CN107198956A - A kind of refrigerator purifying ball - Google Patents

A kind of refrigerator purifying ball Download PDF

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Publication number
CN107198956A
CN107198956A CN201710264817.3A CN201710264817A CN107198956A CN 107198956 A CN107198956 A CN 107198956A CN 201710264817 A CN201710264817 A CN 201710264817A CN 107198956 A CN107198956 A CN 107198956A
Authority
CN
China
Prior art keywords
refrigerator
purifying ball
weight
parts
purifying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710264817.3A
Other languages
Chinese (zh)
Inventor
刘佳铭
叶飞
朱皓
朱文明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUJIAN HEAL-POWER NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
Original Assignee
FUJIAN HEAL-POWER NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FUJIAN HEAL-POWER NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd filed Critical FUJIAN HEAL-POWER NEW MATERIAL SCIENCE & TECHNOLOGY Co Ltd
Priority to CN201710264817.3A priority Critical patent/CN107198956A/en
Publication of CN107198956A publication Critical patent/CN107198956A/en
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8634—Ammonia
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8612—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20—Method-related aspects
    • A61L2209/22—Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/06—Polluted air

Abstract

The invention discloses a kind of refrigerator purifying ball, the purifying ball is mainly composed of the following components：The parts by weight of diatomite 50~60, the parts by weight of medical stone powder 14~20 of 280~340 mesh, the particle diameter ＜ 20nm parts by weight of white carbon 8~15, the parts by weight of kaolin 6~12 of 3000~5000 mesh, granularity is the 30~50nm parts by weight of tourmaline powder 1~3, the parts by weight of methyl cellulose ether 4~8 of 80~120 mesh, granularity is the 5~10nm parts by weight of Nano silver solution 0.1~1；Granulated by dispensing, water drenching disc granulation, vibrosieve, secondary spray Nano Silver, vibrosieve obtains 4~10mm of particle diameter purifying ball.This product can be directly used in the purification of the air in closed space pollution sources such as refrigerator, it is able to continuously and discharges the negative oxygen ion beneficial to human body, the irritative gas such as ammonia, hydrogen sulfide, acetic acid, trimethylamine in the oxidation of strong adsorption catalysis negative oxygen ion, degraded refrigerator, effectively drive away air pollution source, play air purification effect.The wide market of refrigerator purifying ball.

Description

A kind of refrigerator purifying ball
Technical field
The present invention relates to the air purification field of closing space, more particularly, to the net of elimination refrigerator inside air pollution Change ball.
Background technology
It is that its low temperature and freezing environment enable the breeding of bacterium and leaching evil effect to press down that refrigerator, which intends food preservation, The external embodiment made and delayed, but bacterium do not killed completely, still with certain activity.When food is put long, bacterium is to food The slow decomposition of thing just generates the catabolites such as ammonia, hydrogen sulfide, mercaptan and methylamine, and this is to be characterized in refrigerator with stink Gas with foreign flavor.Gas with foreign flavor in refrigerator not only causes the discomfort on people's sense organ, but also is degrading the original flavor of food, very Room air can be polluted to when opening refrigerator.Therefore, refrigerator inside air pollution is removed to safeguarding health and food It is fresh-keeping significant.
The removal of peculiar smell is typically to be fixed on inside freezer component or put people's ice by deodorizing device and eliminating smell agent etc. in refrigerator Inside case.Most of existing commercially available refrigerator deodorizer is self-faced porous mass (such as medical stone, natural zeolite) or inorganic conjunction Into porous surface material (such as molecular sieve), these eliminating smell agents or more complicated by resource constraint or building-up process, price all compares Height, peat refrigerator deodorizer is respectively 27.8% to the adsorption capacity of ammonia, triethylamine, hydrogen sulfide and formaldehyde, 18.8%, 7.8% and 13.0%, but absorption gas easily reach supersaturation and be desorbed cause secondary pollution；Use Cl2And NH3Modified activated carbon Fiber (ACF) surface polarity, to H2S dynamic adsorption capacity reaches 47% and 64%, in addition to desorption causes secondary pollution, still Deposit modified cumbersome problem；Nano-TiO2Photocatalysis technology is to trimethylamine, ethyl mercaptan, peculiar smell and Escherichia coli and golden yellow Portugal Grape coccus, the clearance of ammonia are respectively 99.25%, 98.71%, 94%, 82%, 61%, and it is that LED uviol lamp wavelength falls to regret At 365nm, using not extensive.Therefore, explore that resource is wide, processing is simple, low cost, remove power it is strong, efficiently, quick, continuation, Green clean type, the refrigerator deodorizer of non-secondary pollution are paid close attention to by domestic and international producer deeply.
The content of the invention
It is an object of the invention to provide one kind it is pollution-free, can produce negative oxygen ion, drive away refrigerator inside air pollution The purifying ball of thing.
To reach above-mentioned purpose, a kind of refrigerator purifying ball of the invention, its raw material is made up of the component of following parts by weight：
The refrigerator purifying ball is prepared by the following method：
It is by the weight than dispensing, the diatomite, medical stone powder, white carbon, kaolin, tourmaline powder and methyl is fine It is placed in after the plain ether of dimension is well mixed in granulating disc, shower water simultaneously transfers to roll into ball with disk rotary, is obtained through vibrosieve To the purifying ball base substrate that particle diameter is 4~10mm, the purifying ball base substrate is again placed in granulating disc, sprays the Nano Silver Solution simultaneously transfers to roll to smooth in appearance with disk rotary, then obtains the purifying ball that particle diameter is 4~10mm through vibrosieve, inspection.
Optionally, in the kaolin, the mass percentage content of silica is 55~65%.
Optionally, the diatomaceous granularity is that 100 mesh, the granularity of medical stone powder are that 320 mesh, kaolinic granularity are 4000 mesh, the granularity of methyl cellulose ether are 100 mesh.
Optionally, the raw material of the refrigerator purifying ball is made up of the component of following parts by weight：
Optionally, the raw material of the refrigerator purifying ball is made up of by mass percentage following component：
Optionally, the raw material of the refrigerator purifying ball is made up of by mass percentage following component：Diatomite 54.0%, wheat Meal stone flour 17.7%, white carbon 10.8%, kaolin 9.1%, tourmaline powder 1.6%, methyl cellulose ether 6.4%, Nano Silver Solution 0.40%.
Refrigerator purifying ball of the present invention has the characteristics that：
1. it is white spherical particle, tasteless, nontoxic, harmless；
2. content of volatile organic compound (VOC), free formaldehyde content, benzene, toluene, the total amount of ethylbenzene and dimethylbenzene, And dissoluble lead (Pb), cadmium (Cd), chromium (Cr), mercury (Hg) are not detected；
3. inside and outside Irradiation index (Ira, Ir)≤1.0；
The negative oxygen ion beneficial to human body is discharged 4. being able to continuously；A kind of permanent electric polarity material of tourmaline system in purifying ball Material, it can produce micro cell by water electrolysis with water Contact, so as to generate H+With OH—, wherein, H+By e–Neutralize and produce H2, OH- With H2O effects produce the sub- OH of negative oxygen ion-(H2O)nAs long as there is H2O is present, that is, is able to continuously and discharges the negative oxygen beneficial to human body Ion；
5. irritative gas such as ammonia, hydrogen sulfide, acetic acid, trimethylamines that can be in strong adsorption refrigerator, and be catalyzed negative oxygen from Son oxidation, degradation reaction, effectively drive away air pollution source；
6. the white carbon of purifying ball, diatomite etc. are in addition to the microcellular structure of itself assigns strong adsorptivity, can also pass through- The interaction of the active group connected on Si-O-Si- keys and constitute network structure, virus that can be in strong adsorption refrigerator, The biological suspension such as bacterium pollutant and settle down, play air purification effect.
This product can be directly used in the purification of refrigerator air in closed space pollution sources.
The present invention is described in further detail following examples.
Embodiment
Embodiment 1
A kind of HQX-01 types refrigerator purifying ball, by weight percentage purifying ball is composed of the following components：
Its preparation process is：
Using granulating disc, 1-6 components are sufficiently mixed uniformly first in purifying ball, then spray the aqueous solution, now with The rotation of disk, water-soluble methyl cellulose ether is mutually bonded with other components, and then rolls into ball, through vibrosieve, is obtained To 4~10mm outward appearances more coarse purifying ball；Coarse purifying ball enters disk spray Nano silver solution for the second time to be continued to roll Dynamic granulation, essence is rolled into the ball of smooth in appearance, through vibrosieve, examines, you can production 4~10mm purifying balls.Ball less than 4mm Grain plus powder enter back into disk plus powder granulation；Spherolite more than 10mm enters back into disk and repeats ball processed after dried, crushed.
Embodiment 2
A kind of HQX-02 types refrigerator purifying ball, it is composed of the following components by weight percentage：
Its preparation process is：
Reference implementation example 1,1-6 components automatic gauge → cooperation → well mixed → first time disk shower water is granulated → is shaken Dynamic screening → second disk spray Nano silver solution granulation → drying → vibrosieve (4~10mm) → inspection → automatic packaging → storage of putting in storage.
Embodiment 3
A kind of HQX-02 types refrigerator purifying ball, it is composed of the following components by weight percentage：
Its preparation process is：
Reference implementation example 1,1-6 components automatic gauge → cooperation → well mixed → first time disk shower water is granulated → is shaken Dynamic screening → second disk spray Nano silver solution granulation → drying → vibrosieve (4~10mm) → inspection → automatic packaging → storage of putting in storage.
The quality index of the refrigerator purifying ball of above-described embodiment manufacture is as follows：
The organoleptic indicator of table 1
Project Index
Color and luster White
Outward appearance Spherical particle
The limits of harmful substances index of table 2
Project Index
Content of volatile organic compound (VOC), g/ ㎏ ≤1
Benzene, toluene, the total amount (㎎/㎏ of ethylbenzene and dimethylbenzene) ≤50
Free formaldehyde , ㎎/kg ≤5
Dissoluble lead, mg/kg ≤30
Soluble cadmium, mg/kg ≤10
Soluble chromium, mg/kg ≤10
Soluble mercury, mg/kg ≤10
The radionuclide limit index of table 3
Project Index (A classes)
External Exposure Index (IRa) ≤1.0
Outreach services (Ir) ≤1.3
The functional parameter of table 4
Project Purifying rate index, % (4h)
Ammonia ≥80
Hydrogen sulfide ≥20
Acetic acid ≥20
Trimethylamine ≥40
The negative aeroion amount of inducing, individual/scm2 ≥1000
Above-described embodiment is only used for further illustrating a kind of refrigerator purifying ball of the present invention, but the invention is not limited in reality Apply example, any simple modification, equivalent variations and modification that every technical spirit according to the present invention is made to above example, Fall into the protection domain of technical solution of the present invention.

Claims (6)

1. a kind of refrigerator purifying ball, it is characterised in that：The raw material of the refrigerator purifying ball is made up of the component of following parts by weight：
The refrigerator purifying ball is prepared by the following method：
By the weight than dispensing, by the diatomite, medical stone powder, white carbon, kaolin, tourmaline powder and methylcellulose It is placed in after ether is well mixed in granulating disc, shower water simultaneously transfers to roll into ball with disk rotary, and grain is obtained through vibrosieve Footpath is 4~10mm purifying ball base substrate, and the purifying ball base substrate is again placed in granulating disc, sprays the Nano silver solution And transfer to roll to smooth in appearance with disk rotary, then obtain the purifying ball that particle diameter is 4~10mm through vibrosieve, inspection.
2. refrigerator purifying ball according to claim 1, it is characterised in that：In the kaolin, the quality hundred of silica It is 55~65% to divide than content.
3. refrigerator purifying ball according to claim 1, it is characterised in that：The diatomaceous granularity is 100 mesh, medical stone The granularity of powder is that 320 mesh, kaolinic granularity are that 4000 mesh, the granularity of methyl cellulose ether are 100 mesh.
4. refrigerator purifying ball according to claim 1, it is characterised in that：The raw material of the refrigerator purifying ball is by following weight The component composition of part：
5. refrigerator purifying ball according to claim 4, it is characterised in that：The raw material of the refrigerator purifying ball is by following component Constitute by mass percentage：
6. refrigerator purifying ball according to claim 5, it is characterised in that：The raw material of the refrigerator purifying ball is by following component Constitute by mass percentage：Diatomite 54.0%, medical stone powder 17.7%, white carbon 10.8%, kaolin 9.1%, tourmaline Powder 1.6%, methyl cellulose ether 6.4%, Nano silver solution 0.40%.
CN201710264817.3A 2017-04-21 2017-04-21 A kind of refrigerator purifying ball Withdrawn CN107198956A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710264817.3A CN107198956A (en) 2017-04-21 2017-04-21 A kind of refrigerator purifying ball

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710264817.3A CN107198956A (en) 2017-04-21 2017-04-21 A kind of refrigerator purifying ball

Publications (1)

Publication Number Publication Date
CN107198956A true CN107198956A (en) 2017-09-26

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CN201710264817.3A Withdrawn CN107198956A (en) 2017-04-21 2017-04-21 A kind of refrigerator purifying ball

Country Status (1)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105148838A (en) * 2015-07-31 2015-12-16 安徽喜尔奇日用品有限公司 Defrosting, deodorizing, bacteria-resisting, and fresh-keeping material and preparation technology thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105148838A (en) * 2015-07-31 2015-12-16 安徽喜尔奇日用品有限公司 Defrosting, deodorizing, bacteria-resisting, and fresh-keeping material and preparation technology thereof

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Application publication date: 20170926

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