CN107189027B - A kind of cashew nut phenol-furfural resin and a kind of paint - Google Patents
A kind of cashew nut phenol-furfural resin and a kind of paint Download PDFInfo
- Publication number
- CN107189027B CN107189027B CN201710146135.2A CN201710146135A CN107189027B CN 107189027 B CN107189027 B CN 107189027B CN 201710146135 A CN201710146135 A CN 201710146135A CN 107189027 B CN107189027 B CN 107189027B
- Authority
- CN
- China
- Prior art keywords
- paint
- cashew nut
- weight
- parts
- furfural
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of furfural
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention provides a kind of preparation methods of cashew nut phenol-furfural resin, comprising: by anacardol and furfural under the catalytic action of solid acid, reacts after heating, obtains cashew nut phenol-furfural resin.Present invention also provides a kind of paints, comprising: vegetable active extracting solution, cashew nut phenol-furfural resin, drier, defoaming agent, levelling agent and dispersing agent.Main component of the application using environment-friendly type component cashew nut phenol-furfural resin as paint, it is under the dilution of environment protecting plant solvent, it is subject to the effect of drier again, the paint made oxidation filming under the action of oxygen in air, the more long the paint film time of formation the firmer, it further include simultaneously defoaming agent in paint, dispersing agent and levelling agent, above-mentioned auxiliary agent is with cashew nut phenol-furfural resin collectively as the component of paint, make paint good luster, weather resistance is good, it does not include simultaneously formaldehyde in the paint of the application, the Chemical Solvents of benzene class, the feature of environmental protection is preferable.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of cashew nut phenol-furfural resins and a kind of paint.
Background technique
Currently, paint industry generally faces problem of environmental pollution, the paint of chemical industry synthesis is due to using a large amount of stone
Oil product, such as benzene, formaldehyde, dimethylbenzene etc. petroleum solvent is very big to environmental hazard, and for the body of constructing operation person
Also injury is generated.
Natural lacquer is a kind of natural resin coating, is to cut open sumac bark, viscous from a kind of white of tough intradermal outflow
Property lotion, the coating to process from strand.Natural lacquer belongs to pure natural product, will not cause damages to environment, but due to
Lacquer tree is fewer and fewer, and production paint amount, which is difficult to meet, is growing the market demand.
Release a wood wax oil now in the market, primary raw material with refine the crude vegetals such as linseed oil, palm wax with
Vegetable wax simultaneously cooperates some other natural component to merge, and toning pigment used has also reached food-grade, therefore it is not
It is a environment-friendly products containing toxic components such as dimethylbenzene, formaldehyde and heavy metals.But wood wax oil protects not timber-work
Foot, not solvent resistant, weatherability is inadequate, and product service life is short.Because of the present circumstance, it is urgent to provide a kind of environmental protection and the oil of better performances
Paint coating.
Summary of the invention
Present invention solves the technical problem that being to provide a kind of environmentally friendly and better performances paint.
In view of this, this application provides a kind of preparation methods of cashew nut phenol-furfural resin, comprising:
It by anacardol and furfural under the catalytic action of solid acid, is reacted after heating, obtains cashew nut phenol-furfural resin.
Preferably, the molar ratio of the anacardol and furfural is 1:(1~3).
Preferably, the solid acid is selected from sulfated zirconia, phosphotungstic acid, WO3-ZrO2One of with ZSM-5 molecular sieve
Or it is a variety of.
Preferably, the temperature of the heating is 60~120 DEG C.
Present invention also provides a kind of paints, comprising: preparation method described in vegetable active extracting solution, above scheme
Prepared cashew nut phenol-furfural resin, drier, defoaming agent, levelling agent and dispersing agent.
Preferably, the content of the vegetable active extracting solution is 8~25 parts by weight, the content of the cashew nut phenol-furfural resin
For 65~85 parts by weight, the content of the drier is 0.3~3 parts by weight, and the content of the defoaming agent is 0.3~3 parts by weight,
The content of the levelling agent is 0.3~3 parts by weight, and the content of the dispersing agent is 0.3~3 parts by weight.
It preferably, further include the powder of 0~40 parts by weight in the paint.
Preferably, the vegetable active extracting solution is selected from walnut oil or orange oil.
Preferably, the content of the cashew nut phenol-furfural resin is 70~85 parts by weight.
Preferably, the content of the vegetable active extracting solution is 10~20 parts by weight.
This application provides a kind of preparation methods of cashew nut phenol-furfural resin, use anacardol to be used as with furfural and react former
Material, under the catalytic action of solid acid, anacardol reacts with furfural, and has obtained cashew nut phenol-furfural resin.The application with
Main component of the cashew nut phenol-furfural resin as paint, since anacardol and furfural are biomass materials, then anacardol
Furfural resin is a kind of environment-friendly type component, under the dilution of environment protecting plant solvent, then is subject to the effect of drier, makes
Paint oxidation filming under the action of oxygen in air, the more long the paint film time of formation the firmer, while in paint
It further include defoaming agent, dispersing agent and levelling agent, above-mentioned auxiliary agent and cashew nut phenol-furfural resin make collectively as the component of paint
Paint good luster, weather resistance are good, while not including the Chemical Solvents of formaldehyde, benzene class, ring in the paint of the application
Guarantor property is preferable.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still
It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention
Limitation.
The embodiment of the invention discloses a kind of preparation methods of cashew nut phenol-furfural resin, comprising:
It by anacardol and furfural under the catalytic action of solid acid, is reacted after heating, obtains cashew nut phenol-furfural resin.
The application provides firstly the preparation method of cashew nut phenol-furfural resin, uses biomass material-anacardol and chaff
For aldehyde as raw material, the cashew nut phenol-furfural resin being prepared has preferable environment-friendly type.
During preparing cashew nut phenol-furfural resin, the anacardol be natural plants waste cashew nut shell in extract
, it is a kind of reproducible resource；For anacardol due to its distinctive molecular structure, molecular weight is bigger, makes the waist being prepared
Fruit phenol-furfural resin has good weatherability.The furfural is extracted from the corncob of natural plants corn.The application
The anacardol is not particularly limited with furfural, is the waste of agricultural product, the application uses anacardol and furfural
As raw material, plant waste is rationally utilized, also solves the problems, such as environmental pollution.The molar ratio of the anacardol and furfural
Preferably 1:(1~3), the molar ratio of the anacardol and furfural directly affects the structure of resin, soft or hard degree and crosslinking journey
Degree etc., the final hardness for influencing paint film；If anacardol ratio is high, the resin hardness formed is high, otherwise hardness is low.
The anacardol and furfural are the polycondensation reactions occurred under the catalytic action of solid acid, and the solid acid is ability
Solid acid known to field technique personnel is not particularly limited this application, in order to make anacardol and furfurol reaction more
Sufficiently, the solid acid is preferably selected from sulfated zirconia, phosphotungstic acid, WO3-ZrO2With one of ZSM-5 molecular sieve or more
Kind.The utilization of the solid acid reduces the pollution to the burn into environment of equipment, while also reducing cost.
In order to keep reaction more abundant, and influence of the impurity to cashew nut phenol-furfural resin is reduced, the application is preferably first by waist
Fruit phenol is mixed with solid acid, adds furfural, specifically:
Anacardol is mixed with furfural, is passed through nitrogen, then is warming up to 60~120 DEG C, furfuryl aldehyde solution is added dropwise in 1h.
After reacting, obtained product is carried out to conventional post-processing, it is exemplary, obtained product is used 50
~60 DEG C of hot water washings, stratification remove residual moisture under reduced pressure after removing water layer to get cashew nut phenol-furfural resin is arrived.
The cashew nut phenol-furfural resin of the application preparation since the raw material of use is plant waste-anacardol and furfural, because
Chemical Solvents in this cashew nut phenol-furfural resin without formaldehyde, benzene class, not will cause as paint to environment and people
Body damages.The present invention also provides a kind of paints as a result, comprising:
Cashew nut phenol-furfural resin prepared by preparation method described in vegetable active extracting solution, above scheme, disappears at drier
Infusion, levelling agent and dispersing agent.
The paint of the application wants ingredient based on cashew nut phenol-furfural resin, in the dilute of environment protecting plant active extract
It releases down, under the action of drier, paint oxidation filming under the action of oxygen in air, while in defoaming agent, levelling
Under the action of agent and dispersing agent, the more long the paint film time that obtained paint is formed the firmer, and formaldehyde, benzene are free of in product
The Chemical Solvents of class will not pollute atmosphere.
According to the present invention, the vegetable active extracting solution be used to adjust cashew nut phenol-furfural resin in paint it is solid containing with
Viscosity.Herein described vegetable active extracting solution is extracting solution well known to those skilled in the art, not special to this application
Limitation, exemplary, the vegetable active extracting solution is preferably walnut oil or orange oil.The content of the vegetable active extracting solution is excellent
It is selected as 8~25 parts by weight, more preferably 10~20 parts by weight.
Key component of the cashew nut phenol-furfural resin described herein as paint, content are preferably 65~85 weights
Part is measured, in embodiment, the content of the cashew nut phenol-furfural resin is more preferably 70~85 parts by weight.
It further include auxiliary agent in herein described paint, the auxiliary agent is specially drier, dispersing agent, levelling agent and disappears
Infusion, wherein the drier is used to accelerate the oxidation, polymerization, drying of paint film, achievees the purpose that quick-drying.The drier is
Drier well known to those skilled in the art, it is exemplary, the drier be specially one of organotin and cyclic potassium naphthenate or
Two kinds.The content of the drier is preferably 0.3~3 parts by weight, and in embodiment, the content of the drier is more preferably
1.0~3.0 parts by weight.The defoaming agent, levelling agent and dispersing agent are auxiliary agent well known to those skilled in the art, to this this Shen
It please be not particularly limited, exemplary, the defoaming agent is preferably brokenly bubble polymer or polysiloxane solution, and the levelling agent is excellent
It is selected as organic silicon modified by polyether, the dispersing agent is preferably the high-molecular-weight poly carboxylic acid amine aqueous solution containing modified polyorganosiloxane.It is described
The content of defoaming agent is preferably 0.3~3.0 parts by weight, more preferably 0.5~2.1 parts by weight；The levelling agent is preferably 0.3~
3.0 parts by weight, more preferably 0.4~2.3 parts by weight；The content of the dispersing agent is preferably 0.3~3.0 parts by weight, more preferably
For 0.4~1.8 parts by weight.In order to make paint that there is preferable filling capacity, in herein described paint further preferably
Powder including 0~40 parts by weight, the content of the powder are more preferably 8~25 parts by weight, and the powder is preferably 1250 mesh
Talcum powder.
The application provides firstly a kind of preparation method of cashew nut phenol-furfural resin, uses anacardol and furfural as anti-
Raw material is answered, under the catalytic action of solid acid, anacardol reacts with furfural, and has obtained cashew nut phenol-furfural resin.?
To on the basis of cashew nut phenol-furfural resin, main component of the application using cashew nut phenol-furfural resin as paint, due to waist
Fruit phenol and furfural are biomass materials, then cashew nut phenol-furfural resin is a kind of environment-friendly type component, in environment protecting plant solvent
Under dilution, then it is subject to the effect of drier, the paint made oxidation filming under the action of oxygen in air, formation
The more long the paint film time the firmer, while further including defoaming agent, dispersing agent and levelling agent in paint, above-mentioned auxiliary agent and anacardol
Furfural resin keeps paint good luster, weather resistance good collectively as the component of paint, while the paint of the application applies
It does not include the Chemical Solvents of formaldehyde, benzene class in material, the feature of environmental protection is preferable.
For a further understanding of the present invention, below with reference to embodiment pair, the system of cashew nut phenol-furfural resin provided by the invention
Preparation Method is described in detail with paint, and protection scope of the present invention is not limited by the following examples.
Raw material in following embodiment is commercial product.
Embodiment 1
With blender, spherical condensation tube, constant pressure funnel and thermometer 250mL four-hole boiling flask in, respectively plus
Enter 100.0g anacardol and the solid acid sulfated zirconia of 0.001g, then is passed through N2The air in reaction system is excluded, is being stirred
Mix down and be warming up to 60~120 DEG C, be slowly added dropwise the furfuryl aldehyde solution 100ml of metering in 1h, back flow reaction 1.5h, product with 50~
60 DEG C of hot water washings, stratification remove residual moisture under reduced pressure after removing water layer, obtain brownish red thick liquid, i.e. anacardol
Phenolic resin (CDF).
Embodiment 2
With blender, spherical condensation tube, constant pressure funnel and thermometer 250mL four-hole boiling flask in, respectively plus
Enter 100.0g anacardol and the solid acid (phosphotungstic acid, WO3-ZrO2 and ZSM-5) of 0.001g, then is passed through N2It excludes in reaction system
Air, be warming up to 60~120 DEG C under stiring, the furfuryl aldehyde solution 75ml of metering, back flow reaction 1h be slowly added dropwise in 1h, produce
Object is washed with 50~60 DEG C of hot water, stratification, is removed residual moisture under reduced pressure after removing water layer, is obtained brownish red thick liquid,
That is anacardol phenolic resin (CDF).
Embodiment 3
Cashew nut phenol-furfural resin prepared by the embodiment 1 of 70 parts by weight, the walnut oil of 20 parts by weight, the powder of 8 parts by weight
The levelling agent of material, the drier (organotin) of 1 parts by weight, the defoaming agent (brokenly bubble polymer) of 0.3 parts by weight, 0.3 parts by weight is (poly-
Ether modified organic silicon) it is mixed with the dispersing agent (the high-molecular-weight poly carboxylic acid amine aqueous solution containing modified polyorganosiloxane) of 0.4 parts by weight, it obtains
To paint.
Embodiment 4
Cashew nut phenol-furfural resin prepared by the embodiment 2 of 70 parts by weight, the orange oil of 20 parts by weight, the powder of 8 parts by weight,
The drier (cyclic potassium naphthenate) of 1 parts by weight, the defoaming agent (polysiloxane solution) of 0.3 parts by weight, the levelling agent of 0.3 parts by weight
The dispersing agent (the high-molecular-weight poly carboxylic acid amine aqueous solution containing modified polyorganosiloxane) of (organic silicon modified by polyether) and 0.4 parts by weight disperses
Uniformly, paint is obtained, paint is brushed to spraying on timber-work.
Embodiment 5
Cashew nut phenol-furfural resin prepared by the embodiment 2 of 85 parts by weight, the walnut oil of 13 parts by weight, 1 parts by weight are urged
Dry agent (organotin), the defoaming agent (brokenly bubble polymer) of 0.3 parts by weight, the levelling agent (organic silicon modified by polyether) of 0.3 parts by weight
It is uniformly dispersed with the dispersing agent (the high-molecular-weight poly carboxylic acid amine aqueous solution containing modified polyorganosiloxane) of 0.4 parts by weight, obtains paint and apply
Paint, is brushed spraying by material on timber-work.
Embodiment 6
Cashew nut phenol-furfural resin prepared by the embodiment 1 of 85 parts by weight, the orange oil of 13 parts by weight, urging for 1 parts by weight are dry
Agent, the defoaming agent of 0.3 parts by weight, the levelling agent of 0.3 parts by weight and the dispersing agent of 0.4 parts by weight are uniformly dispersed, and obtain paint and apply
Paint, is brushed spraying by material on timber-work.
According to the detection means detection embodiment 3 and the paint of the preparation of embodiment 5 of this field detection paint
Performance, while using the lacquer of this field routine and wood wax oil as comparative example, testing result is as described in Table 1:
The performance data table of the paint of 1 embodiment of table and comparative example
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvements and modifications, these improvements and modifications also fall within the scope of protection of the claims of the present invention.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (8)
1. a kind of paint, comprising: vegetable active extracting solution, cashew nut phenol-furfural resin, drier, defoaming agent, levelling agent with
Dispersing agent；
The preparation method of the cashew nut phenol-furfural resin, comprising:
It by anacardol and furfural under the catalytic action of solid acid, is reacted after heating, obtains cashew nut phenol-furfural resin；
The vegetable active extracting solution is selected from walnut oil or orange oil.
2. paint according to claim 1, which is characterized in that the molar ratio of the anacardol and furfural be 1:(1~
3)。
3. paint according to claim 1, which is characterized in that the solid acid is selected from sulfated zirconia, phosphorus tungsten
Acid, WO3-ZrO2With one of ZSM-5 molecular sieve or a variety of.
4. paint according to claim 1, which is characterized in that the temperature of the heating is 60~120 DEG C.
5. paint according to claim 1, which is characterized in that the content of the vegetable active extracting solution is 8~25
Parts by weight, the content of the cashew nut phenol-furfural resin are 65~85 parts by weight, and the content of the drier is 0.3~3 parts by weight,
The content of the defoaming agent is 0.3~3 parts by weight, and the content of the levelling agent is 0.3~3 parts by weight, and the dispersing agent contains
Amount is 0.3~3 parts by weight.
6. paint according to claim 1, which is characterized in that further include 0~40 parts by weight in the paint
Powder.
7. paint according to claim 1, which is characterized in that the content of the cashew nut phenol-furfural resin is 70~85
Parts by weight.
8. paint according to claim 1, which is characterized in that the content of the vegetable active extracting solution is 10~20
Parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710146135.2A CN107189027B (en) | 2017-03-13 | 2017-03-13 | A kind of cashew nut phenol-furfural resin and a kind of paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710146135.2A CN107189027B (en) | 2017-03-13 | 2017-03-13 | A kind of cashew nut phenol-furfural resin and a kind of paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107189027A CN107189027A (en) | 2017-09-22 |
| CN107189027B true CN107189027B (en) | 2019-04-19 |
Family
ID=59870913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710146135.2A Expired - Fee Related CN107189027B (en) | 2017-03-13 | 2017-03-13 | A kind of cashew nut phenol-furfural resin and a kind of paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107189027B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190768A (en) * | 2010-03-06 | 2011-09-21 | 徐州工业职业技术学院 | Method for preparing cumylphenol formaldehyde resin through catalysis of macroporous strongly acidic cation exchange resin |
| CN103073690A (en) * | 2013-01-21 | 2013-05-01 | 卡德莱化工(珠海)有限公司 | Cashew nut shell oil-modified phenolic resin as well as preparation method and application thereof |
| CN103619892A (en) * | 2011-06-03 | 2014-03-05 | 三菱瓦斯化学株式会社 | Phenolic resin and material for forming underlayer film for lithography |
| CN106380887A (en) * | 2016-09-27 | 2017-02-08 | 中国林业科学研究院林产化学工业研究所 | Preparation method of lignin-base phenolic aldehyde molding compound |
-
2017
- 2017-03-13 CN CN201710146135.2A patent/CN107189027B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190768A (en) * | 2010-03-06 | 2011-09-21 | 徐州工业职业技术学院 | Method for preparing cumylphenol formaldehyde resin through catalysis of macroporous strongly acidic cation exchange resin |
| CN103619892A (en) * | 2011-06-03 | 2014-03-05 | 三菱瓦斯化学株式会社 | Phenolic resin and material for forming underlayer film for lithography |
| CN103073690A (en) * | 2013-01-21 | 2013-05-01 | 卡德莱化工(珠海)有限公司 | Cashew nut shell oil-modified phenolic resin as well as preparation method and application thereof |
| CN106380887A (en) * | 2016-09-27 | 2017-02-08 | 中国林业科学研究院林产化学工业研究所 | Preparation method of lignin-base phenolic aldehyde molding compound |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107189027A (en) | 2017-09-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Blaiszik et al. | Microcapsules filled with reactive solutions for self-healing materials | |
| CN105968705A (en) | Silicon/boron-modified phenolic resin and preparation method thereof | |
| Ollier et al. | Microencapsulation of epoxy resins: optimization of synthesis conditions | |
| CN106010186B (en) | A kind of pervious concrete pavement protective agent and preparation method thereof | |
| CN106928813A (en) | A kind of preparation method of the cross-linking aqueous epoxy coating of antibacterial colloidal sol | |
| Gupta et al. | Synthesis of a novel limonene based mannich polyol for rigid polyurethane foams | |
| CN102432743A (en) | Polymer emulsion for waterborne metal anticorrosive coating and preparation method of polymer emulsion | |
| CN105505124A (en) | Water-dilutability epoxy woodware transparent primer and preparing method thereof | |
| CN101508865A (en) | Solvent-free cardanol epoxy heavy-duty antiseptic paint and method for producing the same | |
| CN105504214B (en) | A kind of preparation method of biomass polyurethane electrophoresis resin and its electrophoretic paint | |
| CN105418848B (en) | A kind of method that boron trifluoride catalysis prepares C5 Petropols | |
| Wang et al. | Synthesis of novolac‐type phenolic resins using glucose as the substitute for formaldehyde | |
| CN102633989B (en) | Non-ionic active epoxy emulsifier preparation method and waterborne epoxy resin preparation method | |
| CN107189027B (en) | A kind of cashew nut phenol-furfural resin and a kind of paint | |
| CN104356925A (en) | Low-odor polyurethane open white primer and preparation method thereof | |
| CN109337501A (en) | The preparation method of anticorrosive paint based on benzoxazine resin | |
| CN108148163A (en) | A kind of preparation method of modified by cardanol amine epoxy curing agent | |
| CN108070093B (en) | Preparation method of water-based epoxy resin emulsion | |
| CN103880022A (en) | Inorganic polymer material, method for forming same, and inorganic polymer coating film formed thereby | |
| CN101165130B (en) | Preparation technique of organic silicon resin for high temperature resisting powder paint | |
| CN106977683A (en) | No-solvent type polyurethane nano TiO2Composite membrane and preparation method thereof | |
| CN109762457A (en) | Height is crosslinked anti-graffiti environmental protection coating material and preparation method thereof | |
| CN107973899A (en) | A kind of preparation method of the modified epoxy curing agent based on anacardol | |
| CN104449333A (en) | High-transparency high-fullness solvent-type matte carpentry paint and preparation method thereof | |
| CN104804194B (en) | The preparation of poly- titanium Borosiloxane and the method for modifying to phenolic resin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Cao Yexia Inventor after: Ren Guangming Inventor before: Ren Guohua Inventor before: Ren Yujie |
|
| CB03 | Change of inventor or designer information | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180416 Address after: 034099 10 Heping West Street, Xinfu District, Xinzhou, Shanxi Applicant after: Xinzhou Teachers University Address before: 528000 6 Xing Yuan Road, Qi Xing, Xing Tan Town, Shunde District, Foshan, Guangdong Applicant before: Ren Guohua |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190419 Termination date: 20200313 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |