CN107177277A - A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer and preparation method thereof - Google Patents
A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer and preparation method thereof Download PDFInfo
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- CN107177277A CN107177277A CN201710329521.5A CN201710329521A CN107177277A CN 107177277 A CN107177277 A CN 107177277A CN 201710329521 A CN201710329521 A CN 201710329521A CN 107177277 A CN107177277 A CN 107177277A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/44—Amides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
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- Chemical & Material Sciences (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is made up of following raw material：15 20 parts of aqueous epoxy resins；10 20 parts of filling material；50 70 parts of zinc powder；0.5 1 parts of flash rust inhibitor；0.5 1 parts of pH adjusting agent；0.1 0.5 parts of wetting dispersing agent；40 60 parts of deionized water；0.1 0.5 parts of adhesion promoter；5 10 parts of coalescents；5 10 parts of curing agent.The heavy-duty antiseptic paint has good workability, and strong to metal adhesive power, excitant is extremely low, VOC free discharge, environmentally friendly.
Description
Technical field
The present invention relates to anticorrosive paint field, and in particular to a kind of container watersoluble metal heavy anti-corrosion epoxy zinc-rich bottom
Paint and preparation method thereof.
Background technology
Anticorrosive paint refers to apply under harsh corrosive environment and the coating with long-acting service life.Anticorrosive paint
As the favourite son of anticorrosive paint, since applying since 60~seventies of 20th century, developed rapidly, application is more next
It is wider, especially ship, container Offshore Units, seashore and bay structure, offshore oil platform, freeway guardrail,
Bridge, train and railway facility, automobile etc. contain the field of a large amount of metal materials.
At present, I takes charge of main container epoxy zinc-rich paint for solvent-type double-component coating, there is VOC content height, construction
In have obvious peculiar smell, the problems such as inflammable and explosive, develop the container above-mentioned problems of watersoluble metal heavy anti-corrosion epoxy zinc rich paint
It can then be readily solved.
Container plant requirement is not done in production line rhythm of production, production technology under the conditions of big variation, the construction that can have had
Performance, while being not less than the performance of oiliness zinc rich paint again.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer,
Overcome drawbacks described above.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, described container is rich with watersoluble metal heavy anti-corrosion epoxy
Yellow zinc chromate primer paint is made up of following parts by weight raw material：
15-20 parts of aqueous epoxy resins；
10-20 parts of filling material；
50-70 parts of zinc powder；
0.5-1 parts of flash rust inhibitor；
0.5-1 parts of pH adjusting agent；
0.1-0.5 parts of wetting dispersing agent；
40-60 parts of deionized water；
0.1-0.5 parts of adhesion promoter；
5-10 parts of coalescents；
5-10 parts of curing agent.
Further, described filling material includes nano-sheet aluminum oxide, at least one of nanoscale talcum powder.Nanometer sheet
When shape filler is added in coating applied on base material, filler is arranged parallel to base material, and hydrone can be prevented to reach substrate interface, is protected
Protect container substrate interface.
Further, described flash rust inhibitor is BP-4.
Further, described coalescents include propandiol butyl ether, at least one of propylene glycol methyl ether acetate.
Further, described adhesion promoter is organosilan.
Further, described wetting dispersing agent is sodium dioctyl sulfosuccinate.
Further, described curing agent is non-ion aqueous polyamide.
Further, described aqueous epoxy resins, its epoxide equivalent is 400 ~ 800, and solid content is 50 ± 3%.The parameter
Aqueous epoxy resins with having preferably pliability and reactivity.
A kind of preparation method of described container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that institute
The preparation method stated is：
（1）Corresponding raw material is weighed by the formula；
（2）Aqueous epoxy resins are added in agitator, deionized water dilution is added, stirs 10 ~ 20min, add wetting point
Powder；
（3）Color stuffing and zinc powder are added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Bead is added in the mixture, is carried out high dispersive and is ground 60 ~ 90min, with 200 mesh filter screen filtrations；
（5）In filtrate add flash rust inhibitor, coalescents, adhesion promoter, curing agent, stirring 20min add go from
Sub- water and thickener adjust viscosity to 200-500cP, add pH adjusting agent regulation filtrate pH to 7.5-9.Described thickener
For the waterborne epoxy coatings thickener of conventional commercial, those skilled in the art can need to adjust addition according to production.
Beneficial effect：
The anticorrosive paint has suitable viscosity, sagging performance, rapid draing ability, and workability is excellent.Paint film has excellent
Adhesive force, pliability, the impact resistance of show, reach the same paint film antiseptic property of oiliness zinc rich paint；Add zinc powder increase resistance to
Corrosive nature, neutral salt spray performance was more than 2500 hours；The anti-flash rusting agent of water paint is added, control system ensures high ph-values, anti-base
The corrosion paint film of material steel corrosion and zinc powder.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
Aqueous epoxy resins used, its epoxide equivalent is 400 ~ 800, and solid content is 50 ± 3%, and organosilan is road health
Peaceful Z6040, remaining raw material is conventional commercial product.
Embodiment 1
A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, described container is rich with watersoluble metal heavy anti-corrosion epoxy
Yellow zinc chromate primer paint is made up of following parts by weight raw material：
15 parts of aqueous epoxy resins；
20 parts of nano-sheet aluminum oxide；
50 parts of zinc powder；
1 part of flash rust inhibitor；
0.5 part of pH adjusting agent；
0.5 part of sodium dioctyl sulfosuccinate；
60 parts of deionized water；
0.5 part of organosilan；
5 parts of propandiol butyl ether；
Non-ion aqueous 10 parts of polyamide.
A kind of preparation method of described container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that institute
The preparation method stated is：
（1）Corresponding raw material is weighed by the formula；
（2）Aqueous epoxy resins are added in agitator, deionized water dilution is added, stirs 10 ~ 20min, add wetting point
Powder；
（3）Nano-sheet aluminum oxide and zinc powder are added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Bead is added in the mixture, is carried out high dispersive and is ground 60 ~ 90min, with 200 mesh filter screen filtrations；
（5）In filtrate add flash rust inhibitor, coalescents, adhesion promoter, curing agent, stirring 20min add go from
Sub- water and thickener adjust viscosity to 1000-2000cP, add pH adjusting agent regulation filtrate pH to 7.5-9.
Embodiment 2
A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, described container is rich with watersoluble metal heavy anti-corrosion epoxy
Yellow zinc chromate primer paint is made up of following parts by weight raw material：
20 parts of aqueous epoxy resins；
5 parts of nano-sheet aluminum oxide, 5 parts of nanoscale talcum powder；
70 parts of zinc powder；
0.5 part of BP-4；
1 part of pH adjusting agent；
0.1 part of sodium dioctyl sulfosuccinate；
40 parts of deionized water；
0.1 part of organosilan；
5 parts of propylene glycol methyl ether acetate；
Non-ion aqueous 5 parts of polyamide.
A kind of preparation method of described container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that institute
The preparation method stated is：
（1）Corresponding raw material is weighed by the formula；
（2）Aqueous epoxy resins are added in agitator, deionized water dilution is added, stirs 10 ~ 20min, add wetting point
Powder；
（3）Nano-sheet aluminum oxide, nanoscale talcum powder and zinc powder are added in agitator, 30 ~ 50min is quickly stirred, it is ensured that
It is well mixed；
（4）Bead is added in the mixture, is carried out high dispersive and is ground 60 ~ 90min, with 200 mesh filter screen filtrations；
（5）In filtrate add flash rust inhibitor, coalescents, adhesion promoter, curing agent, stirring 20min add go from
Sub- water and thickener adjust viscosity to 1000-2000cP, add pH adjusting agent regulation filtrate pH to 7.5-9.
Embodiment 3
A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, described container is rich with watersoluble metal heavy anti-corrosion epoxy
Yellow zinc chromate primer paint is made up of following parts by weight raw material：
18 parts of aqueous epoxy resins；
15 parts of nano-sheet aluminum oxide, 5 parts of nanoscale talcum powder；
57 parts of zinc powder；
0.3 part of BP-4；
0.4 part of pH adjusting agent；
0.4 part of sodium dioctyl sulfosuccinate；
50 parts of deionized water；
0.3 part of organosilan；
3 parts of propandiol butyl ether, 4 parts of propylene glycol methyl ether acetate；
Non-ion aqueous 6 parts of polyamide.
A kind of preparation method of described container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that institute
The preparation method stated is：
（1）Corresponding raw material is weighed by the formula；
（2）Aqueous epoxy resins are added in agitator, deionized water dilution is added, stirs 10 ~ 20min, add wetting point
Powder；
（3）Nano-sheet aluminum oxide, nanoscale talcum powder and zinc powder are added in agitator, 30 ~ 50min is quickly stirred, it is ensured that
It is well mixed；
（4）Bead is added in the mixture, is carried out high dispersive and is ground 60 ~ 90min, with 200 mesh filter screen filtrations；
（5）In filtrate add flash rust inhibitor, coalescents, adhesion promoter, curing agent, stirring 20min add go from
Sub- water and thickener adjust viscosity to 1000-2000cP, add pH adjusting agent regulation filtrate pH to 7.5-9.
In order to further illustrate container watersoluble metal heavy anti-corrosion epoxy zinc rich primer disclosed in this invention, the present invention
Corresponding test also is carried out to the cured paint film of embodiment 1,2,3, test event is as follows：
Sagging performance：By national standard《GB9264-88》Determine relative sagging performance.
Rate of drying：By national standard《GB/T 1728–1979》Cotton pellet method is blown to be tested.
Hardness：Press《The hardness of film pencil determination methods of GB6739-86》Tested.
Salt spray test：2500 hours neutral salt spray tests.
Adhesive force：By national standard《GB9286-1988》By carrying out cross-cut methods test to film coated surface.
Pliability：Press《GB T 1731-1993》Paint film flexibility determination method is tested.
Shock resistance：Press《GB/T 1732-93》Paint film impact resistance determination method is tested.
Weatherability：Press《GBT 1767-1979》Paint film weatherability determination method.
Test result such as following table：
Claims (9)
1. a kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that the aqueous gold of described container
Category heavy antisepsis epoxy zinc rich primer is made up of following parts by weight raw material：
15-20 parts of aqueous epoxy resins；
10-20 parts of filling material；
50-70 parts of zinc powder；
0.5-1 parts of flash rust inhibitor；
0.5-1 parts of pH adjusting agent；
0.1-0.5 parts of wetting dispersing agent；
40-60 parts of deionized water；
0.1-0.5 parts of adhesion promoter；
5-10 parts of coalescents；
5-10 parts of curing agent.
2. container according to claim 1 watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that described
Filling material includes nano-sheet aluminum oxide, at least one of nanoscale talcum powder.
3. container according to claim 1 watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that described
Flash rust inhibitor is BP-4.
4. container according to claim 1 watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that described
Coalescents include propandiol butyl ether, at least one of propylene glycol methyl ether acetate.
5. container according to claim 1 watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that described
Adhesion promoter is organosilan.
6. container according to claim 1 watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that described
Wetting dispersing agent is sodium dioctyl sulfosuccinate.
7. container according to claim 1 watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that described
Curing agent is non-ion aqueous polyamide.
8. container according to claim 1 watersoluble metal heavy anti-corrosion epoxy zinc rich primer, it is characterised in that described
Aqueous epoxy resins, its epoxide equivalent is 400 ~ 800, and solid content is 50 ± 3%.
9. the preparation method of the container watersoluble metal heavy anti-corrosion epoxy zinc rich primer according to claim 1-8, it is special
Levy and be, described preparation method is：
（1）Corresponding raw material is weighed by the formula；
（2）Aqueous epoxy resins are added in agitator, deionized water dilution is added, stirs 10 ~ 20min, add wetting point
Powder；
（3）Color stuffing and zinc powder are added in agitator, 30 ~ 50min is quickly stirred, it is ensured that be well mixed；
（4）Bead is added in the mixture, is carried out high dispersive and is ground 60 ~ 90min, with 200 mesh filter screen filtrations；
（5）In filtrate add flash rust inhibitor, coalescents, adhesion promoter, curing agent, stirring 20min add go from
Sub- water and thickener adjust viscosity to 1000-2000cP, add pH adjusting agent regulation filtrate pH to 7.5-9.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710329521.5A CN107177277A (en) | 2017-05-11 | 2017-05-11 | A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710329521.5A CN107177277A (en) | 2017-05-11 | 2017-05-11 | A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107177277A true CN107177277A (en) | 2017-09-19 |
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|---|---|---|---|
| CN201710329521.5A Pending CN107177277A (en) | 2017-05-11 | 2017-05-11 | A kind of container watersoluble metal heavy anti-corrosion epoxy zinc rich primer and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107619635A (en) * | 2017-10-18 | 2018-01-23 | 江苏建中能源科技有限公司 | A kind of epoxy zinc-enriched paint and its production method |
| CN109385178A (en) * | 2018-09-19 | 2019-02-26 | 惠州市惠阳区嘉泰涂料有限公司 | A kind of abrasion-resistance water epoxy coating of normal temperature cure |
| CN109468001A (en) * | 2018-09-19 | 2019-03-15 | 惠州市惠阳区嘉泰涂料有限公司 | A kind of waterborne inorganic einc-rich primer and preparation method thereof |
| CN109943202A (en) * | 2018-05-10 | 2019-06-28 | 成都拜迪新材料有限公司 | A kind of aqueous epoxy nano fiber anticorrosive paint and preparation method thereof |
| CN115491098A (en) * | 2021-06-19 | 2022-12-20 | 河南青山环保科技有限公司 | Water-based flaky magnet powder heavy-duty anticorrosive primer and preparation method thereof |
| CN116496677A (en) * | 2023-04-25 | 2023-07-28 | 广州境好新材料有限公司 | Thermosetting container water-based epoxy zinc-rich paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104771A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料（深圳）有限公司 | Water-based epoxy zinc-rich primer |
| CN102746765A (en) * | 2012-07-23 | 2012-10-24 | 河北晨阳工贸集团有限公司 | Waterborne epoxy zinc-rich primer and preparation method thereof |
| CN106519905A (en) * | 2016-11-21 | 2017-03-22 | 牛宝芬 | Waterborne heavy anticorrosion coating for metal |
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2017
- 2017-05-11 CN CN201710329521.5A patent/CN107177277A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101104771A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料（深圳）有限公司 | Water-based epoxy zinc-rich primer |
| CN102746765A (en) * | 2012-07-23 | 2012-10-24 | 河北晨阳工贸集团有限公司 | Waterborne epoxy zinc-rich primer and preparation method thereof |
| CN106519905A (en) * | 2016-11-21 | 2017-03-22 | 牛宝芬 | Waterborne heavy anticorrosion coating for metal |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107619635A (en) * | 2017-10-18 | 2018-01-23 | 江苏建中能源科技有限公司 | A kind of epoxy zinc-enriched paint and its production method |
| CN109943202A (en) * | 2018-05-10 | 2019-06-28 | 成都拜迪新材料有限公司 | A kind of aqueous epoxy nano fiber anticorrosive paint and preparation method thereof |
| CN109385178A (en) * | 2018-09-19 | 2019-02-26 | 惠州市惠阳区嘉泰涂料有限公司 | A kind of abrasion-resistance water epoxy coating of normal temperature cure |
| CN109468001A (en) * | 2018-09-19 | 2019-03-15 | 惠州市惠阳区嘉泰涂料有限公司 | A kind of waterborne inorganic einc-rich primer and preparation method thereof |
| CN115491098A (en) * | 2021-06-19 | 2022-12-20 | 河南青山环保科技有限公司 | Water-based flaky magnet powder heavy-duty anticorrosive primer and preparation method thereof |
| CN116496677A (en) * | 2023-04-25 | 2023-07-28 | 广州境好新材料有限公司 | Thermosetting container water-based epoxy zinc-rich paint and preparation method thereof |
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Application publication date: 20170919 |