A kind of unitary-core flame-resistant conveying belt and working method thereof with transition layer
Technical field
The present invention relates to a kind of colliery and use fire retarding conveying band, relate in particular to a kind of fabric unitary-core flame-resistant conveying belt and working method thereof.
Background technology
Unitary-core flame-resistant conveying belt is the main tool of transportation coal under the present coal mine; Stipulate according to MT914-2008 " the fabric unitary-core flame-resistant conveying belt is used in the colliery "; Unitary-core flame-resistant conveying belt divides two types: a kind of is the plastics unitary-core flame-resistant conveying belts; Be called for short the PVC type; It is to soak surface, plasticizing back by the fabric whole belt core to apply one deck PVC RESINS again and form, and its advantage is that technology is simple, cost is low, production efficiency is high, flame retardant properties is good, shortcoming be prone to skid, groove forming character is poor, carry that the inclination angle is little, conveying efficiency is low; Another kind is the rubber face unitary-core flame-resistant conveying belt; Be called for short the PVG type; It is to soak surface, plasticizing back by the fabric whole belt core to cover one deck flame retardant rubber again and form; Its advantage is good springiness, be prone to grooving, carry that the inclination angle is big, conveying efficiency is high, shortcoming be the bond properties of rubber and belt carcass poor, be prone to delamination, foaming, work-ing life and lack.In addition, the cover thickness of unitary-core flame-resistant conveying belt is thinner in the prior art, general PVG type rubber cover 1.5mm, and PVC rubber cover 1mm, in case tectum grinds off, belt carcass has just lost use value, causes the waste of the resource and the energy.
Summary of the invention
In order to overcome the deficiency of existing PVC, PVG unitary-core flame-resistant conveying belt; The invention provides a kind of unitary-core flame-resistant conveying belt with transition layer; It has not only satisfied the requirement of MT914-2008 " the fabric unitary-core flame-resistant conveying belt is used in the colliery " fully; And improved the bond strength of rubber face unitary-core flame-resistant conveying belt significantly, improve the thickness of rubber cover simultaneously, thereby prolong the work-ing life of conveying belt.
The present invention solves the problems of the technologies described above the technical scheme of being taked to be:
A kind of unitary-core flame-resistant conveying belt with transition layer is provided, comprises framework material, tectum, it is characterized in that between framework material, tectum, transition layer being set; Described framework material is to soak the closely knit integral body after the plasticizing by the fabric whole belt core, and transition layer is fire-retardant thermoplastic elastomer, and tectum is the vulcanized rubber combination material of flame-retardant and anti-static.
In order to obtain the unitary-core flame-resistant conveying belt of above-mentioned band transition layer, the present invention has adopted following working method:
At first, the fabric whole belt core soaked to mould plastify into closely knit integral body, obtain framework material;
Secondly, framework material sticks on transition layer through two extruders under 170-180 ℃ hot state;
Once more, transition layer after the stickup and framework material stick on tectum on the surface of transition layer through two extruders under 160-170 ℃ hot state again.
Described thermoplastic elastomer is a kind of blend that comprises powdery paracril and SE; The blend prescription is by weight: powdery paracril 40-60 part, SE 40-60 part, flame-retardant plasticizer 10-15 part, fire retardant 50-100 part; Carbon black 10-20 part, 5 parts in zinc oxide, 1 part of Triple Pressed Stearic Acid, sulphur 1-1.5 part; Promotor 1-2 part, 1 part of stablizer, anti-aging agent 1-2 part; Blending process is: at first SE and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer are carried out heat in the high speed kneader and mix preplasticizing; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor again and in the low speed kneader, carry out cold mixing, make the powdery blend; Blend is through the twin screw extruder mixing granulator, and then is bonded together through two extruders dynamic vulcanization and framework material; Described thermoplastic elastic body thickness is the 0.5-3 millimeter.
Described thermoplastic elastomer also can be a kind of powdery paracril and poly blend of comprising; The blend prescription is by weight: powdery paracril 40-60 part, Vilaterm 40-60 part, flame-retardant plasticizer 10-15 part, fire retardant 60-120 part; Carbon black 10-20 part, 5 parts in zinc oxide, 1 part of Triple Pressed Stearic Acid, sulphur 1-1.5 part; Promotor 1-2 part, 1 part of stablizer, anti-aging agent 1-2 part; Blending process is: at first Vilaterm and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer are carried out heat in the high speed kneader and mix preplasticizing; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor again and in the low speed kneader, carry out cold mixing, make the powdery blend; Blend is through the twin screw extruder mixing granulator, and then is bonded together through two extruders dynamic vulcanization and framework material, and described thermoplastic elastic body thickness is the 0.5-3 millimeter.
Described thermoplastic elastomer can also be a kind of powdery paracril and polyacrylic blend of comprising; The blend prescription is by weight: powdery paracril 40-60 part, Vestolen PP 7052 40-60 part, 5 parts of Vestolen PP 7052 maleic anhydride graft reactants (PP-g-MA); Flame-retardant plasticizer 15-20 part; Fire retardant 60-120 part, carbon black 8-15 part, anti-aging agent 1-2 part; Resol 3-5 part, tin protochloride 0.4-0.6 part; Blending process is: at first Vestolen PP 7052 and maleic anhydride graft reactant (PP-g-MA), flame-retardant plasticizer, fire retardant, carbon black, anti-aging agent, resol, tin protochloride are carried out heat in the high speed kneader and mix preplasticizing; After being cooled to normal temperature; Add the powdery paracril again and in the low speed kneader, carry out cold mixing, make the powdery blend; Blend is through the twin screw extruder mixing granulator, and then is bonded together through two extruders dynamic vulcanization and framework material; Described thermoplastic elastic body thickness is the 0.5-3 millimeter.
Described vulcanized rubber combination material is a kind of blend that comprises powdery paracril and chlorinated polyethylene rubber; The blend prescription is by weight: powdery paracril 40-60 part, chlorinated polyethylene rubber 40-60 part, 1 part of Triple Pressed Stearic Acid, 5 parts in zinc oxide; Graphitized carbon black 10-15 part, flame-retardant plasticizer 10-15 part, fire retardant 50-100 part; Anti-aging agent 1-2 part, promotor 1.5-3 part, sulphur 1.5-2.5 part; Blending process is: at first powdery chlorinated polyethylene rubber and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer are carried out heat in the high speed kneader and mix preplasticizing; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor again and in the low speed kneader, carry out cold mixing, make the powdery blend; Blend is through the twin screw extruder mixing granulator, and then is bonded together through two extruders dynamic vulcanization and transition layer; Described vulcanized rubber combination material thickness is the 0.5-3 millimeter.
Described vulcanized rubber combination material also can be that a kind of powdery paracril and chlorosulphonation of comprising gathered the blend of second rubber, and the blend prescription is by weight: powdery paracril 40-60 part, chlorosulfonated polyethylene rubber 40-60 part, 1 part of Triple Pressed Stearic Acid; Zinc oxide 3-5 part, Natural manganese dioxide 3-5 part, plumbous oxide 3-5 part; Graphitized carbon black 10-15 part, flame-retardant plasticizer 10-15 part, fire retardant 50-100 part; Anti-aging agent 1-2 part, promotor 1.5-3 part, sulphur 1.5-2.5 part; Blending process is: at first with powdery chlorosulfonated polyethylene rubber and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer; Triple Pressed Stearic Acid etc. carry out heat and mix preplasticizing in the high speed kneader; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor etc. again and in the low speed kneader, carry out cold mixing, make the powdery blend).Blend is through the twin screw extruder mixing granulator, and then is bonded together through two extruders dynamic vulcanization and transition layer; Described vulcanized rubber combination material thickness is the 0.5-3 millimeter.
Described vulcanized rubber combination material also can be a kind of blend that comprises powdery paracril and polyurethane termoplastic elastomer, and the blend prescription is by weight: powdery paracril 40-60 part, polyurethane termoplastic elastomer 40-60 part; 1 part of Triple Pressed Stearic Acid, zinc oxide 2-4 part, graphitized carbon black 10-15 part; Flame-retardant plasticizer 10-15 part, fire retardant 70-130 part, anti-aging agent 1-2 part; Promotor 1.5-3 part, sulphur 1.5-2.5 part; Blending process is: at first in banburying, make blend by above-mentioned prescription, blend is through the twin screw extruder mixing granulator, and then is bonded together through two extruders dynamic vulcanization and transition layer; Described vulcanized rubber combination material thickness is the 0.5-3 millimeter.
Described flame-retardant plasticizer can be selected a kind of or combination in clorafin, triaryl phosphate (TCP), three (β-chloroethyl) SULPHOSUCCINIC ACID ESTER (TCEP), three (2,3-two chloropropyls) SULPHOSUCCINIC ACID ESTER (TDCPP), the tolyl diphenyl phosphoester (CDP); Fire retardant can be selected a kind of or combination in active aluminium hydroxide, Marinco H, zinc borate, red phosphorus, Antimony Trioxide: 99.5Min, ammonium polyphosphate, melamine cyanurate, the decabromodiphenyl oxide; Anti-aging agent can be selected N-phenyl-αNai An (antioxidant A), N-phenyl-β naphthylamines (antioxidant D), 2; 2; 4-trimethylammonium-1; 2-dihyaroquinoline polymer (arborescens) (anti-aging agent RD), 2,2 '-thiobis (4-methyl-6-tert butyl phenol) (a kind of or combination among antioxidant 2246-S), the N-sec.-propyl-N '-diphenyl-para-phenylene diamine (antioxidant 4010NA); Promotor can be selected a kind of or combination in 2-benzothiazolyl mercaptan (captax), dibenzothiazole disulfide (altax), N cyclohexyl 2 benzothiazole sulfenamide (accelerant CZ), tetramethyl-thiuram disulfide (TM monex TD), the cadmium diethyl dithiocarbamate (accelerant C ED).
The present invention compared with prior art, the beneficial effect that has is:
Between whole belt core and tectum, increased the transition layer of thermoplastic elastomer; And thermoplastic elastomer and rubber and plastics all have very high bond strength; Make tectum can be bonded together more firmly, thereby solved delamination, the bubble problem of rubber face of the prior art effectively through transition layer and whole belt core; Simultaneously, because tectum and transition layer have formed whole rubber cover, its thickness reaches as high as 6mm, is 4 times of prior art, thereby has prolonged the work-ing life of inhibiting tape; In addition, owing to used thermoplastic elastomer, can take extruder for shaping and dynamic vulcanization technology, from and can reach save energy and the purpose of enhancing productivity.
Description of drawings
Accompanying drawing is the cross-sectional structure synoptic diagram of product of the present invention.
Among the figure, 1-framework material, 2-transition layer, 3-tectum.
Embodiment
To help understanding of the present invention through following embodiment, but can not limit content of the present invention.Can arbitrary combination between described thermoplastic elastomer and the described vulcanized rubber combination material, do not receive the restriction of embodiment.
Embodiment 1
Shown in accompanying drawing, the unitary-core flame-resistant conveying belt of band transition layer of the present invention comprises framework material 1, transition layer 2, tectum 3.Framework material 1 is the closely knit integral body of fabric whole belt core after soaking plasticizing, and whole belt core is by cotton and synthon (terylene, nylon) difference Split Down zygonema, is woven into the fabric one-piece construction more than three layers or three layers with parallel then; Transition layer 2 is fire-retardant thermoplastic elastomers; Tectum 3 is vulcanized rubber combination material of flame-retardant and anti-static.
Production technique is: at first the fabric whole belt core is soaked to mould and plastify into closely knit integral body, obtain framework material 1; , framework material sticks on it through two extruders under 170-180 ℃ hot state with transition layer; Once more, transition layer after the stickup and framework material stick on tectum on the surface of transition layer through two extruders under 160-170 ℃ hot state again.
Described thermoplastic elastomer is a kind of powdery paracril and poly blend of comprising; The blend prescription is by weight: 50 parts of powdery paracrils, 50 parts of Vilaterm, TCP12 part, 50 parts of zinc borates; 30 parts of ammonium polyphosphates, 10 parts in red phosphorus, 10 parts of carbon blacks; 5 parts in zinc oxide, 1 part of Triple Pressed Stearic Acid, 1 part in sulphur; 1 part of altax, TM monex TD0.5 part, 1 part of barium zinc stabilizer, 1.5 parts of anti-aging agent RDs.Blending process is: at first Vilaterm and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer are carried out heat in the high speed kneader and mix preplasticizing; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor again and in the low speed kneader, carry out cold mixing, make the powdery blend; Blend is through the twin screw extruder mixing granulator, and then is bonded together 1.5 millimeters of described thermoplastic elastic body thicknesses through two extruders dynamic vulcanization and framework material 1.
Described vulcanized rubber combination material is a kind of blend that comprises powdery paracril and chlorinated polyethylene rubber; The blend prescription is by weight: 50 parts of powdery paracrils, 50 parts of chlorinated polyethylene rubbers, 1 part of Triple Pressed Stearic Acid, 5 parts in zinc oxide; 12 parts of graphitized carbon blacks, flame-retardant plasticizer TCEP12 part, 30 parts of active aluminium hydroxides, 10 parts of Antimony Trioxide: 99.5Mins; 15 parts of melamine cyanurates, 30 parts of zinc borates, 1 part of anti-aging agent RD, antioxidant 2246-S0.5 part; 1 part of accelerant CZ, accelerant C ED1 part, 1.5 parts in sulphur.Blending process is: at first with powdery chlorinated polyethylene rubber and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer; Triple Pressed Stearic Acid etc. carry out heat and mix preplasticizing in the high speed kneader; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor etc. again and in the low speed kneader, carry out cold mixing; Making the powdery blend) blend is through the twin screw extruder mixing granulator, and then be bonded together 1.5 millimeters of described vulcanized rubber combination material thickness through two extruders dynamic vulcanization and thermoplastic elastomer.
Described tectum and transition layer form the rubber cover of shelling not open, and thickness is 3 millimeters.
Embodiment 2
Product structure and production technique are with embodiment 1.
Described thermoplastic elastomer is a kind of powdery paracril and polyacrylic blend of comprising, the blend prescription is by weight: 50 parts of powdery paracrils, 50 parts of Vestolen PP 7052,5 parts of Vestolen PP 7052 maleic anhydride graft reactants (PP-g-MA); TDCPP15 part, 40 parts in fire retardant active hydrogen Natural manganese dioxide, 30 parts of ammonium polyphosphates; 10 parts in red phosphorus, 12 parts of carbon blacks, 1 part of antioxidant A; 1 part of antioxidant D, 4 parts in resol, 0.5 part of tin protochloride.Blending process is: at first with the Vestolen PP 7052 Vestolen PP 7052, in the high speed kneader, carry out heat with maleic anhydride graft reactant (PP-g-MA), flame-retardant plasticizer, fire retardant, carbon black, anti-aging agent, resol, tin protochloride etc. and mix preplasticizing; After being cooled to normal temperature; Add the powdery paracril again and in the low speed kneader, carry out cold mixing; Making the powdery blend) blend is through the twin screw extruder mixing granulator; And then be bonded together 2 millimeters of thickness through two extruders dynamic vulcanization and the whole belt core that soaks after the plasticizing.
Described vulcanized rubber combination material is that a kind of powdery paracril and chlorosulphonation of comprising gathered the blend of second rubber, and the blend prescription is by weight: 50 parts of powdery paracrils, 50 parts of chlorosulfonated polyethylene rubbers, 1 part of Triple Pressed Stearic Acid; 4 parts in zinc oxide, 4 parts in Natural manganese dioxide, 4 parts in plumbous oxide, 12 parts of graphitized carbon blacks; 8 parts of clorafins, TCP7 part, 50 parts of zinc borates, 10 parts of Antimony Trioxide: 99.5Mins; 10 parts in red phosphorus, 10 parts of melamine cyanurates, antioxidant 4010 Na1 part; 0.5 part of captax, 1 part of altax, 2.2 parts in sulphur.Blending process is: at first with powdery chlorosulfonated polyethylene rubber and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer; Triple Pressed Stearic Acid etc. carry out heat and mix preplasticizing in the high speed kneader; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor etc. again and in the low speed kneader, carry out cold mixing, make the powdery blend).Blend is through the twin screw extruder mixing granulator, and then is bonded together 2 millimeters of thickness through two extruders dynamic vulcanization and thermoplastic elastomer.
Described tectum and transition layer form the rubber cover of shelling not open, and thickness is 4 millimeters.
Embodiment 3
Product structure and production technique are with embodiment 1.
Described thermoplastic elastomer is a kind of blend that comprises powdery paracril and SE, and the blend prescription is by weight: 45 parts of powdery paracrils, 55 parts of SE, 5 parts of clorafins, 10 parts of CDP; 10 parts of Antimony Trioxide: 99.5Mins, 10 parts in red phosphorus, 20 parts of zinc borates, 10 parts of decabromodiphenyl oxides, 15 parts of carbon blacks; 5 parts in zinc oxide, 1 part of Triple Pressed Stearic Acid, 1 part in sulphur, 1 part of accelerant CZ; 0.5 part of TMTD, 1 part of lead sulfate tribasic, 1 part of dibasic lead phosphite, 1.5 parts of anti-aging agent RDs.Blending process is: at first with SE and flame-retardant plasticizer, fire retardant, carbon black, Triple Pressed Stearic Acid, stablizer; Triple Pressed Stearic Acid etc. carry out heat and mix preplasticizing in the high speed kneader; After being cooled to normal temperature; Add powdery paracril, sulphur, zinc oxide, promotor etc. again and in the low speed kneader, carry out cold mixing, make the powdery blend); Blend is through the twin screw extruder mixing granulator, and then is bonded together 2.5 millimeters of thickness through two extruders dynamic vulcanization and the whole belt core that soaks after the plasticizing.
Vulcanized rubber combination material of the present invention is a kind of blend that comprises powdery paracril and polyurethane termoplastic elastomer, and the blend prescription is by weight: 50 parts of powdery paracrils, 50 parts of polyurethane termoplastic elastomers, 1 part of Triple Pressed Stearic Acid; 2 parts in zinc oxide, 10 parts of graphitized carbon blacks, TDCPP15 part, 12 parts of Antimony Trioxide: 99.5Mins; 30 parts of ammonium polyphosphates, 20 parts in white lake, 10 parts of melamine cyanurates, 1 part of antioxidant 4010 Na; 1 part of captax, 1.5 parts of DM, 2 parts in sulphur.Blending process is: at first in banburying, make blend by above-mentioned prescription, blend is through the twin screw extruder mixing granulator, and then is bonded together 2.5 millimeters of thickness through two extruders dynamic vulcanization and thermoplastic elastomer.
Described tectum and transition layer form the rubber cover of shelling not open, and thickness is 5 millimeters.
4, embodiment detected result
According to the product that the foregoing description obtains, detected result is following:
Explain: described rubber cover is the integral body that is formed by tectum and transition layer, and tectum and transition layer are shelled not opened.Can be known by above-mentioned detected result: the product that obtains of the present invention has better properties.