CN107164089A - A kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract - Google Patents

A kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract Download PDF

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Publication number
CN107164089A
CN107164089A CN201710354140.2A CN201710354140A CN107164089A CN 107164089 A CN107164089 A CN 107164089A CN 201710354140 A CN201710354140 A CN 201710354140A CN 107164089 A CN107164089 A CN 107164089A
Authority
CN
China
Prior art keywords
seed oil
rosmarinus officinalis
peony seed
officinalis extract
antioxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710354140.2A
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Chinese (zh)
Inventor
张延龙
白章振
于蕊
牛立新
付炜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaanxi Peony Industry Development Co Ltd
Northwest A&F University
Original Assignee
Shaanxi Peony Industry Development Co Ltd
Northwest A&F University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaanxi Peony Industry Development Co Ltd, Northwest A&F University filed Critical Shaanxi Peony Industry Development Co Ltd
Priority to CN201710354140.2A priority Critical patent/CN107164089A/en
Publication of CN107164089A publication Critical patent/CN107164089A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00Preserving by using additives, e.g. anti-oxidants
    • C11B5/0092Mixtures
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D9/00Other edible oils or fats, e.g. shortenings, cooking oils
    • A23D9/06Preservation of finished products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00Preserving by using additives, e.g. anti-oxidants
    • C11B5/0021Preserving by using additives, e.g. anti-oxidants containing oxygen
    • C11B5/0028Carboxylic acids; Their derivates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00Preserving by using additives, e.g. anti-oxidants
    • C11B5/0021Preserving by using additives, e.g. anti-oxidants containing oxygen
    • C11B5/0035Phenols; Their halogenated and aminated derivates, their salts, their esters with carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00Preserving by using additives, e.g. anti-oxidants
    • C11B5/0085Substances of natural origin of unknown constitution, f.i. plant extracts

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Botany (AREA)
  • Biochemistry (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The invention discloses a kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract, the complex natural antioxidant is (0.5~2.5) in mass ratio by Tea Polyphenols, Rosmarinus officinalis extract, ascorbyl palmitate:(1~3):1 composition.The present invention is by the way that Tea Polyphenols, Rosmarinus officinalis extract, ascorbyl palmitate are compounded, obvious collaboration facilitation is generated between three, it is added to antioxidant effect in peony seed oil and is significantly higher than pure one-component, and antioxidant effect is better than TBHQ, is significantly higher than BHA, BHT and other naturals.Complex natural antioxidant of the present invention is green non-poisonous, with good heat endurance and significant antioxidant effect, available for the anti-oxidant of peony seed oil.

Description

A kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract
Technical field
The present invention relates to a kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract.
Background technology
Peony seed oil is rich in unrighted acid, and its content is up to more than 90%, and polyunsaturated fatty acid alpha-linolenic acid surpasses 40% is crossed, its nutritive value exceeds well over olive oil, tea-seed oil, walnut oil.Therefore, peony seed oil in 2011 is by health ministry batch Standard is new energy food, and this is significant to greatly develop woody oleiferous plants crop and the grain and oil crisis of solution China.But due to Its high degree of unsaturation, during longer-term storage, easy light, heat, oxygen, the influence of water grading factors and aoxidize, generated The compound such as oxide and aldehyde, ketone, cause grease discoloration, it is spoiled, reduce edibility, or even endanger it is healthy.In order to press down Oxidation deterioration in peony seed oil storage processed, extends storage time, most common method is exactly to add antioxidant.
Oil antioxidant is divided into artificial synthesized antioxidant and natural.Artificial synthesized antioxidant, such as fourth Base BHA (BHA), dibutyl hydroxy toluene (BHT), tert-butylhydroquinone (TBHQ) etc., with significant anti-oxidant Effect, but its security is the problem of be always extensive concern.There are some researches prove BHA, BHT, TBHQ of high dose have carcinogenic work With, therefore many countries limit the use to artificial synthesized antioxidant, the U.S., European Union etc. prohibits the use of synthesis anti-oxidant Agent.Natural is extracted directly from plant, because being got well with safe, antioxidant effect and having certain health-care effect etc. Feature and enjoy favor.Natural antioxygen also demonstrate that to natural anti-oxidation and artificial synthesized antioxidant comparative studies in the late two decades The potential advantages of agent, and the trend of substituted artificial synthesized antioxidant.
The content of the invention
The technical problems to be solved by the invention be to provide it is a kind of there is good heat endurance, it is green non-poisonous and have The peony seed oil complex natural antioxidant of significant antioxidant effect.
Solving the technical scheme that is used of above-mentioned technical problem is:The peony seed oil complex natural antioxidant is more by tea Phenol, Rosmarinus officinalis extract, ascorbyl palmitate are (0.5~2.5) in mass ratio:(1~3):1 composition.
Complex natural antioxidant of the present invention preferably presses matter by Tea Polyphenols, Rosmarinus officinalis extract, ascorbyl palmitate Amount is than being (1~2):(1~3):1 composition.
Complex natural antioxidant of the present invention is further preferably by Tea Polyphenols, Rosmarinus officinalis extract, vitamin-c palmitate Ester is 1 in mass ratio:1:1 composition.
Complex natural antioxidant of the present invention be used for peony seed oil it is anti-oxidant when, wherein ascorbyl palmitate adds Dosage is the 0.01% of peony seed oil quality, and the addition of Tea Polyphenols is the 0.005%~0.025% of peony seed oil quality, fan Repeatedly the addition of fragrant extract is the 0.01%~0.03% of peony seed oil quality.
Natural Antioxidant Tea Polyphenol in complex natural antioxidant of the present invention is a kind of Polyphenols active material, to people Body health has important physiological action, such as removes free radical, lowering blood pressure and blood fat, hypoglycemic safe, with good heat Stability, green non-pollution, and antioxidant effect are good, are the ideal substitutes of artificial synthesized antioxidant.Rosmarinus officinalis extract With good anti-oxidant, anti-aging effect, also with scalp blood circulation is stimulated, the effect of hair care hair care is played.Synergy Agent ascorbyl palmitate is that (WHO) the food additives committee of the World Health Organization is assessed as with trophism, nontoxic, height Imitate, using the food additives of safety, synergist is commonly used in grease, anti-oxidant, food (grease) can be played for food The effects such as color protection, fortification.
The present invention by by Tea Polyphenols, Rosmarinus officinalis extract and synergist ascorbyl palmitate compound, three it Between generate obvious collaboration facilitation, be added to antioxidant effect in peony seed oil and be significantly higher than pure one-component, and anti- Oxidation effectiveness is better than TBHQ, is significantly higher than BHA, BHT and other naturals.
Complex natural antioxidant of the present invention is green non-poisonous, with good heat endurance and significant antioxidant effect, Available for the anti-oxidant of peony seed oil.
Embodiment
With reference to embodiment, the present invention is described in more detail, but protection scope of the present invention is not limited only to these realities Apply example.
Embodiment 1
100mg Tea Polyphenols, 100mg Rosmarinus officinalis extracts, 100mg ascorbyl palmitates are well mixed, obtain male The oily complex natural antioxidant of red seed.
Embodiment 2
200mg Tea Polyphenols, 300mg Rosmarinus officinalis extracts, 100mg ascorbyl palmitates are well mixed, obtain male The oily complex natural antioxidant of red seed.
Embodiment 3
50mg Tea Polyphenols, 200mg Rosmarinus officinalis extracts, 100mg ascorbyl palmitates are well mixed, tree peony is obtained Seed oil complex natural antioxidant.
Embodiment 4
250mg Tea Polyphenols, 150mg Rosmarinus officinalis extracts, 100mg ascorbyl palmitates are well mixed, obtain male The oily complex natural antioxidant of red seed.
In order to prove beneficial effects of the present invention, inventor adds embodiment 1 and embodiment 2 into peony seed oil respectively Complex natural antioxidant, using Schaal Oven Methods, is placed in 60 ± 1 DEG C of baking ovens, its peroxidating is determined after one week Value, the measure of peroxide value is with reference to GB/T-5538 2005, using peroxide value as the evaluation criterion of antioxidant effect, to this hair The antioxygenic property of bright complex natural antioxidant is evaluated, and with the Natural Antioxidant Tea Polyphenol of pure single component (TP), Rosmarinus officinalis extract (RE), artificial antioxidant BHA, BHT, TBHQ of pure single component, and synergist ascorbic acid The antioxygenic property of composite antioxidant after palmitate (AP) and citric acid (CA) compounding is compared, at the same with without Any oxidation resistant peony seed oil does blank control, and result of the test is as shown in table 1.
The antioxidant effect of the different antioxidants of table 1
Note:To be that optimal antioxidant effect that inventor is determined by experiment is corresponding add the addition of single component in table Dosage, wherein 0.01%TP+0.01%RE+0.01%AP represent the addition of Tea Polyphenols for peony seed oil quality 0.01%, The addition of Rosmarinus officinalis extract is that the 0.01% of the peony seed oil quality, addition of ascorbyl palmitate is peony seed oil The 0.01% of quality, the implication that other antioxidants are represented is same.
From table 1, added in peony seed oil single natural TP, RE and single artificial antioxidant TBHQ, BHA, BHT antioxidant effect be substantially less than the embodiment of the present invention 1 and 2 complex natural antioxidant, and the present invention answer The antioxidant effect for closing natural is also significantly better than the antioxidant that TP is compounded with RE, CA three.

Claims (3)

1. a kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract, it is characterised in that:The composite natral antioxygen Agent is (0.5~2.5) in mass ratio by Tea Polyphenols, Rosmarinus officinalis extract, ascorbyl palmitate:(1~3):1 composition.
2. the peony seed oil complex natural antioxidant according to claim 1 containing Rosmarinus officinalis extract, it is characterised in that: The complex natural antioxidant is (1~2) in mass ratio by Tea Polyphenols, Rosmarinus officinalis extract, ascorbyl palmitate:(1~ 3):1 composition.
3. the peony seed oil complex natural antioxidant according to claim 1 containing Rosmarinus officinalis extract, it is characterised in that: The complex natural antioxidant is 1 in mass ratio by Tea Polyphenols, Rosmarinus officinalis extract, ascorbyl palmitate:1:1 composition.
CN201710354140.2A 2017-05-18 2017-05-18 A kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract Pending CN107164089A (en)

Priority Applications (1)

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CN201710354140.2A CN107164089A (en) 2017-05-18 2017-05-18 A kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract

Applications Claiming Priority (1)

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CN201710354140.2A CN107164089A (en) 2017-05-18 2017-05-18 A kind of peony seed oil complex natural antioxidant containing Rosmarinus officinalis extract

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828508A (en) * 2017-12-08 2018-03-23 四川理工学院 The antioxidizing antistaling agent and its preservation method of a kind of tea-seed oil
CN108812874A (en) * 2018-04-23 2018-11-16 海南舒普生物科技有限公司 A kind of natural anti-oxidation color stabilizer for capsicum red pigment
CN110326673A (en) * 2019-08-09 2019-10-15 大连工业大学 A kind of linseed oil and preparation method thereof containing composite antioxidant
CN112314875A (en) * 2020-10-26 2021-02-05 苏州闻达食品配料有限公司 Composite natural antioxidant, pork ball containing composite natural antioxidant and preparation method of pork ball
CN112899080A (en) * 2021-02-25 2021-06-04 陕西海斯夫生物工程有限公司 Natural composite antioxidant for highly unsaturated fatty acid oil

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060189543A1 (en) * 2005-02-23 2006-08-24 Rosenbloom Richard A Compositions and methods for the treatment of leukemia
CN103392836A (en) * 2013-07-09 2013-11-20 菏泽市牡丹区牡丹研究所 Peony seed oil natural antioxidant composite
CN103767042A (en) * 2014-01-03 2014-05-07 广东广益科技实业有限公司 Natural antioxidant and preparation method natural antioxidant
CN106675780A (en) * 2017-01-05 2017-05-17 天津融信蓝海生物科技有限公司 Compound antioxidant and grease containing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060189543A1 (en) * 2005-02-23 2006-08-24 Rosenbloom Richard A Compositions and methods for the treatment of leukemia
CN103392836A (en) * 2013-07-09 2013-11-20 菏泽市牡丹区牡丹研究所 Peony seed oil natural antioxidant composite
CN103767042A (en) * 2014-01-03 2014-05-07 广东广益科技实业有限公司 Natural antioxidant and preparation method natural antioxidant
CN106675780A (en) * 2017-01-05 2017-05-17 天津融信蓝海生物科技有限公司 Compound antioxidant and grease containing same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107828508A (en) * 2017-12-08 2018-03-23 四川理工学院 The antioxidizing antistaling agent and its preservation method of a kind of tea-seed oil
CN108812874A (en) * 2018-04-23 2018-11-16 海南舒普生物科技有限公司 A kind of natural anti-oxidation color stabilizer for capsicum red pigment
CN110326673A (en) * 2019-08-09 2019-10-15 大连工业大学 A kind of linseed oil and preparation method thereof containing composite antioxidant
CN112314875A (en) * 2020-10-26 2021-02-05 苏州闻达食品配料有限公司 Composite natural antioxidant, pork ball containing composite natural antioxidant and preparation method of pork ball
CN112899080A (en) * 2021-02-25 2021-06-04 陕西海斯夫生物工程有限公司 Natural composite antioxidant for highly unsaturated fatty acid oil

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Application publication date: 20170915