CN107201066A - A kind of anti-sticking aluminium paint - Google Patents
A kind of anti-sticking aluminium paint Download PDFInfo
- Publication number
- CN107201066A CN107201066A CN201710626610.6A CN201710626610A CN107201066A CN 107201066 A CN107201066 A CN 107201066A CN 201710626610 A CN201710626610 A CN 201710626610A CN 107201066 A CN107201066 A CN 107201066A
- Authority
- CN
- China
- Prior art keywords
- powder
- particle diameter
- boron nitride
- aluminium
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
Abstract
The invention discloses a kind of anti-sticking aluminium paint, consisting of：Particle diameter is 0.5 ~ 2 μm of 2 ~ 10wt% of boron nitride powder, particle diameter is 5 ~ 10 μm of 10 ~ 25wt% of boron nitride powder, particle diameter is 1 ~ 5 μm of 2 ~ 10wt% of Aluminum titanate powder, and particle diameter is 2 ~ 6 μm of barium sulfate 2 ~ 10wt% of powder, 0 ~ 0.5wt% of hard fire colour, 1 ~ 4wt% of high temperature adhesive, 0 ~ 1wt% of dispersant, 0 ~ 0.02wt% of defoamer, 0 ~ 1wt% of ethylene glycol, 0 ~ 0.02wt% of preservative, 50 ~ 85wt% of water.The coating has nonwetting property to aluminum melt, the positions such as Rose Box, chute, crystallizing pan are painted on before the hot top casting casting of aluminium bar, be conducive to preventing wetting to refractory material of aluminum melt in casting cycle, bonding, extend the service life of the said equipment, cleaning work after the completion of convenient casting, prevent the fine particle of refractory material to enter in aluminum melt simultaneously, improve the cleanliness factor of product.
Description
Technical field
The present invention relates to aluminium alloy casting technology field, more particularly to a kind of anti-sticking aluminium paint.
Background technology
With expanding economy, China's aluminium section bar demand Continued, and it is used for manufacturing the aluminium bar yield of section bar up to 5
More than thousand ten thousand tons, the manufacturing technology of country's aluminium bar is essentially all heat top foundry engieering at present.It is a kind of semicontinuous casting that hot direct casting, which is made,
Technology is made, the manufacture of the aluminum round rod of the various trades mark is had been widely used for.Generally, due between aluminum melt and refractory material
Wetting action, after the completion of casting, the residual aluminium liquid of solidification can firmly glue with the refractory material of Rose Box, chute, crystallizing pan inwall
Connect, frequently result in coming off and destroying for refractory material when clearing up residual aluminum material, reduce the service life of equipment.The opposing party
Face, due to often containing silica in refractory material, aluminum melt can occur reduction reaction with silica, reduce refractory material
Intensity, makes it slowly come off into little particle and enters in aluminum melt, reduce the cleanliness factor of melt, reduce product quality.
On the other hand, can quilt when it is contacted with aluminum melt for some the irony instruments used during aluminium alloy smelting
Aluminium liquid is eroded, and the iron into such as aluminum melt exists in the form of the intermetallic compound of high rigidity, adds in aluminium bar product
Iron content, during subsequent extrusion, the hard particles of these iron content can increase the abrasion of mould, while reducing extrusion type
The surface quality of material.
The content of the invention
In order to overcome the above-mentioned deficiencies of the prior art, the invention provides a kind of anti-sticking aluminium paint,
It constitutes as follows substantially：Particle diameter is 0.5 ~ 2 μm of 2 ~ 10wt% of boron nitride powder, and particle diameter is 5 ~ 10 μm of boron nitride powder 10 ~ 25
Wt %, particle diameter is 1 ~ 5 μm of the wt % of Aluminum titanate powder 2 ~ 10, and particle diameter is 2 ~ 6 μm of barium sulfate 2 ~ 10wt% of powder, hard fire colour
0 ~ 0.5wt%, the wt % of high temperature adhesive 1 ~ 4, dispersant 0 ~ 1 wt %, 0 ~ 0.02wt% of defoamer, 0 ~ 1wt% of ethylene glycol, anti-corrosion
The wt % of agent 0 ~ 0.02, the wt % of water 50 ~ 85；
Described hard fire colour, tolerable temperature is not less than 900 DEG C, preferably cobalt aluminate, i.e. cobalt blue；
Described high temperature adhesive includes the one or more in Alumina gel, aluminium dihydrogen phosphate, aluminum sulfate, preferably Alumina gel,
Aluminium chlorine compares 1.1:1, pH value is 2 ~ 4；
A kind of anti-sticking aluminium paint preparation process is：First high temperature adhesive, dispersant, defoamer, ethylene glycol, preservative and water are mixed
Conjunction stirs into homogeneous solution, and then one side agitating solution is while by boron nitride powder, metatitanic acid aluminium powder, blanc fixe and hard fire colour
Powder is added in the solution, continues to stir until forming homogeneous system.
The beneficial effects of the invention are as follows：
Compared with prior art, coating application of the present invention is nonwetting with aluminium liquid after drying on the surface contacted with aluminum melt, this
The anti-sticking aluminized coating of layer has not only effectively obstructed aluminum melt and directly contacting by protection surface, prevents aluminum melt to be contaminated, and
The adhesion of residual aluminum material and resistance to material is significantly reduced, follow-up scale removal process is facilitated, the refractory material of Casting Equipment is protected
It is not destroyed.
Embodiment
With reference to specific embodiment, the present invention is further described.
Embodiment 1：
A kind of anti-sticking aluminium paint preparation process is：First by 1 part of high temperature adhesive, 0.3 part of dispersant, 0.01 part of defoamer, 0.48
Part ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 6 parts of particle diameters and being
0.5 ~ 2 μm of boron nitride powder, 12 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 10 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 10 parts
Particle diameter is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is preferably Alumina gel, and concentration is 20wt%, and aluminium chlorine compares 1.1:1, pH value is 2 ~ 4.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 2：
A kind of anti-sticking aluminium paint preparation process is：First by 1 part of high temperature adhesive, 0.3 part of dispersant, 0.01 part of defoamer, 0.48
Part ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 7 parts of particle diameters and being
0.5 ~ 2 μm of boron nitride powder, 13 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 9 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 9 parts of grains
Footpath is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is preferably Alumina gel, and concentration is 20wt%, and aluminium chlorine compares 1.1:1, pH value is 2 ~ 4.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 3：
A kind of anti-sticking aluminium paint preparation process is：First by 1 part of high temperature adhesive, 0.3 part of dispersant, 0.01 part of defoamer, 0.48
Part ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 8 parts of particle diameters and being
0.5 ~ 2 μm of boron nitride powder, 20 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 5 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 5 parts of grains
Footpath is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is preferably Alumina gel, and concentration is 20wt%, and aluminium chlorine compares 1.1:1, pH value is 2 ~ 4.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 4：
A kind of anti-sticking aluminium paint preparation process is：First by 1 part of high temperature adhesive, 0.3 part of dispersant, 0.01 part of defoamer, 0.48
Part ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 8 parts of particle diameters and being
0.5 ~ 2 μm of boron nitride powder, 20 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 5 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 5 parts of grains
Footpath is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is phosphate dihydrogen aluminum solution, and concentration is 37 ~ 42wt%.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 5：
A kind of anti-sticking aluminium paint preparation process is：First by 1 part of high temperature adhesive, 0.3 part of dispersant, 0.01 part of defoamer, 0.48
Part ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 10 parts of particle diameters and being
0.5 ~ 2 μm of boron nitride powder, 24 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 2 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 2 parts of grains
Footpath is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is phosphate dihydrogen aluminum solution, and concentration is 37 ~ 42wt%.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 6：
A kind of anti-sticking aluminium paint preparation process is：First by 1 part of high temperature adhesive, 0.3 part of dispersant, 0.01 part of defoamer, 0.48
Part ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 9 parts of particle diameters and being
0.5 ~ 2 μm of boron nitride powder, 25 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 2 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 2 parts of grains
Footpath is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is phosphate dihydrogen aluminum solution, and concentration is 37 ~ 42wt%.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 7：
A kind of anti-sticking aluminium paint preparation process is：First by 2.5 parts of high temperature adhesives, 0.3 part of dispersant, 0.01 part of defoamer,
0.48 part of ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 6 parts of particle diameters
For 0.5 ~ 2 μm of boron nitride powder, 12 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 9 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 9.5
Part particle diameter is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is aluminum sulfate.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 8：
A kind of anti-sticking aluminium paint preparation process is：First by 2.5 parts of high temperature adhesives, 0.3 part of dispersant, 0.01 part of defoamer,
0.48 part of ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 8 parts of particle diameters
For 0.5 ~ 2 μm of boron nitride powder, 20 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 4 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 4.5
Part particle diameter is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is aluminum sulfate.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Embodiment 9：
A kind of anti-sticking aluminium paint preparation process is：First by 2.5 parts of high temperature adhesives, 0.3 part of dispersant, 0.01 part of defoamer,
0.48 part of ethylene glycol, 0.01 preservative and 60 parts of water are mixed into homogeneous solution；Then stir while adding 8 parts of particle diameters
For 0.5 ~ 2 μm of boron nitride powder, 25 parts of particle diameters are 5 ~ 10 μm of boron nitride powder, and 2 parts of particle diameters are 1 ~ 5 μm of Aluminum titanate powder, 1.5
Part particle diameter is 2 ~ 6 μm of barium sulfate powder, 0.2 part of hard fire colour；Continue to stir 10 minutes until forming homogeneous system.
Described high temperature adhesive is aluminum sulfate.
Described hard fire colour, tolerable temperature is not less than 900 DEG C, and preferably particle diameter is 0.5 ~ 2 μm of aluminic acid cobalt powder；
When actual use, used after being diluted as needed.
Aluminium oxide ceramics plate surface is painted on after being diluted in the water for 3 times of the coating addition that above-mentioned 9 embodiments are obtained,
700 ~ 720 DEG C of drying carry out the test of aluminium dissolved drip angle of wetting after 30 minutes and tested with anchoring strength of coating, are as a result summarized in following table：
Wherein：The high temperature adhesive that embodiment 1 ~ 3 is used is Alumina gel；The high temperature adhesive that embodiment 4 ~ 6 is used is di(2-ethylhexyl)phosphate
Hydrogen aluminium；The high temperature adhesive that embodiment 7 ~ 9 is used is aluminum sulfate.It is qualified that angle of wetting, which is more than 90 °, and angle of wetting is bigger, antistick characteristic
Better.Coating is qualified more than 15MPa with basal body binding force, and adhesion is bigger, and coating is more firm.
Described above is only, to presently preferred embodiments of the present invention, not the scope of the present invention to be defined, therefore is not being taken off
On the premise of design spirit of the present invention, this area ordinary skill technical staff is to construction of the present invention, feature and principle
In the equivalence changes or decoration made, the protection domain that the present patent application patent all should be fallen into.
Claims (4)
1. a kind of anti-sticking aluminium paint, it is characterised in that composition is as follows：Particle diameter is 0.5 ~ 2 μm of 2 ~ 10wt% of boron nitride powder, particle diameter
For 5 ~ 10 μm of the wt % of boron nitride powder 10 ~ 25, particle diameter is 1 ~ 5 μm of the wt % of Aluminum titanate powder 2 ~ 10, and particle diameter is 2 ~ 6 μm of sulphur
Sour barium powder 2 ~ 10wt%, 0 ~ 0.5wt% of hard fire colour, the wt % of high temperature adhesive 1 ~ 4, the wt % of dispersant 0 ~ 1, defoamer 0 ~
0.02wt%, 0 ~ 1wt% of ethylene glycol, the wt % of preservative 0 ~ 0.02, the wt % of water 50 ~ 85.
2. a kind of anti-sticking aluminium paint according to claim 1, it is characterised in that：The hard fire colour, tolerable temperature is not low
In 900 DEG C.
3. a kind of anti-sticking aluminium paint according to claim 1, it is characterised in that：It is molten that described high temperature adhesive includes aluminium
One or more in glue, aluminium dihydrogen phosphate, aluminum sulfate.
4. a kind of anti-sticking aluminium paint according to claim 1, it is characterised in that preparation process is：First by high temperature adhesive,
Dispersant, defoamer, ethylene glycol, preservative and water are mixed into homogeneous solution, then by boron nitride powder, metatitanic acid aluminium powder, sulphur
Sour barium powder and hard fire colour powder are added in the solution, while stirring is until form homogeneous system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710626610.6A CN107201066B (en) | 2017-07-28 | 2017-07-28 | A kind of anti-sticking aluminium paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710626610.6A CN107201066B (en) | 2017-07-28 | 2017-07-28 | A kind of anti-sticking aluminium paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107201066A true CN107201066A (en) | 2017-09-26 |
| CN107201066B CN107201066B (en) | 2019-10-15 |
Family
ID=59911439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710626610.6A Active CN107201066B (en) | 2017-07-28 | 2017-07-28 | A kind of anti-sticking aluminium paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107201066B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021628A (en) * | 2018-07-12 | 2018-12-18 | 商丘师范学院 | It is a kind of can low temperature bonding applied at elevated temperature aqueous boron nitride coating |
| CN109848364A (en) * | 2018-12-11 | 2019-06-07 | 商丘师范学院 | A kind of compression casting boron nitride coating and preparation method thereof |
| CN111019408A (en) * | 2019-12-17 | 2020-04-17 | 大连新翔工业材料有限公司 | Anti-sticking aluminum coating |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1421495A (en) * | 2002-12-19 | 2003-06-04 | 中国科学院兰州化学物理研究所 | Inorganic high-temperature antiwear paint |
| CN102532962A (en) * | 2011-12-31 | 2012-07-04 | 席君杰 | High-temperature anti-sticking material coating and manufacturing and application methods thereof |
| CN202705280U (en) * | 2011-12-31 | 2013-01-30 | 席君杰 | High-temperature anti-sticking material coating |
| CN105219257A (en) * | 2015-08-28 | 2016-01-06 | 厦门市摩索新材料科技有限公司 | High-temperature antisticking and lubricating paint and its preparation method and application |
| CN106336692A (en) * | 2015-11-17 | 2017-01-18 | 中国科学院兰州化学物理研究所 | Fastener coating, and preparation method and application thereof |
-
2017
- 2017-07-28 CN CN201710626610.6A patent/CN107201066B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1421495A (en) * | 2002-12-19 | 2003-06-04 | 中国科学院兰州化学物理研究所 | Inorganic high-temperature antiwear paint |
| CN102532962A (en) * | 2011-12-31 | 2012-07-04 | 席君杰 | High-temperature anti-sticking material coating and manufacturing and application methods thereof |
| CN202705280U (en) * | 2011-12-31 | 2013-01-30 | 席君杰 | High-temperature anti-sticking material coating |
| CN105219257A (en) * | 2015-08-28 | 2016-01-06 | 厦门市摩索新材料科技有限公司 | High-temperature antisticking and lubricating paint and its preparation method and application |
| CN106336692A (en) * | 2015-11-17 | 2017-01-18 | 中国科学院兰州化学物理研究所 | Fastener coating, and preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 胡宝玉等: "《特种耐火材料实用技术手册》", 30 June 2004, 冶金工业出版社 * |
| 舒万艮: "《有色金属精细化工产品生产与应用》", 31 December 1995, 中南工业大学出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021628A (en) * | 2018-07-12 | 2018-12-18 | 商丘师范学院 | It is a kind of can low temperature bonding applied at elevated temperature aqueous boron nitride coating |
| CN109021628B (en) * | 2018-07-12 | 2020-09-04 | 商丘师范学院 | Water-based boron nitride coating capable of being bonded at low temperature and used at high temperature |
| CN109848364A (en) * | 2018-12-11 | 2019-06-07 | 商丘师范学院 | A kind of compression casting boron nitride coating and preparation method thereof |
| CN111019408A (en) * | 2019-12-17 | 2020-04-17 | 大连新翔工业材料有限公司 | Anti-sticking aluminum coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107201066B (en) | 2019-10-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103834249A (en) | Anti-flash-rust water-based acrylic acid iron red antirust priming paint and preparation method thereof | |
| CN107201066A (en) | A kind of anti-sticking aluminium paint | |
| CN104231857A (en) | Composite epoxy anticorrosive paint and preparation method thereof | |
| CN105670365A (en) | Nanometer hole sealing agent for ceramic spayed coating and application of nanometer hole sealing agent | |
| CN103878299A (en) | Sintered strippable light-colored casting coating and preparation method thereof | |
| JP2002105401A (en) | Water-base two-pack protective coating composition | |
| CN104877488A (en) | Preparation process for water-based zinc rich paint taking potassium metasilicate as base material | |
| JPWO2009004684A1 (en) | Aqueous surface treatment solution for galvanized steel sheet and galvanized steel sheet | |
| CN104877498A (en) | Waterborne zinc-enriched paint and preparation method thereof | |
| CN109369142A (en) | The anti-sticking spray paint of steel slag tank and its preparation and application | |
| CN109021628A (en) | It is a kind of can low temperature bonding applied at elevated temperature aqueous boron nitride coating | |
| CN103588443A (en) | Nano water-based functional ceramic composite coating and preparation method thereof | |
| CN106519908A (en) | Anticorrosive coating in radiator | |
| CN105733325A (en) | Inorganic zinc silicate shop primer based on graphene modification and preparing method thereof | |
| CN107841175A (en) | A kind of chromium-free Dyclo paint of rub resistance | |
| KR101130297B1 (en) | Two component zinc type water base paint composition | |
| CN113072827B (en) | Coating for preventing anode steel claw from being oxidized and preparation method thereof | |
| CN1037245C (en) | High-temp paint preventing steel and slag adhesion | |
| CN106634128A (en) | Anti-corrosion metal coating for hydraulic cylinder and preparation method thereof | |
| CN109020554A (en) | Stainless steel crucible coating and preparation method thereof for Melting of Al-li Alloy | |
| CN105969086B (en) | Aqueous anti-stick coating and its application | |
| CN109233470A (en) | A kind of aqueous hybrid inorganic-organic anticorrosive paint containing nanometer aluminium silicate composite powder and preparation method thereof and application method | |
| CN107285788A (en) | A kind of acid/alkali-corrosion-resistant castable | |
| CN108070736A (en) | A kind of ocean engineering high-strength nano grade carborundum acid bronze alloy new material | |
| WO2013059899A9 (en) | "water and alcohol based refractory paints made with bauxite and alumina fused in arc furnaces and applied in moulds for the fusion of carbon steels, high alloy, low- alloy steels and especially manganese and production process" |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |