CN107195923A - A kind of high-efficiency fuel cell flow-guide double-pole plate - Google Patents

A kind of high-efficiency fuel cell flow-guide double-pole plate Download PDF

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Publication number
CN107195923A
CN107195923A CN201710365568.7A CN201710365568A CN107195923A CN 107195923 A CN107195923 A CN 107195923A CN 201710365568 A CN201710365568 A CN 201710365568A CN 107195923 A CN107195923 A CN 107195923A
Authority
CN
China
Prior art keywords
graphite
fuel cell
colloid
pole plate
cell flow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710365568.7A
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Chinese (zh)
Inventor
张孟彤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Hongfeng Industry Co Ltd
Original Assignee
Shanghai Hongfeng Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Hongfeng Industry Co Ltd filed Critical Shanghai Hongfeng Industry Co Ltd
Priority to CN201710365568.7A priority Critical patent/CN107195923A/en
Publication of CN107195923A publication Critical patent/CN107195923A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605Porous electrodes
    • H01M4/8626Porous electrodes characterised by the form
    • H01M4/8631Bipolar electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074Heat exchange unit structures specially adapted for fuel cell
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Fuel Cell (AREA)

Abstract

High-efficiency fuel cell flow-guide double-pole plate disclosed by the invention, combined by airflow guiding plate with hydrogen flow guiding plate, bonded and formed by adhesive between the two, it is characterized in that, the adhesive is made up of colloid with graphite, mass percent between the colloid and graphite is 7~14wt%: 86~93%, and the graphite is spectroscopically pure graphite powder or powder graphite.The advantage that bond effect of the present invention is good, bipolar plates conduct electricity very well.

Description

A kind of high-efficiency fuel cell flow-guide double-pole plate
Technical field
The present invention relates to field of fuel cell technology, more particularly to a kind of high-efficiency fuel cell flow-guide double-pole plate
Background technology
Fuel battery flow guiding bipolar plates are typically combined by two blocks of plates.This two pieces of plate functions be respectively lead air groove face, Lead to constitute between two blocks of plates after hydrogen groove face, and combination and lead cooling fluid.For example:The chuck tabula rasa face of cooling fluid and conduction cooling But the groove face of fluid, and (air enters six pod apertures, air goes out;Hydrogen enters, hydrogen goes out;Cooling fluid is entered, cooling fluid Go out) composition, it is tabula rasa face so to lead air groove face, reverse side by one piece of front, and leads hydrogen groove face by one piece of front, and reverse side is light Plate face;And air groove face is led by one piece of front, reverse side is that but two blocks of plates of fluid groove face constitute one piece of bipolar plates to conduction cooling.It is this bipolar The characteristics of plate:(1) combined by two blocks of plates;It is to lead cooling fluid in the middle of (2) two blocks of plates.Such combination bipolar plates have following Technological deficiency:
1. one piece is tabula rasa face in two blocks of plates, but one piece corresponding with tabula rasa face must have seal groove, and place sealing Cooling fluid flowing, can be limited in cooling splint groove, cooling fluid not channelling is arrived air, hydrogen duct by circle after combination It is interior, also not to leakage outside fuel cell pack.This sealing difficulty is larger, the design and manufacture of increase material fuel cell engineering Difficulty.
2. two blocks of plates are combined into the technology of bipolar plates, it is necessary to assure the mechanical strength of every block of plate, that is to say, that must assure that The thickness of every block of plate, the thinned difficulty of the so serious thickness for adding monoblock bipolar plates, make the weight of fuel cell pack with Volumetric specific power being restricted seriously.
The current technology of European patent EP 1009051, this two pieces of pole plates progress are gluing, above-mentioned skill can be so overcome substantially Art defect.But the patent must use conducting resinl, and two pieces of plate whole surfaces of combination are uniformly coated with into conducting resinl, and certain Temperature makes one piece of bipolar plates with being glued under pressure, the defect of this technology be the conducting resinl of high conductivity often After adhesive effect is not good, and the conducting resinl of low conductivity is coated on the corresponding surface of two pieces of combinations, bipolar plates can be had a strong impact on Conducting function, cause fuel cell pack internal resistance very big;In addition, the even spread technology of conducting resinl also has certain difficulty.
Therefore, Chinese patent Authorization Notice No. CN100356618C disclose a kind of high-efficiency fuel cell flow-guide double-pole plate and Its manufacture method, the bipolar plates are combined by airflow guiding plate with hydrogen flow guiding plate, and the conduction cooling of airflow guiding plate reverse side but flows Body groove or smooth surface are surrounded by shallow and wide type seal groove, the conduction cooling of hydrogen flow guiding plate reverse side but fluid slot or smooth surface be surrounded by with it is upper State and adhesive is provided with the corresponding shallow and wide type seal groove of airflow guiding plate reverse side, shallow and wide type seal groove, airflow guiding plate is with leading hydrogen After airflow plate pressing, adhesive is full of between seal groove, two blocks of plates for zero clearance laminating just.It uses adhesive for epoxy One kind in glue, silicone sealant, solid band of glue.Such way, can be tight when zero clearance laminating is unable between two blocks of plates Ghost image rings the conducting function of bipolar plates.
The content of the invention
Present invention aims at being provided for the deficiency present in above-mentioned prior art, a kind of bond effect is good, bipolar plates The high-efficiency fuel cell flow-guide double-pole plate conducted electricity very well.
In order to realize foregoing invention purpose, the technical solution adopted in the present invention is as follows:
As the high-efficiency fuel cell flow-guide double-pole plate of first aspect present invention, by airflow guiding plate and hydrogen flow guiding plate group Conjunction is formed, and is bonded form by adhesive between the two, wherein the adhesive is made up of colloid with graphite, the colloid and stone Mass percent between ink is 7~14wt%: 86~93%, and the graphite is spectroscopically pure graphite powder or powder graphite.
In a preferred embodiment of the invention, the colloid is formulated by epoxy resin and curing agent.
In a preferred embodiment of the invention, the epoxy resin is selected from E-44 epoxy resin, and the curing agent is 650 polyamide curing agents or phthalic anhydride.
As a result of technical scheme as above, the advantage that bond effect of the present invention is good, bipolar plates conduct electricity very well.
Embodiment
Embodiment 1
High-efficiency fuel cell flow-guide double-pole plate, is combined with hydrogen flow guiding plate by airflow guiding plate, passed through between the two Adhesive is bonded and formed, wherein the adhesive is made up of colloid with graphite particulate, the matter between the colloid and graphite particulate It is 7%: 93% to measure percentage, and graphite is spectroscopically pure graphite powder.
Colloid is formulated by epoxy resin and curing agent, and epoxy resin is selected from E-44 epoxy resin, and curing agent is 650 poly- Amide hardener.
Embodiment 2
High-efficiency fuel cell flow-guide double-pole plate, is combined with hydrogen flow guiding plate by airflow guiding plate, passed through between the two Adhesive is bonded and formed, wherein the adhesive is made up of colloid with graphite particulate, the matter between the colloid and graphite particulate It is 10%: 90% to measure percentage, and graphite is powder graphite.
Colloid is formulated by epoxy resin and curing agent, and epoxy resin is selected from E-44 epoxy resin, and curing agent is adjacent benzene Dicarboxylic acid anhydride.
Embodiment 3
High-efficiency fuel cell flow-guide double-pole plate, is combined with hydrogen flow guiding plate by airflow guiding plate, passed through between the two Adhesive is bonded and formed, wherein the adhesive is made up of colloid with graphite particulate, the matter between the colloid and graphite particulate It is 14%: 86% to measure percentage, and graphite is spectroscopically pure graphite powder.
Colloid is formulated by epoxy resin and curing agent, and epoxy resin is selected from E-44 epoxy resin, and curing agent is adjacent benzene Dicarboxylic acid anhydride.

Claims (3)

1. high-efficiency fuel cell flow-guide double-pole plate, is combined with hydrogen flow guiding plate by airflow guiding plate, passes through glue between the two Glutinous agent, which is bonded, to be formed, it is characterised in that the adhesive is made up of colloid with graphite, the quality hundred between the colloid and graphite Divide than being 7~14wt%: 86~93%, the graphite is spectroscopically pure graphite powder or powder graphite.
2. high-efficiency fuel cell flow-guide double-pole plate as claimed in claim 1, it is characterised in that the colloid by epoxy resin and Curing agent is formulated.
3. high-efficiency fuel cell flow-guide double-pole plate as claimed in claim 2, it is characterised in that the epoxy resin is selected from E-44 Epoxy resin, the curing agent is 650 polyamide curing agents or phthalic anhydride.
CN201710365568.7A 2017-05-22 2017-05-22 A kind of high-efficiency fuel cell flow-guide double-pole plate Pending CN107195923A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710365568.7A CN107195923A (en) 2017-05-22 2017-05-22 A kind of high-efficiency fuel cell flow-guide double-pole plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710365568.7A CN107195923A (en) 2017-05-22 2017-05-22 A kind of high-efficiency fuel cell flow-guide double-pole plate

Publications (1)

Publication Number Publication Date
CN107195923A true CN107195923A (en) 2017-09-22

Family

ID=59874900

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710365568.7A Pending CN107195923A (en) 2017-05-22 2017-05-22 A kind of high-efficiency fuel cell flow-guide double-pole plate

Country Status (1)

Country Link
CN (1) CN107195923A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1553532A (en) * 2003-06-04 2004-12-08 上海神力科技有限公司 High-efficient fuel battery guide bipolar plates and producing method thereof
CN101851479A (en) * 2010-05-17 2010-10-06 山东大学 Application of graphite conductive adhesive to prepare electrode-detection binder
CN102569825A (en) * 2012-02-18 2012-07-11 沈阳飞机工业(集团)有限公司 Conductive plastic composite electrode and manufacture method therefor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1553532A (en) * 2003-06-04 2004-12-08 上海神力科技有限公司 High-efficient fuel battery guide bipolar plates and producing method thereof
CN101851479A (en) * 2010-05-17 2010-10-06 山东大学 Application of graphite conductive adhesive to prepare electrode-detection binder
CN102569825A (en) * 2012-02-18 2012-07-11 沈阳飞机工业(集团)有限公司 Conductive plastic composite electrode and manufacture method therefor

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Application publication date: 20170922