CN107189677A - A kind of environment-friendlyfireproof fireproof paint of container - Google Patents

A kind of environment-friendlyfireproof fireproof paint of container Download PDF

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Publication number
CN107189677A
CN107189677A CN201710365871.7A CN201710365871A CN107189677A CN 107189677 A CN107189677 A CN 107189677A CN 201710365871 A CN201710365871 A CN 201710365871A CN 107189677 A CN107189677 A CN 107189677A
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CN
China
Prior art keywords
parts
environment
polyurethane
carborundum
alchlor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710365871.7A
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Chinese (zh)
Inventor
刘承范
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Chengdu Association Technology Co Ltd
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Chengdu Association Technology Co Ltd
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Filing date
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Application filed by Chengdu Association Technology Co Ltd filed Critical Chengdu Association Technology Co Ltd
Priority to CN201710365871.7A priority Critical patent/CN107189677A/en
Publication of CN107189677A publication Critical patent/CN107189677A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, 80~120 parts of organic siliconresin, 60~100 parts of epoxy resin, 50~80 parts of asbestos fibre, 30~50 parts of expanded graphite, 20~40 parts of silica, 20~40 parts of carborundum, 30~50 parts of alchlor, 10~20 parts of attapulgite powder, 30~50 parts of polyurethane asphalt, 10~20 parts of laccol silicon, 50~80 parts of melamine, 40~60 parts of organophosphorus ester, 10~30 parts of borate, ethyl silicate 40~60 part, 20~40 parts of highly-chlorinated polyethylene, 10~30 parts of polyurethane, 5~20 parts of chlorinated paraffin.The present invention can effectively improve the fire protecting performance of container, extend the useful life of container.

Description

A kind of environment-friendlyfireproof fireproof paint of container
Technical field
The invention belongs to container technology field, more particularly to a kind of environment-friendlyfireproof fireproof paint of container.
Background technology
Container refers to specialize in the large-scale goods container being used in turn with some strength, rigidity and specification.Container energy The huge monster of tens tons of a load-carrying is enough allowed to realize standardization, and the ship being done step-by-step based on this in global range The logistics system that oceangoing ship, harbour, course line, highway, terminal, bridge, tunnel, multimodal transport match.Container is in transportation Middle to be corroded by adverse circumstances, such as high temperature or flame barbecue cause the service life of container to be restricted.
The content of the invention
It is an object of the invention to provide a kind of environment-friendlyfireproof fireproof paint of container, the fire line of container can be effectively improved Can, extend the useful life of container.
The technical scheme that the present invention is provided:
A kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, organic siliconresin 80~120 parts, 60~100 parts of epoxy resin, 50~80 parts of asbestos fibre, 30~50 parts of expanded graphite, silica 20~40 Part, 20~40 parts of carborundum, 30~50 parts of alchlor, 10~20 parts of attapulgite powder, 30~50 parts of polyurethane asphalt, laccol 10~20 parts of silicon, 50~80 parts of melamine, 40~60 parts of organophosphorus ester, 10~30 parts of borate, ethyl silicate 40~60 Part, 20~40 parts of highly-chlorinated polyethylene, 10~30 parts of polyurethane, 5~20 parts of chlorinated paraffin.
Further, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, 90~110 parts of organic siliconresin, epoxy 70~90 parts of resin, 60~70 parts of asbestos fibre, 35~45 parts of expanded graphite, 25~35 parts of silica, carborundum 25~30 Part, 35~45 parts of alchlor, 12~15 parts of attapulgite powder, 35~40 parts of polyurethane asphalt, 12~15 parts of laccol silicon, trimerization 60~70 parts of cyanamide, 45~55 parts of organophosphorus ester, 15~25 parts of borate, 45~55 parts of silester, highly-chlorinated polyethylene 25~30 parts, 13~27 parts of polyurethane, 7~18 parts of chlorinated paraffin.
Further, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, 95~105 parts of organic siliconresin, epoxy 75~85 parts of resin, 62~68 parts of asbestos fibre, 40~42 parts of expanded graphite, 27~30 parts of silica, carborundum 28~32 Part, 37~43 parts of alchlor, 13~14 parts of attapulgite powder, 36~38 parts of polyurethane asphalt, 13~14 parts of laccol silicon, trimerization 62~67 parts of cyanamide, 46~50 parts of organophosphorus ester, 17~22 parts of borate, 48~51 parts of silester, highly-chlorinated polyethylene 27~32 parts, 14~25 parts of polyurethane, 8~11 parts of chlorinated paraffin.
Further, the preparation method of the Environment-friendlyfire-retardant fire-retardant paint comprises the following steps:
A, expanded graphite, silica, carborundum, alchlor, attapulgite powder crushed and mixed, mixed Close powder;
B, addition organic siliconresin, epoxy resin, asbestos fibre, melamine, organophosphorus ester, boric acid into reactor Salt, silester, highly-chlorinated polyethylene, polyurethane, 15 minutes~30 points are stirred with 800 revs/min~1000 revs/min of speed Clock;
C, into reactor add expanded graphite, silica, carborundum, alchlor, attapulgite powder, with 700 turns/ ~1000 revs/min of speed is divided to stir 10 minutes~20 minutes;
D, addition chlorinated paraffin, polyurethane asphalt, laccol silicon into reactor, with 800 revs/min~1000 revs/min of speed Degree stirring 10 minutes~16 minutes.
Further, the expanded graphite, silica, carborundum, alchlor, attapulgite powder are crushed to 100- 200 mesh.
The present invention has the advantages that at least one of following:
The one, present invention, which can be improved effectively, can effectively improve the fire protecting performance of container, extend the use of container Time limit.
Two, Environmental Safety of the present invention, the bad air such as release formaldehyde, is not conducive to loading food and the peace of other goods Entirely.
Three, coating produced by the present invention is uniform, fine and smooth, and smooth, adhesion is strong.
Embodiment
Embodiment 1
A kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, organic siliconresin 80 parts, 60 parts of epoxy resin, 50 parts of asbestos fibre, 30 parts of expanded graphite, 20 parts of silica, 20 parts of carborundum, alchlor 30 parts, 10 parts of attapulgite powder, 30 parts of polyurethane asphalt, 10 parts of laccol silicon, 50 parts of melamine, 40 parts of organophosphorus ester, boron 10 parts of hydrochlorate, ethyl silicate 40 part, 20 parts of highly-chlorinated polyethylene, 10 parts of polyurethane, 5 parts of chlorinated paraffin.
Embodiment 2
A kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, organic siliconresin 120 parts, 100 parts of epoxy resin, 80 parts of asbestos fibre, 50 parts of expanded graphite, 40 parts of silica, 40 parts of carborundum, three oxidation 50 parts of aluminium, 20 parts of attapulgite powder, 50 parts of polyurethane asphalt, 20 parts of laccol silicon, 80 parts of melamine, 60 parts of organophosphorus ester, 30 parts of borate, 60 parts of silester, 40 parts of highly-chlorinated polyethylene, 30 parts of polyurethane, 20 parts of chlorinated paraffin.
Embodiment 3
A kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, organic siliconresin 90 parts, 70 parts of epoxy resin, 60 parts of asbestos fibre, 35 parts of expanded graphite, 25 parts of silica, 25 parts of carborundum, alchlor 35 parts, 12 parts of attapulgite powder, 35 parts of polyurethane asphalt, 12 parts of laccol silicon, 60 parts of melamine, 45 parts of organophosphorus ester, boron 15 parts of hydrochlorate, 45 parts of silester, 25 parts of highly-chlorinated polyethylene, 13 parts of polyurethane, 7 parts of chlorinated paraffin.
Embodiment 4
A kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, organic siliconresin 110 parts, 90 parts of epoxy resin, 70 parts of asbestos fibre, 45 parts of expanded graphite, 35 parts of silica, 30 parts of carborundum, alchlor 45 parts, 15 parts of attapulgite powder, 40 parts of polyurethane asphalt, 15 parts of laccol silicon, 70 parts of melamine, 55 parts of organophosphorus ester, boron 25 parts of hydrochlorate, 55 parts of silester, 30 parts of highly-chlorinated polyethylene, 27 parts of polyurethane, 18 parts of chlorinated paraffin.
Embodiment 5
A kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, organic siliconresin 95 parts, 75 parts of epoxy resin, 62 parts of asbestos fibre, 40 parts of expanded graphite, 27 parts of silica, 28 parts of carborundum, alchlor 37 parts, 13 parts of attapulgite powder, 36 parts of polyurethane asphalt, 13 parts of laccol silicon, 62 parts of melamine, 46 parts of organophosphorus ester, boron 17 parts of hydrochlorate, 48 parts of silester, 27 parts of highly-chlorinated polyethylene, 14 parts of polyurethane, 8 parts of chlorinated paraffin.
The preparation method of the Environment-friendlyfire-retardant fire-retardant paint comprises the following steps:
A, expanded graphite, silica, carborundum, alchlor, attapulgite powder crushed and mixed, mixed Close powder;Wherein, the expanded graphite, silica, carborundum, alchlor, attapulgite powder are crushed to 100 mesh;
B, addition organic siliconresin, epoxy resin, asbestos fibre, melamine, organophosphorus ester, boric acid into reactor Salt, silester, highly-chlorinated polyethylene, polyurethane, are stirred 15 minutes with 800 revs/min of speed;
C, into reactor add expanded graphite, silica, carborundum, alchlor, attapulgite powder, with 700 turns/ The speed divided is stirred 10 minutes;
D, addition chlorinated paraffin, polyurethane asphalt, laccol silicon into reactor, 10 points are stirred with 800 revs/min of speed Clock.
Embodiment 6
A kind of environment-friendlyfireproof fireproof paint of container, the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, organic siliconresin 105 parts, 85 parts of epoxy resin, 68 parts of asbestos fibre, 42 parts of expanded graphite, 30 parts of silica, 32 parts of carborundum, alchlor 43 parts, 14 parts of attapulgite powder, 38 parts of polyurethane asphalt, 14 parts of laccol silicon, 67 parts of melamine, 50 parts of organophosphorus ester, boron 22 parts of hydrochlorate, 51 parts of silester, 32 parts of highly-chlorinated polyethylene, 25 parts of polyurethane, 11 parts of chlorinated paraffin.
The preparation method of the Environment-friendlyfire-retardant fire-retardant paint comprises the following steps:
A, expanded graphite, silica, carborundum, alchlor, attapulgite powder crushed and mixed, mixed Close powder;Wherein, the expanded graphite, silica, carborundum, alchlor, attapulgite powder are crushed to 200 mesh;
B, addition organic siliconresin, epoxy resin, asbestos fibre, melamine, organophosphorus ester, boric acid into reactor Salt, silester, highly-chlorinated polyethylene, polyurethane, are stirred 30 minutes with 1000 revs/min of speed;
C, addition expanded graphite, silica, carborundum, alchlor, attapulgite powder into reactor, with 1000 Rev/min speed stir 20 minutes;
D, addition chlorinated paraffin, polyurethane asphalt, laccol silicon into reactor, 16 points are stirred with 1000 revs/min of speed Clock.
The environment-friendlyfireproof fireproof paint of embodiment 1~6 is subjected to performance test, its result is as shown in table 1.Make according to the method described above Standby environment-friendlyfireproof fireproof paint, physical properties index all meets or exceeds coating container professional standard, and middle semihard is dried Time is shorter, and volume solids content is higher, and paint film flexibility is more preferable.
The coating property table of 1 embodiment of table 1~6
The environment-friendlyfireproof fireproof paint of embodiment 1~6 is subjected to fire protecting performance test, its result is as shown in table 2.According to above-mentioned side Environment-friendlyfireproof fireproof paint prepared by method, with excellent fire prevention and water resistance.
The coating fire protecting performance table of 2 embodiment of table 1~6
Technological project is introduced:
The resistance to combustion time:Under defined base material and specific burning condition, test plate (panel) unexposed surface temperature reaches 220 DEG C or test plate (panel) goes out The time required to now penetrating (min).
Flame propagation ratio:When the flame propagation ratio of asbestos board is " 0 ", the flame propagation ratio of Oak Tree plank is When " 100 ", the surface characteristics of flame data that subject material has.
Fire resistances:Lost with burning quality, be carbonized volume to represent.
Mass loss:Test specimen is under regulation coating ratio and regulation burning condition, the difference (g) of quality before and after burning.
Char volume:Test specimen is under regulation coating ratio and defined burning condition, maximum length that base material is carbonized, most Product (the cm of big width and depth capacity3)。
The resistance to combustion time:Tested by GB/T15442.2 regulation.
Flame propagation ratio:Tested by GB/T15442.3 regulation.
Fire retardance:Tested by GB/T15442.4 regulation.

Claims (5)

1. a kind of environment-friendlyfireproof fireproof paint of container, it is characterised in that the raw material of the Environment-friendlyfire-retardant fire-retardant paint, including, by weight, have 80~120 parts of machine silicones, 60~100 parts of epoxy resin, 50~80 parts of asbestos fibre, 30~50 parts of expanded graphite, titanium dioxide 20~40 parts of silicon, 20~40 parts of carborundum, 30~50 parts of alchlor, 10~20 parts of attapulgite powder, polyurethane asphalt 30~ 50 parts, 10~20 parts of laccol silicon, 50~80 parts of melamine, 40~60 parts of organophosphorus ester, 10~30 parts of borate, silicic acid second 40~60 parts of ester, 20~40 parts of highly-chlorinated polyethylene, 10~30 parts of polyurethane, 5~20 parts of chlorinated paraffin.
2. the environment-friendlyfireproof fireproof paint of a kind of container according to claim 1, it is characterised in that the Environment-friendlyfire-retardant fire-retardant paint Raw material, including, by weight, 90~110 parts of organic siliconresin, 70~90 parts of epoxy resin, 60~70 parts of asbestos fibre, expansion 35~45 parts of graphite, 25~35 parts of silica, 25~30 parts of carborundum, 35~45 parts of alchlor, attapulgite powder 12~ 15 parts, 35~40 parts of polyurethane asphalt, 12~15 parts of laccol silicon, 60~70 parts of melamine, 45~55 parts of organophosphorus ester, boron 15~25 parts of hydrochlorate, 45~55 parts of silester, 25~30 parts of highly-chlorinated polyethylene, 13~27 parts of polyurethane, chlorinated paraffin 7~ 18 parts.
3. the environment-friendlyfireproof fireproof paint of a kind of container according to claim 1, it is characterised in that the Environment-friendlyfire-retardant fire-retardant paint Raw material, including, by weight, 95~105 parts of organic siliconresin, 75~85 parts of epoxy resin, 62~68 parts of asbestos fibre, expansion 40~42 parts of graphite, 27~30 parts of silica, 28~32 parts of carborundum, 37~43 parts of alchlor, attapulgite powder 13~ 14 parts, 36~38 parts of polyurethane asphalt, 13~14 parts of laccol silicon, 62~67 parts of melamine, 46~50 parts of organophosphorus ester, boron 17~22 parts of hydrochlorate, 48~51 parts of silester, 27~32 parts of highly-chlorinated polyethylene, 14~25 parts of polyurethane, chlorinated paraffin 8~ 11 parts.
4. the environment-friendlyfireproof fireproof paint of a kind of container according to claim 1, it is characterised in that the Environment-friendlyfire-retardant fire-retardant paint Preparation method comprises the following steps:
A, expanded graphite, silica, carborundum, alchlor, attapulgite powder crushed and mixed, mixed Powder;
B, into reactor add organic siliconresin, epoxy resin, asbestos fibre, melamine, organophosphorus ester, borate, Silester, highly-chlorinated polyethylene, polyurethane, are stirred 15 minutes~30 minutes with 800 revs/min~1000 revs/min of speed;
C, into reactor add expanded graphite, silica, carborundum, alchlor, attapulgite powder, with 700 revs/min~ 1000 revs/min of speed is stirred 10 minutes~20 minutes;
D, addition chlorinated paraffin, polyurethane asphalt, laccol silicon into reactor, are stirred with 800 revs/min~1000 revs/min of speed Mix 10 minutes~16 minutes.
5. the environment-friendlyfireproof fireproof paint of a kind of container according to claim 1, it is characterised in that the expanded graphite, two Silica, carborundum, alchlor, attapulgite powder are crushed to 100-200 mesh.
CN201710365871.7A 2017-05-19 2017-05-19 A kind of environment-friendlyfireproof fireproof paint of container Pending CN107189677A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710365871.7A CN107189677A (en) 2017-05-19 2017-05-19 A kind of environment-friendlyfireproof fireproof paint of container

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710365871.7A CN107189677A (en) 2017-05-19 2017-05-19 A kind of environment-friendlyfireproof fireproof paint of container

Publications (1)

Publication Number Publication Date
CN107189677A true CN107189677A (en) 2017-09-22

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173667A (en) * 2011-01-25 2011-09-07 常州工程职业技术学院 Non-intumescent fireproofing coating and preparation method thereof
CN105694566A (en) * 2016-03-08 2016-06-22 杨超 Fire-retardant coating for ultrathin steel structure
CN105778755A (en) * 2016-03-08 2016-07-20 杨超 Method for preparing ultrathin formed steel structure fireproof coating
CN106219090A (en) * 2016-07-28 2016-12-14 江苏昌悦重工科技有限公司 The fire-resistant special container of anticorrosion
CN106590258A (en) * 2016-12-24 2017-04-26 严志海 Steel structure fireproof paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173667A (en) * 2011-01-25 2011-09-07 常州工程职业技术学院 Non-intumescent fireproofing coating and preparation method thereof
CN105694566A (en) * 2016-03-08 2016-06-22 杨超 Fire-retardant coating for ultrathin steel structure
CN105778755A (en) * 2016-03-08 2016-07-20 杨超 Method for preparing ultrathin formed steel structure fireproof coating
CN106219090A (en) * 2016-07-28 2016-12-14 江苏昌悦重工科技有限公司 The fire-resistant special container of anticorrosion
CN106590258A (en) * 2016-12-24 2017-04-26 严志海 Steel structure fireproof paint

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Application publication date: 20170922