CN107200948A - A kind of preparation method of antibacterial food PS packaging films - Google Patents
A kind of preparation method of antibacterial food PS packaging films Download PDFInfo
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- CN107200948A CN107200948A CN201710469333.2A CN201710469333A CN107200948A CN 107200948 A CN107200948 A CN 107200948A CN 201710469333 A CN201710469333 A CN 201710469333A CN 107200948 A CN107200948 A CN 107200948A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Wrappers (AREA)
Abstract
The invention discloses a kind of preparation method of antibacterial food PS packaging films, PS, Nano Silver, triallyl isocyanate are added in uniform bucket, stirring at low speed is well mixed；Then ethylene thiourea, EVA, ethyl acetate, ammonium hydrogen carbonate are put into, stirring at low speed is well mixed；Obtained mixture is extruded using double screw extruder, pelletizing is split after cooling, obtains pellet；It is added in 50 60 DEG C of homogenizers and mixes 10 minutes with remaining raw material again, 130 160 DEG C of fusion plastifications, 150 180 DEG C of mouth mold shapings, inflation, corona, windings is then sequentially passed through on film blowing device, you can.The present invention causes the present invention to prepare PS packaging films and have good antibacterial and mechanical property, good combination property, and preparation method simple by nano-material modified, with good application value.
Description
Technical field
The invention belongs to polymeric material field, it is related to a kind of preparation method of antibacterial food PS packaging films.
Technical background
Plastic flexible packaging material, is generally referred to by plastics（Or plastic composite）Composition, soft texture, Ke Yitong
Cross the material that the modes such as bag, parcel are packed to commodity.In Soft Roll charging using it is most be various plastic sheetings and its
Membranaceous composite, fabric based packaging material etc..The extensive use of flexible packing material is the enterprises and institutions' list for being engaged in flexible package industry
Position provides extremely wide activity space, is also achieved higher than other plastics while excellent service is provided for users
The good benefit of processing and forming industry.Developed rapidly, prospect is very bright.Because the kind of flexible packing material is numerous
Many, performance span is very big, from performance it is similar, close to entirely different product have industrialized production.Flexible packing material is
Membranoid substance, thickness is fairly small, normally only 0.04um or so, every square metre quality only 0.025kg or so, therefore uses flexible package
Material commodity can significantly economize on resources consuming compared with other packaging materials.Not only consumption of raw material is small for plastic flexible packaging material,
And there is the comprehensive advantages such as easy to process, energy charge is low, shaping efficiency is high, thus have the advantages that cheap.Due to
Flexible packing material have the advantages that it is numerous, wherein the particularly pertinent reasonable combination that can be by various materials designs and manufactures
Desired, more satisfactory specific packaging material, thus with splendid cost performance, show the powerful market competitiveness
The extensive concern of people and the favor of user have been obtained, have developed rapidly, its application covers food, medicine, light industry, weaving, day
With all spectra of the almost industrial and agricultural production such as small item, it has also become one of most important kind in plastic package material.
Different plastics can be not only used in flexible package plastics, using different formulations, pass through different process manufacturing property
Different various single thin films, but also can obtain hundreds of different by the various combination between multiple material
Kind, meets a variety of needs.The characteristics of using different flexible packing material different properties, can by the reasonable selection of kind
The demand of numerous commodity packagings can be met.Polystyrene film is to be easiest to one of film of stretching orientation, and PS films are because transparent
Degree is high, is often used as the window material on packing box.It is suitable to thermoforming, and various bowls, disk etc. can be made as packing timber
Material, original of the polystyrene film suitable for packing some fresh food such as fish, meat, vegetables etc. for having respiration storage process
Because being：The characteristics of polystyrene film is that transparency is high, and good stability of the dimension is nontoxic, still, harder, is a kind of gas permeability ratio
Preferable film, thus suitable for some fresh food such as fish, meat, the vegetables etc. for having respiration storage process of packaging.
But so also cause virus and mould to be easily attached to the surface of biodegradable plastic, therefore have the doubt of safety and health.For
This, we set about from the formula and technique of product, develop new high performance material, research and develop a kind of the new of antibacterial food PS packaging films
Technique is the task of top priority of whole industry.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of preparation side of antibacterial food PS packaging films
Method.
The purpose of the present invention is achieved through the following technical solutions：A kind of preparation method of antibacterial food PS packaging films,
Comprise the following steps：First weigh by weight 80-90 parts of PS, EVA10-15 parts, 3-5 parts of Nano Silver, triallyl isocyanate 3-
7 parts, 2-8 parts of lithium perchlorate, 5-10 parts of disproportionated rosin, 10-14 parts of poly butyric ester, 2-3 parts of ethylene thiourea, ethyl acetate
10-15 parts, 16-20 parts of ammonium hydrogen carbonate, 5-15 parts of propylgallate, 4-8 parts of sldium lauryl sulfate, 1-3 parts of Bronyl acetate,
1-4 parts of butyl titanate, 30-40 parts of glycerine；PS, Nano Silver, triallyl isocyanate are added in uniform bucket, 100-120
Rev/min stirring at low speed, is well mixed 8-10 minutes；Then ethylene thiourea, EVA, ethyl acetate, ammonium hydrogen carbonate, 100-120 are put into
Rev/min stirring at low speed, is well mixed 8-10 minutes；Obtained mixture is extruded using double screw extruder, pelletizing after cooling
Split, obtain pellet；It is added in 50-60 DEG C of homogenizer and mixes 10 minutes with remaining raw material again, is then set in blown film
It is standby above to sequentially pass through 130-160 DEG C of fusion plastification, 150-180 DEG C of mouth mold shaping, inflation, corona, winding, you can.
Weigh by weight 85 parts of PS, EVA10-15 parts, 4 parts of Nano Silver, 5 parts of triallyl isocyanate, lithium perchlorate 5
Part, 7 parts of disproportionated rosin, 12 parts of poly butyric ester, 3 parts of ethylene thiourea, 13 parts of ethyl acetate, 18 parts of ammonium hydrogen carbonate, nutgall
10 parts of propyl propionate, 6 parts of sldium lauryl sulfate, 2 parts of Bronyl acetate, 2 parts of butyl titanate, 35 parts of glycerine.
PS, Nano Silver, triallyl isocyanate are added in uniform bucket, 110 revs/min of stirring at low speed, are well mixed 9
Minute；Then input ethylene thiourea, EVA, ethyl acetate, ammonium hydrogen carbonate, 110 revs/min of stirring at low speed, are well mixed 9 minutes；Will
Obtained mixture is extruded using double screw extruder, and pelletizing is split after cooling, obtains pellet.
Pellet and remaining raw material are added in 55 DEG C of homogenizers and mixed 10 minutes.
150 DEG C of fusion plastifications, 160 DEG C of mouth mold shapings, inflation, corona, windings are sequentially passed through on film blowing device, you can.
The invention has the advantages that：The present invention is by nano-material modified so that preparation PS packaging films of the invention have
There are good antibacterial and mechanical property, good combination property, and preparation method simple, with good application value.
Embodiment
Embodiment 1
A kind of preparation method of antibacterial food PS packaging films, comprises the following steps：First weigh by weight 80 parts of PS, EVA10 parts,
3 parts of Nano Silver, 3 parts of triallyl isocyanate, 2 parts of lithium perchlorate, 5 parts of disproportionated rosin, 10 parts of poly butyric ester, ethene sulphur
2 parts of urea, 10 parts of ethyl acetate, 16 parts of ammonium hydrogen carbonate, 5 parts of propylgallate, 4 parts of sldium lauryl sulfate, Bronyl acetate 1
Part, 1 part of butyl titanate, 30 parts of glycerine；PS, Nano Silver, triallyl isocyanate are added in uniform bucket, it is 100 revs/min low
Speed stirring, is well mixed 8 minutes；Then input ethylene thiourea, EVA, ethyl acetate, ammonium hydrogen carbonate, 100 revs/min of stirring at low speed,
It is well mixed 8 minutes；Obtained mixture is extruded using double screw extruder, pelletizing is split after cooling, obtains pellet；Again with
Remaining raw material is added in 50 DEG C of homogenizers and mixed 10 minutes, and 130 DEG C of meltings are then sequentially passed through on film blowing device
Plasticizing, 150 DEG C of mouth mold shapings, inflation, corona, windings, you can.
Embodiment 2
A kind of preparation method of antibacterial food PS packaging films, comprises the following steps：First PS90 parts, EVA10-15 are weighed by weight
Part, 5 parts of Nano Silver, 7 parts of triallyl isocyanate, 8 parts of lithium perchlorate, 10 parts of disproportionated rosin, 14 parts of poly butyric ester, second
3 parts of alkene thiocarbamide, 15 parts of ethyl acetate, 20 parts of ammonium hydrogen carbonate, 5 parts of propylgallate, 8 parts of sldium lauryl sulfate, acetic acid borneol
3 parts of ester, 4 parts of butyl titanate, 40 parts of glycerine；PS, Nano Silver, triallyl isocyanate are added in uniform bucket, 120 turns/
Divide stirring at low speed, be well mixed 10 minutes；Then ethylene thiourea, EVA, ethyl acetate, ammonium hydrogen carbonate, 120 revs/min of low speed are put into
Stirring, is well mixed 10 minutes；Obtained mixture is extruded using double screw extruder, pelletizing is split after cooling, obtains grain
Material；It is added in 50-60 DEG C of homogenizer and mixes 10 minutes with remaining raw material again, is then sequentially passed through on film blowing device
130-160 DEG C of fusion plastification, 150-180 DEG C of mouth mold shaping, inflation, corona, winding, you can.
Embodiment 3
A kind of preparation method of antibacterial food PS packaging films, comprises the following steps：First 85 parts of PS, EVA10-15 are weighed by weight
Part, 4 parts of Nano Silver, 5 parts of triallyl isocyanate, 5 parts of lithium perchlorate, 7 parts of disproportionated rosin, 12 parts of poly butyric ester, second
3 parts of alkene thiocarbamide, 13 parts of ethyl acetate, 18 parts of ammonium hydrogen carbonate, 10 parts of propylgallate, 6 parts of sldium lauryl sulfate, acetic acid borneol
2 parts of ester, 2 parts of butyl titanate, 35 parts of glycerine；PS, Nano Silver, triallyl isocyanate are added in uniform bucket, 110 turns/
Divide stirring at low speed, be well mixed 9 minutes；Then ethylene thiourea, EVA, ethyl acetate, ammonium hydrogen carbonate, 110 revs/min of low speed are put into
Stirring, is well mixed 9 minutes；Obtained mixture is extruded using double screw extruder, pelletizing is split after cooling, obtains grain
Material；It is added in 55 DEG C of homogenizers and mixes 10 minutes with remaining raw material again, 150 is then sequentially passed through on film blowing device
DEG C fusion plastification, 160 DEG C of mouth mold shapings, inflation, corona, windings, you can.
Claims (5)
1. a kind of preparation method of antibacterial food PS packaging films, it is characterised in that the described method comprises the following steps：First by weight
Weigh 80-90 parts of PS, EVA10-15 parts, 3-5 parts of Nano Silver, 3-7 parts of triallyl isocyanate, 2-8 parts of lithium perchlorate, discrimination
Change 5-10 parts of rosin, 10-14 parts of poly butyric ester, 2-3 parts of ethylene thiourea, 10-15 parts of ethyl acetate, ammonium hydrogen carbonate 16-20
Part, 5-15 parts of propylgallate, 4-8 parts of sldium lauryl sulfate, 1-3 parts of Bronyl acetate, 1-4 parts of butyl titanate, glycerine 30-
40 parts；PS, Nano Silver, triallyl isocyanate are added in uniform bucket, 100-120 revs/min of stirring at low speed, are well mixed
8-10 minutes；Then input ethylene thiourea, EVA, ethyl acetate, ammonium hydrogen carbonate, 100-120 revs/min of stirring at low speed, are well mixed
8-10 minutes；Obtained mixture is extruded using double screw extruder, pelletizing is split after cooling, obtains pellet；Again with residue
Raw material be added in 50-60 DEG C of homogenizer mix 10 minutes, then sequentially passed through on film blowing device 130-160 DEG C melt
Melt plasticizing, 150-180 DEG C of mouth mold shaping, inflation, corona, winding, you can.
2. a kind of preparation method of antibacterial food PS packaging films according to claim 1, it is characterised in that：Weigh by weight
85 parts of PS, EVA10-15 parts, 4 parts of Nano Silver, 5 parts of triallyl isocyanate, 5 parts of lithium perchlorate, 7 parts of disproportionated rosin, poly- hydroxyl
12 parts of base butyrate, 3 parts of ethylene thiourea, 13 parts of ethyl acetate, 18 parts of ammonium hydrogen carbonate, 10 parts of propylgallate, laruyl alcohol sulphur
Sour 6 parts of sodium, 2 parts of Bronyl acetate, 2 parts of butyl titanate, 35 parts of glycerine.
3. a kind of preparation method of antibacterial food PS packaging films according to claim 1, it is characterised in that：By PS, nanometer
Silver, triallyl isocyanate are added in uniform bucket, 110 revs/min of stirring at low speed, are well mixed 9 minutes；Then ethene is put into
Thiocarbamide, EVA, ethyl acetate, ammonium hydrogen carbonate, 110 revs/min of stirring at low speed are well mixed 9 minutes；Obtained mixture is utilized
Double screw extruder is extruded, and pelletizing is split after cooling, obtains pellet.
4. a kind of preparation method of antibacterial food PS packaging films according to claim 1, it is characterised in that：By pellet with remaining
Remaining raw material is added in 55 DEG C of homogenizers and mixed 10 minutes.
5. a kind of preparation method of antibacterial food PS packaging films according to claim 1, it is characterised in that：In film blowing device
On sequentially pass through 150 DEG C of fusion plastifications, 160 DEG C of mouth mold shapings, inflation, corona, windings, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710469333.2A CN107200948A (en) | 2017-06-20 | 2017-06-20 | A kind of preparation method of antibacterial food PS packaging films |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710469333.2A CN107200948A (en) | 2017-06-20 | 2017-06-20 | A kind of preparation method of antibacterial food PS packaging films |
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| Publication Number | Publication Date |
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| CN107200948A true CN107200948A (en) | 2017-09-26 |
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| CN201710469333.2A Pending CN107200948A (en) | 2017-06-20 | 2017-06-20 | A kind of preparation method of antibacterial food PS packaging films |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2711023A1 (en) * | 2017-10-27 | 2019-04-29 | Viscofan Sa | Active polystyrene film (Machine-translation by Google Translate, not legally binding) |
| CN113788772A (en) * | 2021-10-15 | 2021-12-14 | 江苏海洋大学 | Gallic acid derivative containing thiosemicarbazide, and synthesis method and application thereof |
| RU2810791C2 (en) * | 2017-10-27 | 2023-12-28 | Вискофан, С.А. | Active polystyrene film |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153562A (en) * | 2015-08-17 | 2015-12-16 | 安徽省灵普塑胶材料有限公司 | Thermally formed antibacterial and mouldproof preservation box and container |
| CN106117905A (en) * | 2016-07-29 | 2016-11-16 | 王莹 | A kind of heat-resistant polyvinyl chloride film formulation |
-
2017
- 2017-06-20 CN CN201710469333.2A patent/CN107200948A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153562A (en) * | 2015-08-17 | 2015-12-16 | 安徽省灵普塑胶材料有限公司 | Thermally formed antibacterial and mouldproof preservation box and container |
| CN106117905A (en) * | 2016-07-29 | 2016-11-16 | 王莹 | A kind of heat-resistant polyvinyl chloride film formulation |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2711023A1 (en) * | 2017-10-27 | 2019-04-29 | Viscofan Sa | Active polystyrene film (Machine-translation by Google Translate, not legally binding) |
| WO2019086734A1 (en) * | 2017-10-27 | 2019-05-09 | Viscofan, S.A. | Active polystyrene film |
| AU2018359723B2 (en) * | 2017-10-27 | 2022-10-13 | Viscofan, S.A. | Active polystyrene film |
| US11590743B2 (en) | 2017-10-27 | 2023-02-28 | Viscofan, S.A. | Active polystyrene film |
| RU2810791C2 (en) * | 2017-10-27 | 2023-12-28 | Вискофан, С.А. | Active polystyrene film |
| CN113788772A (en) * | 2021-10-15 | 2021-12-14 | 江苏海洋大学 | Gallic acid derivative containing thiosemicarbazide, and synthesis method and application thereof |
| CN113788772B (en) * | 2021-10-15 | 2023-04-11 | 江苏海洋大学 | Gallic acid derivative containing thiosemicarbazide, and synthesis method and application thereof |
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Application publication date: 20170926 |