CN107164044A - A kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry - Google Patents
A kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry Download PDFInfo
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- CN107164044A CN107164044A CN201710335338.6A CN201710335338A CN107164044A CN 107164044 A CN107164044 A CN 107164044A CN 201710335338 A CN201710335338 A CN 201710335338A CN 107164044 A CN107164044 A CN 107164044A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/08—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/288—Partial esters containing free carboxyl groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/042—Sulfate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/09—Heterocyclic compounds containing no sulfur, selenium or tellurium compounds in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/047—Thioderivatives not containing metallic elements
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/36—Seal compatibility, e.g. with rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry, using the polyalphaolefin SpectraSyn of mass ratio 80%TMPAO and 20% oil soluble polyether is compound as fully synthetic composite foundation oil, coordinates a variety of compound additives, including:Antioxidant, metal deactivator, antioxidant preservative, anti-emulsion, extreme pressure agent, antirust agent, anti-foaming agent, antiwear additive, corrosion inhibiter.The composition of the present invention is contacted with ammonia, and chemical change generation soaps sediment does not occur, possesses the performance such as good emulsion resistance, anti-bubble, froth breaking, anti-oxidant, suitable for the lubrication of Large-scale Fertilizer Plant centrifugal syngas compressor, ice maker and Steam Turbine, cooling, flushing, antirust and sealing, so as to ensure that machine is normally run.
Description
Technical field
A kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry of the present invention belongs to turbine lubricants
Field.
Background technology
It is applicable in chemical industry synthesis ammonia and chemical industry heavy load steam turbine, compressor, except there should be special antioxygen
Change outside stability, wear-resistant, extreme pressure, rust-preventing characteristic and resistance to emulsion, its most important feature is that to have anti-ammonia performance.Add due to using
There is the additive formulations technology of special antirust agent, various soaps sediments can not be generated with ammonia reaction, so as to ensure equipment just
Often operation.
Because ammonia is in the presence of having micro-moisture, mixture can be generated with the oxidation product in oil, be precipitated insoluble in oil,
When steam turbine high speed heavy duty is operated, powerful centrifugal force can make to be thrown out of insoluble in the various precipitabilities in oil, adhere to
Shaft coupling, makes shaft coupling dysequilibrium cause to produce vibration.
The content of the invention
It is an object of the invention to provide a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry, connect with ammonia
Touch and chemical change generation soaps sediment do not occur, possess the performance such as good emulsion resistance, anti-bubble, froth breaking, anti-oxidant, it is adaptable to
Large-scale Fertilizer Plant centrifugal syngas compressor, the lubrication of ice maker and Steam Turbine, cooling, flushing, antirust and sealing, can be protected
Card machine is normally run.
The present invention adopts the following technical scheme that solution above-mentioned technical problem:
A kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry, using the poly alpha olefin of mass ratio 80%
SpectraSynTMPAO and 20% oil soluble polyether is compound to coordinate a variety of compound additives as fully synthetic composite foundation oil,
Its each mass percent into being grouped into:
Component | Mass percentage content |
Base oil | Surplus |
Antioxidant | 0.03%~0.05% |
Metal deactivator | 0.02%~0.06% |
Antirust agent | 0.06%~0.1% |
Anti-foaming agent | 30~50ppm |
Anti- emulsion | 0.02%~0.04% |
Antioxidant preservative | 0.2%~0.5% |
Extreme pressure agent | 0.2%~0.5% |
Antiwear additive | 1.0%~1.5% |
Corrosion inhibiter | 0.02%~0.03% |
The mass percentage content of above each component is 100%.
Antioxidant is butyl/octyl diphenylamine T357 and 50% of mass ratio 50% complexing agent of derivative containing benzotriazole
T532。
Metal deactivator is that the 1,4- dihydroxy anthraquinones and 20% mercaptobenzimidazole of mass ratio 80% are combined.
Antirust agent is the dinonyl naphthalene neobalgin T705A and 40% of mass ratio 60% alkenyl succinic acid half ester T747;
Anti-foaming agent is No. 1 composite anti-foam agent.
Anti- emulsion is amine and epoxide condensation product T1001;Antioxidant preservative is 80% dialkyl dithio amino
Formic acid esters and 20% molybdates esters.
Extreme pressure agent is oleic acid glycol ester T403C;Antiwear additive is the thio-ammonium phosphate T307 and 50% of mass ratio 50%
D2EHDTPA phenyl ester T309.
Corrosion inhibiter is alkyl naphthalene sulfonic acid calcium.
The advantage of the invention is that:The present composition is contacted with ammonia, and chemical change generation soaps sediment, tool do not occur
The performance such as standby good emulsion resistance, anti-bubble, froth breaking, anti-oxidant, it is adaptable to Large-scale Fertilizer Plant centrifugal syngas compressor, ice
Lubrication, cooling, flushing, antirust and the sealing of machine and Steam Turbine, can guarantee that machine is normally run.
Embodiment
Embodiment 1:
Following ingredients precentagewise content is reconciled and formed:
Above constituent mass percentage summation is 100%.
Embodiment 2:
Following ingredients precentagewise content is reconciled and formed:
Above constituent mass percentage summation is 100%.
Embodiment 3:
Following ingredients precentagewise content is reconciled and formed:
Above constituent mass percentage summation is 100%.
The typical physical and chemical index of embodiment 1:
The typical physical and chemical index of embodiment 2:
The typical physical and chemical index of embodiment 3:
Claims (7)
1. a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry, it is characterised in that:Using mass ratio 80%
Poly alpha olefin SpectraSynTMPAO and 20% oil soluble polyether is compound as fully synthetic composite foundation oil, coordinates a variety of multiple
Close additive, its each mass percent into being grouped into:
The mass percentage content of above each component is 100%.
2. a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry as claimed in claim 1, its feature exists
In:Antioxidant is butyl/octyl diphenylamine T357 and 50% of mass ratio 50% complexing agent of derivative containing benzotriazole T532.
3. a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry as claimed in claim 1, its feature exists
It is combined in the 1,4- dihydroxy anthraquinones and 20% mercaptobenzimidazole that metal deactivator is mass ratio 80%.
4. a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry as claimed in claim 1, its feature exists
It is the dinonyl naphthalene neobalgin T705A and 40% of mass ratio 60% alkenyl succinic acid half ester T747 in antirust agent;Anti-foaming agent
It is No. 1 composite anti-foam agent.
5. a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry as claimed in claim 1, its feature exists
In anti-emulsion be amine and epoxide condensation product T1001;Antioxidant preservative is 80% dialkyl dithio amino formate
With 20% molybdates esters.
6. a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry as claimed in claim 1, its feature exists
In extreme pressure agent be oleic acid glycol ester T403C;Antiwear additive is the thio of the thio-ammonium phosphate T307 and 50% of mass ratio 50%
Phenyl phosphate T309.
7. a kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry as claimed in claim 1, its feature exists
In corrosion inhibiter be alkyl naphthalene sulfonic acid calcium.
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CN201710335338.6A CN107164044A (en) | 2017-05-12 | 2017-05-12 | A kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry |
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CN201710335338.6A CN107164044A (en) | 2017-05-12 | 2017-05-12 | A kind of extreme-pressure anti-wear composition for anti-ammonia turbine oil for being applicable chemical industry |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114133974A (en) * | 2021-12-08 | 2022-03-04 | 东营市东滨石油技术服务有限公司 | Diesel engine lubricating oil |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101724487A (en) * | 2008-10-15 | 2010-06-09 | 中国石油天然气股份有限公司 | Composition for anti-ammonia turbine oil |
CN104130842A (en) * | 2014-07-25 | 2014-11-05 | 张家港市胜宇石油化工制品有限公司 | Oil-soluble polyether oil for screw-type air compressor |
CN104357183A (en) * | 2014-09-30 | 2015-02-18 | 苏州长盛机电有限公司 | Steam turbine oil composition and preparation method thereof |
-
2017
- 2017-05-12 CN CN201710335338.6A patent/CN107164044A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101724487A (en) * | 2008-10-15 | 2010-06-09 | 中国石油天然气股份有限公司 | Composition for anti-ammonia turbine oil |
CN104130842A (en) * | 2014-07-25 | 2014-11-05 | 张家港市胜宇石油化工制品有限公司 | Oil-soluble polyether oil for screw-type air compressor |
CN104357183A (en) * | 2014-09-30 | 2015-02-18 | 苏州长盛机电有限公司 | Steam turbine oil composition and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114133974A (en) * | 2021-12-08 | 2022-03-04 | 东营市东滨石油技术服务有限公司 | Diesel engine lubricating oil |
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