CN107200951A - A kind of fabric solid-woven tubulose fire retarding conveying band and its manufacture method - Google Patents
A kind of fabric solid-woven tubulose fire retarding conveying band and its manufacture method Download PDFInfo
- Publication number
- CN107200951A CN107200951A CN201710341631.3A CN201710341631A CN107200951A CN 107200951 A CN107200951 A CN 107200951A CN 201710341631 A CN201710341631 A CN 201710341631A CN 107200951 A CN107200951 A CN 107200951A
- Authority
- CN
- China
- Prior art keywords
- parts
- speed
- belt carcass
- fabric
- roots
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 50
- 230000000979 retarding effect Effects 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 53
- 238000004513 sizing Methods 0.000 claims abstract description 47
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 46
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 46
- 238000007598 dipping method Methods 0.000 claims abstract description 27
- 238000005470 impregnation Methods 0.000 claims abstract description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 19
- 238000000576 coating method Methods 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 8
- 229920006235 chlorinated polyethylene elastomer Polymers 0.000 claims abstract description 5
- 229920001971 elastomer Polymers 0.000 claims abstract description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract 3
- 229920000742 Cotton Polymers 0.000 claims description 40
- 239000003063 flame retardant Substances 0.000 claims description 28
- 239000004014 plasticizer Substances 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 20
- 238000004898 kneading Methods 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 17
- 230000000996 additive effect Effects 0.000 claims description 17
- 239000002562 thickening agent Substances 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229920001778 nylon Polymers 0.000 claims description 16
- 239000003513 alkali Substances 0.000 claims description 15
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 claims description 15
- 238000000227 grinding Methods 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 15
- 239000003381 stabilizer Substances 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- 235000012424 soybean oil Nutrition 0.000 claims description 14
- 239000003549 soybean oil Substances 0.000 claims description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 13
- 239000003822 epoxy resin Substances 0.000 claims description 13
- 229920000647 polyepoxide Polymers 0.000 claims description 13
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 12
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 11
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 10
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 10
- 238000009954 braiding Methods 0.000 claims description 10
- 239000011236 particulate material Substances 0.000 claims description 10
- 238000004073 vulcanization Methods 0.000 claims description 10
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 9
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 8
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 8
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 8
- ASLWPAWFJZFCKF-UHFFFAOYSA-N tris(1,3-dichloropropan-2-yl) phosphate Chemical compound ClCC(CCl)OP(=O)(OC(CCl)CCl)OC(CCl)CCl ASLWPAWFJZFCKF-UHFFFAOYSA-N 0.000 claims description 8
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 7
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 claims description 6
- 229920006231 aramid fiber Polymers 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- -1 MCA Chemical compound 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 5
- 238000007765 extrusion coating Methods 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 4
- 239000000347 magnesium hydroxide Substances 0.000 claims description 4
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 4
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 claims description 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical class C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 2
- 229960002447 thiram Drugs 0.000 claims description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 2
- UDWCKMMKPOGURO-UHFFFAOYSA-N 1,2-dihydropyrazolo[3,4-b]pyridin-4-one Chemical compound O=C1C=CNC2=C1C=NN2 UDWCKMMKPOGURO-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical group 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 claims 1
- WQPDQJCBHQPNCZ-UHFFFAOYSA-N cyclohexa-2,4-dien-1-one Chemical group O=C1CC=CC=C1 WQPDQJCBHQPNCZ-UHFFFAOYSA-N 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 claims 1
- 229910017604 nitric acid Inorganic materials 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000000806 elastomer Substances 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 abstract 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 description 8
- 230000003078 antioxidant effect Effects 0.000 description 8
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical compound C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 description 5
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 5
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical group C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 4
- JZLWSRCQCPAUDP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;urea Chemical compound NC(N)=O.NC1=NC(N)=NC(N)=N1 JZLWSRCQCPAUDP-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000003712 anti-aging effect Effects 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- SUIOPXSLPPMBJN-UHFFFAOYSA-N 1,3-dichloropropyl dihydrogen phosphate Chemical class OP(O)(=O)OC(Cl)CCCl SUIOPXSLPPMBJN-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical class CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical group C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- OMUGFZNEOIWQOD-UHFFFAOYSA-N boric acid;zinc Chemical compound [Zn].OB(O)O OMUGFZNEOIWQOD-UHFFFAOYSA-N 0.000 description 1
- OSQHKFSOZNSTBQ-UHFFFAOYSA-N cadmium;carbamic acid Chemical compound [Cd].NC(O)=O OSQHKFSOZNSTBQ-UHFFFAOYSA-N 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/10—Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B25/00—Layered products comprising a layer of natural or synthetic rubber
- B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
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- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B27/00—Layered products comprising a layer of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
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Abstract
The invention discloses a kind of fabric solid-woven tubulose fire retarding conveying band and its manufacture method.The conveyer belt includes coating, fabric whole belt core and belt carcass dipping sizing material:Coating is using the thermoplastic elastomer (TPE) of polyvinyl chloride powder resin/chlorinated polyethylene rubber/thermoplastic polyurethane elastomer blended, and fire resistance is good, and tensile strength is high, coefficient of friction is big, elasticity is excellent, and anti-wear performance is good, and the whole belt core bonding strength after being plastified with impregnation is high;Fabric whole belt core intensity height, thin with body, lightweight, band body is soft after impregnation plasticizing, and lateral stiffness is reasonable, tube-forming energy is good.The present invention is using extruder veneer moulding, Technology of Dynamic Vulcanized production woven tube fire retarding conveying band, and technique is simple, energy resource consumption is low, production efficiency is high.
Description
Technical field
It is a kind of fabric solid-woven tubulose fire retarding conveying band and its system specifically the present invention relates to conveyer belt technical field
Make method.
Background technology
In traditional ribbon conveyer, material is to open wide operation, it is easy to material spilling occurs and flies upward, pollutes environment
Or material it is contaminated the problems such as.Pipe conveyer closed conveying material, can effectively solve material spilling and fly upward, pollute environment or thing
The problems such as material is contaminated, and can realize bending conveying, at a high speed high inclination-angle conveying, conveying and large conveying quantity conveying, thus develop compared with
It hurry up.Tubular conveyor belt is the special conveyer belt of pipe conveyer, in addition to requiring it and having good physical and mechanical properties, is also required
Lateral stiffness is reasonable, tube-forming energy is good, for conveying coal and the tubular conveyor belt of other flammable materials, it is necessary to resistance
Combustion and antistatic property.The tubular conveyor belt of prior art, one is steel cord core tubular conveyor belt(HG/T4224-2011), two
It is fabric core tubular conveyor belt(HG/T4225-2011), both tubular conveyor belts are not fire-retardant, it is difficult to for colliery
Underground and the conveying of flammable materials.
The content of the invention
The purpose of the present invention is to overcome the deficiencies in the prior art to provide a fabric solid-woven tubulose fire retarding conveying band, meets colliery
The need for underground and flammable materials closed conveying.
It is a further object of the present invention to provide the manufacture method of the conveyer belt, technique is simple, it is easy to manufacture, production cost
Low, production efficiency is high.
The purpose of the present invention is achieved by following proposal.
Described fabric solid-woven tubulose fire retarding conveying band, caliber 200-600mm(Bandwidth 800-2250mm), longitudinal through thickness
Tensile strength 1250-4500N/mm, including coating, fabric whole belt core and belt carcass dipping sizing material;
Described overburden cover 3-5mm, composition by weight is:30-50 parts of polyvinyl chloride powder resin (PVC), chlorination gathers
30-40 parts of ethylene rubber (CM), 20-30 parts of TPUE (TPU), cumyl peroxide (DCP) 1.5-
2.5 parts, triallyl cyanurate(TAC)1-2 parts, 1-2 parts of accelerator, 1-2 parts of age resistor, 10-15 parts of conductive black, nanometer
10-15 parts of white carbon, 8-10 parts of Fanglun slurry cake, 10-20 parts of plasticizer, 10-20 parts of flame-retardant plasticizer, 15-25 parts of fire retardant, firmly
1 part of resin acid lead, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 6-8 parts of antistatic additive;
Described fabric whole belt core is made up of warp and weft, and 3-4 layers of braiding structure, width is the 105%-110% of bandwidth;Through
Line is made up of nylon or polyester or aramid fiber with cotton fiber, cotton content 10%-15%, and warp-wise stress line drawing intensity is 1000-
The density of 60% width is 160-200 roots/10cm in the middle of 3000N/ roots, belt carcass, and the density ratio intermediate density of remaining width is reduced
10-15 roots/10mm;Parallel is made up of nylon fiber with cotton fiber, cotton content 35%-45%, and broadwise is by the tensile strength of the line of force
300-500N/ roots, density 120-180 roots/10cm;
Described belt carcass impregnates the composition of sizing material by weight:100 parts of PVC paste resin (EPVC), diphenyl methane
10-15 parts of diisocyanate (MDI), 40-60 parts of plasticizer, 20-40 parts of flame-retardant plasticizer, 15-25 parts of fire retardant, epoxy is big
10-20 parts of soya-bean oil, 2-4 parts of liquid barium zinc compound stabilizer.
Described accelerator is 2- benzothiazolyl mercaptans (captax), dibenzothiazyl disulfide (altax), N-
Cyclohexyl -2-[4-morpholinodithio sulfenamide (accelerant CZ), tetramethylthiuram disulfide (Vulcanization accelerator TMTD), the sulphur of diethyl two
For one kind in carbamic acid cadmium (accelerant C ED) or combination, age resistor is N- phenyl-alpha-naphthylamines (antioxidant A), N- phenyl-β
Naphthylamines (antioxidant D), 2,2,4- trimethyl -1,2- dihyaroquinoline condensates (resin-like) (anti-aging agent RD), 2,2 '-thiobis
In (4- methyl-6-tert-butylphenols) (antioxidant 2246-S), N- isopropyls-N '-diphenyl-para-phenylene diamine (antioxidant 4010NA)
One kind or combination, plasticizer is dioctyl phthalate (DOP), di-n-octyl sebacate (DOS), dioctyl adipate
(DOA) one kind or its combination in, flame-retardant plasticizer is triaryl phosphate (TCP), three(β-chloroethyl)Phosphate (TCEP),
Three (1,3- bis- chloropropyl) phosphates (TDCPP), one kind in cresyl diphenyl phosphate (CDP) or combination, fire retardant is
Aluminium hydroxide, magnesium hydroxide, Firebrake ZB, red phosphorus, antimony oxide, APP, MCA, decabromodiphenyl oxide
In one kind or combination, antistatic additive is alkylbenzene phosphate diethanolamine salt(Antistatic additive P), trihydroxyethyl methyl quaternary ammonium first
Base sulfate(Antistatic agent TM), octadecyldimethyl ethoxy quaternary ammonium nitrate(Antistatic additive SA)In any one.
The manufacture method of described fabric solid-woven tubulose fire retarding conveying band, comprises the following steps:
(1) braided fabric whole belt core:
Described fabric whole belt core is made up of warp and weft, and 3-4 layers of braiding structure, width is the 105%-110% of bandwidth;Through
Line is made up of nylon or polyester or aramid fiber with cotton fiber, cotton content 10%-15%, and warp-wise stress line drawing intensity is 1000-
The density of 60% width is 160-200 roots/10cm in the middle of 3000N/ roots, belt carcass, and the density ratio intermediate density of remaining width is reduced
10-15 roots/10mm;Parallel is made up of nylon fiber with cotton fiber, cotton content 35%-45%, and broadwise is by the tensile strength of the line of force
300-500N/ roots, density 120-180 roots/10cm.
(2) covering layer sizing is prepared:
1) composition of covering layer sizing by weight described in is:30-50 parts of polyvinyl chloride powder resin (PVC), haloflex
30-40 parts of rubber (CM), 20-30 parts of TPUE (TPU), cumyl peroxide (DCP) 1.5-2.5
Part, triallyl cyanurate(TAC)1-2 parts, 1-2 parts of accelerator, 1-2 parts of age resistor, 10-15 parts of conductive black, nanometer hard charcoal
It is black 10-15 parts, 8-10 parts of Fanglun slurry cake, 10-20 parts of plasticizer, 10-20 parts of flame-retardant plasticizer, 15-25 parts of fire retardant, stearic acid
1 part of lead, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 6-8 parts of antistatic additive;
2) above-mentioned sizing material is mixed, granulated, covering layer sizing particle is made:
I:High-speed kneading:By polyvinyl chloride powder resin, accelerator, age resistor, conductive black, Nano carbon white, Fanglun slurry cake, increasing
Modeling agent, flame-retardant plasticizer, fire retardant, lead stearate, two alkali formula lead titanates, epoxy resin, antistatic additive are sequentially added in order
High-speed kneading machine, 1250-1350 revs/min of kneader speed, 105 DEG C -115 DEG C of temperature, is made kneading time 8-12 minute
PVC compounds;
Ⅱ:Cold mixing:The I PVC compounds walked after high-speed kneading are cooled to after normal temperature and added in low speed mixer, are sequentially added
5- is mixed under chlorinated polyethylene rubber, TPUE, cumyl peroxide, triallyl cyanurate, normal temperature
10 minutes, PVC/CM/TPU compounds were made in 150-250 revs/min of mixer speed;
Ⅲ:Granulation:Particulate material, comminutor screw speed is made by dual-screw pelletizer in the PVC/CM/TPU compounds of II step
450-600 revs/min, 155 DEG C -165 DEG C of temperature.
(3) belt carcass dipping sizing material is prepared:
1) composition of dipping sizing material by weight described in is:100 parts of PVC paste resin (EPVC), diphenyl methane two
Isocyanates(MDI)LO-15 parts, 40-60 parts of plasticizer, 20-40 parts of flame-retardant plasticizer, 15-25 parts of fire retardant, epoxidized soybean oil
10-20 parts, 2-4 parts of liquid barium zinc compound stabilizer;
2) by above-mentioned sizing material stirring mixing, grinding, deaeration, dipping adhesive paste material is made:
I:High-speed stirred is mixed:By PVC paste resin, methyl diphenylene diisocyanate, plasticizer, the agent of fire-retardant increasing load, resistance
Combustion agent, epoxidized soybean oil, liquid barium zinc compound stabilizer are sequentially added in high speed dispersor, high-speed stirred under normal temperature, agitator
2500-2900 revs/min of speed, mixing time 20-30 minutes, -5500Pa.s of paste viscosity 4000;
II:Grinding:I is walked into the mixed thickener of high-speed stirred to grind three times by three-roll grinder, grinder roll spacing 0.15-
0.25mm, 500-750 revs/min of rotating speed;
III:Deaeration:II is walked into the thickener after grinding by vacuum degasing machine deaeration, in vacuum -0.05MPa to -0.085MPa
Under conditions of normal temperature deaeration 20-30 minutes, be then placed in belt carcass impregnating bath.
(4) belt carcass impregnation, plasticizing:
1) belt carcass impregnation:Fabric whole belt core is passed through full of thickener under the drive of hauling machine with 1-2 ms/min of speed
Impregnating bath and vacuum tank dipping thickener, 11 meters of vacuum tank height, vacuum -0.05MPa to -0.085MPa;
2) belt carcass is plastified:Belt carcass after impregnation is plastified into plasticizing box, 170 DEG C -190 DEG C of plasticization temperature, 30 meters of plasticizing box length,
Speed of the belt carcass in plasticizing box is consistent with impregnation speed.
(5) extrusion coating is molded:By the coating particulate material of (2) step by two extruderses and mould dynamic vulcanization, directly
The plasticizing belt carcass connect with (4) step fits together in hot state, coating 3-5mm;
Extruder rotating speed:30-50 revs/min;
Extruder temperature:160℃-175℃;
Mold temperature:160℃-175℃;
Belt carcass surface temperature:145℃-165℃.
Compared with prior art, the invention has the advantages that:
1st, fabric whole belt core intensity of the invention is high, and band body is thin, lightweight, and band body is soft after impregnation plasticizing, and lateral stiffness is closed
Reason, tube-forming can be good.
2nd, coating of the invention uses polyvinyl chloride powder resin (PVC)/chlorinated polyethylene rubber (CM)/thermoplastic poly ammonia
Ester elastomer (TPU) is blended, and fire resistance is good, and tensile strength is high, and coefficient of friction is big, and elasticity is excellent, and anti-wear performance is good, with impregnation
Whole belt core bonding strength after plasticizing is high.
3rd, contain methyl diphenylene diisocyanate (MDI) tackifier in belt carcass of the invention dipping sizing material, make after plasticizing
Whole belt core and the bonding strength of coating increase substantially, it is ensured that conveyer belt longtime running not delamination.
4th, the present invention is using extruder veneer moulding, Technology of Dynamic Vulcanized production conveyer belt, with technique is simple, the energy disappears
The advantages of consumption is low, production efficiency is high.
Embodiment
Contribute to the understanding of the present invention by following embodiments, but present disclosure can not be limited.
Conveyer belt caliber 200-600mm of the present invention(Bandwidth 800-2250mm), it is desired to longitudinal through thickness stretching is strong
Degree is not less than 1250-4500N/mm.
Embodiment l
The present embodiment provides a kind of band of the fire-retardant conveying of fabric solid-woven tubulose, caliber 300mm (bandwidth l1O0mm), longitudinal through thickness
Tensile strength >=1800N/mm, including coating, fabric whole belt core and belt carcass dipping sizing material;
Described overburden cover 3mm, composition by weight is:2.5 parts of 30 parts of 40 parts of 30 parts of PVC, CM, TPU, DCP,
2 parts of TAC, 0.5 part of captax, 1 part of altax, 1 part of antioxidant A, 1 part of antioxidant D, 10 parts of conductive black, nanometer
12 parts of white carbon, 10 parts of Fanglun slurry cake, 10 parts of DOP, 20 parts of TCP, 10 parts of aluminium hydroxide, 6 parts of antimony oxide, lead stearate
1 part, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 6 parts of antistatic additive P;
Described fabric whole belt core is made up of warp and weft, 4 layers of braiding structure, width 1188mm;Warp is by polyester fiber
Constituted with cotton fiber, cotton content 13%, warp-wise stress line drawing intensity is that the density of 60% width in the middle of 1500N/ roots, belt carcass is
176/lOcm, the density of remaining width is 165/lOcm;Parallel is made up of nylon fiber with cotton fiber, cotton content 38%, latitude
It is 360N/ roots, density 165/lOcm to by the tensile strength of the line of force;
Described belt carcass impregnates the composition of sizing material by weight:EPVC100 parts, 10 parts of MDI, 50 parts of DOP, 40 parts of TCP,
8 parts of antimony oxide, 10 parts of Firebrake ZB, 10 parts of epoxidized soybean oil, 2 parts of liquid barium zinc compound stabilizer.
The present embodiment provides a kind of manufacture method of fabric solid-woven tubulose fire retarding conveying band, comprises the following steps:
(1) braided fabric whole belt core:
Described fabric whole belt core is made up of warp and weft, 4 layers of braiding structure, width 1188mm;Warp is by polyester fiber
Constituted with cotton fiber, cotton content 13%, warp-wise stress line drawing intensity is that the density of 60% width in the middle of 1500N/ roots, belt carcass is
176/lOcm, the density of remaining width is 165/lOcm;Parallel is made up of nylon fiber with cotton fiber, cotton content 38%, latitude
It is 360N/ roots, density 165/lOcm to by the tensile strength of the line of force.
(2) covering layer sizing is prepared:
1) composition of covering layer sizing by weight described in is:2.5 parts of 30 parts of 40 parts of 30 parts of PVC, CM, TPU, DCP,
2 parts of TAC, 0.5 part of captax, 1 part of altax, 1 part of antioxidant A, 1 part of antioxidant D, 10 parts of conductive black, nanometer
12 parts of white carbon, 10 parts of Fanglun slurry cake, 10 parts of DOP, 20 parts of TCP, 10 parts of aluminium hydroxide, 6 parts of antimony oxide, lead stearate
1 part, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 6 parts of antistatic additive P;
2) above-mentioned sizing material is mixed, granulated, covering layer sizing particle is made:
I:High-speed kneading:By PVC, accelerator, age resistor, conductive black, Nano carbon white, Fanglun slurry cake, DOP, TCP, hydrogen-oxygen
Change aluminium, antimony oxide, lead stearate, two alkali formula lead titanates, epoxy resin, antistatic additive sequentially add high-speed kneading in order
Kneading time 8-12 minute, PVC compounds are made in machine, 1250-1350 revs/min of kneader speed, 105 DEG C -115 DEG C of temperature;
II:Cold mixing:The I PVC compounds walked after high-speed kneading are cooled to after normal temperature and added in low speed mixer, are sequentially added
Mixed 5-10 minutes under CM, TPU, DCP, TAC, normal temperature, l50-250 revs/min of mixer speed, PVC/CM/TPU is made and mixes
Close material;
III:Granulation:Particulate material is made by dual-screw pelletizer in the PVC/CM/TPU compounds that II is walked, and comminutor screw rod turns
Fast 450-600 revs/min, 155 DEG C -165 DEG C of temperature.
(3) belt carcass dipping sizing material is prepared:
1) composition of dipping sizing material by weight described in is:EPVC100 parts, MDI10 parts, 50 parts of DOP, 40 parts of TCP, three oxygen
Change 8 parts of two antimony, 10 parts of Firebrake ZB, 10 parts of epoxidized soybean oil, 2 parts of liquid barium zinc compound stabilizer;
2) by above-mentioned sizing material stirring mixing, grinding, deaeration, dipping adhesive paste material is made:
I:High-speed stirred is mixed:EPVC, MDI, DOP, TCP, antimony oxide, Firebrake ZB, epoxidized soybean oil, liquid barium zinc are answered
Close stabilizer to sequentially add in high speed dispersor, high-speed stirred under normal temperature, 2500-2900 revs/min of agitator speed, stirring
Time 20-30 minute, paste viscosity 4000-5500Pa.s;
II:Grinding:I is walked into the mixed thickener of high-speed stirred to grind three times by three-roll grinder, grinder roll spacing 0.15-
0.25mm, 500-750 revs/min of rotating speed;
III:Deaeration:II is walked into the thickener after grinding by vacuum degasing machine deaeration, in vacuum -0.05MPa to -0.085MPa
Bar with lower normal temperature deaeration 20-30 minutes, be then placed in belt carcass impregnating bath.
(4) belt carcass impregnation, plasticizing:
1) belt carcass impregnation:Fabric whole belt core is passed through full of paste under the drive of hauling machine with 1.4-1.6 ms/min of speed
Impregnating bath and vacuum tank the dipping thickener of material, 11 meters of vacuum tank height, vacuum -0.05MPa to -0.085MPa;
2) belt carcass is plastified:Belt carcass after impregnation is plastified into plasticizing box, 170 DEG C -190 DEG C of plasticization temperature, 30 meters of plasticizing box length,
Speed of the belt carcass in plasticizing box is consistent with impregnation speed.
(5) extrusion coating is molded:By the coating particulate material of (2) step by two extruderses and mould dynamic vulcanization, directly
The plasticizing belt carcass connect with (4) step fits together in hot state, coating 3mm;
Extruder rotating speed:30-50 revs/min;
Extruder temperature:160℃-175℃;
Mold temperature:160℃--175℃;
Belt carcass surface temperature:145℃-165℃.
Embodiment 2
The present embodiment provides a kind of fabric solid-woven tubulose fire retarding conveying band, caliber 400mm(Bandwidth 1600mm), longitudinal through thickness drawing
Stretch intensity >=2500N/mm, including coating, fabric whole belt core and belt carcass dipping sizing material:
Described overburden cover 4mm, composition by weight is:2 parts of 25 parts of 35 parts of 40 parts of PVC, CM, TPU, DCP,
TAC l.5 part, 1 part of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of anti-aging agent RD, 1 part of antioxidant 4010NA, conductive charcoal
Black 15 parts, 10 parts of Nano carbon white, 8 parts of Fanglun slurry cake, 15 parts of DOS, 15 parts of TCEP, 10 parts of Firebrake ZB, 8 parts of APP,
1 part of lead stearate, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 7 parts of antistatic agent TM;
Described fabric whole belt core is made up of warp and weft, 4 layers of braiding structure, width 1697mm;Warp is by nylon fiber
Constituted with cotton fiber, cotton content 12%, warp-wise stress line drawing intensity is that the density of 60% width in the middle of 1750N/ roots, belt carcass is
198/lOcm, the density of remaining width is 186/lOcm;Parallel is made up of nylon fiber with cotton fiber, cotton content 36%, latitude
It is 360N/ roots, density 165/lOcm to by the tensile strength of the line of force;
Described belt carcass impregnates the composition of sizing material by weight:EPVC100 parts, MDI12 parts, 45 parts of DOA, 35 parts of TCEP,
10 parts of red phosphorus, 10 parts of aluminium hydroxide, 15 parts of epoxidized soybean oil, 3 parts of liquid barium zinc compound stabilizer.
The present embodiment provides a kind of manufacture method of fabric solid-woven tubulose fire retarding conveying band, comprises the following steps:
(1) braided fabric whole belt core:
Described fabric whole belt core is made up of warp and weft, 4 layers of braiding structure, width 1697mm;Warp is by nylon fiber
Constituted with cotton fiber, cotton content 12%, warp-wise stress line drawing intensity is that the density of 60% width in the middle of 1750N/ roots, belt carcass is
198/lOcm, the density of remaining width is 186/lOcm;Parallel is made up of nylon fiber with cotton fiber, cotton content 36%, latitude
It is 360N/ roots, density 165/lOcm to by the tensile strength of the line of force.
(2) covering layer sizing is prepared:
1) composition of covering layer sizing by weight described in is:2 parts of 25 parts of 35 parts of 40 parts of PVC, CM, TPU, DCP, TAC
L.5 part, 1 part of accelerant CZ, 0.5 part of Vulcanization accelerator TMTD, 1 part of anti-aging agent RD, 1 part of antioxidant 4010NA, conductive black 15
Part, 10 parts of Nano carbon white, 8 parts of Fanglun slurry cake, 15 parts of DOS, 15 parts of TCEP, 10 parts of Firebrake ZB, 8 parts of APP is stearic
1 part of lead plumbate, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 7 parts of antistatic agent TM;
2) above-mentioned sizing material is mixed, granulated, covering layer sizing particle is made:
I:High-speed kneading:By PVC, accelerator, age resistor, conductive black, Nano carbon white, Fanglun slurry cake, DOS, TCEP, boric acid
Zinc, APP, lead stearate, two alkali formula lead titanates, epoxy resin, antistatic additive sequentially add high-speed kneading machine in order,
8-12 minutes kneading times, PVC compounds are made in 1250-1350 revs/min of kneader speed, 105 DEG C-115 DEG C of temperature;
II:Cold mixing:The I PVC compounds walked after high-speed kneading are cooled to after normal temperature and added in low speed mixer, are sequentially added
Mixed 5-10 minutes under CM, TPU, DCP, TAC, normal temperature, 150-250 revs/min of mixer speed, PVC/CM/TPU mixing is made
Material;
III:Granulation:Particulate material is made by dual-screw pelletizer in the PVC/CM/TPU compounds that II is walked, and comminutor screw rod turns
Fast 450-600 revs/min, 155 DEG C -165 DEG C of temperature.
(3) belt carcass dipping sizing material is prepared:
1) composition of dipping sizing material by weight described in is:EPVCIOO parts, 12 parts of MDI, 45 parts of DOA, 35 parts of TCEP,
10 parts of red phosphorus, 10 parts of aluminium hydroxide, 15 parts of epoxidized soybean oil, 3 parts of liquid barium zinc compound stabilizer;
2) by above-mentioned sizing material stirring mixing, grinding, deaeration, dipping adhesive paste material is made:
I:High-speed stirred is mixed:EPVC, MDI, DOP, TCP, antimony oxide, Firebrake ZB, epoxidized soybean oil, liquid barium zinc are combined
Stabilizer is sequentially added in high speed dispersor, high-speed stirred under normal temperature, 2500-2900 revs/min of agitator speed, mixing time
20--30 minutes, paste viscosity 4000-5000Pa.s;
II:Grinding:I is walked into the mixed thickener of high-speed stirred to grind three times by three-roll grinder, grinder roll spacing 0.15-
0.25mm, 500-750 revs/min of rotating speed;
III:Deaeration:II is walked into the thickener after grinding by vacuum degasing machine deaeration, in vacuum 0.05-0.085MPa condition
Lower normal temperature deaeration 20-30 minutes, is then placed in belt carcass impregnating bath.
(4) belt carcass impregnation, plasticizing:
1) belt carcass impregnation:Fabric whole belt core is passed through full of paste under the drive of hauling machine with 1.2-1.4 ms/min of speed
Impregnating bath and vacuum tank the dipping thickener of material, 11 meters of vacuum tank height, vacuum 0.05-0.085MPa;
2) belt carcass is plastified:Belt carcass after impregnation is plastified into plasticizing box, 170 DEG C -190 DEG C of plasticization temperature, 30 meters of plasticizing box length,
Speed of the belt carcass in plasticizing box is consistent with impregnation speed.
(5) extrusion coating is molded:By the coating particulate material of (2) step by two extruderses and mould dynamic vulcanization, directly
The plasticizing belt carcass connect with (4) step fits together in hot state, coating 4mm;
Extruder rotating speed:30-50 revs/min;
Extruder temperature:160℃-175℃;
Mold temperature:160℃-175℃;
Belt carcass surface temperature:145℃-165℃.
Embodiment 3
The present embodiment provides a kind of fabric solid-woven tubulose fire retarding conveying band, caliber 500mm(Bandwidth 1850mm), through thickness stretching is by force
Spend >=3400 N/mm, including coating, fabric whole belt core and belt carcass dipping sizing material:
Described overburden cover 5mm, composition by weight is:20 parts of 30 parts of 50 parts of PVC, CM, TPU, DCP l.5 part,
1 part of 1 part of TAC, accelerant C ED, 0.5 part of Vulcanization accelerator TMTD ,-S1 parts of antioxidant 2246,1 part of antioxidant 4010 Na is conductive
12 parts of carbon black, 10 parts of Nano carbon white, 9 parts of Fanglun slurry cake, 20 parts of DOA, 10 parts of TDCPP, 10 parts of red phosphorus, melamine urea acid
10 parts of salt, l parts of lead stearate, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 8 parts of antistatic additive SA;
Described fabric whole belt core is made up of warp and weft, 3 layers of braiding structure, width 2015mm;Warp is by aramid fiber
Constituted with cotton fiber, cotton content 12%, warp-wise stress line drawing intensity is that 60% width density is 188 in the middle of 2500N/ roots, belt carcass
Root/10cm, remaining width density is 176/10cm, and parallel is made up of nylon fiber with cotton fiber, cotton content 40%, broadwise by
The tensile strength of the line of force is 450N/ roots, 180/10cm of density;
Described belt carcass impregnates the composition of sizing material by weight:EPVC100 parts, MDI15 parts, 60 parts of DOS, 20 parts of TDCPP,
10 parts of APP, 12 parts of magnesium hydroxide, 20 parts of epoxidized soybean oil, 4 parts of liquid barium zinc compound stabilizer.
The present embodiment provides a kind of manufacture method of fabric solid-woven tubulose fire retarding conveying band, comprises the following steps:
(1) braided fabric whole belt core:
Described fabric whole belt core is made up of warp and weft, 3 layers of braiding structure, width 2015mm;Warp is by aramid fiber
Constituted with cotton fiber, cotton content 12%, warp-wise stress line drawing intensity is that 60% width density is 188 in the middle of 2500N/ roots, belt carcass
Root/10cm, remaining width density is 176/10cm, and parallel is made up of nylon fiber with cotton fiber, cotton content 40%, broadwise by
The tensile strength of the line of force is 450N/ roots, 180/10cm of density.
(2) covering layer sizing is prepared:
1) composition of covering layer sizing by weight described in is:20 parts of 30 parts of 50 parts of PVC, CM, TPU, DCP l.5 part,
1 part of 1 part of TAC, accelerant C ED, 0.5 part of Vulcanization accelerator TMTD ,-S1 parts of antioxidant 2246,1 part of antioxidant 4010NA is conductive
12 parts of carbon black, 10 parts of Nano carbon white, 9 parts of Fanglun slurry cake, 20 parts of DOA, 10 parts of TDCPP, 10 parts of red phosphorus, melamine urea acid
10 parts of salt, l parts of lead stearate, two 4 parts of alkali formula lead titanates, 2 parts of epoxy resin, 8 parts of antistatic additive SA;
2) above-mentioned sizing material is mixed, granulated, covering layer sizing particle is made:
I:High-speed kneading:By PVC, accelerator, age resistor, conductive black, Nano carbon white, Fanglun slurry cake, DOA, TDCPP,
Red phosphorus, melamine urea hydrochlorate, lead stearate, two alkali formula lead titanates, epoxy resin, antistatic additive are sequentially added at a high speed in order
Kneader, 1250-1350 revs/min of kneader speed, 105 DEG C -115 DEG C of temperature, is made PVC and mixed kneading time 8-12 minute
Close material;
II:Cold mixing:The I PVC compounds walked after high-speed kneading are cooled to after normal temperature and added in low speed mixer, are sequentially added
Mixed 5-10 minutes under CM, TPU. DCP. TAC, normal temperature, 150-250 revs/min of mixer speed, PVC/CM/TPU is made and mixes
Close material;
III:Granulation:Particulate material is made by dual-screw pelletizer in the PVC/CM/TPU compounds that II is walked, and comminutor screw rod turns
Fast 450-600 revs/min, 155 DEG C -165 DEG C of temperature.
(3) belt carcass dipping sizing material is prepared:
1) the dipping sizing material described in:Composition by weight is:60 parts of 15 parts of 100 parts of EPVC, MDI, DOS, TDCPP 20
Part, 10 parts of APP, l2 parts of oxygen magnesia, 20 parts of epoxidized soybean oil, 4 parts of liquid barium zinc compound stabilizer;
2) above-mentioned sizing material is whisked into mixing, grinding, deaeration, dipping adhesive paste material is made:
I:High-speed stirred is mixed:EPVC, MDI, DOS. TDCPP, APP, magnesium hydroxide, epoxidized soybean oil, liquid barium zinc
Compound stabilizer is sequentially added in high speed dispersor, high-speed stirred under normal temperature, 2500-2900 revs/min of agitator speed, stirring
Time 20--30 minute, paste viscosity 4000--5500Pa.S;
II:Grinding:I is walked into the mixed thickener of high-speed stirred to grind three times by three-roll grinder, grinder roll spacing 0.15-
0.25mm, 500-750 revs/min of rotating speed;
III:Deaeration:II is walked into the thickener after grinding by vacuum degasing machine deaeration, in vacuum -0.05MPa to -0.085MPa
Under conditions of normal temperature deaeration 20-30 minutes, be then placed in belt carcass impregnating bath.
(4) belt carcass impregnation, plasticizing:
1) belt carcass impregnation:Fabric whole belt core is passed through full of paste under the drive of hauling machine with 1.0-1.2 ms/min of speed
Impregnating bath and vacuum tank the dipping thickener of material, 11 meters of vacuum tank height, vacuum -0.05MPa to -0.085Mpa;
2) belt carcass is plastified:Belt carcass after impregnation is plastified into plasticizing box, 170 DEG C -190 DEG C of plasticization temperature, plasticizing box length 30
Rice, speed of the belt carcass in plasticizing box is consistent with impregnation speed.
(5) extrusion coating is molded:By the coating particulate material of (2) step by two extruderses and mould dynamic vulcanization, directly
The plasticizing belt carcass connect with (4) step fits together in hot state, coating 5mm;
Extruder rotating speed:30-50 revs/min;
Extruder temperature:160℃-175℃;
Mold temperature:160℃-175℃;
145 DEG C -165 DEG C of belt carcass surface temperature.
4th, the performance detection data of embodiment:
。
Claims (8)
1. a kind of fabric solid-woven tubulose fire retarding conveying band, including coating, fabric whole belt core and belt carcass dipping sizing material, its feature
It is:
Described overburden cover 3-5mm, composition by weight is:30-50 parts of polyvinyl chloride powder resin, haloflex rubber
30-40 parts of glue, 20-30 parts of TPUE, 1.5-2.5 parts of cumyl peroxide, triallyl cyanurate 1-2
Part, 1-2 parts of accelerator, 1-2 parts of age resistor, 10-15 parts of conductive black, 10-15 parts of Nano carbon white, 8-10 parts of Fanglun slurry cake,
10-20 parts of plasticizer, 10-20 parts of flame-retardant plasticizer, 15-25 parts of fire retardant, 1 part of lead stearate, two 4 parts of alkali formula lead titanates, ring
2 parts of oxygen tree fat, 6-8 parts of antistatic additive;
Described fabric whole belt core is made up of warp and weft, and 3-4 layers of braiding structure, width is the 105%-110% of bandwidth;Through
Line is made up of nylon or polyester or aramid fiber with cotton fiber, cotton content 10%-15%, and warp-wise stress line drawing intensity is 1000-
The density of 60% width is 160-200 roots/10cm in the middle of 3000N/ roots, belt carcass, and the density ratio intermediate density of remaining width is reduced
10-15 roots/10mm;Parallel is made up of nylon fiber with cotton fiber, cotton content 35%-45%, and broadwise is by the tensile strength of the line of force
300-500N/ roots, density 120-180 roots/10cm;
Described belt carcass impregnates the composition of sizing material by weight:100 parts of PVC paste resin, diphenylmethane diisocyanate
10-15 parts of ester, 40-60 parts of plasticizer, 20-40 parts of flame-retardant plasticizer, 15-25 parts of fire retardant, 10-20 parts of epoxidized soybean oil, liquid
2-4 parts of body barium zinc compound stabilizer.
2. the fabric solid-woven tubulose fire retarding conveying band according to claim l, it is characterised in that described accelerator is 2- sulphur
Alcohol radical benzothiazole, dibenzothiazyl disulfide, N cyclohexyl 2 benzothiazole sulfenamide, tetramethylthiuram disulfide,
One kind or combination in cadmium diethyl dithiocarbamate.
3. fabric solid-woven tubulose fire retarding conveying band according to claim 1, it is characterised in that described age resistor is N- benzene
Base-αnaphthylamine, N- phenyl-beta-naphthylamines, 2,2,4- trimethyl -1,2- dihyaroquinoline condensates, 2,2 '-thiobis (4- methyl -6-
Tert-butyl phenol), one kind in N- isopropyls-N '-diphenyl-para-phenylene diamine or combination.
4. the fabric solid-woven tubulose fire retarding conveying band according to claim l, it is characterised in that described plasticizer is adjacent benzene
One kind or its combination in diformazan dioctyl phthalate, di-n-octyl sebacate, dioctyl adipate.
5. the fabric solid-woven tubulose fire retarding conveying band according to claim l, it is characterised in that described flame-retardant plasticizer is
Triaryl phosphate (TCP), three(The chloroethyls of β mono-)Phosphate (TCEP), three(1,3- bis- chloropropyl)Phosphate (TDCPP), first
One kind or combination in phenyl diphenyl phosphoester (CDP).
6. fabric solid-woven tubulose fire retarding conveying band according to claim 1, it is characterised in that described fire retardant is hydrogen-oxygen
Change in aluminium, magnesium hydroxide, Firebrake ZB, red phosphorus, antimony oxide, APP, MCA, decabromodiphenyl oxide
A kind of or combination.
7. fabric solid-woven tubulose fire retarding conveying band according to claim 1, it is characterised in that described antistatic additive is alkane
Base benzenephosphonic acid ester diethanolamine salt, trihydroxyethyl methyl quaternary ammonium methyl sulfate, octadecyldimethyl ethoxy quaternary ammonium nitric acid
Any one in salt.
8. a kind of manufacture method of fabric solid-woven tubulose fire retarding conveying band as described in claim l, it is characterised in that including with
Lower step:
(1) braided fabric whole belt core:
Described fabric whole belt core is made up of warp and weft, and 3-4 layers of braiding structure, width is the 105%-110% of bandwidth;Through
Line is made up of nylon or polyester or aramid fiber with cotton fiber, cotton content 10%-15%, and warp-wise stress line drawing intensity is 1000-
The density of 60% width is 160-200 roots/10cm in the middle of 3000N/ roots, belt carcass, and the density ratio intermediate density of remaining width is reduced
10-15 roots/10mm;Parallel is made up of nylon fiber with cotton fiber, cotton content 35%-45%, and broadwise is by the tensile strength of the line of force
300-500N/ roots, density 120-180 roots/10cm;
(2) covering layer sizing is prepared:
1) composition of covering layer sizing by weight described in is:30-50 parts of polyvinyl chloride powder resin, chlorinated polyethylene rubber
30-40 parts, 20-30 parts of TPUE, 1.5-2.5 parts of cumyl peroxide, triallyl cyanurate 1-2
Part, 1-2 parts of accelerator, 1-2 parts of age resistor, 10-15 parts of conductive black, 10-15 parts of Nano carbon white, 8-10 parts of Fanglun slurry cake,
10-20 parts of plasticizer, 10-20 parts of flame-retardant plasticizer, 15-25 parts of fire retardant, 1 part of lead stearate, two 4 parts of alkali formula lead titanates, ring
2 parts of oxygen tree fat, 6-8 parts of antistatic additive;
2) above-mentioned sizing material is mixed, granulated, covering layer sizing particle is made:
I:High-speed kneading:By polyvinyl chloride powder resin, accelerator, age resistor, conductive black, Nano carbon white, Fanglun slurry cake, increasing
Modeling agent, flame-retardant plasticizer, fire retardant, lead stearate, two alkali formula lead titanates, epoxy resin, antistatic additive are sequentially added in order
High-speed kneading machine, 1250-1350 revs/min of kneader speed, 105 DEG C -115 DEG C of temperature, is made kneading time 8-12 minute
PVC compounds;
II:Cold mixing:The I PVC compounds walked after high-speed kneading are cooled to after normal temperature and added in low speed mixer, are sequentially added
5- is mixed under chlorinated polyethylene rubber, TPUE, cumyl peroxide, triallyl cyanurate, normal temperature
10 minutes, PVC/CM/TPU compounds were made in 150-250 revs/min of mixer speed;
III:Granulation:Particulate material is made by dual-screw pelletizer in the PVC/CM/TPU compounds that II is walked, and comminutor screw rod turns
Fast 450-600 revs/min, 155 DEG C -165 DEG C of temperature:
(3) belt carcass dipping sizing material is prepared:
1) composition of dipping sizing material by weight described in is:1OO parts of PVC paste resin, diphenylmethane diisocyanate
10-15 parts of ester, 60 parts of plasticizer 40-, 40 parts of flame-retardant plasticizer 20-, 15-25 parts of fire retardant, 10-20 parts of epoxidized soybean oil,
2-4 parts of liquid barium zinc compound stabilizer;
2) by above-mentioned sizing material stirring mixing, grinding, deaeration, dipping adhesive paste material is made:
I:High-speed stirred is mixed:By PVC paste resin, methyl diphenylene diisocyanate, plasticizer, flame-retardant plasticizer, resistance
Combustion agent, epoxidized soybean oil, liquid barium zinc compound stabilizer are sequentially added in high speed dispersor, high-speed stirred under normal temperature, agitator
2500-2900 revs/min of speed, mixing time 20-30 minutes, -5500Pa.s of paste viscosity 4000;
II:Grinding:I is walked into the mixed thickener of high-speed stirred to grind three times by three-roll grinder, grinder roll spacing 0.15-
0.25mm, 500-750 revs/min of rotating speed;
III:Deaeration:II is walked into the thickener after grinding by vacuum degasing machine deaeration, in vacuum 0.05-0.085MPa condition
Lower normal temperature deaeration 20-30 minutes, is then placed in belt carcass impregnating bath;
(4) belt carcass impregnation, plasticizing:
1) belt carcass impregnation:Fabric whole belt core is passed through full of thickener under the drive of hauling machine with 1-2 ms/min of speed
Impregnating bath and vacuum tank dipping thickener, 11 meters of vacuum tank height, vacuum -0.05MPa to -0.085MPa;
2) belt carcass is plastified:Belt carcass after impregnation is plastified into plasticizing box, 170 DEG C -190 DEG C of plasticization temperature, 30 meters of plasticizing box length,
Speed of the belt carcass in plasticizing box is consistent with impregnation speed;
(5) extrusion coating is molded:By the coating particulate material of (2) step by two extruderses and mould dynamic vulcanization, directly with
(4) the plasticizing belt carcass of step fits together in hot state, coating 3-5mm;
Extruder rotating speed:30-50 revs/min;
Extruder temperature:160℃-175℃;
Mold temperature:160℃-175℃;
Belt carcass surface temperature:145℃-165℃.
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