CN107190503A - A kind of textile fabrics containing rare earth element - Google Patents
A kind of textile fabrics containing rare earth element Download PDFInfo
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- CN107190503A CN107190503A CN201710469112.5A CN201710469112A CN107190503A CN 107190503 A CN107190503 A CN 107190503A CN 201710469112 A CN201710469112 A CN 201710469112A CN 107190503 A CN107190503 A CN 107190503A
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- rare earth
- earth element
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- promethium
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/06—Inorganic compounds or elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
- D06M10/04—Physical treatment combined with treatment with chemical compounds or elements
- D06M10/08—Organic compounds
- D06M10/10—Macromolecular compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Artificial Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention relates to a kind of textile fabrics containing rare earth element, including textile fabrics body and rare earth element, the rare earth element is artificial promethium and neodymium cerium alloy, the combination of the rare earth element and textile fabrics uses Electrostatic Absorption method, damage of the Electrostatic Absorption method to textile fabrics is smaller, the addition of the rare earth element will not change its color and pliability, ray and the ferromagnetism of alloy that the rare earth element has, except for industry and sphere of life, certain effect is also produced to health, the present invention utilizes the magnetic field produced by the ray and the ferromagnetism of alloy in active element in rare earth, the characteristic such as thermal source and light, realize feature of the rare earth in textile fabrics, textile fabrics are made to realize the purpose of health care.
Description
Technical field
The present invention relates to health care Material Field, specially a kind of textile fabrics containing rare earth element.
Background technology
Rare earth element is a kind of preternatural material, and it can discharge emergent ray i.e. light and heat, and its alloy has very strong magnetic
Property, huge energy can be produced after atom fission, is the rich resource of China and strategic material.Textile fabrics are blindage, guarantor
The basic material of warm, body-building protector, decoration, at present using nanometer, far infrared（Ceramic powder material）, bamboo carbon fibre, with iron oxide
Based on the textile fabrics of magnetic material manufacture occur in succession, and its effect is obvious.A kind of wear-resisting moisture absorption textile fabric face
Material（Publication number CN104862985A）It is main using plumetis fiber, viscose glue there is provided a kind of wear-resisting Hygroscopic textile fiber fabric
Fiber, nitrile rubber fiber, wick Down Fiber, polyacrylonitrile fibre, cocoon fiber, bar hundred yarn fiber and tribute silk fibrous material system
Into present invention process is simple, and cost is low, is effectively improved the tensile strength, tearing brute force, anti-wear performance of fabric, enhances
The snugness of fit and service life of fabric.A kind of double anti-type radiation-proof fabrics（Publication number CN202144132U）There is provided one
Double anti-type radiation-proof fabrics, including upper, middle and lower three-decker are planted, wherein three-decker is respectively flexible parent metal layer of cloth, anti-electromagnetism spoke
Penetrate layer and Effect of X-Ray Shielding Fibre layer, this three layers compound to be fixedly connected, the present invention not only can be with anti-electromagnetic radiation but also can be with X-ray-preventing spoke
Penetrate, reach the effect of double protection, and it is relatively simple for structure, it is comfortable and easy to wear, but above invention application is smaller, function
Property it is not enough.
There is essential different, the weaving for adding rare earth element and material from above-mentioned patent publication us in the present patent application
The report of fabric is very few, and rare earth element paranormal phenomena and physical characteristic be not available for above material, such as ray,
Thermal source, light, the ferromagnetism of alloy, rare earth material belong to professional very strong Material Field.Current rare earth element has been widely used
In fields such as electronics, petrochemical industry, metallurgy, machinery, the energy, light industry, environmental protection, agriculturals, by rare earth element and materials application
In life, health care is realized, with good development prospect.
The content of the invention
In order to overcome the shortcomings of prior art, the present invention provides a kind of textile fabrics containing rare earth element, will be dilute
Earth elements are combined with textile fabrics, make full use of radioactivity that rare earth element is faint and the ferromagnetism of alloy, realize that health is protected
Strong purpose.
The present invention provides following technical scheme：A kind of textile fabrics containing rare earth element, including textile fabrics and dilute
Rare earth element promethium and neodymium cerium alloy are mixed in earth elements, the textile fabrics, the rare earth element promethium and neodymium cerium alloy are with spinning
Textured fiber product combination uses Electrostatic Absorption method.In any of the above-described scheme preferably, the Electrostatic Absorption method step is such as
Under：A. the neodymium cerium alloy is fused into ball powder-grinding after alloy under vacuum；B. the rare earth element promethium, neodymium cerium alloy powder
End and epoxide resin are uniformly mixed, and form mixing solution；C. the textile fabrics and the mixing solution are placed in electrostatic
In container, sprayed through sprayer；D. after the textile fabrics absorption rare earth element, solidified in electrostatic generation container,
E. the rare earth element uniformly penetrates into textile fabrics.
In any of the above-described scheme preferably, the textile fabrics material therefor is natural fiber, and the weaving is fine
Dimension product multilayer, many gaps.
In any of the above-described scheme preferably, the rare earth element promethium is artificial element, and usual valences are+3, to change
Solvate form is present.
In any of the above-described scheme preferably, the rare earth element promethium is with chloride（RECL3）Form is present, and can radiate
The low beta radiation of energy, its ray radiation scope is in below 100MSV.
In any of the above-described scheme preferably, the neodymium cerium alloy is powdered.
In any of the above-described scheme preferably, the neodymium cerium alloy is using neodymium alloy atomic ratio as Nd2 (Fe, B) 16-
18, cerium alloy atomic ratio Ce1 (Co, Cu, Fe) 4-6, are made under 2000-3000 DEG C of vacuum condition.
In any of the above-described scheme preferably, the weight ratio of the rare earth element promethium and textile fabrics is（0.10-
0.2）：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics is 1:（8-15）.
In any of the above-described scheme preferably, the rear earth element nd cerium alloy is used for the micro mist average grain of chopped fiber
Diameter is in below 5UM, and the micro mist average particulate diameter for long filament is in below 3UM.
In any of the above-described scheme preferably, the epoxide resin for solidification after epoxy resin, wherein curing agent with
Epoxide resin ratio is 0.5：1(±0.1).
In any of the above-described scheme preferably, the addition of the epoxide resin is the 0.8- of textile fabric quality
1.5%。
In any of the above-described scheme preferably, the epoxide resin is through acetone（CH3COCH3）Dispersant dissolves.
In any of the above-described scheme preferably, the discharge voltage of the electrostatic generation container is 0~8KV.
In any of the above-described scheme preferably, temperature adjustment is to 100-200 DEG C in the electrostatic generation container.
In any of the above-described scheme preferably, the solidification time is 0.8-1.6 hours in the electrostatic generation container
Left and right.
In any of the above-described scheme preferably, the β ray maximums of the rare earth element contained in the textile fabrics
For 2-3 millis tesla.
The beneficial effects of the invention are as follows a kind of textile fabrics containing rare earth element, by rare earth element and textile fabric condition
The important technological means of the present invention with reference to the material for being related to two kinds of different fields, ray that rare earth element has and
The ferromagnetism of alloy, the particularity of this physics of rare earth element determines its effect to health.The present invention effectively utilizes this
The faint ray of a little elements and heating, the ferromagnetism of luminous and alloy, make textile fabrics possess the characteristic of rare earth element.One
Kind has faint beta rays in the textile fabrics containing rare earth element, the maximum in magnetic field is 2-3 millis tesla, to health
Positive role is produced, the effect of health care can be reached.
A kind of preparation method of the textile fabrics containing rare earth element of the present invention preferentially uses Electrostatic Absorption method, this preparation
Method has no report in document and data, this method using the multilayer of textile fabrics, many gaps, surface area is big the characteristics of,
Under conditions of having quiet electrically and thermally, the absorption affinity on enhancing textile fabrics surface, damage of this method to textile fabrics is smaller,
The tissue of textile fabrics is more complete, improves value-added content of product.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common
The every other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
Embodiment 1
Mixed in a kind of textile fabrics containing rare earth element, including textile fabrics and rare earth element, the textile fabrics
Rare earth element promethium and neodymium cerium alloy, the rare earth element promethium and neodymium cerium alloy use Electrostatic Absorption with textile fabrics combination
Method.The Electrostatic Absorption method step is as follows：A. the neodymium cerium alloy is fused into ball powder-grinding after alloy under vacuum；B. institute
State rare earth element promethium, neodymium cerium alloy powder and epoxide resin uniformly to mix, form mixing solution；C. the textile fabrics and institute
State mixing solution to be placed in electrostatic generation container, sprayed through sprayer；D. after the textile fabrics absorption rare earth element, quiet
Solidified in electric generation container, rare earth element uniformly penetrates into textile fabrics described in e..
In the present embodiment, textile fabrics material therefor is natural fiber, the textile fabrics belong to long fibre and multilayer,
Many gaps, surface area is big, and under the static conditions for having heat energy, kinetic energy to produce, superficial attractive forces are then greatly enhanced, and can be utilized quiet
Electro ultrafiltration adsorbs rare earth element.
In the present embodiment, the rare earth element promethium is artificial element, and artificial promethium is with chloride（RECL3）Form is present, energy
The low beta radiation of enough radianies, the ray radiation scope of rare earth element promethium is in below 50MSV, and rear earth element nd, cerium are alloy
Rare earth material, its alloy to be powdered, rear earth element nd cerium alloy be used for the micro mist average particulate diameter of chopped fiber 5UM with
Under, the micro mist average particulate diameter for long filament is in below 3UM, and the neodymium cerium alloy is using neodymium alloy atomic ratio as 2：16, cerium is closed
Gold atom compares 1：4, alloy is melted under 2000 DEG C of vacuum conditions, the alloy is handled in 1100 DEG C of vacuum and inert gas
1 hour, then 4 hours are handled by 400 DEG C of star spectra datas, the then ball powder-grinding in alkyl protection solution, until being averaged
A diameter of 3UM powder, is then dried in a vacuum, and is preserved after sub-sieve in inert gas.
In the present embodiment, rare earth element promethium and neodymium the cerium alloy input is uniformly mixed in the epoxide resin after dissolving,
The weight ratio of promethium and textile fabrics is 0.1：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics is 1:
10, the wherein addition of epoxide resin is the 0.8% of textile fabric quality, and epoxy resin is cured epoxy resin, wherein
The ratio of curing agent and epoxide resin is 0.5：0.9, the epoxy resin after solidification is then dissolved in acetone（CH3COCH3）It is scattered
In agent, epoxy series polymer solution is formed, respectively by artificial promethium（RECL3）The ring after dissolving is put into rare earth alloy powder
Turn into mixing solution in oxygen series polymer solution, after uniform stirring.
In the present embodiment, the associated methods of the rare earth element and textile fabrics use Electrostatic Absorption method, the weaving
The mixing solution of fabric and rare earth element powder and epoxide resin is placed in electrostatic generation container, and mixing solution is sent out through electrostatic
Raw container internal sprayer injection, textile fabrics adsorb rare earth element in the case where there is static conditions using electrostatic interaction, then will be quiet
Temperature adjustment is solidified 1 hour by electrostatic interaction rare earth element being covered in textile fabrics to 100 DEG C in electric generation container
On.
The present invention is contained in the textile fabrics containing rare earth element using rare earth element and textile fabrics combination technology
Rare earth element β ray magnetic maximum be 2 milli teslas, it is fainter, to health produce positive role, had
The faint ray and the ferromagnetism of alloy having are obvious to health care's health-care efficacy.
Textile containing rare earth element, magnetic field is in undaform, rheology experiment prove when fluid transverse cuts magnetic field and
Directions of rays be 90 DEG C of angles by when, synthermal lower liquid produces 1 ‰（m2/s）Viscosity B coefficent.
Embodiment 2
In step be the same as Example 1 described in the present embodiment, the present embodiment 2, the textile fabrics material therefor is natural fiber, should
Textile fabrics belong to long fibre and multilayer, many gaps, and surface area is big, under the static conditions for having heat energy, kinetic energy to produce, surface
Absorption affinity is then greatly enhanced, and can adsorb rare earth element using electrostatic interaction.The rare earth element promethium is artificial element, artificial promethium
With chloride（RECL3）Form exist, can the low beta radiation of radiant, the ray radiation scope of rare earth element promethium is in 80MSV
Hereinafter, rear earth element nd, cerium are the rare earth material of alloy, and its alloy is powdered, and rear earth element nd cerium alloy is used for chopped fiber
Micro mist average particulate diameter in below 4UM, the micro mist average particulate diameter for long filament is in 2UM neodymium cerium alloys as described below
Using neodymium alloy atomic ratio as 2：18, cerium alloy atomic ratio 1：6, alloy is melted under 2000 DEG C of vacuum conditions, the alloy exists
Handle 1 hour, then handled 4 hours by 400 DEG C of star spectra datas in 1100 DEG C of vacuum and inert gas, then protect molten in alkyl
Ball powder-grinding in liquid, until obtaining the powder that average diameter is 3UM, is then dried in a vacuum, after sub-sieve in inert gas
Preserve.
In the present embodiment, rare earth element promethium and neodymium the cerium alloy input is uniformly mixed in the epoxide resin after dissolving,
The weight ratio of promethium and textile fabrics is 0.1：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics is 1:
10, the wherein addition of epoxide resin is the 0.8% of textile fabric quality, and epoxy resin is cured epoxy resin, wherein
The ratio of curing agent and epoxide resin is 0.5：1, the epoxy resin after solidification is then dissolved in acetone（CH3COCH3）Dispersant
In, epoxy series polymer solution is formed, respectively by artificial promethium（RECL3）The epoxy after dissolving is put into rare earth alloy powder
Turn into mixing solution in series polymer solution, after uniform stirring.
In the present embodiment, the associated methods of the rare earth element and textile fabrics use Electrostatic Absorption method, the weaving
The mixing solution of fabric and rare earth element powder and epoxide resin is placed in electrostatic generation container, and mixing solution is sent out through electrostatic
Raw container internal sprayer injection, textile fabrics adsorb rare earth element in the case where there is static conditions using electrostatic interaction, then will be quiet
Temperature adjustment is solidified 1 hour by electrostatic interaction rare earth element being covered in textile fabrics to 100 DEG C in electric generation container
On, damage of the Electrostatic Absorption method to textile fabrics is smaller, and the tissue of fabric is more complete.
The present invention is contained in the textile fabrics containing rare earth element using rare earth element and textile fabrics combination technology
Rare earth element β ray magnetic maximum be 3 milli teslas, it is fainter, to health produce positive role, had
The faint ray and the ferromagnetism of alloy having are obvious to health care's health-care efficacy.Red blood cell is in the textile containing rare earth element
Under the magnetic fields of generation, movement velocity is accelerated, and molecular structure changes, and the flow velocity of blood is accelerated, its envelope membrane surface negative electricity
Aggregation is less likely to occur, makes blood for lotus density increase, the like charges increase between cell and cell, repellence enhancing, cell
Speed is speeded, and the textile fabrics containing rare earth element can accelerate the flowing velocity of blood.
Embodiment 3
In step be the same as Example 1 described in the present embodiment, the present embodiment 3, the textile fabrics material therefor is natural fiber, should
Textile fabrics belong to long fibre and multilayer, many gaps, and surface area is big, under the static conditions for having heat energy, kinetic energy to produce, surface
Absorption affinity is then greatly enhanced, and can adsorb rare earth element using electrostatic interaction.The rare earth element promethium is artificial element, artificial promethium
With chloride（RECL3）Form is present, can the low beta radiation of radiant, the ray radiation scope of rare earth element promethium exists
Below 100MSV, rear earth element nd, cerium are the rare earth material of alloy, and its alloy is powdered, and rear earth element nd cerium alloy is used for
The micro mist average particulate diameter of chopped fiber is in below 5UM, and the micro mist average particulate diameter for long filament is in 3UM neodymium ceriums as described below
Alloy is using neodymium alloy atomic ratio as 2：16, cerium alloy atomic ratio 1：4, alloy is melted under 2500 DEG C of vacuum conditions, should
Alloy is handled 1.5 hours in 1200 DEG C of vacuum and inert gas, then is handled 4 hours by 400 DEG C of star spectra datas, then in hydrocarbon
Ball powder-grinding in base protection solution, until obtaining the powder that average diameter is 3UM, is then dried in a vacuum, lazy after sub-sieve
Property gas in preserve.
In the present embodiment, rare earth element promethium and neodymium the cerium alloy input is uniformly mixed in the epoxide resin after dissolving,
The weight ratio of promethium and textile fabrics is 0.1：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics is 1:
10, the wherein addition of epoxide resin is the 1% of textile fabric quality, and epoxy resin is cured epoxy resin, wherein solid
Agent and the ratio of epoxide resin are 0.5：1.1, the epoxy resin after solidification is then dissolved in acetone（CH3COCH3）Dispersant
In, epoxy series polymer solution is formed, respectively by artificial promethium（RECL3）The epoxy after dissolving is put into rare earth alloy powder
Turn into mixing solution in series polymer solution, after uniform stirring.
In the present embodiment, the associated methods of the rare earth element and textile fabrics use Electrostatic Absorption method, the weaving
The mixing solution of fabric and rare earth element powder and epoxide resin is placed in electrostatic generation container, and mixing solution is sent out through electrostatic
Raw container internal sprayer injection, textile fabrics adsorb rare earth element in the case where there is static conditions using electrostatic interaction, then will be quiet
Temperature adjustment is solidified 1 hour by electrostatic interaction rare earth element being covered in textile fabrics to 100 DEG C in electric generation container
On, damage of the Electrostatic Absorption method to textile fabrics is smaller, and the tissue of fabric is more complete.
Textile with rare earth element, magnetic field is in undaform, and experiment is proved when fluid includes blood transverse cuts magnetic field
And directions of rays be 90 DEG C of angles by when, synthermal lower liquid and blood produce 3 ‰（m2/s）Viscosity B coefficent, containing rare earth member
The textile fabrics of element can accelerate the flowing velocity of blood.
A kind of textile fabrics containing rare earth element of the present invention can play reduction blood viscosity so that VPV adds
Hurry up, cellular immune function can be improved, the textile with rare earth element can be obviously improved microcirculation, can adjust blood pressure and
Lipid-loweringing, effective percentage 87.5%.A kind of textile fabrics containing rare earth element of the present invention, combine rare earth element and textile fabrics
The material of two kinds of different fields, makes textile fabrics possess the characteristic of rare earth element.
Embodiment 4
In step be the same as Example 1 described in the present embodiment, the present embodiment 4, the textile fabrics material therefor is natural fiber, should
Textile fabrics belong to long fibre and multilayer, many gaps, and surface area is big, under the static conditions for having heat energy, kinetic energy to produce, surface
Absorption affinity is then greatly enhanced, and can adsorb rare earth element using electrostatic interaction.The rare earth element promethium is artificial element, artificial promethium
With chloride（RECL3）Form is present, can the low beta radiation of radiant, the ray radiation scope of rare earth element promethium exists
Below 100MSV, rear earth element nd, cerium are the rare earth material of alloy, and its alloy is powdered, and rear earth element nd cerium alloy is used for
The micro mist average particulate diameter of chopped fiber is in below 5UM, and the micro mist average particulate diameter for long filament is in 3UM neodymium ceriums as described below
Alloy is using neodymium alloy atomic ratio as 2：18, cerium alloy atomic ratio 1：6, alloy is melted under 3000 DEG C of vacuum conditions, should
Alloy is handled 1.5 hours in 1200 DEG C of vacuum and inert gas, then is handled 4 hours by 400 DEG C of star spectra datas, then in hydrocarbon
Ball powder-grinding in base protection solution, until obtaining the powder that average diameter is 3UM, is then dried in a vacuum, lazy after sub-sieve
Property gas in preserve.
In the present embodiment, rare earth element promethium and neodymium the cerium alloy input is uniformly mixed in the epoxide resin after dissolving,
The weight ratio of promethium and textile fabrics is 0.1：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics is 1:
10, the wherein addition of epoxide resin is the 1.5% of textile fabric quality, and epoxy resin is cured epoxy resin, wherein
The ratio of curing agent and epoxide resin is 0.5：1, the epoxy resin after solidification is then dissolved in acetone（CH3COCH3）Dispersant
In, epoxy series polymer solution is formed, respectively by artificial promethium（RECL3）The epoxy after dissolving is put into rare earth alloy powder
Turn into mixing solution in series polymer solution, after uniform stirring.
In the present embodiment, the associated methods of the rare earth element and textile fabrics use Electrostatic Absorption method, the weaving
The mixing solution of fabric and rare earth element powder and epoxide resin is placed in electrostatic generation container, and mixing solution is sent out through electrostatic
Raw container internal sprayer injection, textile fabrics adsorb rare earth element in the case where there is static conditions using electrostatic interaction, then will be quiet
Temperature adjustment is solidified 1 hour by electrostatic interaction rare earth element being covered in textile fabrics to 200 DEG C in electric generation container
On, damage of the Electrostatic Absorption method to textile fabrics is smaller, and the tissue of fabric is more complete.
Textile with rare earth element can be with anti-inflammatory analgetic, effective percentage 87.5%.A kind of spinning containing rare earth element of the present invention
Textured fiber product, combine the material of two kinds of different fields of rare earth element and textile fabrics, textile fabrics is possessed rare earth member
The characteristic of element.
Embodiment 5
In step be the same as Example 1 described in the present embodiment, the present embodiment 5, the textile fabrics material therefor is natural fiber, should
Textile fabrics belong to long fibre and multilayer, many gaps, and surface area is big, under the static conditions for having heat energy, kinetic energy to produce, surface
Absorption affinity is then greatly enhanced, and can adsorb rare earth element using electrostatic interaction.The rare earth element promethium is artificial element, artificial promethium
With chloride（RECL3）Form is present, can the low beta radiation of radiant, the ray radiation scope of rare earth element promethium exists
Below 100MSV, rear earth element nd, cerium are the rare earth material of alloy, and its alloy is powdered, and rear earth element nd cerium alloy is used for
The micro mist average particulate diameter of chopped fiber is in below 5UM, and the micro mist average particulate diameter for long filament is in 3UM neodymium ceriums as described below
Alloy is using neodymium alloy atomic ratio as 2：18, cerium alloy atomic ratio 1：6, alloy is melted under 3000 DEG C of vacuum conditions, should
Alloy is handled 2 hours in 1200 DEG C of vacuum and inert gas, then is handled 4 hours by 400 DEG C of star spectra datas, then in alkyl
Ball powder-grinding in solution is protected, until obtaining the powder that average diameter is 3UM, is then dried in a vacuum, in inertia after sub-sieve
Preserved in gas.
In the present embodiment, rare earth element promethium and neodymium the cerium alloy input is uniformly mixed in the epoxide resin after dissolving,
The weight ratio of promethium and textile fabrics is 0.15：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics is 1:
15, the wherein addition of epoxide resin is the 1.5% of textile fabric quality, and epoxy resin is cured epoxy resin, wherein
The ratio of curing agent and epoxide resin is 0.5：0.9, the epoxy resin after solidification is then dissolved in acetone（CH3COCH3）It is scattered
In agent, epoxy series polymer solution is formed, respectively by artificial promethium（RECL3）The ring after dissolving is put into rare earth alloy powder
Turn into mixing solution in oxygen series polymer solution, after uniform stirring.
In the present embodiment, the associated methods of the rare earth element and textile fabrics use Electrostatic Absorption method, the weaving
The mixing solution of fabric and rare earth element powder and epoxide resin is placed in electrostatic generation container, and mixing solution is sent out through electrostatic
Raw container internal sprayer injection, textile fabrics adsorb rare earth element in the case where there is static conditions using electrostatic interaction, then will be quiet
Temperature adjustment is solidified 1 hour by electrostatic interaction rare earth element being covered in textile fabrics to 200 DEG C in electric generation container
On, damage of the Electrostatic Absorption method to textile fabrics is smaller, and the tissue of fabric is more complete.
Textile with rare earth element can adjust the function of nervous system, improve immunity of organisms, efficient
86.7%。
Embodiment 6
In step be the same as Example 1 described in the present embodiment, the present embodiment 6, the textile fabrics material therefor is natural fiber, should
Textile fabrics belong to long fibre and multilayer, many gaps, and surface area is big, under the static conditions for having heat energy, kinetic energy to produce, surface
Absorption affinity is then greatly enhanced, and can adsorb rare earth element using electrostatic interaction.The rare earth element promethium is artificial element, artificial promethium
With chloride（RECL3）Form is present, can the low beta radiation of radiant, the ray radiation scope of rare earth element promethium exists
Below 100MSV, rear earth element nd, cerium are the rare earth material of alloy, and its alloy is powdered, and rear earth element nd cerium alloy is used for
The micro mist average particulate diameter of chopped fiber is in below 5UM, and the micro mist average particulate diameter for long filament is in 3UM neodymium ceriums as described below
Alloy is using neodymium alloy atomic ratio as 2：17, cerium alloy atomic ratio 1：5, alloy is melted under 3000 DEG C of vacuum conditions, should
Alloy is handled 2 hours in 1200 DEG C of vacuum and inert gas, then is handled 4 hours by 400 DEG C of star spectra datas, then in alkyl
Ball powder-grinding in solution is protected, until obtaining the powder that average diameter is 3UM, is then dried in a vacuum, in inertia after sub-sieve
Preserved in gas.
In the present embodiment, rare earth element promethium and neodymium the cerium alloy input is uniformly mixed in the epoxide resin after dissolving,
The weight ratio of promethium and textile fabrics is 0.12：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics is 1:
15, the wherein addition of epoxide resin is the 1.5% of textile fabric quality, and epoxy resin is cured epoxy resin, wherein
The ratio of curing agent and epoxide resin is 0.5：1, the epoxy resin after solidification is then dissolved in acetone（CH3COCH3）Dispersant
In, epoxy series polymer solution is formed, respectively by artificial promethium（RECL3）The epoxy after dissolving is put into rare earth alloy powder
Turn into mixing solution in series polymer solution, after uniform stirring.
In the present embodiment, the associated methods of the rare earth element and textile fabrics use Electrostatic Absorption method, the weaving
The mixing solution of fabric and rare earth element powder and epoxide resin is placed in electrostatic generation container, and mixing solution is sent out through electrostatic
Raw container internal sprayer injection, textile fabrics adsorb rare earth element in the case where there is static conditions using electrostatic interaction, then will be quiet
Temperature adjustment is solidified 1 hour by electrostatic interaction rare earth element being covered in textile fabrics to 200 DEG C in electric generation container
On, damage of the Electrostatic Absorption method to textile fabrics is smaller, and the tissue of fabric is more complete.
Textile with rare earth element can promote union etc., improve immunity of organisms, effective percentage 77.5%.
More than in six embodiments, selection rare earth element and textile fabrics and the combination side using Electrostatic Absorption method
Formula, is a brand-new technology for health care, and the present invention effectively utilizes the faint ray and heating, hair of these elements
The ferromagnetism of light and alloy, makes textile fabrics possess the characteristic of rare earth element, realizes rare earth element in textile fabrics
Feature, the work that alloy atom is when handled is controlled by the proportioning of ray power control rare earth element metering and by ferromagnetism size
Skill, its effect can be respectively present, and can also be existed simultaneously.The associated methods Electrostatic Absorption method of rare earth element and textile fabrics, this
Kind of preparation method has no report in document and data, and this method takes full advantage of the multilayers of textile fabrics, many gaps, surface
The characteristics of product is big, under conditions of having quiet electrically and thermally, greatly enhances the absorption affinity on textile fabrics surface, can be made using electrostatic
With absorption rare earth element.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Claims (10)
1. a kind of textile fabrics containing rare earth element, including textile fabrics and rare earth element, it is characterised in that：The weaving
Rare earth element promethium and neodymium cerium alloy, the rare earth element promethium and neodymium cerium alloy and textile fabrics combination are mixed in fabric
Using Electrostatic Absorption method.
2. a kind of textile fabrics containing rare earth element according to claim 1, it is characterised in that：The Electrostatic Absorption method
Step is as follows：A. the neodymium cerium alloy is fused into ball powder-grinding after alloy under vacuum；B. the rare earth element promethium, neodymium
Cerium alloy powder and epoxide resin are uniformly mixed, and form mixing solution；C. the textile fabrics and the mixing solution are placed in
In electrostatic generation container, sprayed through sprayer；D. after the textile fabrics absorption rare earth element, in electrostatic generation container
Solidified, rare earth element uniformly penetrates into textile fabrics described in e..
3. a kind of textile fabrics containing rare earth element according to claim 1, it is characterised in that：The textile fabrics
Material therefor is natural fiber, the textile fabrics multilayer, many gaps.
4. a kind of textile fabrics containing rare earth element according to claim 1, it is characterised in that：The rare earth element promethium
It is artificial element, usual valences are+3, are existed with compound form.
5. a kind of textile fabrics containing rare earth element according to claim 1, it is characterised in that：The rare earth element promethium
Exist in a chloride-form, the low beta radiation of energy radiant, its ray radiation scope is in below 100MSV.
6. a kind of textile fabrics containing rare earth element according to claim 1, it is characterised in that：The neodymium cerium alloy is
It is powdered.
7. a kind of textile fabrics containing rare earth element according to claim 2, it is characterised in that：The neodymium cerium alloy is
Using neodymium alloy atomic ratio as Nd2 (Fe, B) 16-18, cerium alloy atomic ratio Ce1 (Co, Cu, Fe) 4-6, in 2000-3000 DEG C of vacuum
Under the conditions of be made.
8. a kind of textile fabrics containing rare earth element according to claim 2, it is characterised in that：The rare earth element promethium
Weight ratio with textile fabrics is（0.10-0.2）：10, the weight ratio of the rear earth element nd cerium alloy and textile fabrics
For 1:(8-15).
9. a kind of textile fabrics containing rare earth element according to claim 2, it is characterised in that：The rear earth element nd
Cerium alloy is used for the micro mist average particulate diameter of chopped fiber in below 5UM, for long filament micro mist average particulate diameter 3UM with
Under.
10. a kind of textile fabrics containing rare earth element according to claim 2, it is characterised in that：The epoxide resin
For the epoxy resin after solidification, wherein curing agent and epoxide resin ratio is 0.5：1(±0.1).
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| JP2000110062A (en) * | 1998-10-03 | 2000-04-18 | Sekaicho Rubber Co Ltd | Multi-functional stretchable woven or knitted fabric and product made from it |
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| CN102921237A (en) * | 2012-11-08 | 2013-02-13 | 中材科技股份有限公司 | Process for manufacturing high-filtering, high-temperature-resistant and anti-corrosive membrane-covered hybrid fiber punched felt |
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Application publication date: 20170922 |