CN107177332A - A kind of net taste mattress glue spraying of SBS graft types and preparation method thereof - Google Patents
A kind of net taste mattress glue spraying of SBS graft types and preparation method thereof Download PDFInfo
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- CN107177332A CN107177332A CN201710412549.5A CN201710412549A CN107177332A CN 107177332 A CN107177332 A CN 107177332A CN 201710412549 A CN201710412549 A CN 201710412549A CN 107177332 A CN107177332 A CN 107177332A
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- sbs
- glue spraying
- mattress
- net taste
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- 239000003292 glue Substances 0.000 title claims abstract description 32
- 238000005507 spraying Methods 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 35
- 229920005989 resin Polymers 0.000 claims abstract description 35
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims abstract description 24
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims abstract description 24
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 229920001971 elastomer Polymers 0.000 claims abstract description 17
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 16
- 239000000806 elastomer Substances 0.000 claims abstract description 16
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003208 petroleum Substances 0.000 claims abstract description 13
- RMOUBSOVHSONPZ-UHFFFAOYSA-N Isopropyl formate Chemical compound CC(C)OC=O RMOUBSOVHSONPZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000003756 stirring Methods 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 4
- 125000005456 glyceride group Chemical group 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 239000012528 membrane Substances 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 238000006253 efflorescence Methods 0.000 abstract description 6
- 239000004014 plasticizer Substances 0.000 abstract description 6
- 206010037844 rash Diseases 0.000 abstract description 6
- 239000004744 fabric Substances 0.000 abstract description 4
- 230000005764 inhibitory process Effects 0.000 abstract description 4
- 230000009967 tasteless effect Effects 0.000 abstract description 4
- 102100026735 Coagulation factor VIII Human genes 0.000 abstract 1
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 abstract 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000004926 polymethyl methacrylate Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- -1 as spray painting Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- HKFDLEWUVASVEU-UHFFFAOYSA-N formaldehyde methyl prop-2-enoate Chemical compound C(C=C)(=O)OC.C=O HKFDLEWUVASVEU-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/006—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Graft Or Block Polymers (AREA)
Abstract
The present invention discloses net taste mattress glue spraying of a kind of SBS graft types and preparation method thereof, includes the component of following parts by weight：10~15 parts of methyl iso-butyl ketone (MIBK)；5~10 parts of isopropyl formate；10~20 parts of aromatics environmentally friendly solvent oil；15~25 parts of hexahydrotoluene；10~18 parts of SBS elastomers；0.1~0.5 part of BPO；5~15 parts of MMA；0~8 part of BA；2 0~3 part of HEMA；1~3 part of terminator；10~15 parts of hydrogenated petroleum resin；12~18 parts of modified by hydrogenated rosin resin.The net taste mattress glue spraying of SBS graft types of the present invention, water white transparency, bonding force are strong, color inhibition, resistance to efflorescence, high temperature resistant, oil resistant, anti-plasticizer, poisonless, tasteless and non-residue, it is the preferable glue spraying selection of high-grade mattress manufacturer, during spraying application, smell is small, glued membrane noresidue solvent and resin smell, glued membrane, will not dirty hypochromatic mattress fabric after applying glue to be pure white and translucent.
Description
Technical field：
The present invention relates to adhesive area, it is related to during mattress production a kind of net taste spray of used SBS graft types
Glue and preparation method thereof.
Background technology：
Current mattress production business requires mattress glue spraying, and water white transparency simultaneously has strong bonding force, color inhibition, resistance to efflorescence, resistance to height
Temperature.The net taste glue spraying of nontoxic, tasteless, noresidue (smell and solvent) is glued, what is had also requires that grease proofing, anti-plasticizer oozes out.City
Some mattress glue manufacturers on field, have selected the solvent and tackifying resin of cheap low-quality, and glue yellow is muddy, in tackifying resin
Impurity, poisonous and hazardous organic solvent residual in glued membrane, absorption impairs the health of consumer in mattress.SBS elasticity
Body molecular structure includes substantial amounts of-C=C- unsaturated double-bonds, the defect of this also decision itself, the chemistry containing-C=C- double bonds
Molecular structure, 1, easily degraded by the dioxygen oxidation in air, its performance is：Glued membrane easily turns yellow, become fragile, efflorescence.2nd, stability
Difference, its performance is：Temperature easily loses bonding force when raising, and bonding strength is reduced rapidly.This kind of product is sprayed on light fabric
Mattress when can pollute fabric, have residual smell, the kinds of risks such as degumming, it is impossible to meet the demand of mattress manufacturer.
In view of this, the present inventor proposes following technical scheme.
The content of the invention：
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of net taste glue spraying of SBS graft types and its preparation
Method.
In order to solve the above-mentioned technical problem, present invention employs following technical proposals：The net taste mattress spray of the SBS graft types
Glue, it is characterised in that：Include the component of following parts by weight：10~15 parts of methyl iso-butyl ketone (MIBK)；5~10 parts of isopropyl formate；Virtue
Fragrant 10~20 parts of class environmentally friendly solvent oil；15~25 parts of hexahydrotoluene；10~18 parts of SBS elastomers；0.1~0.5 part of BPO；
5~15 parts of MMA；0~8 part of BA；0~3 part of 2-HEMA；1~3 part of terminator；10~15 parts of hydrogenated petroleum resin；Hydrogenation pine
Fragrant 12~18 parts of modified resin.
Furthermore, in above-mentioned technical proposal, the parts by weight of each component are：10 parts of methyl iso-butyl ketone (MIBK)；Formic acid isopropyl
6 parts of ester；12 parts of aromatics environmentally friendly solvent oil；18 parts of hexahydrotoluene；15 parts of SBS elastomers；0.2 part of BPO；9 parts of MMA；BA
2 parts；1 part of 2-HEMA；1.8 parts of terminator；11 parts of hydrogenated petroleum resin；14 parts of modified by hydrogenated rosin resin.
Furthermore, in above-mentioned technical proposal, described SBS elastomers are styrene butadiene block copolymer elastomer
SBS1401。
Furthermore, in above-mentioned technical proposal, described hydrogenated petroleum resin is a kind of white Petropols of perhydrogenating；
Modified by hydrogenated rosin resin is a kind of white hydrogenated rosin glyceride.
In order to solve the above-mentioned technical problem, present invention employs following second of technical scheme, the net taste bed of the SBS graft types
The preparation method of pad glue spraying comprises the following steps：
Step one：By methyl iso-butyl ketone (MIBK), isopropyl formate, aromatics environmentally friendly solvent oil, hexahydrotoluene at normal temperatures
Stir into uniform mixed liquor；
Step 2：SBS elastomers are added in the uniform mixed liquor of step one, stirring and dissolving is into homogeneous transparent solution；
Step 3：It is passed through protective gas N2 into homogeneous transparent solution, and is warming up to 65 DEG C -95 DEG C, pressure≤
0.01MPa；
Step 4：Add initiator B PO, MMA, BA, 2-HEMC stirring；
Step 5：Stirring reaction 4 hours at a temperature of 75-90 DEG C；
Step 6：Terminator is added to cool≤30 DEG C；
Step 7：Add hydrogenated petroleum resin, hydrogenated rosin resin stirring and dissolving uniform.
After adopting the above technical scheme, the present invention has the advantages that compared with prior art：
1. the net taste mattress glue spraying of SBS graft types of the present invention meets《Nuisance in indoor decorating and refurnishing materials adhesive
Matter is limited the quantity》GB18583-2008, national standard and《Environmental labelling product technical requirements adhesive》HT2541-2016；
2nd, the present invention increases due to being grafted esters of acrylic acid polar group, intermolecular force on SBS strands, therefore
With traditional SBS adhesive ratio, bonding force and bonding strength is greatly improved；Due to-C=C- the double bonds on SBS strands
Middle introducing esters of acrylic acid group, double-strand number is greatly decreased, and it is also significantly dropped by the possibility that dioxygen oxidation in air is degraded
It is low, therefore have more preferable color inhibition, resistance to efflorescence, resistant to elevated temperatures advantage than traditional product.
3rd, esters of acrylic acid in process of grafting, can produce self-polymeric reaction in the present invention, self-polymeric reaction generation
PMMA etc., can improve the toughness of glued membrane, simultaneously because PMMA is larger with plasticizer molecule polarity spectrum in mattress material, there is anti-
The effect of oily, anti-plasticizer infiltration.
4th, mixed solvent reasonable mixture ratio in the present invention, tackifying resin used is entirely perhydrogenating white resin, the present invention
Product appearance be colourless transparent liquid.Mixed solvent used is environmentally friendly, light taste, quick-dry type, during spraying application, gas
Taste is small, glued membrane noresidue solvent and resin smell, and glued membrane is pure white and translucent., will not dirty hypochromatic mattress fabric after applying glue.
5th, the net taste mattress glue spraying of SBS graft types produced by the present invention, water white transparency, bonding force are strong, color inhibition, resistance to efflorescence,
High temperature resistant, oil resistant, anti-plasticizer, poisonless, tasteless and non-residue, are the preferable glue spraying selections of high-grade mattress manufacturer.
Embodiment：
With reference to specific embodiment, the present invention is further described.
Embodiment one：
A kind of net taste mattress glue spraying of SBS graft types, includes the component of following parts by weight：
10~15 parts of methyl iso-butyl ketone (MIBK)；
5~10 parts of isopropyl formate；
10~20 parts of aromatics environmentally friendly solvent oil；
15~25 parts of hexahydrotoluene；
10~18 parts of SBS elastomers；
0.1~0.5 part of BPO；
5~15 parts of MMA；
0~8 part of BA；
0~3 part of 2-HEMA；
1~3 part of terminator；
10~15 parts of hydrogenated petroleum resin；
12~18 parts of modified by hydrogenated rosin resin.
As preferred embodiment, the net taste mattress glue spraying of SBS graft types in the present embodiment, the parts by weight of each component are：
10 parts of methyl iso-butyl ketone (MIBK)；
6 parts of isopropyl formate；
12 parts of aromatics environmentally friendly solvent oil；
18 parts of hexahydrotoluene；
15 parts of SBS elastomers；
0.2 part of BPO；
9 parts of MMA；
2 parts of BA；
1 part of 2-HEMA；
1.8 parts of terminator；
11 parts of hydrogenated petroleum resin；
14 parts of modified by hydrogenated rosin resin.
Described methyl iso-butyl ketone (MIBK) is water sample transparency liquid, as spray painting, nitrocellulose, some fiber ethers, camphor, oil
The solvent of fat, natural and synthetic rubber；
Described SBS elastomers be to a kind of rubber performance the most similar thermoplastic elastomer (TPE), be benzene in the present embodiment
Ethylene-butylene block copolymer elastomer SBS1401.
Described BPO is benzoyl peroxide, and MMA is formaldehyde methyl acrylate, and 2-HEMA is the easy flow fluid of water white transparency
Body, -12 DEG C of fusing point, 205-208 DEG C of 95 DEG C of boiling point (1.333kPa) (1atm), 87 DEG C (0.67kPa), 71-73 DEG C
(0.267kPa), relative density 1.074 (20/4 DEG C), refractive index 1.4505,108 DEG C of flash-point (opening cup).It is miscible with water, it is dissolved in general
Logical organic solvent.
Described hydrogenated petroleum resin is a kind of white Petropols of perhydrogenating, relative density 1.01, and color is shallower, resistance to old
The property changed is improved.It is developed to realize the performance of binder resin high-quality, is mainly used in hot melt adhesive, hot melt pressure is quick
Sense type adhesive and solvent.
Described terminator is the use agent of polymer chemistry chain polymerization course of reaction, can be terminated in chain polymerization reaction
The material that polymerisation proceeds.These materials can make them lose activity with triggering free radical and Propagating Radical to react,
So as to the growth of terminating chain, stop polymerisation and proceed, its effect is the terminator of free radical, polymerization is terminated in good time anti-
Should, molecular weight uniform, the high-quality polymeric articles of molecular structure stabilized can be obtained
Described modified by hydrogenated rosin resin is a kind of white hydrogenated rosin glyceride, as solvent pressure-sensitive adhesive, molten
Ageing-resistant, the non-corrosive tackifying resin of formulation all-purpose adhesive, PUR etc., 80~90 DEG C of softening point, with good antioxygen
Change performance.
The preparation method for making the above-mentioned net taste mattress glue spraying of SBS graft types comprises the following steps：
Step one：By methyl iso-butyl ketone (MIBK), isopropyl formate, aromatics environmentally friendly solvent oil, hexahydrotoluene at normal temperatures
Stir into uniform mixed liquor；
Step 2：SBS elastomers are added in the uniform mixed liquor of step one, stirring and dissolving is into homogeneous transparent solution；
Step 3：It is passed through protective gas N2 into homogeneous transparent solution, and is warming up to 65 DEG C -95 DEG C, pressure≤
0.01MPa；
Step 4：Add initiator B PO, MMA, BA, 2-HEMC stirring；
Step 5：Stirring reaction 4 hours at a temperature of 75-90 DEG C；
Step 6：Terminator is added to cool≤30 DEG C；
Step 7：Add hydrogenated petroleum resin, hydrogenated rosin resin stirring and dissolving uniform.
More specifically, its manufacturing process is as follows：
Into volume 500ml reactor, methyl iso-butyl ketone (MIBK) 30g, isopropyl formate 18g, fragrance environmental protection are added
Solvent naphtha 36g, hexahydrotoluene 54g.At normal temperatures, after stirring 5 minutes, it is passed through after adding the 45g of SBS 1401, stirring and dissolving
Inert protective gas N2, pressure≤0.01MPa, and empty three times.Heat temperature raising.Temperature control is added within 75~85 DEG C draws
Agent BPO 0.6g are sent out, grafted monomers MMA 36g is then added, maintains the temperature between 80~95 DEG C, 4 hours time, reacted
Bi Hou, adds terminator 5.4g, when being cooled to≤30 DEG C, adds the white Petropols 33g of perhydrogenating, and white hydrogenated rosin is sweet
Grease resin 42g, stirring and dissolving is uniform, obtains water white transparency glue.
Film sample washs the unreacted free monomer of removing with ethanol, determines its solid content, calculate list after air-drying
The conversion ratio of body, by using isopropyl alcohol extraction mode, extracts the PMMA of monomer autohemagglutination generation, can calculate the grafting of monomer
Rate.Viscosity is measured with rotary viscosimeter.
Glue characteristic is in table 1 below after SBS grafting
Embodiment two：
The method of type as described in embodiment one, produces the net taste mattress glue spraying of SBS graft types, except that using not
With grafted monomers and ratio, the SBS obtained by addition MMA 30g, BA 6g is grafted glue characteristic in table 1 below.
Embodiment three：
The method production of type, the net taste mattress glue spraying of SBS graft types, except that using not as described in embodiment one
With grafted monomers and ratio, add MMA 33g, 2-HEMC 3g, resulting SBS and be grafted glue characteristic in table 1 below.
Table 1
From these results, it is apparent that the product water white transparency prepared according to the method for the present invention, adds SBS and connect
Branch reaction, substantial amounts of acrylic groups are grafted on SBS strands, and SBS intramolecular number of double bonds is greatly reduced, and is allowed to connect
Properties of product after branch show drastic change, and bonding force, bonding strength, resistance to flavescence, resistance to efflorescence, heat-resisting quantity greatly improve, have oil resistant,
Anti- plasticizer osmosis, glued membrane is nonpoisonous and tasteless, transparent pure white, is that high-grade mattress manufacturer is preferably selected.
Certainly, the foregoing is only the specific embodiment of the present invention, not limit the scope of the present invention, it is all according to
The equivalent change or modification that construction, feature and principle described in scope of the present invention patent are done, all should be included in Shen of the present invention
Please be in the scope of the claims.
Claims (5)
1. a kind of net taste mattress glue spraying of SBS graft types, it is characterised in that：Include the component of following parts by weight：
10~15 parts of methyl iso-butyl ketone (MIBK)；
5~10 parts of isopropyl formate；
10~20 parts of aromatics environmentally friendly solvent oil；
15~25 parts of hexahydrotoluene；
10~18 parts of SBS elastomers；
0.1~0.5 part of BPO；
5~15 parts of MMA；
0~8 part of BA；
0~3 part of 2-HEMA；
1~3 part of terminator；
10~15 parts of hydrogenated petroleum resin；
12~18 parts of modified by hydrogenated rosin resin.
2. the net taste mattress glue spraying of a kind of SBS graft types according to claim 1, it is characterised in that：The parts by weight of each component
For：
10 parts of methyl iso-butyl ketone (MIBK)；
6 parts of isopropyl formate；
12 parts of aromatics environmentally friendly solvent oil；
18 parts of hexahydrotoluene；
15 parts of SBS elastomers；
0.2 part of BPO；
9 parts of MMA；
2 parts of BA；
1 part of 2-HEMA；
1.8 parts of terminator；
11 parts of hydrogenated petroleum resin；
14 parts of modified by hydrogenated rosin resin.
3. the net taste mattress glue spraying of a kind of SBS graft types according to claim 1, it is characterised in that：Described SBS elastomers
For styrene butadiene block copolymer elastomer SBS1401.
4. the net taste mattress glue spraying of a kind of SBS graft types according to claim 1, it is characterised in that：Described non-hydrogenated petroleum
Resin is a kind of white Petropols of perhydrogenating；Modified by hydrogenated rosin resin is a kind of white hydrogenated rosin glyceride.
5. a kind of preparation method of the net taste mattress glue spraying of SBS graft types, it is characterised in that：Comprise the following steps：
Step one：Methyl iso-butyl ketone (MIBK), isopropyl formate, aromatics environmentally friendly solvent oil, hexahydrotoluene are stirred at normal temperatures
Into uniform mixed liquor；
Step 2：SBS elastomers are added in the uniform mixed liquor of step one, stirring and dissolving is into homogeneous transparent solution；
Step 3：Protective gas N2 is passed through into homogeneous transparent solution, and is warming up to 65 DEG C -95 DEG C, pressure≤0.01MPa；
Step 4：Add initiator B PO, MMA, BA, 2-HEMC stirring；
Step 5：Stirring reaction 4 hours at a temperature of 75-90 DEG C；
Step 6：Terminator is added to cool≤30 DEG C；
Step 7：Add hydrogenated petroleum resin, hydrogenated rosin resin stirring and dissolving uniform.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710412549.5A CN107177332B (en) | 2017-06-03 | 2017-06-03 | A kind of SBS graft types ordor removing mattress glue spraying and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710412549.5A CN107177332B (en) | 2017-06-03 | 2017-06-03 | A kind of SBS graft types ordor removing mattress glue spraying and preparation method thereof |
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| CN107177332B CN107177332B (en) | 2018-11-09 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108611054A (en) * | 2018-04-13 | 2018-10-02 | 中科广化（重庆）新材料研究院有限公司 | A kind of no triphen SBS types black glue spraying and preparation method thereof |
| CN109705778A (en) * | 2018-12-14 | 2019-05-03 | 广州都邦材料科技有限公司 | A kind of acidproof pressure-sensitive adhesive, preparation method and applications |
| CN115725250A (en) * | 2022-10-18 | 2023-03-03 | 烟台德邦科技股份有限公司 | PI single-sided adhesive tape applied to protection of cylindrical lithium battery tabs |
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| CN102775955A (en) * | 2011-05-11 | 2012-11-14 | 深圳市顾康力化工有限公司 | Environment-friendly solvent spraying glue and preparation method thereof |
| CN103396748A (en) * | 2013-07-11 | 2013-11-20 | 北京化工大学 | Benzene compound-free and halide-free environment-friendly SBS (Styrene Butadiene Styrene) graft modification adhesive and preparation method thereof |
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| CN102775955A (en) * | 2011-05-11 | 2012-11-14 | 深圳市顾康力化工有限公司 | Environment-friendly solvent spraying glue and preparation method thereof |
| CN103396748A (en) * | 2013-07-11 | 2013-11-20 | 北京化工大学 | Benzene compound-free and halide-free environment-friendly SBS (Styrene Butadiene Styrene) graft modification adhesive and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108611054A (en) * | 2018-04-13 | 2018-10-02 | 中科广化（重庆）新材料研究院有限公司 | A kind of no triphen SBS types black glue spraying and preparation method thereof |
| CN109705778A (en) * | 2018-12-14 | 2019-05-03 | 广州都邦材料科技有限公司 | A kind of acidproof pressure-sensitive adhesive, preparation method and applications |
| CN115725250A (en) * | 2022-10-18 | 2023-03-03 | 烟台德邦科技股份有限公司 | PI single-sided adhesive tape applied to protection of cylindrical lithium battery tabs |
| CN115725250B (en) * | 2022-10-18 | 2023-11-10 | 烟台德邦科技股份有限公司 | PI single-sided adhesive tape applied to cylindrical lithium battery tab protection |
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| Publication number | Publication date |
|---|---|
| CN107177332B (en) | 2018-11-09 |
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