 is the top view of Fig. 2;
Fig. 5 is the structural schematic diagram of spiral board;
Fig. 6 is the structural schematic diagram of outlet flue demisting deduster;
Fig. 7 is the cross section view of Fig. 6;
Fig. 8 is the structural schematic diagram of internal recycle pipeline;
Fig. 9 is the structural schematic diagram of spray liquid pipeline;
Figure 10 is the structural schematic diagram of tower body.
Wherein, 1- fume purifier, 2- tower body, 21- tower wall, 22- priming coat, 23- intermediate course, 24- wearing layer, 3- go out Mouth demisting deduster, 4- spray head, 5- demisting deduster, 6- internal recycle pipeline, 61- enhancement layer, 62- corrosion-resistant coating, 63- are resistance to Mill layer, 7- bracket, 8- spray head, 9- spray liquid pipeline, the first erosion resistant coating of 91-, 92- structure sheaf, the second erosion resistant coating of 93-, 94- are resistance to Mill layer, 10- spiral board, 11- drip ring, 12- top cover, 13- cone connection, 14- water-blocking groove, 15- shell, 16- diversion trench, 17- swirl vane, 18- water return outlet.
Specific embodiment
As shown in Figures 1 to 7, a kind of efficient desulfurizing tower, including tower body 2 are equipped with outlet flue at the top of tower body 2, set in tower body 2 There is multi-stage spray system, the lower part of every grade of spray system is equipped with multiple demisting dedusters 5, and multiple demisting dedusters 5 are arranged in parallel. A discharge mouth demisting deduster 3 is additionally provided in tower body 2, outlet flue demisting deduster 3 is arranged at outlet flue.
The structure of demisting deduster 5 and outlet flue demisting deduster 3 includes shell 15,15 upper end of shell and bottom end difference Equipped with spiral board 10, spiral board 10 includes swirl vane 17, and the direction of rotation of the swirl vane of two spiral boards 10 is opposite.Shell 15 Bottom end side is equipped with water return outlet 18.Be provided with top cover 12 at the top of shell 15,12 upper surface of top cover is sphere curved surface, sphere curved surface to It is recessed.12 lower part of top cover is cone connection 13, and cone connection 13 connects support column, and support column connects shell 15.
As shown in Figure 3, Figure 4, water-blocking groove is equipped at the shell nozzle between the shell and top cover of the demisting deduster 5 14, the diameter of the housing at water-blocking groove 14 is less than lower case diameter.12 upper surface of top cover is set there are four diversion trench 16, four water conservancy diversion Slot 16 is symmetrical two-by-two.
As shown in fig. 7, upper end is equipped with drip ring 11, the water blocking at the shell nozzle of the outlet flue demisting deduster 3 Ring 11 is circular ring shape.
Fume purifier 1 is connected at the outlet flue, fume purifier 1 includes purifying tube, is equipped with inside purifying tube more Grade spiral board 10, purifying tube lower sides are equipped with ash hole.
As shown in Fig. 1, Fig. 8, desulfurizing tower internal recycle pipeline 6, the tube wall of the internal recycle pipeline 6 are set in the tower body 2 Enhancement layer 61, corrosion-resistant coating 62, the wearing layer 63 set gradually including ecto-entad.Wearing layer 63 selects silicon carbide to be made;It is anti- Corrosion layer 62 uses FRP material;Enhancement layer 61 is made of stainless steel.
As shown in Fig. 1, Fig. 9, the spray system includes bracket 7, spray head 8 and spray liquid pipeline 9.The spray liquid pipe The tube wall in road 9 includes the first erosion resistant coating 91, structure sheaf 92, the second erosion resistant coating 93 and the wearing layer 94 that ecto-entad is set gradually. First erosion resistant coating 91 and the second erosion resistant coating 93 are FRP material, and wearing layer 94 is silicon carbide material, and structure sheaf 92 is stainless Steel material.
The spray liquid pipeline 9 is supported by bracket 7, and spray liquid pipeline 9 connects spray head 8, and spray head 8 is arranged in bracket 7 Lower part.
As shown in Figure 1, Figure 10 shows, priming coat 22, intermediate course 23, wear-resisting is successively arranged on the inside of the tower wall 21 of the tower body 2 Layer 24.The wearing layer 24 uses silicon carbide;The intermediate course 23 uses four-layer glass fiber woven roving by suitable glass Flake mortar covers on priming coat 22, and the glass flake plasticine of the intermediate course 23 includes vinylite, glass flake.

Claims (6)

1. a kind of efficient desulfurizing tower, including tower body, tower body top is equipped with outlet flue, and multi-stage spray system is equipped in tower body, special Sign is that the lower part of every grade of spray system is equipped with multiple demisting dedusters, and multiple demisting dedusters are arranged in parallel or series, in tower body It is additionally provided with a discharge mouth demisting deduster, outlet flue demisting deduster is arranged at outlet flue, demisting deduster and smoke Mouth demisting deduster includes shell, and shell upper end and bottom end are respectively equipped with spiral board, and spiral board includes swirl vane, two eddy flows On the contrary, housing bottom side is equipped with water return outlet, case top is provided with top cover, table on top cover for the direction of rotation of the swirl vane of plate Face is sphere curved surface, and sphere curved surface is connected with fume purifier, fume purifier includes purification to recessed at the outlet flue Cylinder, purifying tube inside are equipped with Multi-stage spiral-plate, and purifying tube lower sides are equipped with ash hole,
Desulfurizing tower internal recycle pipeline is set in the tower body, and the tube wall of the internal recycle pipeline includes what ecto-entad was set gradually Enhancement layer, corrosion-resistant coating, wearing layer,
The wearing layer selects silicon carbide or corundum to be made, and corrosion-resistant coating uses FRP material, and enhancement layer is made of stainless steel,
The spray system includes bracket, spray head and spray liquid pipeline, and the tube wall of the spray liquid pipeline includes ecto-entad The first erosion resistant coating, structure sheaf, the second erosion resistant coating and the wearing layer set gradually,
First erosion resistant coating and the second erosion resistant coating are FRP material, and wearing layer is silicon carbide material, and structure sheaf is stainless steel Matter.
2. efficient desulfurizing tower according to claim 1, characterized in that the top cover lower part is cone connection, and taper connects Socket part connects support column, and support column connects shell.
3. efficient desulfurizing tower according to claim 2, characterized in that between the shell and top cover of the demisting deduster Water-blocking groove is equipped at shell nozzle, the diameter of the housing at water-blocking groove is less than lower case diameter, and top cover upper surface sets that there are four lead Chute, four diversion trenches are symmetrical two-by-two.
4. efficient desulfurizing tower according to claim 2, characterized in that at the shell nozzle of the outlet flue demisting deduster Upper end is equipped with drip ring, and the drip ring is circular ring shape.
5. efficient desulfurizing tower according to claim 1, characterized in that be successively arranged primary coat on the inside of the tower wall of the tower body Layer, intermediate course, wearing layer, intermediate course are covered suitable glass flake plasticine the bottom of at using compound glass fiber woven roving On coating.
6. efficient desulfurizing tower according to claim 5, characterized in that the wearing layer uses silicon carbide or corundum, described Intermediate course is covered suitable glass flake plasticine on priming coat using 4-5 layers of glass fibre woven roving, the intermediate folder The glass flake plasticine of layer includes vinylite, glass flake.
CN201710661809.2A 2017-08-04 2017-08-04 Efficient desulfurizing tower Active CN107213703B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108815926A (en) * 2018-06-25 2018-11-16 东台帕瓦环保节能科技有限公司 A kind of pollution-free energy-saving cleaner
CN108671732A (en) * 2018-07-23 2018-10-19 山东恒科环保设备有限公司 A kind of boiler and kiln tail gas minimum discharge integrated apparatus
CN110407437A (en) * 2019-08-27 2019-11-05 第一环保(深圳)股份有限公司 A kind of water mist collection device
CN114452738B (en) * 2022-01-17 2023-08-18 呼和浩特科林热电有限责任公司 Flue gas emission treatment device for thermal power plant

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CN102343697A (en) * 2011-10-12 2012-02-08 成都龙泉防腐工程有限公司 Anticorrosive and wear-resistant material for spraying zones of desulfurization towers
EP2893969A1 (en) * 2012-09-10 2015-07-15 Mitsubishi Hitachi Power Systems, Ltd. Desulfurization device, and soot removal system
CN204798999U (en) * 2015-03-17 2015-11-25 天津博瑞环保设备有限公司 Water slinger device of tube bundle dust remover
CN106000045A (en) * 2016-06-17 2016-10-12 王骞 Deep dedusting, desulfurating and denitrating equipment for boiler flue gas

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN102343697A (en) * 2011-10-12 2012-02-08 成都龙泉防腐工程有限公司 Anticorrosive and wear-resistant material for spraying zones of desulfurization towers
EP2893969A1 (en) * 2012-09-10 2015-07-15 Mitsubishi Hitachi Power Systems, Ltd. Desulfurization device, and soot removal system
CN204798999U (en) * 2015-03-17 2015-11-25 天津博瑞环保设备有限公司 Water slinger device of tube bundle dust remover
CN106000045A (en) * 2016-06-17 2016-10-12 王骞 Deep dedusting, desulfurating and denitrating equipment for boiler flue gas

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Denomination of invention: Efficient desulfurization tower

Effective date of registration: 20231120

Granted publication date: 20190806

Pledgee: Bank of Weifang Co.,Ltd. Anqiu Jingzhi sub branch

Pledgor: SHANDONG HENGKE ENVIRONMENTAL PROTECTION EQUIPMENT CO.,LTD.

Registration number: Y2023370010117

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