CN102860506A - Krill oil microcapsual powder and its preparation method - Google Patents
Krill oil microcapsual powder and its preparation method Download PDFInfo
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Abstract
The invention discloses a krill oil microcapsual powder and its preparation method. The preparation method comprises steps of: preparation of an oil phase solution and an aqueous phase solution, mixing and emulsification of the two solutions, homogenizing, drying and the like. The krill oil microcapsual powder is prepared from the following raw materials of: by weight, 0.001-90% of krill oil, 0.5-90% of sodium caseinate and 0-99% of a filler. In addition, 0.001-10 wt% of an oil phase antioxidant, 0.001-5 wt% of an aqueous phase antioxidant, 0.001-5 wt% of an aqueous stabilizer and 0.001-5 wt% of an anti-caking agent can also be added. The krill oil microcapsual powder has high content of the encapsuled krill oil and has good stability and fluidity. After rehydration, krill oil can be dispersed into water completely in the form of particles (nm); and krill oil is stable if stored for a long time, and has no phenomenon such as floating oil, precipitation, adhesion to bottles and the like. therefore, the application range of krill oil is broadened, and krill oil is applied to fields such as dry mixing, drinks, dairy products, bakery, tablets and the like.
Description
Technical field
The present invention relates to the preparation method of krill oil microcapsule powder, relate in particular to the preparation method that high embedding rate is rich in the krill oil microcapsule powder of high phospholipid content.
Background technology
Krill is single living resources of planting of quantity maximum on the earth, the latest data of FAO's issue shows, about 1.25～7.25 hundred million tons of the total biomass of krill, but about 400～6,000,000 tons of year amount of fishing have become the most important potential fishery resources of world's ocean-going fishing industry.Because krill lives in the waters, frigid zone, be rich in the Omega-3 polyunsaturated fatty acid isoreactivity material take eicosapentaenoic acid (EPA) and DHA (DHA) as representative, be the health products raw material of preciousness.Its unrighted acid is that present occurring in nature is unique with the molecular structure of phosphatide kenel in conjunction with ω-3 (EPA, DHA) and the superpower polyphenoils of diversity (phosphatide type astaxanthin Astaxanthin).It also contains the powerful antioxidant of abundant vitamin E, vitamin A, astaxanthin, Phospholipids, flavonoids and function.
Contained EPA and DHA in the lipid in the krill, contain respectively 5 and 6 unsaturated bonds, this distinctive structure is given it has special effect to human health, and it can prevent the 6 large diseases such as cardiovascular and cerebrovascular disease, inflammatory reaction disease, malignant tumour, dementia, diabetes, hypopsia.
Because particularly the content of EPA and DHA is very high for contained unrighted acid in the krill, therefore may extract high-end product krill oil from krill.In fish oil, they mainly exist with triglycerides or fatty-acid ethyl ester form; And in antarctic krill oil, EPA and DHA mainly are present in the phosphatide.Research finds that krill oil can effectively reduce rat blood serum T-CHOL, triglycerides and low-density lipoprotein cholesterol level, thereby reaches the reduction blood fat, the diseases such as prevention coronary heart disease, atherosclerotic.Utilize antarctic krill oil that obese people is tested, find that krill oil can increase the concentration of EPA and DHA in the obese people blood.The concentration amplification of EPA and DHA has illustrated that krill oil has good absorbability in human body apparently higher than the amplification of taking herring oil (2g/d) and take the amplification of olive oil (2g/d) in taking continuously krill oil (2g/d) human plasma all around.And after measured, krill oil does not produce any toxic and side effect.In addition, contain the Natural Antioxidants astaxanthin in the krill oil, can and delay senility to Green Tea Extract.
In China, krill belongs to the not yet resource of scale development, does not also have the krill product of independent intellectual property right to appear on the market, and in China's patent protection the patent aspect the relevant krill oil extraction only, there is not yet the relevant report of krill oil microcapsule powder or pulverulent product.
Krill oil is outer originally as liquid condition, limited the scope of its application, the fields such as exploitation cold water dispersion type krill oil microcapsule powder not only can be applied to electuary, hard shell capsules, bakes and banks up with earth, tablet, krill oil can also be directly applied in the aqueous systems food, and nano level particle diameter can better be absorbed by the body.Because krill has become one of important content of national marine development strategy deposit, thereby the technical research of quickening krill development of resources, carry out the foundation that the technology of system is integrated and enter Showcase Production Line, the development process that advances the krill resource is significant.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of krill oil microcapsule powder, and krill oil microcapsule powder obtained by this method.This microcapsule powder gets up the krill oil embedding, has not only improved the stability of krill oil, but also has covered bad taste and the smell of krill oil.Meet present health, nutrition and delicious consumption demand.
A kind of krill oil microcapsule powder is the microcapsule powder of wall material parcel krill oil, and non-water raw material weight proportioning is as follows: krill oil 0.5～90%, wall material 0.5～90%, filler 0～99%, described wall material is casein sodium.
Described wall material also has the mixture of one or more and casein sodium in lactalbumin, remodeling starch, Arabic gum, pectin, xanthans, carragheen, konjac glucomannan, sodium carboxymethylcellulose pyce, sodium cellulose glycolate, the sodium alginate.
Described filler weight proportion is preferably 0.001～99%, and preferably one or more in white granulated sugar, glucose, lactose, mannose, maltose, oligomeric maltose, oligoisomaltose, glucose syrup, maltodextrin, polydextrose, the water-soluble dietary fiber are with the mixture of arbitrary proportion composition.
Can also outer be added with the oil phase antioxidant of krill oil weight 0.001～10%, described oil phase antioxidant is astaxanthin, lutein ester, canthaxanthin, lutein, one or both mixtures that form with arbitrary proportion of beta carotene, zeaxanthin, rosemary, Xue MingRosma rinus officinalis, dl-alpha-tocopherol, mixing natural VE, VA, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone
Can also outer be added with krill oil weight 0.001～5% water antioxidant, described water antioxidant is ascorbic acid, sodium ascorbate, Calcium Ascorbate, D-araboascorbic acid and sodium salt thereof, sodium lactate, the mixture that one or both in the Tea Polyphenols form with arbitrary proportion.
Can also outer be added with krill oil weight 0.001～5% water stabilizing agent, described water stabilizing agent is phosphoric acid, Sodium Acid Pyrophosphate, sodium pyrophosphate, calcium dihydrogen phosphate, potassium dihydrogen phosphate, diammonium hydrogen phosphate, dipotassium hydrogen phosphate, calcium monohydrogen phosphate, tricalcium phosphate, tripotassium phosphate, tertiary sodium phosphate, calgon, sodium phosphate trimer, sodium dihydrogen phosphate, a kind of in the sodium hydrogen phosphate.
Krill oil microcapsule powder vegetation method of the present invention is the microcapsule powder of wall material parcel krill oil, and non-water raw material weight proportioning is as follows: krill oil 0.5～90%, wall material 0.5～90%, filler 0～99%, and described wall material is casein sodium; Preparation process is as follows:
1. oil phase preparation: krill oil is obtained oil phase under 20～90 ℃ of conditions;
2. water preparation: under 20～90 ℃ of conditions, wall material and filler are added to the water, are stirred to and dissolve to get water, wherein the consumption of water is 0.1～9 times of non-water raw material gross mass;
3. emulsification: oil phase is slowly added aqueous phase, after the stirring and emulsifying again homogeneous obtain emulsion,
4. the gained emulsion obtains the krill oil microcapsule powder through super-dry.
Krill oil microcapsule powder vegetation method of the present invention, on the basis of the above, one or more mixture in wall material lactalbumin, remodeling starch, Arabic gum, pectin, xanthans, carragheen, konjac glucomannan, sodium carboxymethylcellulose pyce, sodium cellulose glycolate, the sodium alginate can also be arranged.
Krill oil microcapsule powder vegetation method of the present invention, described filler preferably are one or more mixtures that form with arbitrary proportion in white granulated sugar, glucose, lactose, mannose, maltose, oligomeric maltose, oligoisomaltose, glucose syrup, maltodextrin, polydextrose, the water-soluble dietary fiber.Can also outer be added with the oil phase antioxidant of krill oil weight 0.001～10% to oil phase, described oil phase antioxidant is astaxanthin, lutein ester, canthaxanthin, lutein, one or both mixtures that form with arbitrary proportion of beta carotene, zeaxanthin, rosemary, Xue MingRosma rinus officinalis, dl-alpha-tocopherol, mixing natural VE, VA, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone
Krill oil microcapsule powder vegetation method of the present invention, can also outer be added with the oil phase antioxidant of krill oil weight 0.001～10% to oil phase, described oil phase antioxidant is astaxanthin, lutein ester, canthaxanthin, lutein, one or both mixtures that form with arbitrary proportion of beta carotene, zeaxanthin, rosemary, Xue MingRosma rinus officinalis, dl-alpha-tocopherol, mixing natural VE, VA, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone; Or ∕ and be added with krill oil weight 0.001～5% water antioxidant outward to aqueous phase, described water antioxidant is ascorbic acid, sodium ascorbate, Calcium Ascorbate, D-araboascorbic acid and sodium salt thereof, sodium lactate, the mixture that in the Tea Polyphenols one or both form with arbitrary proportion: or ∕ and be added with krill oil weight 0.001～5% water stabilizing agent outward to aqueous phase, described water stabilizing agent is phosphoric acid, Sodium Acid Pyrophosphate, sodium pyrophosphate, calcium dihydrogen phosphate, potassium dihydrogen phosphate, diammonium hydrogen phosphate, dipotassium hydrogen phosphate, calcium monohydrogen phosphate, tricalcium phosphate, tripotassium phosphate, tertiary sodium phosphate, calgon, sodium phosphate trimer, sodium dihydrogen phosphate, a kind of in the sodium hydrogen phosphate.Further krill oil microcapsule powder preparation method is characterized in that: non-water raw material obtains by following weight proportion:
Krill oil 0.001～90%
Oil phase antioxidant 0.001～10%
Wall material 0.5～90%
Water antioxidant 0.001～5%
Water stabilizing agent 0.001～5%
Anticaking agent 0.001～5%
Flavoring essence 0～5%
Filler 0.001～99%
Concrete steps are:
1, oil phase preparation: under 20～90 ℃ of conditions, krill oil, oil phase essence and oil phase antioxidant are mixed, stirring and dissolving gets the solution I;
2, water preparation: under 20～90 ℃ of conditions, wall material, water antioxidant, water essence, anticaking agent and filler are added to the water, are stirred to dissolve and get the dissolving II, wherein the consumption of water is 0.1～9 times of non-water raw material gross mass;
3, emulsification: oil phase is slowly added aqueous phase, mechanical agitation, rotating speed 60～300rpm, behind stirring and emulsifying 0.1～1h, cutter speed of agitator 8000～30000rpm shears 0.1～6h;
4, homogeneous: colostric fluid is high-pressure homogeneous through 5～100MPa, and the krill oil particle diameter slowly stirs 0.1～5h at 20nm～2000nm behind the homogeneous;
5, the gained emulsion obtains the krill oil microcapsule powder through super-dry.
Oil phase antioxidant described in the krill oil microcapsule powder preparation method of the present invention is: astaxanthin, lutein ester, canthaxanthin, lutein, one or more mixtures that form with arbitrary proportion of beta carotene, zeaxanthin, rosemary, Xue MingRosma rinus officinalis, dl-alpha-tocopherol, mixing natural VE, VA, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone; Preferably astaxanthin or mixing natural VE are as the oil phase antioxidant.
Water antioxidant of the present invention is ascorbic acid, sodium ascorbate, Calcium Ascorbate, D-araboascorbic acid and sodium salt thereof, sodium lactate, the mixture that one or more in the Tea Polyphenols form with arbitrary proportion; Especially the mixture that preferred lactic acid and Tea Polyphenols form with arbitrary proportion.
Water stabilizing agent of the present invention is phosphoric acid, Sodium Acid Pyrophosphate, sodium pyrophosphate, calcium dihydrogen phosphate, potassium dihydrogen phosphate, diammonium hydrogen phosphate, dipotassium hydrogen phosphate, calcium monohydrogen phosphate, tricalcium phosphate, tripotassium phosphate, tertiary sodium phosphate, calgon, sodium phosphate trimer, sodium dihydrogen phosphate, the mixture that one or more in the sodium hydrogen phosphate form with arbitrary proportion; The mixture that preferably phosphoric acid potassium dihydrogen of the present invention and dipotassium hydrogen phosphate form with arbitrary proportion.
Anticaking agent of the present invention is specific the restriction not, and anticaking agent usually used in this field can use in the present invention, such as: microcrystalline cellulose, calcium phosphate, silica.The mixture that preferably phosphoric acid calcium of the present invention and silica form with arbitrary proportion.
Essence of the present invention is specific the restriction not, and food-grade essence usually used in this field all can use in the present invention, comprises natural edible essence and artificial synthetic flavoring essence.Such as: one or more mixtures that form with arbitrary proportion such as fruity essence, milk-taste essence, flower flavor essence, tea essence.
Filler of the present invention is white granulated sugar, glucose, lactose, mannose, maltose, oligomeric maltose, oligoisomaltose, glucose syrup, maltodextrin, polydextrose, water-soluble dietary fiber.The present inventor finds that through long-term endeavour packing material plays conclusive effect to the embedding of krill oil, and is relevant with the physical characteristic of itself, the good material of resistance to water soak that preferred molecular weight is less.The DE value of filler (accounting for the percentage of syrup dry with glucose meter) is higher, and the embedding effect is better, but the easier moisture absorption of krill oil microcapsule powder: the filler molecular weight is approximately little, and the embedding effect is better, and vice versa; In general, the DE value is higher, and molecular weight also reduces relatively, and hygroscopicity also strengthens relatively.The oligomeric maltose of the preferred DE=35-40 of filler of the present invention, or the mixture that forms with arbitrary proportion of maltodextrin and poly-glucose sugar.
Among the present invention as the used krill oil of raw material from krill, generally take content of phospholipid as the calculating standard, contained content of phospholipid 1～50%.The technical staff produces required consumption take the krill oil of different content of phospholipid as initiation material, and in the preferred embodiment of the present invention, the content of phospholipid of krill oil is 38-42%.
Purpose of the present invention is achieved through the following technical solutions;
1. oil phase preparation: under 20～90 ℃ of conditions, krill oil, oil phase essence and oil phase antioxidant are mixed, stirring and dissolving gets solution;
2. water preparation: under 20～90 ℃ of conditions, wall material, water antioxidant, water essence, anticaking agent and filler are added to the water, are stirred to dissolve and get the dissolving II, wherein the consumption of water is 0.1～9 times of non-water raw material gross mass;
3. emulsification: oil phase is slowly added aqueous phase, mechanical agitation, rotating speed 60～300rpm, behind stirring and emulsifying 0.1～1h, cutter speed of agitator 8000～30000rpm shears 0.1～6h;
4. homogeneous: colostric fluid is high-pressure homogeneous through 5～100MPa, and the krill oil particle diameter slowly stirs 0.1～5h at 20nm～2000nm behind the homogeneous;
5. dry: the gained emulsion is to realize by any one drying mode in pressure spray dryer method, centrifugal spray drying method, the fluid-bed drying.
Compare with the state of the art, the present invention optimizes selection and the proportioning of wall material and filler, makes that emulsion process is easier carries out, and need not to add emulsifying agent, has reduced manufacturing cost, the security that has also improved product simultaneously.The preparation method of krill oil microcapsule powder of the present invention is dispersed in krill oil in the cold water with the form of nanoparticle fully.The good stability of product, water-soluble rear without phenomenons such as floating oil, precipitation, sticking bottles.Production process of the present invention produces without waste residue, waste gas, waste water, and production technology environmental protection and technique are simple, and industrialization is simple.
The specific embodiment
The below is described further content of the present invention with specific embodiment, the content that embodiment does not limit the present invention in any way.
Embodiment 1
Calcium phosphate 3g, dipotassium hydrogen phosphate 1 g, potassium dihydrogen phosphate 3 g, Tea Polyphenols 3 g are placed the container of 3000mL, add the 1200mL purified water, 70 ℃ stir after, add casein sodium 100g, lactalbumin 100g, maltodextrin 386.5 g, polydextrose 300 g and be stirred to dissolving and form aqueous phase substrate.Mixing natural VE 0. 5 g are added to normal temperature mixes among the krill oil 100g.Then this oil mixture is slowly poured in the aqueous phase substrate, 180～220rpm stirs 30min, and behind 8000～10000rpm emulsification pretreatment 30min, homogeneous 40Mpa is by twice, and the emulsion average grain diameter that obtains is less behind 200nm.Emulsion is passed through pressure spray dryer, atomisation pressure 10MPa, 160 ℃ of EATs, 80 ℃ of leaving air temps are collected powder, add 0.3% food agent silica according to the quality of powder, after mixing, by 40 eye mesh screens, collect krill oil microcapsule powder product.Content of phospholipid is not less than 8% in this microcapsule powder product, can dissolve to form stable emulsion in water.
Dissolving method: get the water that 5g krill oil microcapsule powder is put into 150mL, after the stirring and dissolving, pour in the airtight bottle of 150mL, keep 10min for 95 ℃, the bottle that falls is placed, and microcapsule powder can form stable emulsion with water, places phenomenons such as having no floating oil, precipitation, sticking bottle in 6 months.
Embodiment 2
Calcium phosphate 3g, dipotassium hydrogen phosphate 1 g, potassium dihydrogen phosphate 3 g, Tea Polyphenols 3 g are placed the container of 3000mL, add the 1200mL purified water, 70 ℃ stir after, add casein sodium 100g, lactalbumin 100g, maltodextrin 286.5 g, polydextrose 300 g and be stirred to dissolving and form aqueous phase substrate.Mixing natural VE 0. 5 g are added to normal temperature mixes among the krill oil 200g.Then this oil mixture is slowly poured in the aqueous phase substrate, 180～220rpm stirs 30min, and behind 8000～10000rpm emulsification pretreatment 30min, homogeneous 40Mpa is by twice, and the emulsion average grain diameter that obtains is less behind 200nm.Emulsion is passed through centrifugal spray drying, 160 ℃ of EATs, 80 ℃ of leaving air temps are collected powder, add 0.3% food agent silica according to the quality of powder, after mixing, by 40 eye mesh screens, collect krill oil microcapsule powder product.Content of phospholipid is not less than 8% in this microcapsule powder product, can dissolve to form stable emulsion in water.
Dissolving method: get the water that 5g krill oil microcapsule powder is put into 150mL, after the stirring and dissolving, pour in the airtight bottle of 150mL, keep 10min for 95 ℃, the bottle that falls is placed, and microcapsule powder can form stable emulsion with water, places phenomenons such as having no floating oil, precipitation, sticking bottle in 6 months.
Embodiment 3
Calcium phosphate 1g, sodium phosphate trimer 1 g, calgon 1 g, Tea Polyphenols 3 g are placed the container of 3000mL, add the 1500mL purified water, 70 ℃ stir after, add casein sodium 80g, oligomeric maltose 120g, maltodextrin 290.5 g, polydextrose 100 g and be stirred to dissolving and form aqueous phase substrate.Mixing natural VE 1.0 g are added to normal temperature mixes among the krill oil 400g.Then this oil mixture is slowly poured in the aqueous phase substrate, 180～220rpm stirs 30min, and behind 8000～10000rpm emulsification pretreatment 30min, homogeneous 40Mpa is by twice, and the emulsion average grain diameter that obtains is less behind 200nm.Emulsion is passed through centrifugal spray drying, 160 ℃ of EATs, 80 ℃ of leaving air temps are collected powder, add 0.3% food agent silica according to the quality of powder, after mixing, by 40 eye mesh screens, collect krill oil microcapsule powder product.Content of phospholipid is not less than 8% in this microcapsule powder product, can dissolve to form stable emulsion in water.
Dissolving method: get the water that 5g krill oil microcapsule powder is put into 150mL, after the stirring and dissolving, pour in the airtight bottle of 150mL, keep 10min for 95 ℃, the bottle that falls is placed, and microcapsule powder can form stable emulsion with water, places phenomenons such as having no floating oil, precipitation, sticking bottle in 6 months.
Embodiment 4
Calcium phosphate 1g, sodium phosphate trimer 1 g, calgon 1 g, sodium ascorbate 1 g are placed the container of 3000mL, add the 1500mL purified water, 70 ℃ stir after, add casein sodium 80g, oligomeric maltose 120g, polydextrose 393 g are stirred to dissolving and form aqueous phase substrate.Mixing natural VE 1.0 g are added to normal temperature mixes among the krill oil 400g.Then this oil mixture is slowly poured in the aqueous phase substrate, 180～220rpm stirs 30min, and behind 8000～10000rpm emulsification pretreatment 30min, homogeneous 40Mpa is by twice, and the emulsion average grain diameter that obtains is less behind 200nm.Emulsion is passed through centrifugal spray drying, 160 ℃ of EATs, 80 ℃ of leaving air temps are collected powder, add 0.3% food agent silica according to the quality of powder, after mixing, by 40 eye mesh screens, collect krill oil microcapsule powder product.Content of phospholipid is not less than 16% in this microcapsule powder product, can dissolve to form stable emulsion in water.
Dissolving method: get the water that 5g krill oil microcapsule powder is put into 150mL, after the stirring and dissolving, pour in the airtight bottle of 150mL, keep 10min for 95 ℃, the bottle that falls is placed, and microcapsule powder can form stable emulsion with water, places phenomenons such as having no floating oil, precipitation, sticking bottle in 6 months.
Embodiment 5
Calcium phosphate 1g, sodium phosphate trimer 1 g, calgon 1 g, sodium ascorbate 1 g are placed the container of 3000mL, add the 1500mL purified water, 70 ℃ stir after, add casein sodium 100g, oligomeric maltose 493g and be stirred to dissolving and form aqueous phase substrate.Content 80% astaxanthin 0.01g added to normal temperature mixes among the krill oil 400g.Then this oil mixture is slowly poured in the aqueous phase substrate, 180～220rpm stirs 30min, and behind 8000～10000rpm emulsification pretreatment 30min, homogeneous 40Mpa is by twice, and the emulsion average grain diameter that obtains is less behind 200nm.Emulsion is passed through centrifugal spray drying, 160 ℃ of EATs, 80 ℃ of leaving air temps are collected powder, add 0.3% food agent silica according to the quality of powder, after mixing, by 40 eye mesh screens, collect krill oil microcapsule powder product.Content of phospholipid is not less than 16% in this microcapsule powder product, can dissolve to form stable emulsion in water.
Dissolving method: get the water that 5g krill oil microcapsule powder is put into 150mL, after the stirring and dissolving, pour in the airtight bottle of 150mL, keep 10min for 95 ℃, the bottle that falls is placed, and microcapsule powder can form stable emulsion with water, places phenomenons such as having no floating oil, precipitation, sticking bottle in 6 months.
Embodiment 6
Calcium phosphate 3g, sodium ascorbate 1 g are placed the container of 3000mL, add the 1500mL purified water, 70 ℃ stir after, add casein sodium 200g, oligomeric maltose 293g and be stirred to dissolving and form aqueous phase substrate.Content 80% astaxanthin 0.01g added to normal temperature mixes among the krill oil 500g.Then this oil mixture is slowly poured in the aqueous phase substrate, 180～220rpm stirs 30min, and behind 8000～10000rpm emulsification pretreatment 30min, homogeneous 40Mpa is by twice, and the emulsion average grain diameter that obtains is less behind 200nm.Emulsion is passed through centrifugal spray drying, 160 ℃ of EATs, 80 ℃ of leaving air temps are collected powder, add 0.3% food agent silica according to the quality of powder, after mixing, by 40 eye mesh screens, collect krill oil microcapsule powder product.Content of phospholipid is not less than 20% in this microcapsule powder product, can dissolve to form stable emulsion in water.
Dissolving method: get the water that 5g krill oil microcapsule powder is put into 150mL, after the stirring and dissolving, pour in the airtight bottle of 150mL, keep 10min for 95 ℃, the bottle that falls is placed, and microcapsule powder can form stable emulsion with water, places phenomenons such as having no floating oil, precipitation, sticking bottle in 6 months.
Embodiment 7
Add among the krill oil 500g astaxanthin 0.01g of content 80% to 20 ℃ and mix rear adding 750mL purified water and stir, homogeneous 40Mpa is stand-by by twice.With calcium phosphate 3g, sodium ascorbate 1 g, casein sodium 200g, oligomeric maltose 293g place boiling drier, fully after the boiling, the krill oil slurries are slowly sucked in the boiling drier 90 ℃ of dryings of air intake, to moisture≤0.3%, collect powder, add 0.3% food agent silica according to the quality of powder, after mixing, by 40 eye mesh screens, collect krill oil microcapsule powder product.Content of phospholipid is not less than 20% in this microcapsule powder product, can dissolve to form stable emulsion in water.
Dissolving method: get the water that 5g krill oil microcapsule powder is put into 150mL, after the stirring and dissolving, pour in the airtight bottle of 150mL, keep 10min for 95 ℃, the bottle that falls is placed, and microcapsule powder can form stable emulsion with water, places phenomenons such as having no floating oil, precipitation, sticking bottle in 6 months.
Claims (10)
1. a krill oil microcapsule powder is the microcapsule powder of wall material parcel krill oil, and non-water raw material weight proportioning is as follows: krill oil 0.5～90%, wall material 0.5～90%, filler 0～99%, described wall material is casein sodium.
2. krill oil microcapsule powder as claimed in claim 1 is characterized in that: described wall material also has one or more and the sodium-caseinate mixture in lactalbumin, remodeling starch, Arabic gum, pectin, xanthans, carragheen, konjac glucomannan, sodium carboxymethylcellulose pyce, sodium cellulose glycolate, the sodium alginate.
3. such as claim 1 or 2 said krill oil microcapsule powders, it is characterized in that: described filler weight proportion is 0.001～99%, is one or more mixtures that form with arbitrary proportion in white granulated sugar, glucose, lactose, mannose, maltose, oligomeric maltose, oligoisomaltose, glucose syrup, maltodextrin, polydextrose, the water-soluble dietary fiber.
4. such as claim 1 or 2 said krill oil microcapsule powders, it is characterized in that: the oil phase antioxidant that is added with krill oil weight 0.001～10% outward, described oil phase antioxidant is astaxanthin, lutein ester, canthaxanthin, lutein, one or both mixtures that form with arbitrary proportion of beta carotene, zeaxanthin, rosemary, Xue MingRosma rinus officinalis, dl-alpha-tocopherol, mixing natural VE, VA, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone.
5. such as claim 1 or 2 said krill oil microcapsule powders, it is characterized in that: be added with krill oil weight 0.001～5% water antioxidant outward, described water antioxidant is ascorbic acid, sodium ascorbate, Calcium Ascorbate, D-araboascorbic acid and sodium salt thereof, sodium lactate, the mixture that one or both in the Tea Polyphenols form with arbitrary proportion; Be added with krill oil weight 0.001～5% water stabilizing agent outward, described water stabilizing agent is phosphoric acid, Sodium Acid Pyrophosphate, sodium pyrophosphate, calcium dihydrogen phosphate, potassium dihydrogen phosphate, diammonium hydrogen phosphate, dipotassium hydrogen phosphate, calcium monohydrogen phosphate, tricalcium phosphate, tripotassium phosphate, tertiary sodium phosphate, calgon, sodium phosphate trimer, sodium dihydrogen phosphate, a kind of in the sodium hydrogen phosphate.
6. a krill oil microcapsule powder vegetation method is the microcapsule powder of wall material parcel krill oil, and non-water raw material weight proportioning is as follows: krill oil 0.5～90%, wall material 0.5～90%, filler 0～99%, and the wall material is casein sodium; Preparation process is as follows:
1. oil phase preparation: krill oil is obtained oil phase under 20～90 ℃ of conditions;
2. water preparation: under 20～90 ℃ of conditions, wall material and filler are added to the water, are stirred to and dissolve to get water, wherein the consumption of water is 0.1～9 times of non-water raw material gross mass;
3. emulsification: oil phase is slowly added aqueous phase, after the stirring and emulsifying again homogeneous obtain emulsion,
4. the gained emulsion obtains the krill oil microcapsule powder through super-dry.
7. krill oil microcapsule powder vegetation method as claimed in claim 6 is characterized in that: the wall material is the mixture of one or more and casein sodium in lactalbumin, remodeling starch, Arabic gum, pectin, xanthans, carragheen, konjac glucomannan, sodium carboxymethylcellulose pyce, sodium cellulose glycolate, the sodium alginate.
8. such as claim 6 or 7 said krill oil microcapsule powder vegetation methods, it is characterized in that: described filler is one or more mixtures that form with arbitrary proportion in white granulated sugar, glucose, lactose, mannose, maltose, oligomeric maltose, oligoisomaltose, glucose syrup, maltodextrin, polydextrose, the water-soluble dietary fiber.
9. krill oil microcapsule powder vegetation method as claimed in claim 8, it is characterized in that: be added with the oil phase antioxidant of krill oil weight 0.001～10% outward to oil phase, described oil phase antioxidant is astaxanthin, lutein ester, canthaxanthin, lutein, one or both mixtures that form with arbitrary proportion of beta carotene, zeaxanthin, rosemary, Xue MingRosma rinus officinalis, dl-alpha-tocopherol, mixing natural VE, VA, butylated hydroxy anisole, dibutyl hydroxy toluene, n-propyl gallate, ditert-butylhydro quinone; Or ∕ and be added with krill oil weight 0.001～5% water antioxidant outward to aqueous phase, described water antioxidant is ascorbic acid, sodium ascorbate, Calcium Ascorbate, D-araboascorbic acid and sodium salt thereof, sodium lactate, the mixture that in the Tea Polyphenols one or both form with arbitrary proportion: or ∕ and be added with krill oil weight 0.001～5% water stabilizing agent outward to aqueous phase, described water stabilizing agent is phosphoric acid, Sodium Acid Pyrophosphate, sodium pyrophosphate, calcium dihydrogen phosphate, potassium dihydrogen phosphate, diammonium hydrogen phosphate, dipotassium hydrogen phosphate, calcium monohydrogen phosphate, tricalcium phosphate, tripotassium phosphate, tertiary sodium phosphate, calgon, sodium phosphate trimer, sodium dihydrogen phosphate, a kind of in the sodium hydrogen phosphate.
10. krill oil microcapsule powder vegetation method as claimed in claim 9, it is characterized in that: non-water raw material obtains by following weight proportion:
Krill oil 0.001～90%
Oil phase antioxidant 0.001～10%
Wall material 0.5～90%
Water antioxidant 0.001～5%
Water stabilizing agent 0.001～5%
Anticaking agent 0.001～5%
Flavoring essence 0～5%
Filler 0.001～99%
Concrete steps are:
1, oil phase preparation: under 20～90 ℃ of conditions, krill oil, oil phase essence and oil phase antioxidant are mixed, stirring and dissolving gets the solution I;
2, water preparation: under 20～90 ℃ of conditions, wall material, water antioxidant, water essence, anticaking agent and filler are added to the water, are stirred to dissolve and get the dissolving II, wherein the consumption of water is 0.1～9 times of non-water raw material gross mass;
3, emulsification: oil phase is slowly added aqueous phase, mechanical agitation, rotating speed 60～300rpm, behind stirring and emulsifying 0.1～1h, cutter speed of agitator 8000～30000rpm shears 0.1～6h;
4, homogeneous: colostric fluid is high-pressure homogeneous through 5～100MPa, and the krill oil particle diameter slowly stirs 0.1～5h at 20nm～2000nm behind the homogeneous;
5, the gained emulsion obtains the krill oil microcapsule powder through super-dry.
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1465264A (en) * | 2002-06-19 | 2004-01-07 | 西藏圣岗实业有限公司 | Method for preparing microcapsule powder of instant buttered tea |
| CN101646426A (en) * | 2006-11-03 | 2010-02-10 | 普罗诺瓦生物医药挪威公司 | Fatty acid alcohols |
| CN101669920A (en) * | 2008-09-10 | 2010-03-17 | 阜宁怀仁生物有限公司 | Strong anti-oxidation DHA microcapsule and preparation method thereof |
| CN101856125A (en) * | 2010-06-12 | 2010-10-13 | 嘉吉烯王生物工程（武汉）有限公司 | Spray freeze-drying preparation technology for polyunsaturated fatty acid oil microcapsule |
| CN101884415A (en) * | 2010-06-18 | 2010-11-17 | 南京工业大学 | DHA microcapsule and preparation process thereof |
| CN102228257A (en) * | 2011-06-27 | 2011-11-02 | 湖北福星生物科技有限公司 | Algal oil DHA (Docosahexaenoic Acid) microcapsule and preparation method thereof |
| CN102987382A (en) * | 2012-08-08 | 2013-03-27 | 辽宁省大连海洋渔业集团公司 | Krill oil microcapsule powder and preparation method thereof |
-
2012
- 2012-08-08 CN CN2012102803072A patent/CN102860506A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1465264A (en) * | 2002-06-19 | 2004-01-07 | 西藏圣岗实业有限公司 | Method for preparing microcapsule powder of instant buttered tea |
| CN101646426A (en) * | 2006-11-03 | 2010-02-10 | 普罗诺瓦生物医药挪威公司 | Fatty acid alcohols |
| CN101669920A (en) * | 2008-09-10 | 2010-03-17 | 阜宁怀仁生物有限公司 | Strong anti-oxidation DHA microcapsule and preparation method thereof |
| CN101856125A (en) * | 2010-06-12 | 2010-10-13 | 嘉吉烯王生物工程（武汉）有限公司 | Spray freeze-drying preparation technology for polyunsaturated fatty acid oil microcapsule |
| CN101884415A (en) * | 2010-06-18 | 2010-11-17 | 南京工业大学 | DHA microcapsule and preparation process thereof |
| CN102228257A (en) * | 2011-06-27 | 2011-11-02 | 湖北福星生物科技有限公司 | Algal oil DHA (Docosahexaenoic Acid) microcapsule and preparation method thereof |
| CN102987382A (en) * | 2012-08-08 | 2013-03-27 | 辽宁省大连海洋渔业集团公司 | Krill oil microcapsule powder and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| RUBEN BUSTOS等: "Oxidative stability of carotenoid pigments and polyunsaturated fatty acids in microparticulate diets containning krill oil for nutrition of marine fish larvae", 《JOURNAL OF FOOD ENGINEERING》 * |
| 康吟等: "鱼油微胶囊化壁材的分类及应用", 《北京水产》 * |
| 汪多仁: "《药用中间体》", 31 January 2008, 海洋出版社 * |
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