CN107173839B - A kind of oily phase suspension system and the preparation method and application thereof based on single diglycerine fatty acid ester and glycerin/propylene glycol - Google Patents
A kind of oily phase suspension system and the preparation method and application thereof based on single diglycerine fatty acid ester and glycerin/propylene glycol Download PDFInfo
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- CN107173839B CN107173839B CN201710283321.0A CN201710283321A CN107173839B CN 107173839 B CN107173839 B CN 107173839B CN 201710283321 A CN201710283321 A CN 201710283321A CN 107173839 B CN107173839 B CN 107173839B
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- fatty acid
- acid ester
- propylene glycol
- suspension system
- glycerin
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
- A23P10/00—Shaping or working of foodstuffs characterised by the products
- A23P10/30—Encapsulation of particles, e.g. foodstuff additives
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
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Abstract
The invention discloses a kind of oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol, the suspension system includes vegetable oil, emulsifier, edible solid powder raw material, glycerin/propylene glycol and food additives, the emulsifier includes one or both of single diglycerine fatty acid ester, phosphatide, and at least containing single diglycerine fatty acid ester；The food additives are selected from essence, sweetener, any one of acid；Product of the invention exists without significant foam, and stability is good, placement process without lamination and product it is uniform, the material after solving the problems, such as colloid mill easily formed the foam for being difficult to eliminate, product stability difference easily layering, product effective content differ greatly.
Description
Technical field:
The present invention relates to suspension systems, and in particular to a kind of oil based on single diglycerine fatty acid ester and glycerin/propylene glycol
Phase suspension system and the preparation method and application thereof.
Background technique:
Soft gel products have the characteristics that prevent content oxygenolysis, cover bad smell, easily swallow, wherein content
Preparation be soft capsule products production one of critical process.Nowadays, soft capsule content is broadly divided into pure oil systems on the market
With the big type of suspending system two, wherein pure oil systems refer to all formula grease compression mouldings after evenly mixing, product tool
There is the features such as good simple production process, product homogeneity, not easy oil leakage；Suspending system refers to insoluble solid substance to compare
Big particle is dispersed in Heterodisperse system formed in oil medium, and there is product type to enrich, taste is coordinated, city
The advantages that field demand is big.However, the solid particle in suspension product content cannot mutually dissolve each other with oily, the solid in placement process
Particle is easy, so that lamination occurs in product, to stablize suspending system, it will usually add suspension in the product
Or thickener (such as cera alba), there are mainly two types of modes for production technology at this time: 1, it is right that colloid mill is crossed after mixing all raw materials
After cool down, last compression moulding；2, raw material is divided into two parts, a part is for dissolving thickener, and another part is for mixing
Then surplus material crosses colloid mill, finally will be used to suppress after two parts material combination cooling.There are following for both the above technique
Insufficient: 1, the material after crossing colloid mill easily forms the foam for being difficult to eliminate；2, product stability is poor, with prolonging for resting period
It is long, it is easily layered, product stability decline；3, the technique that material is remixed after excessively complete colloid mill is easy to cause material mixing uneven
Even, the effective content of final products differs greatly.
Summary of the invention:
In view of the deficiencies of the prior art, it is an object of the present invention to provide one kind based on single diglycerine fatty acid ester and glycerol/
The oily phase suspension system of propylene glycol has good stability, non-foam presence and product uniform, the object after solving colloid mill
The problem of material easily forms the poor easily layering of the foam for being difficult to eliminate, product stability, the effective content of product differs greatly.
The present invention is achieved by the following technical programs:
A kind of oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol, the suspension system include planting
Object oil, emulsifier, edible solid powder raw material, glycerin/propylene glycol and food additives, the emulsifier include single double sweet
One or both of oil and fat acid esters, phosphatide, and at least containing single diglycerine fatty acid ester；The food additives are selected from perfume
Essence, sweetener, any one of acid；By mass percentage, which includes following components: vegetable oil 50-
85%, single diglycerine fatty acid ester 1~5%, phosphatidase 1~4%, edible solid powder raw material 5-45%, glycerol or the third two
Alcohol 0.1-2%, food additives 0-5%；Partial size >=120 mesh of the edible solid powder raw material.
Fatty acid is selected from oleic acid, linoleic acid, palmitinic acid, behenic acid, stearic acid, laurel in the list diglycerine fatty acid ester
Any one of acid, linolenic acid etc..
The edible solid powder is in fruit vegetable powder, milk powder, sugar, glucosides, newborn mineral salt, seawood meal and sugar alcohol etc.
It is any.
The preparation method of the oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol, including with
Lower step:
(1) load weighted vegetable oil is poured into pill tank, when oil temperature reaches 60~65 DEG C, is added with stirring formula ratio
Single diglycerine fatty acid ester, phosphatide continue stirring 10~15 minutes at 70~75 DEG C to after mixing, stopping heating, cooling
To 60-63 DEG C, it is added with stirring edible solid powder raw material, is stirred evenly, 40 are cooled to while stirring with cool condensate~
45 DEG C obtain mixture；
(2) it will be added in the mixture after step (1) cooling in the glycerol of formula ratio or propylene glycol stirring, mixing time
For 15~20min；
(3) homogeneous: being transferred to colloid mill for the mixture that step (2) obtains by the compressed air of 0.08~0.1MPa,
Cross twice of colloid mill；
(5) cooling/bubble removing: being transferred to pill tank for the material of excessively complete colloid mill, be cooled under stirring 30~35 DEG C with
Lower target product to obtain the final product.
Step (1) is cooled to 60-63 DEG C and uses water temperature for 50-55 DEG C of circulating water condensing equipment, is cooled to 40~45 DEG C
Use water temperature for 15~25 DEG C of circulating water condensing equipment.
The oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol is applied to field of food
In, content of the multi-phase suspension system as chewable soft capsule.
Key point of the invention is the type and dosage of emulsifier, in emulsifier single diglycerine fatty acid ester and glycerol or
Temperature in the proportion and preparation method of propylene glycol when glycerol or the additive amount of propylene glycol, order of addition and addition, and drop
Temperature control during temperature.
Beneficial effects of the present invention are as follows:
Product of the invention exists without significant foam, and stability is good, placement process without lamination and product it is uniform, solve
Material after crossing colloid mill easily forms the foam for being difficult to eliminate, product stability difference is easily layered, the effective content difference of product
Larger problem.
Detailed description of the invention:
Fig. 1 is flow diagram of the invention；
Fig. 2 is the flow diagram of comparative example.
Specific embodiment:
It is to further explanation of the invention, rather than limiting the invention below.
Embodiment:
A kind of oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol, the suspension system include planting
Object oil, emulsifier, edible solid powder raw material, glycerin/propylene glycol and food additives, the emulsifier include single double sweet
One or both of oil and fat acid esters, phosphatide, and at least containing single diglycerine fatty acid ester；The food additives are selected from perfume
Essence, sweetener, any one of acid；By mass percentage, which includes following components: vegetable oil 50-
85%, single diglycerine fatty acid ester 1~5%, phosphatidase 1~4%, edible solid powder raw material 5-45%, glycerol or the third two
Alcohol 0.1-2%, food additives 0-5%；Partial size >=120 mesh of the edible solid powder raw material.It is described to be based on Dan Shuan
The preparation method of fatty acid glyceride and the oily phase suspension system of glycerin/propylene glycol, flow chart is as shown in Figure 1, include following step
It is rapid:
(1) it mixes: the temperature on the temperature control panel of material-compound tank being transferred to 75 DEG C, opens heater switch, is carried out in tank
Heating；Load weighted vegetable oil is poured into material-compound tank, when oil temperature in tank reaches 60~65 DEG C, opens blender in material-compound tank,
Mixing speed is 60-100r/min, is added with stirring the emulsifier of formula ratio, including single diglycerine fatty acid ester, phosphatide, 70~
Continue stirring 10~15 minutes at 75 DEG C to dissolution after mixing, stop heating, uses water temperature for 50-55 DEG C of recirculated water cooling
Solidifying equipment is cooled to 60-63 DEG C, is added with stirring the edible solid powder raw material of partial size >=120 purposes, it is sufficiently stirred 40~
Obtain within 60 minutes oil powder mixture A；Circulating water condensing equipment is opened, circulating water temperature is set as 15~25 DEG C, with 15~25 DEG C
Circulating water condensing equipment is cooled to 45 DEG C while stirring and obtains mixture；
(2) it glycerol adding: will be added in the mixture after step (1) cooling in the glycerol stirring of formula ratio, mixing speed
For 150~200r/min, mixing time is that 15~20min obtains oil powder mixture B；
(3) the oil powder mixture B that step (2) obtains homogeneous: is transferred to by glue by the compressed air of 0.08~0.1MPa
Body mill, crosses twice of colloid mill；
(5) cooling/bubble removing: being transferred to pill tank for the material of excessively complete colloid mill, opens agitating paddle, mixing speed setting
For 100~150r/min, circulating water condensing equipment is opened, water temperature is set as 15~25 DEG C, is cooled to 30 under mixture stirs
~35 DEG C or less up to target product.
Comparative example:
Reference implementation example, the difference is that suspension system is free of glycerol or propylene glycol, the preparation side of the suspension system
Method, flow chart are as shown in Figure 2, comprising the following steps:
(1) it mixes: the temperature on the temperature control panel of material-compound tank being transferred to 75 DEG C, opens heater switch, is carried out in tank
Heating；Load weighted vegetable oil is poured into material-compound tank, when oil temperature in tank reaches 60~65 DEG C, opens blender in material-compound tank,
Mixing speed is 60-100r/min, is added with stirring the emulsifier of formula ratio, including glycerin monostearate, phosphatide, 70~75
Continue stirring 10~15 minutes to dissolution at DEG C and obtain oil and emulsifier mixture after mixing, be added with stirring partial size >=
The edible solid powder raw milk mineral salt of 120 purposes, galactooligosaccharide, steviol glycoside are sufficiently stirred 40~60 minutes
To oil powder mixture A；Circulating water condensing equipment is opened, circulating water temperature is set as 15~25 DEG C, with 15~25 DEG C of recirculated water cooling
Solidifying equipment is cooled to 45 DEG C while stirring and obtains oil powder mixture B；
(2) the oil powder mixture B that step (1) obtains homogeneous: is transferred to by glue by the compressed air of 0.08~0.1MPa
Body mill, crosses twice of colloid mill；
(3) cooling/bubble removing: being transferred to pill tank for the material of excessively complete colloid mill, opens agitating paddle, mixing speed setting
For 100~150r/min, circulating water condensing equipment is opened, water temperature is set as 15~25 DEG C, is cooled to 30 under mixture stirs
~35 DEG C or less up to target product.
Embodiment 1:
Reference implementation example, by mass percentage, the suspension system includes following components: sunflower oil 53.8%, single
Tristerin 3%, phosphatidase 2 %, glycerol 2%, newborn mineral salt 38%, galactooligosaccharide 1%, steviol glycoside 0.2%.It is described
The preparation method reference implementation example of suspension system.
Comparative example 1:
Reference implementation example 1, the difference is that suspension system is free of glycerol, by mass percentage, suspension system includes
Following components: sunflower oil 55.8%, glycerin monostearate 3%, newborn mineral salt 38%, galactooligosaccharide 1%, steviol glycoside
0.2%, phosphatidase 2 %.The preparation method of the suspension system refers to comparative example.
Embodiment 2:
Reference implementation example, by mass percentage, the suspension system includes following components: grape seed oil 55.3%, single
Olein 2%, propylene glycol 1%, seawood meal 40%, steviol glycoside 0.2%, phosphatidase 1 .5%.The preparation of the suspension system
Method reference implementation example.
Comparative example 2:
Reference implementation example 2, the difference is that suspension system is free of propylene glycol, by mass percentage, suspension system packet
Include following components: grape seed oil 56.3%, glyceryl monooleate 2%, seawood meal 40%, steviol glycoside 0.2%, phosphatidase 1 .5%.
The preparation method of the suspension system refers to comparative example.
Embodiment 3:
Reference implementation example, by mass percentage, the suspension system includes following components: walnut oil 52.4%, single, double
Tristerin 3%, glycerol 1%, mushroom powder 28%, orange powder 10%, xylitol 5%, citric acid 0.5%, steviol glycoside
0.1%.The preparation method reference implementation example of the suspension system.
Comparative example 3:
Reference implementation example 3, the difference is that suspension system is free of glycerol, by mass percentage, suspension system includes
Following components: walnut oil 53.4%, single, bi-tristearin 3%, mushroom powder 28%, orange powder 10%, xylitol 5%, lemon
Acid 0.5%, steviol glycoside 0.1%.The preparation method of the suspension system refers to comparative example.
Embodiment 4:
Reference implementation example, by mass percentage, the suspension system includes following components: linseed oil 65%, DHA algal
Oil 20%, glyceryl monolaurate 4%, propylene glycol 0.5%, apple powder 4%, xylitol 5%, flavoring apple essence 1%, malic acid
0.3%, steviol glycoside 0.2%.The preparation method reference implementation example of the suspension system.
Comparative example 4:
Reference implementation example 4, the difference is that suspension system is free of propylene glycol, by mass percentage, suspension system packet
Include following components: linseed oil 65%, DHA algal oil 20%, glyceryl monolaurate 4%, apple powder 4.5%, xylitol 5%,
Flavoring apple essence 1%, malic acid 0.3%, steviol glycoside 0.2%.The preparation method of the suspension system refers to comparative example.
4 embodiments (embodiment 1-4) and 4 comparative examples (comparative example 1-4) are configured into 1kg simultaneously, a part pours into examination
Guan Zhong is put into 37 DEG C of baking ovens, records after 3 days and after 7 days its settling ratio, and another part places room temperature, its state is observed after 7 days.
As a result referring to table 1:
Table 1
Table 1 illustrate, product stability of the invention is good, placement process without lamination and product it is uniform.
Claims (6)
1. a kind of oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol, which is characterized in that the suspension system
System includes vegetable oil, emulsifier, edible solid powder raw material, glycerin/propylene glycol and food additives, the emulsifier packet
One or both of single diglycerine fatty acid ester, phosphatide are included, and at least containing single diglycerine fatty acid ester；The food addition
Agent is selected from essence, sweetener, any one of acid；By mass percentage, which includes following components: plant
Oily 50-85%, single diglycerine fatty acid ester 1~5%, phosphatidase 1~4%, edible solid powder raw material 5-45%, glycerol or
Propylene glycol 0.1-2%, food additives 0-5%；Partial size >=120 mesh of the edible solid powder raw material；It is described edible
Solid powder is any one of fruit vegetable powder, milk powder, sugar, glucosides, newborn mineral salt, seawood meal and sugar alcohol.
2. the oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol according to claim 1, feature
Be, it is described list diglycerine fatty acid ester in fatty acid be selected from oleic acid, linoleic acid, palmitinic acid, behenic acid, stearic acid, lauric acid,
Any one of linolenic acid.
3. a kind of preparation of the oily phase suspension system based on single diglycerine fatty acid ester and glycerin/propylene glycol described in claim 1
Method, which comprises the following steps:
(1) load weighted vegetable oil is poured into pill tank, when oil temperature reaches 60~65 DEG C, is added with stirring the Dan Shuan of formula ratio
Fatty acid glyceride, phosphatide continue stirring 10~15 minutes at 70~75 DEG C to after mixing, stop heating, be cooled to 60-
63 DEG C, it is added with stirring edible solid powder raw material, is stirred evenly, is cooled to 40~45 DEG C while stirring with condensed water and obtain
To mixture；
(2) it will be added in the mixture after step (1) cooling in the glycerol of formula ratio or propylene glycol stirring, mixing time 15
~20min；
(3) mixture that step (2) obtains is transferred to by colloid mill by the compressed air of 0.08~0.1MPa, crosses twice of colloid
Mill；
(4) material of excessively complete colloid mill is transferred to pill tank, 30~35 DEG C is cooled under stirring up to target product.
4. the preparation of the oily phase suspension system according to claim 3 based on single diglycerine fatty acid ester and glycerin/propylene glycol
Method, which is characterized in that step (1) is cooled to 60-63 DEG C and uses water temperature for 50-55 DEG C of circulating water condensing equipment, is cooled to
40~45 DEG C use water temperature for 15~25 DEG C of circulating water condensing equipment.
5. the oily phase described in any one of claim 1-2 claim based on single diglycerine fatty acid ester and glycerin/propylene glycol
The application of suspension system, which is characterized in that described mutually suspension is with the oil of glycerin/propylene glycol based on single diglycerine fatty acid ester
System is applied in field of food.
6. the oily phase suspension system according to claim 5 based on single diglycerine fatty acid ester and glycerin/propylene glycol is answered
With, which is characterized in that described be used as based on single diglycerine fatty acid ester and the oily phase suspension system of glycerin/propylene glycol can be chewed
The content of soft capsule.
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| CN201710283321.0A CN107173839B (en) | 2017-04-26 | 2017-04-26 | A kind of oily phase suspension system and the preparation method and application thereof based on single diglycerine fatty acid ester and glycerin/propylene glycol |
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| CN201710283321.0A CN107173839B (en) | 2017-04-26 | 2017-04-26 | A kind of oily phase suspension system and the preparation method and application thereof based on single diglycerine fatty acid ester and glycerin/propylene glycol |
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| CN107173839B true CN107173839B (en) | 2019-10-22 |
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| CN109007934A (en) * | 2018-07-03 | 2018-12-18 | 广州普正生物科技有限公司 | A kind of ultra micro suspension system |
| CN110584084A (en) * | 2019-10-17 | 2019-12-20 | 广州白云山汉方现代药业有限公司 | Emulsion stabilizer and nutrient emulsion containing same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927200A (en) * | 2006-09-06 | 2007-03-14 | 王爱民 | Bilobalide self-tiny-emulsifying soft capsule and its preparing process |
| CN101721931A (en) * | 2009-11-26 | 2010-06-09 | 广州普正生物科技有限公司 | Multi-phase suspension system, preparation method and application thereof |
| CN102614116A (en) * | 2012-04-26 | 2012-08-01 | 河南中医学院 | Self-emulsifying substrate and application thereof |
| CN105878183A (en) * | 2016-04-08 | 2016-08-24 | 山东大学 | Simethicone solid self-emulsifying preparation and preparation process thereof |
| CN105997925A (en) * | 2016-05-09 | 2016-10-12 | 中国药科大学 | Tanshinone iia soft capsule and preparation method thereof |
-
2017
- 2017-04-26 CN CN201710283321.0A patent/CN107173839B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1927200A (en) * | 2006-09-06 | 2007-03-14 | 王爱民 | Bilobalide self-tiny-emulsifying soft capsule and its preparing process |
| CN101721931A (en) * | 2009-11-26 | 2010-06-09 | 广州普正生物科技有限公司 | Multi-phase suspension system, preparation method and application thereof |
| CN102614116A (en) * | 2012-04-26 | 2012-08-01 | 河南中医学院 | Self-emulsifying substrate and application thereof |
| CN105878183A (en) * | 2016-04-08 | 2016-08-24 | 山东大学 | Simethicone solid self-emulsifying preparation and preparation process thereof |
| CN105997925A (en) * | 2016-05-09 | 2016-10-12 | 中国药科大学 | Tanshinone iia soft capsule and preparation method thereof |
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