CN107185313A - Eliminate the material and device of motor vehicle interiors air pollutants - Google Patents

Eliminate the material and device of motor vehicle interiors air pollutants Download PDF

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Publication number
CN107185313A
CN107185313A CN201710449794.3A CN201710449794A CN107185313A CN 107185313 A CN107185313 A CN 107185313A CN 201710449794 A CN201710449794 A CN 201710449794A CN 107185313 A CN107185313 A CN 107185313A
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China
Prior art keywords
dicarboxylic acids
acid
acids
dicarboxylic
salt
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CN201710449794.3A
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蒋理
何健
曹良
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Kunshan Ruicheng Xinmei New Material Co Ltd
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Kunshan Ruicheng Xinmei New Material Co Ltd
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Priority to CN201710449794.3A priority Critical patent/CN107185313A/en
Publication of CN107185313A publication Critical patent/CN107185313A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2068—Other inorganic materials, e.g. ceramics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D45/00—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
    • B01D45/02—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising gravity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0036—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions by adsorption or absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D51/00—Auxiliary pretreatment of gases or vapours to be cleaned
    • B01D51/02—Amassing the particles, e.g. by flocculation
    • B01D51/04—Amassing the particles, e.g. by flocculation by seeding, e.g. by adding particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
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    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
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    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
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    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
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    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28073—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28076—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
    • B60H3/00—Other air-treating devices
    • B60H3/06—Filtering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2259/455—Gas separation or purification devices adapted for specific applications for transportable use
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60H—ARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
    • B60H3/00—Other air-treating devices
    • B60H3/06—Filtering
    • B60H2003/0691—Adsorption filters, e.g. activated carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
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    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y02A50/2351—Atmospheric particulate matter [PM], e.g. carbon smoke microparticles, smog, aerosol particles, dust
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Abstract

The present invention relates to the material and device for eliminating motor vehicle interiors air pollutants, the major function material used is the nanoparticles preparation with surface microviscosity or the metallorganic framework material of super large hole adsorption capacity.And the critical piece of the processing unit includes rechargeable battery, charge and discharge electrical switch, fan, functional material filter core, metal gas sensor, organic gas sensor, particulate matter sensors, the data processing terminal with internet function outwardly transmits the function of signal by WI FI or mobile internet, signal receiving device, understands the signal（Word or audio frequency）Application program.Compared with prior art, the advantage of the invention is that：Can once be driven on automobile with effective guarantee or outdoor docking process in the air pollutants that accumulate be substantially eliminated, and then ensure that occupant enters and enjoyed the inner space of vehicle cleaned completely.

Description

Eliminate the material and device of motor vehicle interiors air pollutants
Technical field
The present invention relates to the technical scheme and related device for keeping the cleaning of means of transport inner air.Further, this hair It is bright using to metal, inorganic oxide, volatile organic matter and bacterium, the steam of the bioactive substance such as virus has highly sensitive Degree, the nanochemistry material pref of Large Copacity suction-operated eliminates the pollutant of inner space of vehicle.Further, it is of the invention The device of use have it is difunctional, can under passenger car running status outwardly air blast promote air circulation；In dead ship condition Lower continuous air extraction is implemented to eliminate the clean operation of pollutant.Further, device of the present invention can pass through wireless network The clean-up performance of Immediate Report in-car air.
Background technology
Automobile is being increasingly becoming part indispensable in popular life.Calculated by 79 years old average life span, everyone The time of about 5 years is, in driving, to be driven equivalent to daily more than 100 minutes, the total driving range of life is about 130 Ten thousand kilometers.But the public is often limited only to mechanical event to the understanding of potentially danger involved during automobile use Barrier, weather conditions, condition of road surface or human factor, such as exceed the speed limit, drunk driving, driving with poison, if proper use of safety belt etc. side Face, and the closed of automotive interior is usually ignored, the air pollution as caused by fine particulates may be to occupant in small space The harm that body is produced.
Reported according to National Renewable Energy laboratory (NATIONAL RENEWABLE ENERGY LABORATORY) Accuse, the temperature of some parts surfaces of automotive interior under sunlight irradiation can be up to 120 DEG C；And due to automobile omnibearing Glass structure cause high degree of solar radiation, all wavelengths are longer than the transmitance that 315 nano-ultraviolet lights all have at least 63%, short It is higher in the DUV transmitance of 315 nano wave lengths.
And then provide report confirmation, high temperature positioned at the ecological center (THE ECOLOGY CENTER) of state of Michigan Ann Arbor Inner space of vehicle is caused to diffuse more than 160 kinds volatile organic chemicals with the collective effect of solar radiation.Wherein have prominent Go out health hazard include formaldehyde (FORMALDEHYDE), PBDE (POLYBROMINATED DIPHENYLETHERS, ) and phthalic acid ester (PHTHALIC ACID ESTERS, E.G.DI 2-ETHYL-HEXYL PHTHALATE, DEHP) PBDE Deng.Formaldehyde, acetaldehyde, the aldehyde material such as methacrylaldehyde is widely used in the plastics of automotive interior, leather, wooden and metal parts table Face, can discharge under high temperature and illumination condition, may be interacted with people's vivo protein and cause headache, uncomfortable in chest, ophthalmodynia is planted Thing neurological disorders, the consequence such as blood pollution and gene mutation.PBDE is widely used fire retardant, it is known that to nerveous system System, reproductive system, immune system causes harm, while may trigger cutaneum carcinoma.Phthalic acid ester is the polychlorostyrene largely used Indispensable softening agent in vinyl material, can be to development system, reproductive system and liver, and the organ such as kidney causes damage.
Publilc health institute of Harvard University (HARVARD SCHOOL OF PUBLIC HEALTH) examines in inner space of vehicle Measure benzene (BENZENE), toluene (TOLUENE), dimethylbenzene (XYLENE) etc. is by the World Health Organization (WORLD HEALTH ORGANIZATION, WHO) and Environmental Protection Agency (US ENVIRONMENTAL PROTECTION AGENCY, EPA) identification Height carcinogenicity material.
Investigation of the Environmental Protection Agency to cities such as Los Angeles and Washington D.C.s is found, because general-utility car air-conditioning mistake Filter can not stop that gas passes through, and the carbon monoxide of automotive interior and the content of nitrogen oxides may be higher than periphery outdoor space Go out more than 7 times, the scene being particularly under traffic congestion state can also be more serious.
By Canadian University of Ottawa (UNIVERSITY OF OTTAWA) and USA New York City University (THECITY UNIVERSITY OF NEW YORK, CUNY) combine and shown in China and the United States' investigation that totally 10 cities are carried out, in the side of automobile To disk, radio knob, panel assembly, handle for doors and windows, seat, safety belt, drinking cup stand, the position such as carpet and ceiling is all present The aspergillus niger of high concentration, mushroom, endotoxin, Legionella bacteria, anaphylactogen, infective virus, microorganism colloidal sol etc..In addition, high temperature Micro including chromium, the arsenic of metal part surface release steam condition is also resulted in the collective effect of illumination, lead and mercury etc. are to people Body has the composition of irreversible injury.Further, automobile passenger is breathed, metabolism, and the residue such as F＆B used can be led Cause microorganism and the bacterial reproductions such as endotoxin (ENDOTOXIN).Further, occupant's smoking in the car can produce fine particle PM2.5. this kind of particulate matter would generally be adsorbed in the porous material surface of vehicle body by force, and by a very long period with Slow speed is discharged to vehicle body space.
Germany is being used for reference, Japan, the state such as South Korea and Russia relevant laws and regulations and the United Nations's European economy are affixed one's name to (UNECE) On the basis of vehicle interior air regulation (VEHICLE INTERIOR AIR QUALITY, VIAQ), Environment Protect in China portion in Issue within 2016《Air Quality Evaluation guide in passenger car》(exposure draft), it is proposed that including benzene, toluene, dimethylbenzene, The proposed standard of the monitoring concentration range of 8 kinds of volatile organic matters including ethylbenzene, styrene, formaldehyde, acetaldehyde and isopropyl aldehyde.Should Guide not yet enters implementation phase at present.In a word, high temperature and illumination can cause automobile interior material to decompose, and slowly release a large amount of The metal and organic pollution of complicated ingredient.These pollutants can be gradually in the state of automobile door and window closes (parking) for a long time Accumulation, and then irreversible injury constantly is caused to the internal organ and skin of occupant.These injuries infant and have breathing to old man The patient of tract disease is more so.It is therefore desirable to develop effectively to reduce or eliminate inner space of vehicle and by tiny particles content caused Air pollution method and device.
Extensive statistics shows that about 90% traffic accident is drawn by artificial (especially driver) factor Rise.The notice concentration degree of driver may be due to the alcohol in suction body, drugs or pernicious gas (such as first Alkane, carbon dioxide, carbon monoxide, etc.) and be severely impaired.
The U.S. Patent number 5221292 possessed by KANSEI companies discloses a kind of air cleaner unit, and it is arranged in On rear portion parcel shelf in the passenger accommodation of vehicle, the air cleaner unit includes：With with entering that automotive occupant room is connected The housing of gas port, the air outlet connected with Vehicular occupant room and the exhaust outlet connected with outside vehicle；It is arranged in the housing Air filter unit so that the air being supplied in the housing is cleaned by the air filter unit and by air Delivery port is supplied to Vehicular occupant room；For the air from vehicle passenger compartment to be supplied into Vehicular occupant room and outside vehicle Fan；Motor for rotating the fan, its bottom for being disposed across the housing and the rear parcel shelf are simultaneously Extend downwardly；With the housing is connected to take the valve of one of first state and the second state, the first state is institute State air inlet to connect with the exhaust outlet, second state is that the air inlet is connected with the atmosphere communicating port by air Filter unit.The patent does not include the chemical substance and its reaction details of any air pollution, lacks on air cleaning yet Any statement of mechanism.
The U.S. Patent number 5486138 possessed by JENS SORENSEN discloses a kind of reduction vehicle interior air pollution The method of degree, the vehicle interior, which has, leads to the Controllable Income Air system of the vehicle interior, and for detect one or The detecting system of multiple situations, comprises the following steps：Or more (a) condition, and (b) controlled in response to this detection into The air for entering vehicle interior enters so that one or more conditions cause and/or due to the potential energy of the kinetic energy conversion to vehicle Amount and/one or more conditions are the physical slant degree of vehicle.
The U.S. Patent number 6206775 possessed by VALEO CLIMATISATION companies discloses a kind of promotion automobile and multiplied The device of member's cabin inner air flow, including entering filter element and circulation filter element, and as needed regulation and control air inlet in time with The valve of circulating air ratio.The device also have matched simultaneously is monitored to major air pollutants nitric oxide and carbon monoxide Sensor.But the patent does not indicate the particular theory of operation of these sensors.
The U.S. Patent number 6939396 possessed by FORD GLOBAL TECHNOLOGIES LLC companies is disclosed for leading to Cross the device that the absorbing unit being arranged in vehicle removes pollutant from air in vehicle occupant compartment.Characterized in that, described Device has the absorption mode that can be operated when engine is operated and during tail-off, and thus described device includes：It is described logical Fan in wind system, for the first air intake of surrounding air, is arranged to go out to the first air that passenger compartment supplies air Mouthful, it is arranged between the air intake and air outlet slit.When wherein described equipment has when engine is operated and closed Manipulable absorption mode, and the equipment has desorption mode, and the desorption mode can be when engine is operation For the second air intake of surrounding air, the first heater of heating environment air, the pollution absorbing unit are arranged to It is arranged to by the surrounding air desorption of the heating.Secondary heating mechanism is then used for the mixture for heating air and pollutant, should The mixture of heating is arranged to heat the surrounding air in first heater, is positioned at the first heater and entrance discrimination Control valve between pipe, the valve is arranged to the second air intake and is connected to the source of negative air pressure provided by inlet manifold.Should Absorbing unit in device contains activated carbon as function adsorbent, with limited adsorptive selectivity and adsorption capacity.
The content of the invention
For problems of the prior art, it is that passenger car inner space eliminates gaseous contaminant that the present invention, which provides one, Technical solution, including high capacity highly effective rate nano adsorption material preparation, and with ultra-large three-dimensional manometer hole net The metallorganic framework material of network realizes the device mechanism and wireless messages extension Transmission system of continuous operation.
The technical solution for eliminating passenger car inner space gaseous contaminant of present disclosure uses two class Large Copacities High efficiency nano sorbing material：
1. there is the natural fiber material of surface microviscosity and the preparation of other auxiliary materials compositions is equipped with：
Preparation based on nanometer microviscosity functional material catches granule micronic dust, ADSORPTION OF GOLD in different size ranges Category, organic matter and bioactive materials steam, can effectively remove in air the micronic dust of 10 microns, 2.5 microns and following size, So as to reduce harm of the multiple pollutant to occupant's health.Catharsis of the nanometer microviscosity functional material to automotive interior air It is derived from nanoscale function surface and the bacterium in air, dust, smog, metal, the powered particle phase knot of organic matter isopolarity Close, and be gathered into the harm that the particle of relatively large-scale settled and eliminated PM2.5.It is demonstrated experimentally that floating dust diameter is smaller, easier quilt Tacky surfaces are adsorbed, and are assembled and then are settled and be fixed in filter core.
2. the metallorganic framework material with ultra-large molecular dimension three-dimensional cavity network：
Refer to that for example there are many of two bidentate organic compounds of coordinate bond comprising at least one and at least one metal ion Mesoporous metal organic backbone.
Metal in metallorganic framework material can be can form porous metals organic matter framework material any Suitable metal, it has the structure for the target chemical substances for allowing reversible load effective dose.For example, metal can be selected from element It is known containing one of metal group, such as Ia in the periodic table of elements, IIa, IIIa races, IIIa races to Villa races in periodic table With Ib to VIb races, included metal is such as, but not limited to, Li, Na, K, Rb, Cs, Fr, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ro, Os, Co, Rh, Ir, Ni, Pt, Cu, Ag, Au, Zn, Cd, Hg, Al, Ga, In, Ti, Si, Ge, Sn, Pb, As, Sb and Bi.
Organic group in metallorganic framework material refers to the organic compound for including at least one functional group, the official Can roll into a ball can form at least two with given metal ion and/or with a coordinate bond of two or more metallic atoms Key, such as two coordinate bonds.For example, following functional group can form the suitable functional group of coordinate bond：-CO2H ,-CS2,- NO2,-B (OH)2,-SO3H ,-Si (OH)3,-Ge (OH)3,-Sn (OH)3,-Si (SH)4,-Ge (SH)4,-Sn (SH)3,-P03H ,- As03H ,-As04H ,-P (SH) (SH)3,-CH (RSH)2,-C (RSH)3,-CH (RNH2)2,-(RNH2)3,-CH (ROH)2,-C (ROH)3,-C (RCN)3, wherein R is the alkylidene for example with 1,2,3,4 or 5 carbon atom, such as methylene, ethylidene, just Propylene, isopropenyl, n-butene, isobutene, tertiary butylene or n-pentene base, or the aryl comprising one or two aromatic kernel, example Such as the two C6 rings that can be condensed, and can suitably be replaced independently of one another in each case at least one replace Base, and/or can include at least one hetero atom in each case independently of one another, such as N, O and/or S. are in embodiment In, it can also be such as-CH (SH) that the above-mentioned group R of functional group therein, which can be not present,2,-C (SH)3,-CH (NH2)2,-C (NH2)3,-CH (OH)2,-C (OH)3,-CH (CN)2Or-C (CN)3.Include at least one functional group (or at least two functional groups) Organic compound can be derived from saturated aliphatic compound, unsaturated lipid compounds of group, aromatic compounds or aliphatic series and aromatics Compound.Aliphatic compounds (or aliphatic portion of aliphatic series and aromatic compounds) can be straight chain and/or side chain and/or ring-type 's.For example, aliphatic compounds (or aliphatic portion of aliphatic series and aromatic compounds) can include 1 to about 15 carbon atom, example Such as from about 2 to about 14 carbon atoms, or about 3 to about 12 carbon atom atoms.
Aromatic compounds or aromatic series and the aryl moieties of aliphatic compound can have one or more rings, example Such as two, three, four or five rings.This ring can each other be separated and/or existed in molten form.Independently of one another, often Individual ring can include at least one hetero atom, such as N, O, S, B, P, Si or Al.In embodiments, at least one two tooth is organic Compound can be dicarboxylic acids, tricarboxylic acids, other derivatives of tetrabasic carboxylic acid or imidazoles or amine.
Suitable dicarboxylic acids can include such as oxalic acid, butanedioic acid, tartaric acid, Isosorbide-5-Nitrae-butane dicarboxylic acid, and 4- oxos pyrans- 2,6- dicarboxylic acids, 1,6- hexane dicarboxylic acid, decane dicarboxylic acid, heptadecane dicarboxylic acid, 1,9- heptadecane dicarboxylic acid, heptadecane dicarboxyl Acid, acetylenedicarboxylic acid, 1,2- phthalic acid, 2,3- pyridinedicarboxylic acids, pyridine -2,3- dioctyl phthalate, 1,3-butadiene-Isosorbide-5-Nitrae-dicarboxyl It is sour, Isosorbide-5-Nitrae-phthalic acid, terephthalic acid (TPA), imidazoles -2,4- dicarboxylic acids, 2- methylquinoline -3,4- dicarboxylic acids, quinoline -2,4- Dicarboxylic acids, quinoxaline -2,3- dicarboxylic acids, 6- chloro-quinoxaline -2,3- dicarboxylic acids, 4,4'- diamino-phenyl ethane -3,3'- bis- Carboxylic acid, quinoline -3,4- dicarboxylic acids, 7- chloro-4-hydroxyl quinoline -2,8- dicarboxylic acids, dicarboxylic acids, di-imidodicarboxylic acid, pyridine -2, 6- dicarboxylic acids, 2-methylimidazole -4,5- dicarboxylic acids, thiophene -3,4- dicarboxylic acids, 2- isomers fluorenyl imidazole-4,5-dicarboxylic acids, four Hydrogen pyrans -4,4- dicarboxylic acids , perylene -3,9- dicarboxylic acids , perylene dioctyl phthalate, Pluriol E 200- dicarboxylic acids, 3,6- dioxaoctanes Dicarboxylic acids, 3,5- cyclohexadiene -1,2- dicarboxylic acids, octahydro dicarboxylic acids, pentane -3,3 carboxylic acid, 4,4'- diaminostilbenes, 1- hexichol Base -3,3'- dicarboxylic acids, 4,4'- diamino-diphenyl -3,3'- dicarboxylic acids, benzal -3,3'- dicarboxylic acids, Isosorbide-5-Nitrae-bis- (phenylaminos Base) benzene -2,5- dicarboxylic acids, 1,1- naphthyl -5,5'- dicarboxylic acids, chloro- 8- methylquinolines -2, the 3- dicarboxylic acids of 7-, 1- anilino- anthracenes Quinone -2,4'- dicarboxylic acids, PolyTHF -200- dicarboxylic acids, Isosorbide-5-Nitrae-bis- (carboxymethyl) piperazine -2,3- dioctyl phthalate, 7- chloroquinolines - 3,8- dicarboxylic acids, 1- (4- carboxyls) phenyl -3- (4- chlorine) phenylpyrrazolin -4,5- dicarboxylic acids, Isosorbide-5-Nitrae, 5,6,7,7- chlordene -5- drops Bornylene -2,3- dicarboxylic acids, benzene borine dicarboxylic acids, 1,3- dibenzyl -2- oxoimidazolinium -4,5- dicarboxylic acids, Isosorbide-5-Nitrae-hexamethylene Dicarboxylic acids, naphthalene -1,8- dicarboxylic acids, 2- benzophenone -1,3- dicarboxylic acids, 1,3- dibenzyl -2- oxo-imidazole alkane -4,5- cis two Carboxylic acid, 2,2'- diquinoline -4,4'- dicarboxylic acids, pyridine -3,4- dicarboxylic acids, 3,6,9- trioxa decane dicarboxylic acids, O- hydroxyls two Benzophenone dicarboxylic acid, Pluriol E 300- dicarboxylic acids, Pluriol E 400- dicarboxylic acids, Pluriol E 600- dicarboxylic acids, Pyrazoles -3,4- dicarboxylic acids, 2,3- pyrazine dicarboxylic acids, 5,6- dimethyl -2,3- pyrazine dicarboxylic acids, 4,4'- diaminodiphenyl ethers two Iminodicarboxylic acid, 4,4'- diaminodiphenyl-methane diimine dicarboxylic acids, 4'- diaminodiphenylsulfones, diimino dicarboxyl Acid, NDA, 1,3- adamantane dicarboxylic acids, 1,8- naphthalenedicarboxylic acid, 2,3- naphthalene dicarboxylic acids, 8- methoxyl groups -2,3- naphthalene two Formic acid, 8- nitro -2,3- naphthalene sulfonic acids, 8- sulfo group -2,3- naphthalenedicarboxylic acids, anthracene -2,3- dicarboxylic acids, 2', 3'- diphenyl-to three Benzene -4,4 "-dicarboxylic acids, diphenyl ether 4,4'- dicarboxylic acids, imidazole-4,5-dicarboxylic acid, heterochromatic alkene -2, the 8- dicarboxylic acids of 4 (1H)-oxos, 5- tert-butyl group -1,3- phthalic acids, 7,8- quinolinedicarboxylic acids, imidazole-2-carboxylic acid, 4- cyclohexene -1,2- dicarboxylic acids, hexylene glycol two Carboxylic acid, tetradecane dicarboxylic acid, 1,7- heptan dicarboxylic acids, 5- hydroxyl -1,3- phthalic acids, pyrazine -2,3- dicarboxylic acids, furans -2-, 5- Dicarboxylic acids, 1- nonene -6,9- dicarboxylic acids, eicosadienoic acid, 4,4'- dihydroxydiphenyl methane -3,3'- dicarboxylic acids, 1- ammonia Base -4- methyl -9,10- dioxo -9,10- dihydro-anthraquinone e-2,3- dicarboxylic acids, 2,5-Pyridinedicarboxylic acid, cyclohexene -2,3- bis- Methylquinoline -6,8 dicarboxylic acids between carboxylic acid, 2,9- dichloro fluorine borine -4,11- dicarboxylic acids, the chloro- 3- of 7-, 2,4- dichloro benzophenones - 2', 5'- dicarboxylic acids, 1,3- phthalic acid, 2, dipicolimic acid 2,1- methylpyrrole -3,4- dicarboxylic acids, 1- benzyl -1H- pyrroles Cough up -3,4- dicarboxylic acids, anthraquinone -1,5- dicarboxylic acids, 3,5- pyrazoles dicarboxylic acids, 2- nitrobenzene-Isosorbide-5-Nitrae-dicarboxylic acids, heptane -1,7- bis- Carboxylic acid, cyclobutane -1,1 Isosorbide-5-Nitrae-dicarboxylic acids, 1,14- tetradecane dicarboxylic acid, 5,6- dehydrogenation norbornane -2,3- dicarboxylic acids, 5- second Base -2,3- pyridinedicarboxylic acids or its esters.
Suitable tricarboxylic acids can include such as 2- hydroxyls -1,2,3- tricarballylic acids, the quinoline tricarboxylic acids of 7- chloro- 2,3,8-, 1,2,4- benzenetricarboxylic acid, butane tricarboxylic acid, 2- phosphines -1,2,4- butane tricarboxylic acids, 1,3,5- benzenetricarboxylic acid, 1- hydroxyls -1,2, 3- tricarballylic acids, 4,5- dihydro -4,5- dioxos -- 1H- pyrrolo-es [2,3-F] quinoline -2,7,9- tricarboxylic acids, 5- acetyl group -3- Amino -6- methylbenzenes -1,2,4- tricarboxylic acids, 3- amino -5- benzoyl -6- methylbenzenes -1,2,4- tricarboxylic acids, 1,2,3- the third three Carboxylic acid or laurate and its esters.
Suitable tetrabasic carboxylic acid can include, for example, 1,1- dioxolyl [BCD] thiophene -3,4,9,10- tetrabasic carboxylic acids, Perylene-tetrabasic carboxylic acid, Li such as perylenes -3,4,9,10- tetrabasic carboxylic acid Huo perylene -1,12- sulfonyls -3,4,9,10 tetrabasic carboxylic acids, BTCA, such as 1,2,3,4- BTCA or meso -1,2,3,4- BTCAs, decane -2,4,6,8- tetrabasic carboxylic acids, Isosorbide-5-Nitrae, 7,10, 13,16- hexaoxacyclooctadecane-6s -2,3,11,12- tetrabasic carboxylic acids, 1,2,4,5- benzene tetracarboxylic acid, 1,2,11,12- dodecyl tetracarboxylic acid Acid, 1,2,5,6 hexane tetrabasic carboxylic acid, 1,2,7,8- octane tetrabasic carboxylic acid, Isosorbide-5-Nitrae, 5,8- naphthalenetetracarbacidic acidics, 1,2,9,10- decane tetrabasic carboxylic acid, Benzophenone tetrabasic carboxylic acid, 3,3', 4,4'- benzophenone tetrabasic carboxylic acids, tetrahydrofuran tetrabasic carboxylic acid or pentamethylene tetrabasic carboxylic acid, such as ring penta Alkane -1,2,3,4- tetrabasic carboxylic acids and its esters.
Suitable metallorganic skeleton for the inventive method includes being used for one or more targeteds with multiple Learn multiple holes in the accessible site of the reversible intake of material.Metallorganic skeleton, such as comprising multiple come-at-able holes Porous metals organic matter skeleton and/or composition metal organic matter skeleton (be coated with the metallorganic of the load of polymeric material Compound between framework material, such as polymer) it can load target chemical substances, such as target can with metallorganic skeleton With the chemical entities connected each other.Multiple holes of porous metals organic matter skeleton can include micropore and/or mesoporous." micropore " is fixed Justice is the micropore with about 2nm or smaller diameter, such as the diameter or about 1nm in the range of about 2nm to about 0.01nm are to about Diameter in the range of 0.1nm；The diameter of " mesoporous " in the range of about 2 to about 50nm is defined, e.g., from about 5nm to about 40nm scopes Diameter about 30nm in the range of interior diameter, or about 10nm to about 40nm.Micropore and/or Jie can be checked by means of adsorbing measurement The presence in hole, these measurement according to DIN 66135, DIN 66131 and/or DIN 66134 determine metallorganic skeleton for The absorptivity of the nitrogen of 77 Kelvins.Target chemical entities can be containing with multiple holes in metallorganic framework material The molecule of at least one complementary functional group of one or more sites.Such complementary functional groups can pass through metallorganic bone The noncovalent interaction in one or more of multiple holes in frame material site has high-affinity.In such embodiment party In case, metallorganic framework material can include at least one two bidentate organic compound (or one or more other parts), It can produce the site with required function, such as the site pre-selected target with least complementary functional group with functionalization Learn the One function group of entity.This ability of metallorganic framework material functionalization is useful, because hole can be arranged Have an orderly site of high concentration, its characteristic such as hydrophobicity, hydrophily, polarity, nonpolar and/or spatial character can be customized with The target chemical entities of degree of functionality are matched, so as to allow adjustment metallorganic framework material/target chemical entities system with reality Existing desired diffusion/rate of release of the target chemical entities from the hole of metallorganic framework material.In embodiments, target Learning entity can be functionalized with one or more functional groups, for example, to improve metallorganic framework material intake level And/or absorption/release dynamics of regulation target chemistry material.There may be (or addition) to metallorganic framework material and/ Or the functional group of target chemical entities include such as halogen, alcohol, ether, ketone, carboxylic acid, ester, carbonic ester, amine, acid amides, imines, urea, Aldehyde, isocyanates, tosylate, alkane, alkene, alkynes or its combination.
It can select and/or the specific construction unit of further functionalization so that obtain the required gold with preset aperture Belong to organic matter framework material structure.Generally, the molecular dimension of at least one two bidentate organic compounds or other parts is bigger, metal The aperture of organic matter framework material is bigger.It is also an option that this porous metals organic matter framework material of the present invention, porous gold The aperture for belonging to organic matter framework material can be by selecting suitable part and/or at least one two bidentate organic compound to control System so that average pore size or about 1.0nm of the average pore size in the range of about 0.1nm or about in the range of 0.5nm to about 10nm are extremely Average pore size in the range of about 5nm.
In some embodiments, metallorganic framework material can include pore-size distribution.In such embodiment In, the metallorganic framework material used in the method for the invention can be 100% metallorganic framework material, wherein Total metallorganic framework material pore volume more than 70%, is greater than 85%, or more than 99%, by being less than with aperture 100nm, is, for example, less than 50nm or less than 40nm.In embodiments, no more than total metallorganic framework material pore volume 5%, the emptying aperture that the emptying aperture more than 0.5% of more than 2% or total pore volume of such as total pore volume is more than 50nm by aperture is formed, Or more than 100nm or more than 200nm.
Suitable for the present invention method porous metals organic matter framework material can include following characteristics one or It is multiple：Surface area (Langmuir surface areas) in multiple holes is greater than about 500m2/g；The surface area in multiple holes can be about 500 To about 15,000m2/ g, or the surface area in multiple holes can be about 1,000 to about 10,000m2/ g, or multiple holes surface Product can be about 2,000 to about 6,000m2/g；The average pore sizes in multiple holes comprising porous metals organic matter framework material are About 0.005 to about 15cm3/ g, e.g., from about 0.05 to about 5cm3/g；And the skeleton of porous metals organic matter framework material has About 0.03 to about 5g/cm3Or about 0.3 to about 1.5g/cm3In the range of density.
Above-mentioned 1 and 2 nano material referred to is desirably placed filter core, and in the fan exhausting institute shape positioned at downstream Into slight negative pressure difference driving under, continuously diffusive migration enters to the outer surface of functional material body or internal cavity surface One step is adsorbed and solidified.By operator scheme so, can once it be driven or outdoor docking process on automobile with effective guarantee The air pollutants of middle accumulation are substantially eliminated, and then ensure that occupant enters and enjoyed the inner space of vehicle cleaned completely.
Compared with prior art, the advantage of the invention is that：The present invention includes high capacity highly effective rate nano adsorption material system Agent, and the metallorganic framework material with ultra-large three-dimensional manometer hole network realize the device mechanism of continuous operation And wireless messages extension Transmission system, can once be driven on automobile with effective guarantee or outdoor docking process in the sky that accumulates Gas pollutant is substantially eliminated, and then ensures that occupant enters and enjoyed the inner space of vehicle cleaned completely.
Brief description of the drawings
Fig. 1 is that metallorganic framework material MOF-177 is adsorbed and wrapped up solidification toxic gas material carbon monoxide (little Huang Ball) and methane (rheum officinale ball) pattern diagram.
Embodiment
With reference to embodiment, the present invention is furture elucidated.
Material and device for eliminating passenger car inside air pollution.The major function material wherein used is with table The nanoparticles preparation of face microviscosity or the metallorganic framework material of super large hole adsorption capacity.And the processing unit Critical piece includes rechargeable battery, charge and discharge electrical switch, fan, functional material filter core, metal gas sensor, organic matter Gas sensor, particulate matter sensors, the data processing terminal with internet function passes through WI-FI or mobile Internet Network outwardly transmits the function of signal, and signal receiving device understands the application program of the signal (word or audio frequency).
The effective efficiency composition in functional material filter core contained by the device is according to the demand of specific occasion from llowing group of materials It is middle to choose：Maltose, sodium lignin sulfonate, corn hemicellulose, sodium alginate, cyamopsis tetragonolobus, glycerine, rosin resin, calcium chloride And urea.Remaining content in preparation beyond remove function composite material is supplemented to 100% by aqueous solvent, and is configured to substantially The water system mix preparation of phase；It is 0.1-5% that content range during maltose is used in said preparation；Using during sodium lignin sulfonate Content range is 0.1-7%；The use of content range during corn hemicellulose is 0.1-10%；Use content during sodium alginate Scope is 0.1-4%；It is 0.1-3% that content range during cyamopsis tetragonolobus is used in said preparation；It is using content range during glycerine 0.1-5%；It is 0.1-5% that content range during rosin resin is used in said preparation；Content during calcium chloride is used in said preparation Scope is 0.1-3%；It is 0.1-8% that content range during urea is used in said preparation；
The effective efficiency composition in functional material filter core contained by the device is metallorganic framework material.Wherein it is in The metal of state of atom chooses one, two or more component mixing compositions as needed from following metallic salt component：Li+,Na+,K+,Rb+,Be2+,Mg2+,Ca2+,Sr2+,Ba2+,Sc3+,Y3+,Ti4+,Zr4+,Hf4+,V4+,V3+,V2+,Nb3+,Ta3+,Cr+, Cr2+,Cr6+,Mo3+,W3+,Mn3+,Mn2+,Re3+,Re2+,Fe3+,Fe2+,Ru3+,Ru2+,Os3+,Os2+,Co3+,Co2+,Rh2+,Rh+, Ir2+,Ir+,Ni2+,Ni+,Pd2+,Pd+,Pt2+,Pt+,Cu2+,Cu+,Ag+,Au+,Zn2+,Cd2+,Hg2+,Al3+,Ga3+,In3+,Tl3 +,Si4+,Si2+,Ge4+,Ge2+,Sn4+,Sn2+,Pb4+,Pb2+,As5+,As3+,As+,Sb5+,Sb3+,Sb+,Bi5+,Bi3+,Bi+。
The effective efficiency composition in functional material filter core contained by the device is metallorganic framework material.Its multiple hole In surface area be greater than about 500m2/g；The surface area in multiple holes can be about 500 to about 15,000m2/ g, or multiple holes table Area can be about 1,000 to about 10,000m2/ g, or the surface area in multiple holes can be about 2,000 to about 6,000m2/g； The average pore sizes in multiple holes comprising porous metals organic matter framework material are about 0.005 to about 15cm3/ g, e.g., from about 0.05 To about 5cm3/g；And the skeleton of porous metals organic matter framework material has about 0.03 to about 5g/cm3Or about 0.3 to about 1.5g/cm3In the range of density.Wherein it is used for organic matter functional group or the inorganic salts anionic radical evidence for connecting metallic atom center Need to choose a kind of from following candidate materials, combination of two or more：Alkylamine and its corresponding alkylammonium salt, it contains tool There are the straight chain of 1 to 20 carbon atom, side chain or cyclic aliphatic group；Gulf arylamine and its corresponding virtue with 1 to 5 phenyl ring Base ammonium salt；Containing the straight chain with 1 to 20 carbon atom, the Wan Ji phosphonium salts of side chain or cyclic aliphatic group；With 1 to 5 The Fang Ji phosphonium salts of phenyl ring, alkyl organic acid and its corresponding salt, it contains the straight chain with 1 to 20 carbon atom, side chain or ring Shape aliphatic group；Aryl organic acid and its corresponding salt, with 1 to 5 phenyl ring；Straight chain containing 1 to 20 carbon atom, side chain Or the aliphatic alcohol of cyclic aliphatic group；Aryl alcohol with 1 to 5 phenyl ring；By sulfate, nitrate, nitrite, sulfurous acid Salt, bisulfites, phosphate, hydrophosphate, dihydric phosphate, diphosphate, triphosphate, phosphite, chloride, chlorine Inorganic anion in hydrochlorate, bromide, bromate, iodate, iodate, carbonate, the group of bicarbonate composition, diphosphonic acid Salt, sulfide, disulfate, selenides, selenate, selenate, tellurides, tellurate, hydrotelluric acid, nitride, phosphide, arsenic Compound, arsenate, arsenic acid hydrogen salt, disodium hydrogen arsenate, stibate, stibate, metaantimmonic acid hydrogen salt, borate, borate, hydrogen borate Salt, perchlorate, chlorite, hypochlorite, perbromate, bromate, hypobromite, periodate, iodate, hypoiodous acid Salt, and the inorganic anion respective acids and salt；Ammonia, carbon dioxide, methane, oxygen, argon gas, nitrogen, ethene, hexane, Benzene, toluene, (T, M, P) dimethylbenzene, chlorobenzene, nitrobenzene, naphthalene, thiophene, pyridine, acetone, 1,2- dichloroethanes, dichloromethane, four Hydrogen furans, monoethanolamine, triethylamine, trifluoromethane sulfonic acid DMF, N, N- diethylformamides, dimethyl is sub- Sulfone, chloroform, bromofom, methylene bromide, iodoform, diiodomethane, halogenated organic solvent, DMA, N, pyrrolidones, Amide solvent, picoline, lutidines, Anaesthetie Ether, and its mixture.Oxalic acid, butanedioic acid, tartaric acid, Isosorbide-5-Nitrae-butane Dicarboxylic acids, 4- oxo pyrans -2,6- dicarboxylic acids, 1,6- hexane dicarboxylic acid, decane dicarboxylic acid, heptadecane dicarboxylic acid, 1,9- ten seven Alkane dicarboxylic acids, heptadecane dicarboxylic acid, acetylenedicarboxylic acid, 1,2- phthalic acid, 2,3- pyridinedicarboxylic acids, pyridine -2,3- dioctyl phthalate, 1,3-butadiene-Isosorbide-5-Nitrae-dicarboxylic acids, Isosorbide-5-Nitrae-phthalic acid, terephthalic acid (TPA), imidazoles -2,4- dicarboxylic acids, 2- methylquinoline -3, 4- dicarboxylic acids, quinoline -2,4- dicarboxylic acids, quinoxaline -2,3- dicarboxylic acids, 6- chloro-quinoxaline -2,3- dicarboxylic acids, 4,4'- diaminos Base diphenylphosphino ethane -3,3'- dicarboxylic acids, quinoline -3,4- dicarboxylic acids, 7- chloro-4-hydroxyl quinoline -2,8- dicarboxylic acids, dicarboxylic acids, two is sub- Diamino dicarboxylic acid, pyridine -2,6- dicarboxylic acids, 2-methylimidazole -4,5- dicarboxylic acids, thiophene -3,4- dicarboxylic acids, 2- isomers fluorenyls Imidazole-4,5-dicarboxylic acid, oxinane -4,4- dicarboxylic acids , perylene -3,9- dicarboxylic acids , perylene dioctyl phthalate, Pluriol E 200- dicarboxyls Acid, 3,6- dioxaoctane dicarboxylic acids, 3,5- cyclohexadiene -1,2- dicarboxylic acids, octahydro dicarboxylic acids, pentane -3,3 carboxylic acid, 4,4'- Diaminostilbene, 1- diphenyl -3,3'- dicarboxylic acids, 4,4'- diamino-diphenyl -3,3'- dicarboxylic acids, benzal -3,3'- dicarboxyl Acid, Isosorbide-5-Nitrae-bis- (phenyl amino) benzene -2,5- dicarboxylic acids, 1,1- naphthyl -5,5'- dicarboxylic acids, the chloro- 8- methylquinolines -2,3- bis- of 7- Carboxylic acid, 1- anilino- anthraquinone -2,4'- dicarboxylic acids, PolyTHF -200- dicarboxylic acids, Isosorbide-5-Nitrae-bis- (carboxymethyl) piperazine -2,3- bis- Formic acid, 7- chloroquinoline -3,8- dicarboxylic acids, 1- (4- carboxyls) phenyl -3- (4- chlorine) phenylpyrrazolin -4,5- dicarboxylic acids, Isosorbide-5-Nitrae, 5, 6,7,7- chlordene -5- ENB -2,3- dicarboxylic acids, benzene borine dicarboxylic acids, 1,3- dibenzyl -2- oxoimidazoliniums -4,5- bis- Carboxylic acid, Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid, naphthalene -1,8- dicarboxylic acids, 2- benzophenone -1,3- dicarboxylic acids, 1,3- dibenzyl -2- oxo miaows The cis dicarboxylic acids of oxazolidine -4,5-, 2,2'- diquinoline -4,4'- dicarboxylic acids, pyridine -3,4- dicarboxylic acids, 3,6,9- trioxa decane Dicarboxylic acids, O- hydroxy benzophenone keto-dicarboxylic acids, Pluriol E 300- dicarboxylic acids, Pluriol E 400- dicarboxylic acids, Pluriol E 600- dicarboxylic acids, pyrazoles -3,4- dicarboxylic acids, 2,3- pyrazine dicarboxylic acids, 5,6- dimethyl -2,3- pyrazine dicarboxylic acids, 4,4'- bis- Amino-diphenylethers di-imidodicarboxylic acid, 4,4'- diaminodiphenyl-methane diimine dicarboxylic acids, 4'- diaminodiphenylsulfones, two Iminodicarboxylic acid, NDA, 1,3- adamantane dicarboxylic acids, 1,8- naphthalenedicarboxylic acid, 2,3- naphthalene dicarboxylic acids, 8- methoxies Base -2,3- naphthalenedicarboxylic acid, 8- nitro -2,3- naphthalene sulfonic acids, 8- sulfo group -2,3- naphthalenedicarboxylic acids, anthracene -2,3- dicarboxylic acids, 2', 3'- bis- Phenyl-para-terpheny -4,4 "-dicarboxylic acids, diphenyl ether 4,4'- dicarboxylic acids, imidazole-4,5-dicarboxylic acid, the 4 heterochromatic alkene of (1H)-oxo - 2,8- dicarboxylic acids, 5- tert-butyl group -1,3- phthalic acids, 7,8- quinolinedicarboxylic acids, imidazole-2-carboxylic acid, 4- cyclohexene -1,2- dicarboxyls Acid, hexylene glycol dicarboxylic acids, tetradecane dicarboxylic acid, 1,7- heptan dicarboxylic acids, 5- hydroxyl -1,3- phthalic acids, pyrazine -2,3- dicarboxyl Acid, furans -2-, 5- dicarboxylic acids, 1- nonene -6,9- dicarboxylic acids, eicosadienoic acid, 4,4'- dihydroxydiphenyl methane -3, 3'- dicarboxylic acids, 1- amino -4- methyl -9,10- dioxo -9,10- dihydro-anthraquinone e-2,3- dicarboxylic acids, 2,5-Pyridinedicarboxylic acid, Methylquinoline -6,8 dicarboxylic acids, 2,4- between cyclohexene -2,3- dicarboxylic acids, 2,9- dichloro fluorine borine -4,11- dicarboxylic acids, the chloro- 3- of 7- Dichloro benzophenone -2', 5'- dicarboxylic acids, 1,3- phthalic acid, 2, dipicolimic acid 2,1- methylpyrrole -3,4- dicarboxylic acids, 1- benzyl -1H- pyrroles -3,4- dicarboxylic acids, anthraquinone -1,5- dicarboxylic acids, 3,5- pyrazoles dicarboxylic acids, 2- nitrobenzene-Isosorbide-5-Nitrae-dicarboxylic acids, Heptane -1,7- dicarboxylic acids, cyclobutane -1,1 Isosorbide-5-Nitrae-dicarboxylic acids, 1,14- tetradecane dicarboxylic acid, 5,6- dehydrogenation norbornanes -2,3- Dicarboxylic acids, 5- ethyls -2,3- pyridinedicarboxylic acid or its esters.2- hydroxyls -1,2,3- tricarballylic acids, the quinoline three of 7- chloro- 2,3,8- Carboxylic acid, 1,2,4- benzenetricarboxylic acid, butane tricarboxylic acid, 2- phosphines -1,2,4- butane tricarboxylic acids, 1,3,5- benzenetricarboxylic acid, 1- hydroxyls - 1,2,3- tricarballylic acid, 4,5- dihydro -4,5- dioxos -- 1H- pyrrolo-es [2,3-F] quinoline -2,7,9- tricarboxylic acids, 5- acetyl Base -3- amino -6- methylbenzenes -1,2,4- tricarboxylic acids, 3- amino -5- benzoyl -6- methylbenzenes -1,2,4- tricarboxylic acids, 1,2, 3- tricarballylic acids or laurate and its esters.1,1- dioxolyl [BCD] thiophene -3,4,9,10- tetrabasic carboxylic acid , perylenes-tetracarboxylic acid Acid, Li such as perylenes -3,4,9,10- tetrabasic carboxylic acid Huo perylene -1,12- sulfonyls -3,4,9,10 tetrabasic carboxylic acids, BTCA, such as 1,2,3, 4- BTCAs or meso -1,2,3,4- BTCAs, decane -2,4,6,8- tetrabasic carboxylic acids, Isosorbide-5-Nitrae, 7,10,13,16- six Oxa- ring octadecane -2,3,11,12- tetrabasic carboxylic acids, 1,2,4,5- benzene tetracarboxylic acid, 1,2,11,12- dodecyl tetrabasic carboxylic acid, 1,2, 5,6 hexane tetrabasic carboxylic acids, 1,2,7,8- octane tetrabasic carboxylic acid, Isosorbide-5-Nitrae, 5,8- naphthalenetetracarbacidic acidics, 1,2,9,10- decane tetrabasic carboxylic acid, hexichol first Ketone tetrabasic carboxylic acid, 3,3', 4,4'- benzophenone tetrabasic carboxylic acids, tetrahydrofuran tetrabasic carboxylic acid or pentamethylene tetrabasic carboxylic acid, such as pentamethylene -1,2, 3,4- tetrabasic carboxylic acids and its esters.
The effective efficiency composition in functional material filter core contained by the device is by above-mentioned disclosed preparation and above-mentioned is draped over one's shoulders The metallorganic framework material of dew is mixed.The scope of the binary mixture ratio includes 1：10,2.5：7.5,5：5, 7.5：2.5,10：1.
Charge and discharge electrical switch operator scheme in the device is：When automobile engine is in running status, to the dress Battery charging in putting；When automobile engine is closed, battery discharge is allowed；
Fan operation pattern in the device is：When automobile engine is in running status, the fan pair in the device Device external environment condition air blast；When automobile engine is closed, fan in the device is from device external environment condition exhausting；
The dress centers double fan operator scheme：When automobile engine is in running status, the wind in the device Fan 1 pair of device external environment condition air blast；When automobile engine is closed, fan 2 in the device is from device external rings Border exhausting；Wherein, the fan 2 that the fan 1 in the device is located in independent parallel air channel, the device is located at functional material filter core Downstream air channel；
The weight range of sensitivity that the metallic vapour sensor that the dress is centered has is that part per trillion (1PPT) is arrived Hundred a ten thousandths (1PPM)；
The weight range of sensitivity that the organic matter gaseous state sensor that the dress is centered has is part per trillion (1PPT) To hundred a ten thousandths (1PPM)；
What the particulate matter sensors that the dress is centered had is 10 microns (PM10), 2.5 microns to geometric scale (PM2.5) and 1 micron of (PM1.0) particulate matter the weight range of sensitivity be part per billion (1PPB) to 500/1000000ths (500PPM)；
The data processing with internet function that the dress is centered is with transmission chip and terminal in WI-FI or wireless network The disclosed sensor signal of external environment transmission under the conditions of network (including 3G, 4G, 5G, 6G LTE)；
Above-mentioned transmitted word or sound signal are obtained by external device by appropriate application program and read or receive Listen；
Outer signals are obtained and arrangement for reading includes fixing equipment (such as, but not limited to computer, TV), handheld device (such as, but not limited to mobile phone, wrist-watch, reader) and wearable device (such as, but not limited to wrist-watch, bracelet)；
What the device may be eliminated causes the trace meter steam plasma of passenger car inside air pollution to include but do not limit to In Cr+,Cr2+,Cr6+,Os3+,Os2+,Zn2+,Cd2+,Hg2+,Hg+,Al3+,Pb4+,Pb2+,As5+,As3+,As+；
What the device may be eliminated causes the trace organic substance including but not limited to benzene of passenger car inside air pollution, Toluene, dimethylbenzene, ethylbenzene, styrene, formaldehyde, acetaldehyde, isopropyl aldehyde, PBDE and phthalic acid ester steam, and two Carbonoxide, carbon monoxide, nitric oxide, sulfur dioxide, hydrogen sulfide, the gaseous contaminant such as methane；
What the device may be eliminated causes the trace active biomaterial of passenger car inside air pollution to include but do not limit to In aspergillus niger, mushroom, endotoxin, Legionella bacteria, Escherichia coli, anaphylactogen, infective virus, microorganism colloidal sol etc..
Nano-functional material filter core contained by the device is cylindrical, including but not limited to cylinder, cylindroid, square column, Rectangle post, triangular column, irregular shape post etc..
Embodiment 1：Nano-fiber materials with surface microviscosity and the system for being equipped with other auxiliary materials compositions Agent eliminates the Determination of Trace Volatile organic pollution in air.The preparation being made into following ratio is packed into logical after natural drying With the stationary phase post of gas chromatograph.Then using the mixing containing following 10 kinds of gas each 10ppb (10/1000000000ths) concentration Gas standard specimen, benzene, toluene, dimethylbenzene, ethylbenzene, styrene, formaldehyde, acetaldehyde, isopropyl aldehyde, PBDE and phthalic acid Ester is used as test object.Test frequency is twice daily, in the test period of continuous 40 days, to be placed in the red of stationary phase post downstream External detector can not detect the characteristic signal of carbon-hydrogen link stretching vibration in 2850-2950 wavenumber ranges.Prove every time 60 During the test of second, all gas pollutants discharged from gaseous mixture standard specimen are absorbed by the preparation in stationary phase completely. It is possible thereby to inference, under conditions of above-mentioned volatile organic contaminant concentration is respectively 1ppb (part per billion), said preparation Effectively will be more than 1 year during work.
The preparation of table 1 is constituted
Embodiment 2：Metallorganic framework material MOF-177 is by metallic zinc Zn and organic group ((the 4- carboxylics of 1,3,5- tri- Base phenyl) benzene) (1,3,5-tris (4-carboxyphenyl) benzene) synthesis three-dimensional porous material.The material have than 5200 meters of surface area2/ gram, 1.75 centimetres of porosity3/ gram.By 3 cubic metres of ordinary passenger car inner space average out to, every time at family Under outer sunlight condition it is closed parking 8 hours calculate, it is possible to create and accumulate pernicious gas carbon monoxide and methane be respectively 1.0ppb (part per billion), then can be used for containing 1.0 grams of metallorganic framework material MOF-177 for the device of filter core The effective time length for eliminating pernicious gas is 292 times, i.e., close to the effective life of 10 months.
The present invention implements difunctional running in the way of pendant device in vehicle occupant compartment：When engine is in running status When, the battery of the device is placed in charge mode, and outwardly air blast promotes in-car air circulation circulation to fan；When engine is in During closed mode, the battery of the device is placed in discharge mode, and the inside exhausting formation local underpressure of fan is poor, and in this way Pollutant in continuous drawing air is adsorbed on the absorption filter element in the device by the induction diffusive migration of highly directive Unit.Air pollution in vehicle occupant compartment was effectively eliminated before occupant enters automobile so as to reach, and in driving shape The final purpose that the automobile passenger of state does not cause harm.
Embodiments of the invention is the foregoing is only, is not intended to limit the invention.All principles in the present invention Within, the equivalent substitution made should be included in the scope of the protection.The content category that the present invention is not elaborated In prior art known to this professional domain technical staff.

Claims (10)

1. eliminating the material of motor vehicle interiors air pollutants, preparation is eliminated by particulate matter and metallorganic framework material is mixed Conjunction is formed, it is characterised in that：The metal of described metallorganic framework material is that can form porous metals organic matter skeleton Any suitable metal of material, it has the structure for the target chemical substances for allowing reversible load effective dose.
2. the material according to claim 1 for eliminating motor vehicle interiors air pollutants, it is characterised in that：Described Grain thing eliminates preparation and chosen from llowing group of materials：Maltose, sodium lignin sulfonate, corn hemicellulose, sodium alginate, guanidine that Beans, glycerine, rosin resin, calcium chloride and urea；Remaining content in preparation beyond remove function composite material is mended by aqueous solvent 100% is charged to, and is configured to substantially homogeneous water system mix preparation；It is 0.1-5% wherein using content range during maltose； The use of content range during sodium lignin sulfonate is 0.1-7%；The use of content range during corn hemicellulose is 0.1-10%；Make It is 0.1-4% with content range during sodium alginate；The use of content range during cyamopsis tetragonolobus is 0.1-3%；Use containing during glycerine Amount scope is 0.1-5%；The use of content range during rosin resin is 0.1-5%；Content model during calcium chloride is used in said preparation Enclose for 0.1-3%；The use of content range during urea is 0.1-8%.
3. the material according to claim 1 for eliminating motor vehicle interiors air pollutants, it is characterised in that in original The metal of sub- state chooses one, two or more component mixing compositions as needed from following metallic salt component：Li+, Na+, K+, Rb+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Sc3+, Y3+, Ti4+, Zr4+, Hf4+, V4+, V3+, V2+, Nb3+, Ta3+, Cr+, Cr2+, Cr6+, Mo3+, W3+, Mn3+, Mn2+, Re3+, Re2+, Fe3 +, Fe2+, Ru3+, Ru2+, Os3+, Os2+, Co3+, Co2+, Rh2+, Rh+, Ir2+, Ir+, Ni2+, Ni+, Pd2+, Pd+, Pt2+, Pt+, Cu2+, Cu+, Ag+, Au+, Zn2+, Cd2+, Hg2+, Al3+, Ga3+, In3 +, Tl3+, Si4+, Si2+, Ge4+, Ge2+, Sn4+, Sn2+, Pb4+, Pb2+, As5+, As3+, As+, Sb5 +, Sb3+, Sb+, Bi5+, Bi3+, Bi+；The scope of the mass ratio of preparation and the metallorganic framework material is 1：10,2.5：7.5,5：5,7.5：2.5 or 10：1.
4. the material according to claim 1 for eliminating motor vehicle interiors air pollutants, it is characterised in that：Metal has Surface area in multiple holes of machine thing framework material is greater than about 500m 2/g;The surface area in multiple holes can be about 500 to about 15, 000m 2/g, or the surface area in multiple holes can be about 1,000 to about 10,000m 2/g, or the surface area in multiple holes can About 2,000 are thought to about 6,000m 2/g;The average pore sizes in multiple holes comprising porous metals organic matter framework material are about 0.005 to about 15cm 3/g, e.g., from about 0.05 to about 5cm 3/g;And the skeleton of porous metals organic matter framework material has Density in the range of about 0.03 to about 5g/cm 3 or about 0.3 to about 1.5g/cm 3；Wherein it is used to connect metallic atom center Organic matter functional group or inorganic salts anion a kind of, combination of two or more is chosen from following candidate materials as needed： Alkylamine and its corresponding alkylammonium salt, it contains the straight chain with 1 to 20 carbon atom, side chain or cyclic aliphatic group;Gulf Arylamine and its corresponding aryl ammonium salt with 1 to 5 phenyl ring;Containing the straight chain with 1 to 20 carbon atom, side chain or The Wan Ji phosphonium salts of cyclic aliphatic group;Fang Ji phosphonium salts with 1 to 5 phenyl ring, alkyl organic acid and its corresponding salt, it contains There are the straight chain with 1 to 20 carbon atom, side chain or cyclic aliphatic group;Aryl organic acid and its corresponding salt, with 1 to 5 Individual phenyl ring;The aliphatic alcohol of straight chain containing 1 to 20 carbon atom, side chain or cyclic aliphatic group;With 1 to 5 phenyl ring Aryl alcohol;By sulfate, nitrate, nitrite, sulphite, bisulfites, phosphate, hydrophosphate, biphosphate Salt, diphosphate, triphosphate, phosphite, chloride, chlorate, bromide, bromate, iodate, iodate, carbonic acid Inorganic anion in salt, the group of bicarbonate composition, diphosphate, sulfide, disulfate, selenides, selenate, selenic acid Salt, tellurides, tellurate, hydrotelluric acid, nitride, phosphide, arsenide, arsenate, arsenic acid hydrogen salt, disodium hydrogen arsenate, metaantimmonic acid Salt, stibate, metaantimmonic acid hydrogen salt, borate, borate, hydrogen borate salt, perchlorate, chlorite, hypochlorite, perbromic acid The respective acids and salt of salt, bromate, hypobromite, periodate, iodate, hypoiodite, and the inorganic anion; Ammonia, carbon dioxide, methane, oxygen, argon gas, nitrogen, ethene, hexane, benzene, toluene,（T, M, P）Dimethylbenzene, chlorobenzene, nitrobenzene, Naphthalene, thiophene, pyridine, acetone, 1,2- dichloroethanes, dichloromethane, tetrahydrofuran, monoethanolamine, triethylamine, trifluoromethane sulfonic acid N, Dinethylformamide, N, N- diethylformamides, dimethyl sulfoxide (DMSO), chloroform, bromofom, methylene bromide, iodoform, diiodomethane, Halogenated organic solvent, DMA, N, pyrrolidones, amide solvent, picoline, lutidines, diethyl Ether, and its mixture；
Oxalic acid, butanedioic acid, tartaric acid, Isosorbide-5-Nitrae-butane dicarboxylic acid, 4- oxo pyrans -2,6- dicarboxylic acids, 1,6- hexane dicarboxylic acid, the last of the ten Heavenly stems Alkane dicarboxylic acids, heptadecane dicarboxylic acid, 1,9- heptadecane dicarboxylic acid, heptadecane dicarboxylic acid, acetylenedicarboxylic acid, 1,2- phthalic acid, 2,3- pyridinedicarboxylic acids, pyridine -2,3- dioctyl phthalate, 1,3-butadiene-Isosorbide-5-Nitrae-dicarboxylic acids, Isosorbide-5-Nitrae-phthalic acid, terephthaldehyde Acid, imidazoles -2,4- dicarboxylic acids, 2- methylquinoline -3,4- dicarboxylic acids, quinoline -2,4- dicarboxylic acids, quinoxaline -2,3- dicarboxylic acids, 6- chloro-quinoxaline -2,3- dicarboxylic acids, 4,4'- diamino-phenyl ethane -3,3'- dicarboxylic acids, quinoline -3,4- dicarboxylic acids, the chloro- 4- of 7- Oxyquinoline -2,8- dicarboxylic acids, dicarboxylic acids, di-imidodicarboxylic acid, pyridine -2,6- dicarboxylic acids, 2-methylimidazole -4,5- dicarboxyl Acid, thiophene -3,4- dicarboxylic acids, 2- isomers fluorenyl imidazole-4,5-dicarboxylic acids, oxinane -4,4- dicarboxylic acids , perylenes -3,9- bis- Carboxylic acid , perylene dioctyl phthalate, Pluriol E 200- dicarboxylic acids, 3,6- dioxaoctane dicarboxylic acids, 3,5- cyclohexadiene -1,2- bis- Carboxylic acid, octahydro dicarboxylic acids, pentane -3,3 carboxylic acid, 4,4'- diaminostilbenes, 1- diphenyl -3,3'- dicarboxylic acids, 4,4'- diaminourea two Phenyl -3,3'- dicarboxylic acids, benzal -3,3'- dicarboxylic acids, Isosorbide-5-Nitrae-bis-（Phenyl amino）Benzene -2,5- dicarboxylic acids, 1,1- naphthyl - 5,5'- dicarboxylic acids, chloro- 8- methylquinolines -2, the 3- dicarboxylic acids of 7-, 1- anilino- anthraquinone -2,4'- dicarboxylic acids, PolyTHF - 200- dicarboxylic acids, Isosorbide-5-Nitrae-bis-（Carboxymethyl）Piperazine -2,3- dioctyl phthalate, 7- chloroquinoline -3,8- dicarboxylic acids, 1-（4- carboxyls）Phenyl- 3-（4- chlorine）Phenylpyrrazolin -4,5- dicarboxylic acids, Isosorbide-5-Nitrae, 5,6,7,7- chlordene -5- ENB -2,3- dicarboxylic acids, benzene borine Dicarboxylic acids, 1,3- dibenzyl -2- oxoimidazolinium -4,5- dicarboxylic acids, Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid, naphthalene -1,8- dicarboxylic acids, 2- benzene Formyl benzene -1,3- dicarboxylic acids, 1, the 3- cis dicarboxylic acids of dibenzyl -2- oxo-imidazole alkane -4,5-, 2,2'- diquinolines -4,4'- bis- Carboxylic acid, pyridine -3,4- dicarboxylic acids, 3,6,9- trioxa decane dicarboxylic acids, O- hydroxy benzophenone keto-dicarboxylic acids, Pluriol E 300- dicarboxylic acids, Pluriol E 400- dicarboxylic acids, Pluriol E 600- dicarboxylic acids, pyrazoles -3,4- dicarboxylic acids, 2,3- pyrazines Dicarboxylic acids, 5,6- dimethyl -2,3- pyrazine dicarboxylic acids, 4,4'- diaminodiphenyl ether di-imidodicarboxylic acids, 4,4'- diaminourea Diphenyl methane diimine dicarboxylic acids, 4'- diaminodiphenylsulfones, di-imidodicarboxylic acid, NDA, 1,3- Buddha's warrior attendant Alkane dicarboxylic acids, 1,8- naphthalenedicarboxylic acid, 2,3- naphthalene dicarboxylic acids, 8- methoxyl group -2,3- naphthalenedicarboxylic acids, 8- nitro -2,3- naphthalene sulfonic acids, 8- Sulfo group -2,3- naphthalenedicarboxylic acid, anthracene -2,3- dicarboxylic acids, 2', 3'- diphenyl-para-terpheny -4,4 "-dicarboxylic acids, diphenyl ether 4,4'- dicarboxylic acids, imidazole-4,5-dicarboxylic acid, 4（1H）Heterochromatic alkene -2, the 8- dicarboxylic acids of-oxo, 5- tert-butyl group -1,3- benzene diformazans Acid, 7,8- quinolinedicarboxylic acids, imidazole-2-carboxylic acid, 4- cyclohexene -1,2- dicarboxylic acids, hexylene glycol dicarboxylic acids, tetradecane dicarboxylic acid, 1, 7- dicarboxylic acids in heptan, 5- hydroxyl -1,3- phthalic acids, pyrazine -2,3- dicarboxylic acids, furans -2-, 5- dicarboxylic acids, 1- nonenes -6,9- Dicarboxylic acids, eicosadienoic acid, 4,4'- dihydroxydiphenyl methane -3,3'- dicarboxylic acids, 1- amino -4- methyl -9,10- dioxies Generation -9,10- dihydro-anthraquinones e-2,3- dicarboxylic acids, 2,5-Pyridinedicarboxylic acid, cyclohexene -2,3- dicarboxylic acids, 2,9- dichloro fluorine boron Methylquinoline -6,8 dicarboxylic acids between alkane -4,11- dicarboxylic acids, the chloro- 3- of 7-, 2,4- dichloro benzophenone -2', 5'- dicarboxylic acids, 1,3- Phthalic acid, 2, dipicolimic acid 2,1- methylpyrrole -3,4- dicarboxylic acids, 1- benzyl -1H- pyrroles -3,4- dicarboxylic acids, anthraquinone - 1,5- dicarboxylic acids, 3,5- pyrazoles dicarboxylic acids, 2- nitrobenzene-Isosorbide-5-Nitrae-dicarboxylic acids, heptane -1,7- dicarboxylic acids, cyclobutane -1,1 Isosorbide-5-Nitrae - Dicarboxylic acids, 1,14- tetradecane dicarboxylic acid, 5,6- dehydrogenation norbornane -2,3- dicarboxylic acids, 5- ethyls -2,3- pyridinedicarboxylic acid or Its esters；
2- hydroxyls -1,2,3- tricarballylic acids, the quinoline tricarboxylic acids of 7- chloro- 2,3,8-, 1,2,4- benzenetricarboxylic acid, butane tricarboxylic acid, 2- Phosphine -1,2,4- butane tricarboxylic acids, 1,3,5- benzenetricarboxylic acid, 1- hydroxyls -1,2,3- tricarballylic acids, 4,5- dihydro -4,5- dioxies Generation--1H- pyrrolo-es [2,3-F] quinoline -2,7,9- tricarboxylic acids, 5- acetyl group -3- amino -6- methylbenzenes -1,2,4- tricarboxylics Acid, 3- amino -5- benzoyl -6- methylbenzenes -1,2,4- tricarboxylic acids, 1,2,3- tricarballylic acid or laurate and its esters；
1,1- dioxolyl [BCD] thiophene -3,4,9,10- tetrabasic carboxylic acid , perylenes-tetrabasic carboxylic acid, Li such as perylenes -3,4,9,10- tetra- Carboxylic acid Huo perylene -1,12- sulfonyls -3,4,9,10 tetrabasic carboxylic acids, BTCA, such as 1,2,3,4- BTCAs or meso - 1,2,3,4- BTCA, decane -2,4,6,8- tetrabasic carboxylic acids, Isosorbide-5-Nitrae, 7,10,13,16- hexaoxacyclooctadecane-6s -2,3,11, 12- tetrabasic carboxylic acids, 1,2,4,5- benzene tetracarboxylic acid, 1,2,11,12- dodecyl tetrabasic carboxylic acid, 1,2,5,6 hexane tetrabasic carboxylic acid, 1,2,7, 8- octane tetrabasic carboxylic acids, Isosorbide-5-Nitrae, 5,8- naphthalenetetracarbacidic acidics, 1,2,9,10- decane tetrabasic carboxylic acid, benzophenone tetrabasic carboxylic acid, 3,3', 4,4'- bis- Benzophenonetetracarboxylic acid, tetrahydrofuran tetrabasic carboxylic acid or pentamethylene tetrabasic carboxylic acid, such as pentamethylene -1,2,3,4- tetrabasic carboxylic acids and its esters.
5. including the elimination motor vehicle interiors air pollutants device of the material described in claim 1-4 any one, it is special Levy and be, including functional material filter core, provided with the material described in claim 1-4 any one in functional material filter core；The dress Put and also include rechargeable battery, charge and discharge electrical switch, fan, functional material filter core, metal gas sensor, organic gas Sensor, particulate matter sensors, the data processing terminal with internet function, by WI-FI or mobile internet to External world's transmission signal, the application program of signal receiving device solution read signal, signal is word or sound signal.
6. elimination motor vehicle interiors air pollutants device according to claim 5, it is characterised in that：In the device Charge and discharge electrical switch operator scheme is：When automobile engine is in running status, the battery in the device is charged；In vapour When car engine is closed, battery discharge is allowed；Fan operation pattern in the device is：Fortune is in automobile engine During row state, the fan in the device is to device external environment condition air blast；When automobile engine is closed, in the device Fan from device external environment condition exhausting；The dress centers double fan operator scheme：Operation shape is in automobile engine During state, the fan 1 in the device is to device external environment condition air blast；When automobile engine is closed, in the device Fan 2 is from device external environment condition exhausting；Wherein, the fan 1 in the device is located at the fan 2 in independent parallel air channel, the device Positioned at the downstream air channel of functional material filter core.
7. elimination motor vehicle interiors air pollutants device according to claim 5, it is characterised in that：Set in the device The weight range of sensitivity that the metallic vapour sensor put has is part per trillion（1PPT）To hundred a ten thousandths（1PPM）；Should The weight range of sensitivity that filling the organic matter gaseous state sensor centered has is part per trillion（1PPT）To million/ One（1PPM）；What the particulate matter sensors that the dress is centered had is 10 microns to geometric scale（PM10）, 2.5 microns （PM2.5）With 1 micron（PM1.0）The weight range of sensitivity of particulate matter is part per billion（1PPB）To 500/1000000ths （500PPM）.
8. elimination motor vehicle interiors air pollutants device according to claim 5, it is characterised in that：In the device The data processing with wireless interconnected network telecommunication function set and transmission chip and terminal are with from as follows including but not limited to Chosen in home control network communication protocol：Bluetooth, BLE, ZIGBEE, Z-WAVE, 6LOWPAN, THREAD, WIFI ＆ WIFI-AH, 3G, 4G, 5G, LTE CAT 0,1,2,3 & LTE-M1,NB-LOT, NFC, RFID,SIGFOX, LORAWAN, INGENU, WEIGHTLESS-N & WEIGHTLESS-P & WEIGHTLESS-W, ANT & ANT+, DIGIMESH, The receiver transmission sensor signal of MIWI, ENOCEAN, DASH7 or WIRELESSHART mode external environment； Wherein optical signal（Luminous intensity or optical wavelength）Or electric signal（Current strength or voltage）It is converted into word or audio frequency Signal is obtained by external device by appropriate application program and reads or listen to；Outer signals are obtained and arrangement for reading is included admittedly Locking equipment, handheld device and wearable device.
9. elimination motor vehicle interiors air pollutants device according to claim 5, it is characterised in that：The device may The trace meter steam plasma including but not limited to Cr+, Cr2+, the Cr6+ that cause passenger car inside air pollution eliminated, Os3+, Os2+, Zn2+, Cd2+, Hg2+, Hg+, Al3+,Pb4+, Pb2+, As5+, As3+, As+；The device can The trace organic substance including but not limited to benzene for causing passenger car inside air pollution that can be eliminated, toluene, dimethylbenzene, second Benzene, styrene, formaldehyde, acetaldehyde, isopropyl aldehyde, PBDE and phthalic acid ester steam, and carbon dioxide, an oxidation Carbon, nitric oxide sulfur dioxide, hydrogen sulfide, the gaseous contaminant such as methane；What the device may be eliminated causes empty inside passenger car The trace active biomaterial of gas pollution includes but is not limited to aspergillus niger, mushroom, endotoxin, Legionella bacteria, Escherichia coli, mistake Quick original, infective virus, microorganism colloidal sol.
10. elimination motor vehicle interiors air pollutants device according to claim 5, it is characterised in that：The device institute The nano-functional material filter core contained is cylindrical, including but not limited to cylinder, cylindroid, square column, rectangle post, triangle Post, irregular shape post.
CN201710449794.3A 2017-06-14 2017-06-14 Eliminate the material and device of motor vehicle interiors air pollutants Pending CN107185313A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2558722A (en) * 2016-11-04 2018-07-18 Ford Global Tech Llc A system and methods for assessing the interior of an autonomous vehicle

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1656104A (en) * 2002-05-30 2005-08-17 巴斯福股份公司 Shaped bodies containing metal-organic frameworks
CN101426798A (en) * 2006-04-18 2009-05-06 巴斯夫欧洲公司 Metal-organic zirconium-based framework materials
CN102006929A (en) * 2007-11-04 2011-04-06 布吕歇尔有限公司 Sorption filter material and use thereof
US20150053080A1 (en) * 2012-03-28 2015-02-26 BLüCHER GMBH Adsorptive filter medium
CN204522547U (en) * 2015-04-07 2015-08-05 韩永利 A kind of multifunctional vehicle mounted air purifier

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1656104A (en) * 2002-05-30 2005-08-17 巴斯福股份公司 Shaped bodies containing metal-organic frameworks
CN101426798A (en) * 2006-04-18 2009-05-06 巴斯夫欧洲公司 Metal-organic zirconium-based framework materials
CN102006929A (en) * 2007-11-04 2011-04-06 布吕歇尔有限公司 Sorption filter material and use thereof
US20150053080A1 (en) * 2012-03-28 2015-02-26 BLüCHER GMBH Adsorptive filter medium
CN204522547U (en) * 2015-04-07 2015-08-05 韩永利 A kind of multifunctional vehicle mounted air purifier

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2558722A (en) * 2016-11-04 2018-07-18 Ford Global Tech Llc A system and methods for assessing the interior of an autonomous vehicle
US10479328B2 (en) 2016-11-04 2019-11-19 Ford Global Technologies, Llc System and methods for assessing the interior of an autonomous vehicle

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