CN106398133A - Antistatic PET heat shrinkable film and preparation method thereof - Google Patents
Antistatic PET heat shrinkable film and preparation method thereof Download PDFInfo
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- CN106398133A CN106398133A CN201610716537.7A CN201610716537A CN106398133A CN 106398133 A CN106398133 A CN 106398133A CN 201610716537 A CN201610716537 A CN 201610716537A CN 106398133 A CN106398133 A CN 106398133A
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- parts
- heat shrink
- shrink films
- pet
- antistatic
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- 238000002360 preparation method Methods 0.000 title claims description 10
- 229920006257 Heat-shrinkable film Polymers 0.000 title abstract description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 24
- 239000000314 lubricant Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 21
- 230000000996 additive effect Effects 0.000 claims abstract description 21
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 21
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 20
- 229920006300 shrink film Polymers 0.000 claims description 54
- 229920000728 polyester Polymers 0.000 claims description 53
- 239000012752 auxiliary agent Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000005259 measurement Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- -1 phthalic acid ester Chemical class 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical group C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical group [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 230000008602 contraction Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
- C08J2471/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
The invention provides an antistatic PET heat shrinkable film, the heat shrinkable film comprises the following raw materials by weight: 80-110 parts of PET resin, 1-5 parts of an additive, 2-5 parts of a lubricant, 1-4 parts of a plasticizer, 2.5-6 parts of an antioxidant and 5-15 parts of an antistatic agent. The PET heat shrinkable film has strong impact resistance, good toughness and excellent antistatic performances.
Description
Technical field
The present invention relates to a kind of heat shrink films are and in particular to a kind of antistatic PET heat shrink films and preparation method thereof.
Background technology
Heat shrink films are used for sale and the transport of various products, and its Main Function is to consolidate, cover and protect product.Shrink
Film must have higher paracentesis resistance, good shrinkage and certain shrinkage stress.In contraction process, film can not produce
Raw hole.In heat shrink films, the relatively broad PVC heat shrink films intensity of purposes is high, and elastic pulling force is big, to any geometry
Commodity can wrap, and can avoid tying up the damage that commodity are caused, there is good loosening, rain-proof, dust-proof, antitheft etc.
Effect；PVC shrink film is widely used in wine product, food, sporting goods, sterilizing dinnerware, electronic apparatus, commodity, handicraft, guarantor
Build the packaging of all kinds of commodity of product, audio-visual product, medicine, stationery, toy, door, plastic cement five metals, glass ceramics etc. so as to outer
Shape is more distinct attractive in appearance, improves product packaging class, product is risen dust-proof, the protective effect such as recklessly spend.It is ideal at present
Film packing material.But the inadequate environmental protection of existing PVC heat shrink films, present more widely for PET heat shrink films,
PET heat-shrinkable film is a kind of new heat shrink wrap material, is easily recycled because it has, nontoxic, tasteless, mechanical performance
Well, the features such as particularly meet environmental protection, become replacement polyvinyl chloride (PVC) thermal contraction in developed country's polyester (PET)
The ideal substitute of film.But the antistatic property of PET heat shrink films in the market is not good enough.
Content of the invention
For solving above-mentioned problem, it is an object of the invention to provide a kind of antistatic PET heat shrink films, described
PET heat shrink films impact resistance is strong, good toughness and have excellent antistatic property.
For reaching above-mentioned purpose, the technical scheme is that：
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：80 ~ 110 parts of PET resin,
1 ~ 5 part of auxiliary agent, 2 ~ 5 parts of lubricant, 1 ~ 4 part of plasticizer, 2.5 ~ 6 parts of antioxidant, 5 ~ 15 parts of antistatic additive.
Preferably, described heat shrink films include the raw material of following weight proportion：90 ~ 100 parts of PET resin, auxiliary agent 2.5 ~ 3.5
Part, 3 ~ 4 parts of lubricant, 2 ~ 3 parts of plasticizer, 4 ~ 4.5 parts of antioxidant, 8 ~ 12 parts of antistatic additive.
Preferably, described heat shrink films include the raw material of following weight proportion：95 parts of PET resin, 3 parts of auxiliary agent, lubricant
3.5 parts, 2.5 parts of plasticizer, 4.2 parts of antioxidant, 10 parts of antistatic additive.
Further, described auxiliary agent is HANKINS NCP-2.
Separately, described lubricant is zinc stearate or butyl stearate.
Separately have, described plasticizer is phthalic acid ester, fatty group dibasic acid, citrate, epoxy-ester, aliphatic acid
The composition of one or more of ester, polyester plasticizer.
Again, described antioxidant is diphenylamines.
Further, described antistatic additive is AEO.
Another object of the present invention is to providing a kind of preparation method of PET heat shrink films as described above, its raw material is easy to get,
With low cost and preparation process is simple, step is as follows：
（1）Weigh the raw material of above-mentioned weight portion；
（2）70 ~ 80 DEG C toward reactor in add PET resin, auxiliary agent, lubricant, plasticizer, antioxidant, antistatic additive and with
150 ~ 250rpm rotating speed stirs 30 ~ 40min；
（3）Reactor temperature is increased to 280 ~ 300 DEG C, pressure drops to below 90Pa, reaction 2.5 ~ 3h obtains with this understanding
To polymer melt, then by the polymer melt extrusion of preparation, pelletizing, drying, obtain PET polyester slice；
（4）Above-mentioned PET polyester slice is melt extruded, die head slab, slab spooling, biaxial tension, cooling and shaping, measurement thick
Degree, winding, cutting and rewinding, packaging, finished product.
The beneficial effects of the present invention is：
Compared with prior art, PET heat shrink films provided by the present invention have the advantage that：（1）The PET thermal contraction of the present invention
Film, the transparency is good, shrink uniform and environmental protection；（2）The PET heat shrink films of the present invention, add AEO resist quiet
Electric agent, thus have excellent antistatic property.
Specific embodiment
Technical scheme in the embodiment of the present invention will be carried out with clear, complete description below it is clear that described enforcement
Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
The every other embodiment that technical staff is obtained on the premise of not making creative work, broadly falls into present invention protection
Scope.
The raw material weight proportioning of soup processed of the PET heat shrink films of the present invention sees below specific embodiment.
Embodiment 1
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：80 parts of PET resin, auxiliary agent
1 part, 2 parts of lubricant, 1 part of plasticizer, 2.5 parts of antioxidant, 5 parts of antistatic additive.
Embodiment 2
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：85 parts of PET resin, auxiliary agent
1.5 parts, 2.5 parts of lubricant, 1.5 parts of plasticizer, 2.8 parts of antioxidant, 6 parts of antistatic additive.
Embodiment 3
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：88 parts of PET resin, auxiliary agent
2 parts, 2.8 parts of lubricant, 1.8 parts of plasticizer, 3 parts of antioxidant, 7 parts of antistatic additive.
Embodiment 4
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：90 parts of PET resin, auxiliary agent
2.5 parts, 3 parts of lubricant, 2 parts of plasticizer, 4 parts of antioxidant, 18 parts of antistatic additive, 8 parts of ultra-violet absorber.
Embodiment 5
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：95 parts of PET resin, auxiliary agent
3 parts, 3.5 parts of lubricant, 2.5 parts of plasticizer, 4.2 parts of antioxidant, 10 parts of antistatic additive.
Embodiment 6
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：98 parts of PET resin, auxiliary agent
3.3 parts, 3.8 parts of lubricant, 2.8 parts of plasticizer, 4.4 parts of antioxidant, 11 parts of antistatic additive.
Embodiment 7
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：100 parts of PET resin, helps
3.5 parts of agent, 4 parts of lubricant, 3 parts of plasticizer, 4.5 parts of antioxidant, 12 parts of antistatic additive.
Embodiment 8
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：105 parts of PET resin, helps
4 parts of agent, 4.5 parts of lubricant, 3.5 parts of plasticizer, 5 parts of antioxidant, 13 parts of antistatic additive.
Embodiment 9
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：108 parts of PET resin, helps
4.5 parts of agent, 4.8 parts of lubricant, 3.8 parts of plasticizer, 5.5 parts of antioxidant, 13.5 parts of antistatic additive.
Embodiment 10
A kind of antistatic PET heat shrink films, described heat shrink films include the raw material of following weight proportion：110 parts of PET resin, helps
55 parts of agent, 5 parts of lubricant, 4 parts of plasticizer, 6 parts of antioxidant, 15 parts of antistatic additive.
The preparation method of PET heat shrink films of the present invention is：
（1）Weigh the raw material of above-mentioned weight portion；
（2）70 ~ 80 DEG C toward reactor in add PET resin, auxiliary agent, lubricant, plasticizer, antioxidant, antistatic additive and with
150 ~ 250rpm rotating speed stirs 30 ~ 40min；
（3）Reactor temperature is increased to 280 ~ 300 DEG C, pressure drops to below 90Pa, reaction 2.5 ~ 3h obtains with this understanding
To polymer melt, then by the polymer melt extrusion of preparation, pelletizing, drying, obtain PET polyester slice；
（4）Above-mentioned PET polyester slice is melt extruded, die head slab, slab spooling, biaxial tension, cooling and shaping, measurement thick
Degree, winding, cutting and rewinding, packaging, finished product.
It should be noted that above example is only in order to illustrate technical scheme and unrestricted.Although with reference to relatively
Good embodiment has been described in detail to the present invention, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent, and without deviating from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (9)
1. a kind of antistatic PET heat shrink films are it is characterised in that described heat shrink films include the raw material of following weight proportion：PET
80 ~ 110 parts of resin, 1 ~ 5 part of auxiliary agent, 2 ~ 5 parts of lubricant, 1 ~ 4 part of plasticizer, 2.5 ~ 6 parts of antioxidant, 5 ~ 15 parts of antistatic additive.
2. a kind of antistatic PET heat shrink films according to claim 1 it is characterised in that described heat shrink films include with
The raw material of lower weight proportion：90 ~ 100 parts of PET resin, 2.5 ~ 3.5 parts of auxiliary agent, 3 ~ 4 parts of lubricant, 2 ~ 3 parts of plasticizer, antioxidant
4 ~ 4.5 parts, 8 ~ 12 parts of antistatic additive.
3. a kind of antistatic PET heat shrink films according to claim 1 it is characterised in that described heat shrink films include with
The raw material of lower weight proportion：95 parts of PET resin, 3 parts of auxiliary agent, 3.5 parts of lubricant, 2.5 parts of plasticizer, 4.2 parts of antioxidant, resist quiet
10 parts of electric agent.
4. a kind of antistatic PET heat shrink films according to claim 1 or 2 or 3 are it is characterised in that described auxiliary agent is
HANKINS NCP-2.
5. a kind of antistatic PET heat shrink films according to claim 1 or 2 or 3 are it is characterised in that described lubricant is
Zinc stearate or butyl stearate.
6. a kind of antistatic PET heat shrink films according to claim 1 or 2 or 3 are it is characterised in that described plasticizer is
One or more of phthalic acid ester, fatty group dibasic acid, citrate, epoxy-ester, fatty acid ester, polyester plasticizer
Composition.
7. a kind of antistatic PET heat shrink films according to claim 1 or 2 or 3 are it is characterised in that described antioxidant is
Diphenylamines.
8. a kind of antistatic PET heat shrink films according to claim 1 or 2 or 3 are it is characterised in that described antistatic additive
For AEO.
9. the preparation method of the antistatic PET heat shrink films described in claim 1 is it is characterised in that comprise the following steps：
Weigh the raw material of above-mentioned weight portion；
70 ~ 80 DEG C toward reactor in add PET resin, auxiliary agent, lubricant, plasticizer, antioxidant, antistatic additive with 150 ~
250rpm rotating speed stirs 30 ~ 40min;
Reactor temperature is increased to 280 ~ 300 DEG C, pressure drops to below 90Pa, reaction 2.5 ~ 3h is gathered with this understanding
Close melt, then by the polymer melt extrusion of preparation, pelletizing, drying, obtain PET polyester slice；
Above-mentioned PET polyester slice is melt extruded, die head slab, slab spooling, biaxial tension, cooling and shaping, measurement thickness, receipts
Volume, cutting and rewinding, packaging, finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716537.7A CN106398133A (en) | 2016-08-25 | 2016-08-25 | Antistatic PET heat shrinkable film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610716537.7A CN106398133A (en) | 2016-08-25 | 2016-08-25 | Antistatic PET heat shrinkable film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106398133A true CN106398133A (en) | 2017-02-15 |
Family
ID=58004324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610716537.7A Pending CN106398133A (en) | 2016-08-25 | 2016-08-25 | Antistatic PET heat shrinkable film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106398133A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832823A (en) * | 2017-03-20 | 2017-06-13 | 江苏裕兴薄膜科技股份有限公司 | A kind of high temperature resistant PET polyester films and preparation method thereof |
| CN108641310A (en) * | 2018-05-04 | 2018-10-12 | 宁国市千洪电子有限公司 | A kind of fire-retardant heat shrink films and manufacturing method |
| CN110525002A (en) * | 2019-09-20 | 2019-12-03 | 杭州和顺科技股份有限公司 | Composite antibacterial antistatic anti-slip packaging film and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040191493A1 (en) * | 2001-08-01 | 2004-09-30 | Satoshi Hayakawa | Heat shrinking polyester film roll |
| CN101265405A (en) * | 2008-05-07 | 2008-09-17 | 常熟市飞腾化纤有限公司 | Antistatic film material and its preparation method |
| CN103483784A (en) * | 2013-09-29 | 2014-01-01 | 太仓市鸿运包装材料有限公司 | Flame-retardant PET (polyethylene glycol terephthalate) heat shrink film and preparation method thereof |
| CN103483785A (en) * | 2013-09-29 | 2014-01-01 | 太仓市鸿运包装材料有限公司 | PETG (polyethylene terephthalate glycol) heat shrinking film and preparation method thereof |
-
2016
- 2016-08-25 CN CN201610716537.7A patent/CN106398133A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040191493A1 (en) * | 2001-08-01 | 2004-09-30 | Satoshi Hayakawa | Heat shrinking polyester film roll |
| CN101265405A (en) * | 2008-05-07 | 2008-09-17 | 常熟市飞腾化纤有限公司 | Antistatic film material and its preparation method |
| CN103483784A (en) * | 2013-09-29 | 2014-01-01 | 太仓市鸿运包装材料有限公司 | Flame-retardant PET (polyethylene glycol terephthalate) heat shrink film and preparation method thereof |
| CN103483785A (en) * | 2013-09-29 | 2014-01-01 | 太仓市鸿运包装材料有限公司 | PETG (polyethylene terephthalate glycol) heat shrinking film and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832823A (en) * | 2017-03-20 | 2017-06-13 | 江苏裕兴薄膜科技股份有限公司 | A kind of high temperature resistant PET polyester films and preparation method thereof |
| CN106832823B (en) * | 2017-03-20 | 2018-11-30 | 江苏裕兴薄膜科技股份有限公司 | A kind of high temperature resistant PET polyester film and preparation method thereof |
| CN108641310A (en) * | 2018-05-04 | 2018-10-12 | 宁国市千洪电子有限公司 | A kind of fire-retardant heat shrink films and manufacturing method |
| CN110525002A (en) * | 2019-09-20 | 2019-12-03 | 杭州和顺科技股份有限公司 | Composite antibacterial antistatic anti-slip packaging film and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20170215 |