CN107189713A - A kind of stainless steel tableware, which dissipates to sell, uses label adhesive agent - Google Patents
A kind of stainless steel tableware, which dissipates to sell, uses label adhesive agent Download PDFInfo
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- CN107189713A CN107189713A CN201710574649.8A CN201710574649A CN107189713A CN 107189713 A CN107189713 A CN 107189713A CN 201710574649 A CN201710574649 A CN 201710574649A CN 107189713 A CN107189713 A CN 107189713A
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- parts
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- stainless steel
- adhesive agent
- modified
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- 239000000853 adhesive Substances 0.000 title claims abstract description 36
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 25
- 239000010935 stainless steel Substances 0.000 title claims abstract description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229920002643 polyglutamic acid Polymers 0.000 claims abstract description 34
- 235000004443 Ricinus communis Nutrition 0.000 claims abstract description 32
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 32
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 30
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 30
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000005642 Oleic acid Substances 0.000 claims abstract description 30
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 30
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 30
- 108010020346 Polyglutamic Acid Proteins 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 22
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims abstract description 20
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000008108 microcrystalline cellulose Substances 0.000 claims abstract description 14
- 229940016286 microcrystalline cellulose Drugs 0.000 claims abstract description 14
- 239000001341 hydroxy propyl starch Substances 0.000 claims abstract description 12
- 235000013828 hydroxypropyl starch Nutrition 0.000 claims abstract description 12
- 239000003365 glass fiber Substances 0.000 claims abstract description 11
- 229920001983 poloxamer Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 5
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229960000502 poloxamer Drugs 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000009413 insulation Methods 0.000 claims description 36
- 239000001293 FEMA 3089 Substances 0.000 claims description 25
- 238000002156 mixing Methods 0.000 claims description 25
- 238000010792 warming Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 229920000881 Modified starch Polymers 0.000 claims description 14
- 239000004368 Modified starch Substances 0.000 claims description 14
- 238000000227 grinding Methods 0.000 claims description 14
- 238000003801 milling Methods 0.000 claims description 14
- 235000019426 modified starch Nutrition 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 13
- 230000004048 modification Effects 0.000 claims description 8
- 238000012986 modification Methods 0.000 claims description 8
- 238000010992 reflux Methods 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000003595 mist Substances 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- 238000013517 stratification Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 claims description 4
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 229920000523 polyvinylpolypyrrolidone Polymers 0.000 claims description 3
- 235000013809 polyvinylpolypyrrolidone Nutrition 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 238000004132 cross linking Methods 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 claims 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 3
- 240000000528 Ricinus communis Species 0.000 description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- -1 ethers Ester Chemical class 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 239000003643 water by type Substances 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 238000000605 extraction Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229910000604 Ferrochrome Inorganic materials 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical class OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/08—Ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Dissipate to sell the invention discloses a kind of stainless steel tableware and use label adhesive agent, be related to field of adhesive technology, be made up of the raw material of following parts by weight：15 25 parts of hydroxypropyl starch ether, hydrogenated castor oleic acid/5 10 parts of polyglutamic acid, 35 parts of microcrystalline cellulose, 35 parts of polyethylene glycol oxide, 13 parts of six acrylate of dipentaerythrite, 13 parts of poloxamer, 0.5 2 parts of nano zine oxide, 0.1 1 parts of molecular screen primary powder, 0.1 1 parts of glass fiber powder, 0.01 0.1 parts of bimaleimide resin, 150 250 parts of deionized water.The adhesive strength that label is pasted on 8h after stainless steel tableware is reached more than 4MPa by the made adhesive agent of the present invention；And stainless steel tableware using it is preceding it is soaked into 15min in water after label can be disposably completely exfoliated, while the adhesive agent residual quantity on stainless steel tableware is only 0.04%, then can be removed completely after hot-water soak.
Description
Technical field：
The present invention relates to adhesive processing technique field, and in particular to a kind of stainless steel tableware, which dissipates to sell, uses label adhesive agent.
Background technology：
Stainless steel, some other trace element is mixed by ferrochrome and is made again.Because its metallicity is good,
And than other metal corrosion resistants, the vessel being made are attractive and durable.Therefore, more and more it is used to manufacture tableware, and gradually
Into vast family.
At present, stainless steel tableware typically sells mode using scattered, but when when dispatching from the factory for the ease of mark product information and sale
For the ease of barcode scanning price, it will usually the adhesive label on stainless steel tableware.But in stainless steel tableware using preceding needing stripping to remove
Remove label, but easily occur being difficult to once peeling off and the problem of label adhesive agent is seriously remained, such as want that the adhesive agent of residual is complete
Complete remove then needs to increase scavenging period, and uses cleaning agent, otherwise can there is edible safety hidden danger.
The content of the invention：
The technical problems to be solved by the invention be to provide i.e. achievable label after one kind is soaked through water be completely exfoliated and
The stainless steel tableware of less residue, which dissipates to sell, uses label adhesive agent.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of stainless steel tableware, which dissipates to sell, uses label adhesive agent, is made up of the raw material of following parts by weight：
It is 15-25 parts of hydroxypropyl starch ether, hydrogenated castor oleic acid/5-10 parts of polyglutamic acid, 3-5 parts of microcrystalline cellulose, poly-
3-5 parts of ethylene oxide, 1-3 parts of six acrylate of dipentaerythrite, 1-3 parts of poloxamer, 0.5-2 parts of nano zine oxide, point
Former 0.1-1 parts of the powder of son sieve, 0.1-1 parts of glass fiber powder, 0.01-0.1 parts of bimaleimide resin, deionized water 150-250
Part；
Its preparation method comprises the following steps：
(1) polyethylene glycol oxide and the acrylate of dipentaerythrite six are added under grinding into hydroxypropyl starch ether, and in
Microwave treatment 5min under microwave frequency 2450MHz, power output 700W, stands and nano zine oxide is added after 5min, and mixing is equal
Continue microwave treatment 5min after even, stand microwave treatment 5min again after 5min, gained mixture is naturally cooled under milling
Room temperature, produces modified starch ether；
(2) poloxamer and bimaleimide resin are added into microcrystalline cellulose, and under milling with 5 DEG C/min's
Programming rate is warming up to 110-120 DEG C of insulation grinding 30min, naturally cools to room temperature, produces modified microcrystalline cellulose；
(3) molecular screen primary powder and glass fiber powder are added into hydrogenated castor oleic acid/polyglutamic acid, 70-80 is warming up to
DEG C insulation mixing 10min, add modified starch ether, modified microcrystalline cellulose and deionized water, be continuously heating to reflux state
Insulation mixing 15min, and the concentrated adhesive agent that solid content 55-60% is made.
The preparation method of the hydrogenated castor oleic acid/polyglutamic acid is：By hydrogenated castor oleic acid with 5 DEG C/min heating
Speed is heated to molten condition insulation 5min, adds polyglutamic acid, is sufficiently mixed after microwave frequency 2450MHz, output
Microwave treatment 5min under power 700W, stand 10min after continue microwave treatment 5min, then add N hydroxymethyl acrylamide and
Modified turpentine oil, microwave treatment 5min again after being well mixed, gained mixture is transferred to sealing and standing 5h in -15 DEG C of environment, most
Micro mist is made by micronizer, hydrogenated castor oleic acid/polyglutamic acid is produced.
The hydrogenated castor oleic acid, polyglutamic acid, N hydroxymethyl acrylamide and modified terebinthine mass ratio are 5-
10:5-10:0.5-2:0.2-1。
The modified turpentine oil is formed by turpentine oil through close fine modification, and its method of modifying is：Activity is added into turpentine oil
Charcoal, stands 8h after being sufficiently mixed, filtering, HPMA is added into gained filtrate, and be heated to 110-120 DEG C of insulation
15min is mixed, PVPP is added, continued in 110-120 DEG C of insulation mixing 15min, after 45-55 DEG C
The deionized water of equitemperature is added, rear stratification is sufficiently stirred for, extracted, gained oil reservoir anhydrous sodium sulfate drying is produced and changed
Property turpentine oil.
The turpentine oil, activated carbon, HPMA, PVPP, the mass ratio of deionized water are 1-3:
0.1-0.5:0.1-0.5:0.05-0.3:5-10。
The beneficial effects of the invention are as follows：The present invention is assisted with many using hydroxypropyl starch ether as primary raw material after modified processing
Plant scattered sell of the obtained stainless steel tableware of auxiliary agent and use label adhesive agent, the adhesive agent belongs to aqueous adhesive, safe to use, and mark
Label 8h adhesive strength after being pasted on stainless steel tableware reaches more than 4MPa；And by it in water before stainless steel tableware is used
Label can be disposably completely exfoliated after middle immersion 15min, while the adhesive agent residual quantity on stainless steel tableware is only 0.04%,
It can be removed completely after hot-water soak again, so as to ensure the safety in utilization of stainless steel tableware.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) 3g polyethylene glycol oxides and the acrylic acid of 1g dipentaerythrites six are added under grinding into 20g hydroxypropyl starch ethers
Ester, and in microwave treatment 5min under microwave frequency 2450MHz, power output 700W, 0.5g nano oxygens are added after standing 5min
Change zinc, continue microwave treatment 5min after being well mixed, stand microwave treatment 5min again after 5min, gained mixture is under milling
Room temperature is naturally cooled to, modified starch ether is produced；
(2) add 1g poloxamers and 0.05g bimaleimide resins into 5g microcrystalline celluloses, and under milling with
5 DEG C/min programming rate is warming up to 110-120 DEG C of insulation grinding 30min, naturally cools to room temperature, produces modification of microcrystalline fiber
Element；
(3) 0.2g molecular screen primary powders and 0.1g glass fiber powders are added into 5g hydrogenated castors oleic acid/polyglutamic acid, is risen
Temperature adds modified starch ether, modified microcrystalline cellulose and 250g deionized waters, continues to rise to 70-80 DEG C of insulation mixing 10min
Temperature to reflux state insulation mixes 15min, and the concentrated adhesive agent that solid content 55-60% is made.
The preparation of hydrogenated castor oleic acid/polyglutamic acid：10g hydrogenated castors oleic acid is added with 5 DEG C/min firing rate
Heat to molten condition is incubated 5min, adds 5g polyglutamic acids, is sufficiently mixed after microwave frequency 2450MHz, power output
Microwave treatment 5min under 700W, stands and continues microwave treatment 5min after 10min, then adds 0.5g N hydroxymethyl acrylamides
Turpentine oil is modified with 0.5g, microwave treatment 5min again after being well mixed, gained mixture is transferred to sealing and standing in -15 DEG C of environment
5h, is most made micro mist through micronizer afterwards, produces hydrogenated castor oleic acid/polyglutamic acid.
Modified terebinthine preparation：0.3g activated carbons are added into 3g turpentine oil, 8h is stood after being sufficiently mixed, are filtered, to
0.2g HPMAs are added in gained filtrate, and are heated to 110-120 DEG C of insulation mixing 15min, 0.1g friendships are added
Join PVP, continue, in 110-120 DEG C of insulation mixing 15min, to go after naturally cool to the 10g for adding equitemperature after 45-55 DEG C
Ionized water, is sufficiently stirred for rear stratification, and extraction, gained oil reservoir anhydrous sodium sulfate drying produces modified turpentine oil.
Embodiment 2
(1) 3g polyethylene glycol oxides and the acrylic acid of 2g dipentaerythrites six are added under grinding into 25g hydroxypropyl starch ethers
Ester, and in microwave treatment 5min under microwave frequency 2450MHz, power output 700W, 0.5g nano oxygens are added after standing 5min
Change zinc, continue microwave treatment 5min after being well mixed, stand microwave treatment 5min again after 5min, gained mixture is under milling
Room temperature is naturally cooled to, modified starch ether is produced；
(2) 1g poloxamers and 0.1g bimaleimide resins are added into 5g microcrystalline celluloses, and under milling with 5
DEG C/min programming rate is warming up to 110-120 DEG C of insulation grinding 30min, room temperature is naturally cooled to, modification of microcrystalline fiber is produced
Element；
(3) 0.5g molecular screen primary powders and 0.3g glass fiber powders are added into 10g hydrogenated castors oleic acid/polyglutamic acid,
70-80 DEG C of insulation mixing 10min is warming up to, modified starch ether, modified microcrystalline cellulose and 250g deionized waters is added, continues
It is warming up to reflux state insulation mixing 15min, and the concentrated adhesive agent that solid content 55-60% is made.
The preparation of hydrogenated castor oleic acid/polyglutamic acid：10g hydrogenated castors oleic acid is added with 5 DEG C/min firing rate
Heat to molten condition is incubated 5min, adds 10g polyglutamic acids, is sufficiently mixed after microwave frequency 2450MHz, power output
Microwave treatment 5min under 700W, stand 10min after continue microwave treatment 5min, then add 1gN- NMAs and
0.5g is modified turpentine oil, and microwave treatment 5min again after being well mixed, gained mixture is transferred to sealing and standing in -15 DEG C of environment
5h, is most made micro mist through micronizer afterwards, produces hydrogenated castor oleic acid/polyglutamic acid.
Modified terebinthine preparation：0.1g activated carbons are added into 2g turpentine oil, 8h is stood after being sufficiently mixed, are filtered, to
0.2g HPMAs are added in gained filtrate, and are heated to 110-120 DEG C of insulation mixing 15min, 0.05g friendships are added
Join PVP, continue, in 110-120 DEG C of insulation mixing 15min, to go after naturally cool to the 10g for adding equitemperature after 45-55 DEG C
Ionized water, is sufficiently stirred for rear stratification, and extraction, gained oil reservoir anhydrous sodium sulfate drying produces modified turpentine oil.
Reference examples 1
(1) 3g polyethylene glycol oxides and the acrylic acid of 2g dipentaerythrites six are added under grinding into 25g hydroxypropyl starch ethers
Ester, and in microwave treatment 5min under microwave frequency 2450MHz, power output 700W, 0.5g nano oxygens are added after standing 5min
Change zinc, continue microwave treatment 5min after being well mixed, stand microwave treatment 5min again after 5min, gained mixture is under milling
Room temperature is naturally cooled to, modified starch ether is produced；
(2) 1g poloxamers and 0.1g bimaleimide resins are added into 5g microcrystalline celluloses, and under milling with 5
DEG C/min programming rate is warming up to 110-120 DEG C of insulation grinding 30min, room temperature is naturally cooled to, modification of microcrystalline fiber is produced
Element；
(3) 0.5g molecular screen primary powders and 0.3g glass fiber powders are added into 10g hydrogenated castors oleic acid/polyglutamic acid,
70-80 DEG C of insulation mixing 10min is warming up to, modified starch ether, modified microcrystalline cellulose and 250g deionized waters is added, continues
It is warming up to reflux state insulation mixing 15min, and the concentrated adhesive agent that solid content 55-60% is made.
The preparation of hydrogenated castor oleic acid/polyglutamic acid：10g hydrogenated castors oleic acid is added with 5 DEG C/min firing rate
Heat to molten condition is incubated 5min, adds 10g polyglutamic acids, is sufficiently mixed after microwave frequency 2450MHz, power output
Microwave treatment 5min under 700W, stand 10min after continue microwave treatment 5min, then add 1gN- NMAs and
0.5g turpentine oil, microwave treatment 5min again after being well mixed, gained mixture is transferred to sealing and standing 5h in -15 DEG C of environment, most
Micro mist is made by micronizer, hydrogenated castor oleic acid/polyglutamic acid is produced.
Reference examples 2
(1) 3g polyethylene glycol oxides and the acrylic acid of 2g dipentaerythrites six are added under grinding into 25g hydroxypropyl starch ethers
Ester, and in microwave treatment 5min under microwave frequency 2450MHz, power output 700W, 0.5g nano oxygens are added after standing 5min
Change zinc, continue microwave treatment 5min after being well mixed, stand microwave treatment 5min again after 5min, gained mixture is under milling
Room temperature is naturally cooled to, modified starch ether is produced；
(2) 0.5g molecular screen primary powders and 0.3g glass fiber powders are added into 10g hydrogenated castors oleic acid/polyglutamic acid,
70-80 DEG C of insulation mixing 10min is warming up to, modified starch ether, 5g microcrystalline celluloses and 250g deionized waters is added, continues to rise
Temperature to reflux state insulation mixes 15min, and the concentrated adhesive agent that solid content 55-60% is made.
The preparation of hydrogenated castor oleic acid/polyglutamic acid：10g hydrogenated castors oleic acid is added with 5 DEG C/min firing rate
Heat to molten condition is incubated 5min, adds 10g polyglutamic acids, is sufficiently mixed after microwave frequency 2450MHz, power output
Microwave treatment 5min under 700W, stand 10min after continue microwave treatment 5min, then add 1gN- NMAs and
0.5g is modified turpentine oil, and microwave treatment 5min again after being well mixed, gained mixture is transferred to sealing and standing in -15 DEG C of environment
5h, is most made micro mist through micronizer afterwards, produces hydrogenated castor oleic acid/polyglutamic acid.
Modified terebinthine preparation：0.1g activated carbons are added into 2g turpentine oil, 8h is stood after being sufficiently mixed, are filtered, to
0.2g HPMAs are added in gained filtrate, and are heated to 110-120 DEG C of insulation mixing 15min, 0.05g friendships are added
Join PVP, continue, in 110-120 DEG C of insulation mixing 15min, to go after naturally cool to the 10g for adding equitemperature after 45-55 DEG C
Ionized water, is sufficiently stirred for rear stratification, and extraction, gained oil reservoir anhydrous sodium sulfate drying produces modified turpentine oil.
Reference examples 3
(1) 3g polyethylene glycol oxides and the acrylic acid of 2g dipentaerythrites six are added under grinding into 25g hydroxypropyl starch ethers
Ester, and in microwave treatment 5min under microwave frequency 2450MHz, power output 700W, 0.5g nano oxygens are added after standing 5min
Change zinc, continue microwave treatment 5min after being well mixed, stand microwave treatment 5min again after 5min, gained mixture is under milling
Room temperature is naturally cooled to, modified starch ether is produced；
(2) 1g poloxamers and 0.1g bimaleimide resins are added into 5g microcrystalline celluloses, and under milling with 5
DEG C/min programming rate is warming up to 110-120 DEG C of insulation grinding 30min, room temperature is naturally cooled to, modification of microcrystalline fiber is produced
Element；
(3) 0.5g molecular screen primary powders and 0.3g glass fiber powders are added into 5g hydrogenated castors oleic acid, 5g polyglutamic acids,
70-80 DEG C of insulation mixing 10min is warming up to, modified starch ether, modified microcrystalline cellulose and 250g deionized waters is added, continues
It is warming up to reflux state insulation mixing 15min, and the concentrated adhesive agent that solid content 55-60% is made.
Reference examples 4
(1) 1g poloxamers and 0.1g bimaleimide resins are added into 5g microcrystalline celluloses, and under milling with 5
DEG C/min programming rate is warming up to 110-120 DEG C of insulation grinding 30min, room temperature is naturally cooled to, modification of microcrystalline fiber is produced
Element；
(2) 0.5g molecular screen primary powders and 0.3g glass fiber powders are added into 10g hydrogenated castors oleic acid/polyglutamic acid,
70-80 DEG C of insulation mixing 10min is warming up to, 25g hydroxypropyl starch ethers, modified microcrystalline cellulose and 250g deionizations is added
Water, is continuously heating to reflux state insulation mixing 15min, and the concentrated adhesive agent that solid content 55-60% is made.
The preparation of hydrogenated castor oleic acid/polyglutamic acid：10g hydrogenated castors oleic acid is added with 5 DEG C/min firing rate
Heat to molten condition is incubated 5min, adds 10g polyglutamic acids, is sufficiently mixed after microwave frequency 2450MHz, power output
Microwave treatment 5min under 700W, stand 10min after continue microwave treatment 5min, then add 1gN- NMAs and
0.5g is modified turpentine oil, and microwave treatment 5min again after being well mixed, gained mixture is transferred to sealing and standing in -15 DEG C of environment
5h, is most made micro mist through micronizer afterwards, produces hydrogenated castor oleic acid/polyglutamic acid.
Modified terebinthine preparation：0.1g activated carbons are added into 2g turpentine oil, 8h is stood after being sufficiently mixed, are filtered, to
0.2g HPMAs are added in gained filtrate, and are heated to 110-120 DEG C of insulation mixing 15min, 0.05g friendships are added
Join PVP, continue, in 110-120 DEG C of insulation mixing 15min, to go after naturally cool to the 10g for adding equitemperature after 45-55 DEG C
Ionized water, is sufficiently stirred for rear stratification, and extraction, gained oil reservoir anhydrous sodium sulfate drying produces modified turpentine oil.
Embodiment 3
It is utilized respectively equivalent embodiment 1, embodiment 2, reference examples 1, reference examples 2, reference examples 3, the made adhesive agent of reference examples 4
On the stainless steel tableware that same label is pasted on to same specification, the adhesive strength after its 8h is determined, and after six months will be stainless
Steel tableware, which is put into water, soaks 15min, then peeling label, determines the residual quantity of adhesive agent, as a result as shown in table 1.
The embodiment of the present invention of table 1 and the performance of the made adhesive agent of reference examples
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (5)
1. a kind of stainless steel tableware, which dissipates to sell, uses label adhesive agent, it is characterised in that：It is made up of the raw material of following parts by weight：
15-25 parts of hydroxypropyl starch ether, hydrogenated castor oleic acid/5-10 parts of polyglutamic acid, 3-5 parts of microcrystalline cellulose, polyoxygenated
3-5 parts of ethene, 1-3 parts of six acrylate of dipentaerythrite, 1-3 parts of poloxamer, 0.5-2 parts of nano zine oxide, molecular sieve
Former powder 0.1-1 parts, 0.1-1 parts of glass fiber powder, 0.01-0.1 parts of bimaleimide resin, 150-250 parts of deionized water；
Its preparation method comprises the following steps：
(1) polyethylene glycol oxide and the acrylate of dipentaerythrite six are added under grinding into hydroxypropyl starch ether, and in microwave
Microwave treatment 5min under frequency 2450MHz, power output 700W, nano zine oxide is added after standing 5min, after being well mixed
Continue microwave treatment 5min, stand microwave treatment 5min again after 5min, gained mixture naturally cools to room temperature under milling,
Produce modified starch ether；
(2) poloxamer and bimaleimide resin are added into microcrystalline cellulose, and under milling with 5 DEG C/min heating
Speed is warming up to 110-120 DEG C of insulation grinding 30min, naturally cools to room temperature, produces modified microcrystalline cellulose；
(3) molecular screen primary powder and glass fiber powder are added into hydrogenated castor oleic acid/polyglutamic acid, 70-80 DEG C of guarantor is warming up to
Temperature mixing 10min, adds modified starch ether, modified microcrystalline cellulose and deionized water, is continuously heating to reflux state insulation
Mix 15min, and the concentrated adhesive agent that solid content 55-60% is made.
2. stainless steel tableware according to claim 1, which dissipates to sell, uses label adhesive agent, it is characterised in that：The rilanit special
The preparation method of acid/polyglutamic acid is：Hydrogenated castor oleic acid is heated to molten condition insulation with 5 DEG C/min firing rate
5min, adds polyglutamic acid, is sufficiently mixed after microwave treatment 5min under microwave frequency 2450MHz, power output 700W,
Stand and continue microwave treatment 5min after 10min, then add N hydroxymethyl acrylamide and modified turpentine oil, after being well mixed again
Secondary microwave treatment 5min, gained mixture is transferred to sealing and standing 5h in -15 DEG C of environment, and micro mist most is made through micronizer afterwards,
Produce hydrogenated castor oleic acid/polyglutamic acid.
3. stainless steel tableware according to claim 2, which dissipates to sell, uses label adhesive agent, it is characterised in that：The rilanit special
Acid, polyglutamic acid, N hydroxymethyl acrylamide and modified terebinthine mass ratio are 5-10:5-10:0.5-2:0.2-1.
4. stainless steel tableware according to claim 2, which dissipates to sell, uses label adhesive agent, it is characterised in that：The modified turpentine oil
Formed by turpentine oil through close fine modification, its method of modifying is：Activated carbon is added into turpentine oil, 8h, mistake are stood after being sufficiently mixed
Filter, HPMA is added into gained filtrate, and is heated to 110-120 DEG C of insulation mixing 15min, adds crosslinking poly-
Ketone is tieed up, is continued in 110-120 DEG C of insulation mixing 15min, after naturally cool to the deionized water that equitemperature is added after 45-55 DEG C,
Rear stratification is sufficiently stirred for, is extracted, gained oil reservoir anhydrous sodium sulfate drying produces modified turpentine oil.
5. stainless steel tableware according to claim 4, which dissipates to sell, uses label adhesive agent, it is characterised in that：The turpentine oil, work
Property charcoal, HPMA, PVPP, deionized water mass ratio be 1-3:0.1-0.5:0.1-0.5:0.05-
0.3:5-10。
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212985A (en) * | 1997-09-29 | 1999-04-07 | 中国科学院福建物质结构研究所 | Water-resistant adhesive for label |
| CN1220295A (en) * | 1997-12-17 | 1999-06-23 | 陈宝元 | Multifunctional trademark adhesive and its preparing method |
| WO2003014245A1 (en) * | 2001-08-03 | 2003-02-20 | National Starch And Chemical Investment Holding Coporation | Starch based adhesive |
| JP2017039815A (en) * | 2015-08-18 | 2017-02-23 | ミヨシ油脂株式会社 | Aqueous adhesive for cardboard and manufacturing method therefor, and cardboard sheet and manufacturing method therefor |
-
2017
- 2017-07-14 CN CN201710574649.8A patent/CN107189713B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1212985A (en) * | 1997-09-29 | 1999-04-07 | 中国科学院福建物质结构研究所 | Water-resistant adhesive for label |
| CN1220295A (en) * | 1997-12-17 | 1999-06-23 | 陈宝元 | Multifunctional trademark adhesive and its preparing method |
| WO2003014245A1 (en) * | 2001-08-03 | 2003-02-20 | National Starch And Chemical Investment Holding Coporation | Starch based adhesive |
| JP2017039815A (en) * | 2015-08-18 | 2017-02-23 | ミヨシ油脂株式会社 | Aqueous adhesive for cardboard and manufacturing method therefor, and cardboard sheet and manufacturing method therefor |
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| CN107189713B (en) | 2019-02-12 |
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