Background technique
Machine oil filter material for combustion engine industrial filter generally constitutes body paper by cellulose fibre, synthetic fibers, and body paper is through setting
It is made after rouge dipping solidification, the main feature with higher bursting strength and the easy processings such as stiffness and flexibility.
Phenolic resin has heat curing type and two kinds of thermoplasticity.Thermosetting resin is from impregnation filter paper is started up to filter core passes through
The reaction process that assembly filter core is made in hot setting is divided into three phases.Its mechanism of action: first stage phenolic resin starts to soak
When stain handles filter paper, because the resin molecular weight is low and strand is shorter, apparent reinforcing effect not formed to filter paper, through too low
After temperature is dry, strand, which is constantly crosslinked to combine, becomes second stage phenolic resin when forming macromolecular chain;Phenolic aldehyde containing second stage
The filter paper of resin has had certain intensity, can keep intensity by the processing such as embossing, then pass through 180 DEG C of high temperature phenol
Urea formaldehyde enters phase III further crosslinking curing and forms space network, so that filter paper is obtained enough intensity and reaches dipping
The purpose of processing.But the curing degree of phenolic resin, which is extremely difficult to 100%, to be fully cured, and required energy is higher, high temperature
Curing time is longer.
Existing to be solidified using phenolic resin, there are following inevitable in conventional machine oil filter material production technology
Defect: filter paper brittleness is larger when curing degree is high, is easily broken during giving a discount, and lacks flexibility;Curing rate is slower, required
Solidification temperature is higher, and energy consumption is high;Brown is presented in color deeply after solidification, unsightly;Production cost is higher.
Therefore, a kind of new curing system is developed, the drawbacks of being brought with improvement using single thermoset phenolic resin, is reached
Low-temperature fast-curing effect is always current an open question always.
Summary of the invention
In view of the deficiencies of the prior art, a kind of rapid curing dip-coating glue of the present invention, using the oil strainer of the dip-coating glue
Paper and preparation method thereof, the filter paper have low-temperature fast-curing characteristic, and curing time is short, curing time 5-6min, have height
Stiffness, high bursting strength and excellent processing performance, beautiful appearance.
Technical scheme is as follows:
A kind of rapid curing dip-coating glue, raw material components and its weight percent composition are as follows:
Thermosetting resin 60-75%, thermoplastic resin 20-35%, promotor 0.5-2%, curing agent 1-5%,
The promotor is hexamethylenetetramine, and promotor is dicyandiamide.
Preferred according to the present invention, described rapid curing dip-coating glue, raw material components and its weight percent composition
It is as follows:
Thermosetting resin 65-70%, thermoplastic resin 25-30%, promotor 0.5-1%, curing agent 3-5%.
Highly preferred, described rapid curing dip-coating glue, raw material components and its weight percent composition are as follows:
Thermosetting resin 68%, thermoplastic resin 28%, promotor 1%, curing agent 3%.
According to the present invention, a kind of low-temperature fast-curing oil filter paper is solidified using above-mentioned dip-coating glue dilution dipping
It arrives, impregnation increment 20-26%, the dip-coating glue dilution is that hybrid resin addition methanol dilution to mass concentration is 25-
28% dilution.
According to the present invention, a kind of preparation method of low-temperature fast-curing oil filter paper, comprises the following steps that
(1) prepared by body paper: weighing and is impregnated by the composite fibre that needle pulp fibres, broad-leaved pulp fibres, PET fiber form
40-50min size degradation is diluted with water after size degradation and is discongested, and discongests rear defibrination mixing, wet strength agent is added online, by inclined wire paper
Machine is manufactured paper with pulp, and the body paper with porous loose structure is made;
(2) prepared by dip-coating glue dilution: taking curing agent, promotor not to be dissolved with methanol according to the ratio, it is molten to obtain curing agent
Liquid, accelerator solution take thermoset phenolic resin, thermal plastic phenolic resin to be added in methanol according to the ratio, are stirred at room temperature 3-5 points
Clock is added curing agent solution and stirs 5-8 minutes, is eventually adding accelerator solution and stirs 10-15 minutes, obtains the dilution of dip-coating glue
Liquid;
(3) coat: by the dip-coating glue dilution of step (2) by the way of double roller metered film transfer dip-coating to step
(1) on body paper made from, oil filter paper is obtained after dry solidification.
Preferred according to the present invention, in step (1), in composite fibre, by weight, needle pulp fibres account for 50%, are wealthy
Leaf pulp fibres account for 30%, PET fiber and account for 20%.
Preferred according to the present invention, the wet strength agent is polyamide Hydrin resin, and the quality of wet strength agent is dense
Degree is 1-4%, and the flow that wet strength agent is added online is 3-6L/h, and the additional amount of wet strength agent accounts for the 1-3 ‰ of composite fibre dry weight.
Preferred according to the present invention, in step (2), the mass concentration of dip-coating glue is 25- in dip-coating glue dilution
28%.
Preferred according to the present invention, in step (3), coating speed is 40-60m/min.
It is preferred according to the present invention, in step (3), gluing gap: 598 μm of fore side, 621 μm of transmission side.
Preferred according to the present invention, in step (3), the dry solidification is that the body paper after dip-coating successively connects by 8 groups
The cylinder group connect is dried, and 70 DEG C of 1# dryer temperature, 80 DEG C of 2# dryer temperature, 90 DEG C of 3# drying cylinder temperature, 4# dryer temperature 120
DEG C, 120 DEG C of 5# dryer temperature, 150 DEG C of 6# dryer temperature, 150 DEG C of 7# dryer temperature, 120 DEG C of 8# dryer temperature, every group it is dry when
Between be 48s.
The index for the body paper that step (1) of the present invention obtains is as follows: quantitative: 155g/m2, thickness: 850 μm, air permeability:
380L/m2* S, maximum diameter of hole: 70 μm, average pore size: 65 μm.
The oil filter paper finished product filter paper that the present invention obtains, index are as follows: quantitative: 208g/m2, thickness: 900 μm, volatile matter
Matter: 4%, stiffness: 13mN*m, bursting strength: 250KPa, air permeability: 380L/m2* S, maximum diameter of hole: 70 μm, average pore size: 65 μ
m。
The heated formaldehyde and unreacted ortho para decomposited of promotor hexamethylenetetramine in dip-coating glue of the invention
Active site reaction, while dehydration forms methine key bridge, curing agent dicyandiamide is diamines substance, and both ends pass through the hydroxyl with phenolic aldehyde
Base carries out dehydration, forms cross-linked structure, produces so that the further polycondensation of resin be made to obtain insoluble three-dimensional-structure solidification
Object.The present invention provides group required for phenolic resin curing by curing agent and promotor, enables phenolic resin in low temperature
Rapid curing under state is able to maintain certain flexibility and is easy to add after solidifying due to the effect filter paper of thermal plastic phenolic resin
Work, to keep color after further solidification vivid, intensity is stiff.
Beneficial effects of the present invention are as follows:
1, using dip-coating glue dip-coating body paper of the invention, under identical oven temperature conditions, phenolic aldehyde is used than existing
Speed 10% can be improved in resin, can be improved yield, additional income.
2, using dip-coating glue dip-coating body paper of the invention, the product of acquisition also has good under the premise of guaranteeing filter paper
Flexibility, be easy to subsequent workshop section discounting processing.
3, dip-coating glue of the invention due to curing rate it is very fast, when being made into filter core volatile substance it is less be conducive to environmental protection,
Such product can be applied to the processing of environment-friendly filter element.
In embodiment, embodiment 1:
Dip-coating glue:
The low-temperature fast-curing dip-coating glue of oil filter paper, raw material components and its weight percent composition are as follows:
Thermosetting resin 68%, thermoplastic resin 28%, dicyandiamide 1%, hexamethylenetetramine 3%.
A kind of preparation method of low-temperature fast-curing oil filter paper, comprises the following steps that
(1) prepared by body paper: weighing and is impregnated by the composite fibre that needle pulp fibres, broad-leaved pulp fibres, PET fiber form
45min size degradation, in composite fibre, by weight, needle pulp fibres account for 50%, broad-leaved pulp fibres and account for 30%, PET fiber and account for
20%.It is imported after fluffer is discongested after the completion of size degradation and discongests stock tank, using cone after discongesting stock tank and plain boiled water dilution is added
It is imported after shape paste mill grinding and destroies forebay, the fiber mixed reaches header box by fan pump, will be diluted to 2% in header box
The wet strength agent of concentration is added in wood pulp cellulose online with the flow that metering pump is adjusted to 5L/h, is manufactured paper with pulp and is provided by oblique net paper machine
The body paper for thering is porosity and looseness to construct;
(2) prepared by dip-coating glue dilution: taking curing agent, promotor not to be dissolved with methanol according to the ratio, it is molten to obtain curing agent
Liquid, accelerator solution take thermoset phenolic resin, thermal plastic phenolic resin to be added in methanol according to the ratio, are stirred at room temperature 3-5 points
Clock is added curing agent solution and stirs 5-8 minutes, is eventually adding accelerator solution and stirs 10-15 minutes, obtains the dilution of dip-coating glue
Liquid;The mass concentration of dip-coating glue is 28% in dip-coating glue dilution.
(3) coat: by the dip-coating glue dilution of step (2) by the way of double roller metered film transfer dip-coating to step
(1) on body paper made from, oil filter paper is obtained after dry, coating speed is 40-60m/min.Gluing gap: 598 μm of fore side
621 μm of transmission side.It is specific dry are as follows: 1#70 DEG C 2#80 DEG C 3#90 DEG C 4#120 DEG C 5#120 DEG C 6#150 DEG C of 7#150 in step (3)
DEG C of 8#120 DEG C every section of drying time is 48s.
Embodiment 3:
With dip-coating glue described in embodiment 1, the difference is that, raw material components and its weight percent composition are as follows:
Thermosetting resin 65%, thermoplastic resin 30%, dicyandiamide 1%, hexamethylenetetramine 4.
Experimental example:
It is spare in normal temperature state naturally dry by dip-coating glue dip-coating body paper of the invention.Pattern obtained is in 180 DEG C of items
Solidifying the different time under part, room temperature balances after 1h air permeability, curing degree, stiffness, bursting strength after the impregnation of re-test pattern, and
It is compared as a control group with existing using thermosetting phenolic resin coating body paper, the present invention and control group solidify different time
Test result afterwards see the table below shown in 1.
Body paper is all made of the same kind body paper of oblique net paper machine production as substrate, is all made of same dip coating manner and carries out.
Air permeability, curing degree, stiffness, bursting strength after the impregnation of the different curing times of table 1
It can be seen that from upper 1 data of table and the coating process of promotor and curing agent curing rate under the same conditions be added
Fastly, pattern intensity is high.
The baking oven that the pattern that two kinds solidify 4min is placed again into 180 DEG C under the state of cooling is heated into 1min, takes out pattern
Pattern is done bending immediately to find to keep bending state using the pattern that gluing solution of the invention obtains after cooling, and is used
The pattern that thermosetting phenolic resin coating obtains rebounds back straightened condition again.It is certain that gluing solution of the invention can be such that pattern has
Processing toughness.