CN107163866A - A kind of medical UV-curable water-borne conductive pressure sensitive adhesive - Google Patents
A kind of medical UV-curable water-borne conductive pressure sensitive adhesive Download PDFInfo
- Publication number
- CN107163866A CN107163866A CN201710392700.3A CN201710392700A CN107163866A CN 107163866 A CN107163866 A CN 107163866A CN 201710392700 A CN201710392700 A CN 201710392700A CN 107163866 A CN107163866 A CN 107163866A
- Authority
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- China
- Prior art keywords
- water
- pressure sensitive
- sensitive adhesive
- conductive pressure
- medical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004820 Pressure-sensitive adhesive Substances 0.000 title claims abstract description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- 239000000243 solution Substances 0.000 claims abstract description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 8
- 235000011187 glycerol Nutrition 0.000 claims abstract description 8
- 239000003973 paint Substances 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 6
- 229920001661 Chitosan Polymers 0.000 claims abstract description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 4
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical group CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 239000007858 starting material Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 abstract description 6
- 206010070834 Sensitisation Diseases 0.000 abstract description 4
- 230000003013 cytotoxicity Effects 0.000 abstract description 4
- 231100000135 cytotoxicity Toxicity 0.000 abstract description 4
- 239000003999 initiator Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000008313 sensitization Effects 0.000 abstract description 4
- 229920002678 cellulose Polymers 0.000 abstract description 2
- 239000001913 cellulose Substances 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 150000004676 glycans Chemical class 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract description 2
- -1 light trigger Chemical compound 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 11
- 239000007787 solid Substances 0.000 description 5
- 239000005030 aluminium foil Substances 0.000 description 3
- 206010040844 Skin exfoliation Diseases 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000007719 peel strength test Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
- C08F251/02—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof on to cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/02—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/314—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2451/00—Presence of graft polymer
Abstract
A kind of medical UV-curable water-borne conductive pressure sensitive adhesive, is prepared using following steps：1) water-soluble high-molecular material or chitosan, are configured to the aqueous solution that mass concentration is 1 10%；2) acrylic acid, hydroxypropyl acrylate, crosslinking agent, light trigger, glycerine and sodium hydroxide, stirring to whole dissolvings, are added into above-mentioned solution；3) 1.0 2.0mm wet film, is coated into using paint film spreader；4) take out and produce after, being irradiated under ultraviolet curing machine fluorescent tube.Whole raw material of the invention is water solubility, using water as solvent, reduces the vitro cytotoxicity and sensitization of environmental pollution and product；With cellulose matrix or glycan substrate, natural environmental-protective, and be conducive to adjusting the application viscosity of pressure sensitive adhesive；Using water-soluble photoinitiator, be conducive to the foul odour for avoiding oil-soluble initiator from being produced after decomposing；Rapid curing is irradiated using UV light, curing rate is exceedingly fast, production ultrahigh in efficiency.
Description
Technical field
The invention belongs to technical field of polymer materials, specially a kind of medical UV-curable water-borne conductive pressure sensitive adhesive.
Background technology
In recent years, electromyograph(EMG, electrocardiograph, Electrogastrograph meter, electric stimulating instrument and the height of electron medicine device such as high impedance
Frequency electric knife etc. is widely used in diagnosis and treatment disease, and they are contacted with electrode and human epidermal, and the life of human body is reflected on instrument
Thing electric signal, therefore it is accomplished by conductive electrode and energy and human epidermal close contact.Conductive pressure sensitive adhesive is both pressure sensitive
, it is and conductive, it is that what is activated in the presence of solvent-free by finger pressure remain the viscous-elastic material of viscosity.With
Under the conditions of the lighter finger pressure of power, glue surface can mutually be glued moment with human skin, after being combined with medical special equipment, can be very well
Transmit current signal in ground.Because it has good cohesive force and non-drying, using terminate can easily with skin peeling, and
Skin surface does not leave residue, therefore has broad application prospects.
But existing conductive pressure sensitive adhesive manufacturing process is not environmentally friendly enough, finished product has certain cytotoxicity and sensitization ring
Protect, so as to limit the application of conductive pressure sensitive adhesive to a certain extent.
The content of the invention
For solve prior art exist conductive pressure sensitive adhesive manufacturing process not environmentally, finished product have certain cytotoxicity and
Sensitization environmental protection, so as to limit the defect of the application of conductive pressure sensitive adhesive to a certain extent, the present invention provides a kind of medical ultraviolet
Photocuring waterborne conductive pressure sensitive adhesive.
A kind of medical UV-curable water-borne conductive pressure sensitive adhesive, is prepared using following steps：
1), water is substantially dissolved in by water-soluble high-molecular material such as sodium carboxymethylcellulose or hydroxyethyl cellulose etc. are overnight
In or dissolve chitosan in volume ratio be 1% acetum in, obtain mass concentration be 1-10% the aqueous solution；
2) above-mentioned solution 10-50mL, is taken to add acrylic acid 5-30g, hydroxypropyl acrylate 1-20g, crosslinking agent 0.1-1, light
Initiator 0.1-2.0, glycerine 5-30g and sodium hydroxide 0.1-1.0g, are evenly stirred until whole dissolvings；
3), it is coated using paint film spreader, obtains the wet film that thickness is 1.0-2.0mm；
4), above-mentioned wet film is positioned over below ultraviolet curing machine fluorescent tube at 10-40cm, irradiation is taken out after 5-120 seconds
To the waterborne conductive pressure sensitive adhesive.
Further, described crosslinking agent is water-soluble cross-linked dose of trimethylol-propane trimethacrylate etc..
Further, described light trigger is the water miscible initiator of Irgacure series.
Further, the ultraviolet curing machine is the cold light type ultraviolet curing machine that power is 500-2000W.The purple
Outside line curing fluorescent tube is high-pressure sodium lamp.
Beneficial effect：Whole raw material of the invention is water solubility, using water as solvent, reduces the body of environmental pollution and product
Outer cytotoxicity and sensitization；With cellulose matrix or glycan substrate, natural environmental-protective, and be conducive to adjusting the painting of pressure sensitive adhesive
Cloth viscosity；Using water-soluble photoinitiator, be conducive to the foul odour for avoiding oil-soluble initiator from being produced after decomposing；Utilize UV light spokes
According to rapid curing, curing rate is exceedingly fast, production ultrahigh in efficiency.
Embodiment
Embodiment 1
It will dissolve chitosan in the acetum that volume ratio is 1%, obtain the aqueous solution that mass concentration is 2%.(2)
Above-mentioned solution 40mL is taken to add acrylic acid 30g, hydroxypropyl acrylate 15g, crosslinking agent 0.7g, light trigger 0.8g, glycerine
30g, sodium hydroxide 0.8g, stir until solid all dissolves.(3) it is coated using paint film spreader, obtains thickness
For 2.0mm wet film.(4) wet film is positioned over below the cold light type ultraviolet curing machine fluorescent tube that power is 2000W at 30cm, spoke
Conductive pressure sensitive adhesive is obtained according to being taken out after 50 seconds.
Embodiment 2
(1) by water-soluble high-molecular material such as sodium carboxymethylcellulose it is overnight be substantially dissolved in water obtain mass concentration be
3% aqueous solution.(2) above-mentioned solution 20mL is taken to add acrylic acid 10g, hydroxypropyl acrylate 10g, crosslinking agent 0.5g are light-initiated
Agent 0.4g, glycerine 20g, sodium hydroxide 0.2g, stir until solid all dissolves.(3) carried out using paint film spreader
Coating, obtains the wet film that thickness is 1.0mm.(4) wet film is positioned over the cold light type ultraviolet curing machine fluorescent tube that power is 1000W
At the 20cm of lower section, irradiation is taken out after 80 seconds and obtains conductive pressure sensitive adhesive.
Embodiment 3
(1) it is substantially dissolved in water-soluble high-molecular material hydroxyethyl cellulose is overnight in water, it is 5% to obtain mass concentration
The aqueous solution.(2) above-mentioned solution 30mL is taken to add acrylic acid 15g, hydroxypropyl acrylate 20g, crosslinking agent 0.7g, light trigger
0.6g, glycerine 25g, sodium hydroxide 0.4g, stir until solid all dissolves.(3) applied using paint film spreader
Cloth, obtains the wet film that thickness is 1.5mm.(4) wet film is positioned under the cold light type ultraviolet curing machine fluorescent tube that power is 1500W
At square 25cm, irradiation is taken out after 60 seconds and obtains conductive pressure sensitive adhesive.
Embodiment 4
(1) it will dissolve chitosan in the acetum that volume ratio is 1%, obtain the aqueous solution that mass concentration is 1%.
(2) above-mentioned solution 10mL is taken to add acrylic acid 5g, hydroxypropyl acrylate 1g, crosslinking agent 0.1g, light trigger 0.1g, glycerine
5g, sodium hydroxide 0.1g, stir until solid all dissolves.(3) it is coated using paint film spreader, obtaining thickness is
1.0mm wet film.(4) wet film is positioned over below the cold light type ultraviolet curing machine fluorescent tube that power is 500W at 10cm, irradiation 5
Taken out after second and obtain conductive pressure sensitive adhesive.
Embodiment 5
Hydroxyethyl cellulose will be dissolved it is overnight be substantially dissolved in water, obtain mass concentration be 10% the aqueous solution.(2)
Above-mentioned solution 50mL is taken to add acrylic acid 30g, hydroxypropyl acrylate 20g, crosslinking agent 1g, light trigger 2.0g, glycerine 30g,
Sodium hydroxide 1g, stirs until solid all dissolves.(3) it is coated using paint film spreader, acquisition thickness is 2.0mm
Wet film.(4) wet film is positioned over below the cold light type ultraviolet curing machine fluorescent tube that power is 2000W at 40cm, irradiated 120 seconds
Take out afterwards and obtain conductive pressure sensitive adhesive.
For the performance of the medical UV-curable water-borne conductive pressure sensitive adhesive of the checking present invention, following test is done：
1st, the measure of electrical contact performance
Medical UV-curable water-borne conductive pressure sensitive adhesive made from embodiment 1-5 is coated on aluminium foil and forms pole plate, so
Be placed in afterwards by what pole plate entire area was consolidated on 20cm × 30cm metal plate, use accurate LCR measuring instruments determine frequency for
AC impedance under 1000kHz.It the results are shown in Table 1.
2nd, holding power is tested
Medical UV-curable water-borne conductive pressure sensitive adhesive made from embodiment 1-5 is coated on aluminium foil and forms pole plate, so
Tested afterwards according to GB/T4851-2014, the 25mm × 60mm cut in advance sample is attached to experiment plate surface, gone forward side by side
Row rolling laminating.In 1min, first whole experiment exemplar is gently placed on test stand, makes the free end of sample vertical, then will
Counterweight is gently applied on fixture.Record sample is kept completely separate the required time from breadboard.It the results are shown in Table 1.
3rd, 180 ° of peel strength tests
Medical UV-curable water-borne conductive pressure sensitive adhesive made from embodiment 1-5 is coated on aluminium foil and forms pole plate, so
Tested afterwards according to GB/T2792-2014, peeling rate is 300mm/min, records Average peel force.It the results are shown in Table 1:
The embodiment 1-5 of table 1 the performance test results
Claims (5)
1. a kind of medical UV-curable water-borne conductive pressure sensitive adhesive, it is characterised in that prepared using following steps：
1), by water-soluble high-molecular material it is overnight be substantially dissolved in water or dissolve chitosan in volume ratio be 1% acetic acid
In solution, the aqueous solution that mass concentration is 1-10% is obtained；
2), take above-mentioned solution 10-50mL to add acrylic acid 5-30g, it is hydroxypropyl acrylate 1-20g, crosslinking agent 0.1-1g, light-initiated
Agent 0.1-2.0g, glycerine 5-30g and sodium hydroxide 0.1-1.0g, are evenly stirred until whole dissolvings；
3), it is coated using paint film spreader, obtains the wet film that thickness is 1.0-2.0mm；
4), above-mentioned wet film is positioned over below ultraviolet curing machine fluorescent tube at 10-40cm, irradiation is taken out after 5-120 seconds, obtains water
Property conductive pressure sensitive glue.
2. medical UV-curable water-borne conductive pressure sensitive adhesive as claimed in claim 1, it is characterised in that the step 1) in
Water-soluble high-molecular material is sodium carboxymethylcellulose or hydroxyethyl cellulose.
3. medical UV-curable water-borne conductive pressure sensitive adhesive as claimed in claim 1, it is characterised in that described crosslinking agent is
Trimethylol-propane trimethacrylate.
4. the medical UV-curable water-borne conductive pressure sensitive adhesive as described in claim any one of 1-3, it is characterised in that described
Light trigger is the serial water soluble starters of Irgacure.
5. medical UV-curable water-borne conductive pressure sensitive adhesive as claimed in claim 4, it is characterised in that the ultraviolet curing
Machine is the cold light type ultraviolet curing machine that power is 500-2000W.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710392700.3A CN107163866B (en) | 2017-05-27 | 2017-05-27 | Medical ultraviolet-curing water-based conductive pressure-sensitive adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710392700.3A CN107163866B (en) | 2017-05-27 | 2017-05-27 | Medical ultraviolet-curing water-based conductive pressure-sensitive adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107163866A true CN107163866A (en) | 2017-09-15 |
| CN107163866B CN107163866B (en) | 2020-09-15 |
Family
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|---|---|---|---|
| CN201710392700.3A Active CN107163866B (en) | 2017-05-27 | 2017-05-27 | Medical ultraviolet-curing water-based conductive pressure-sensitive adhesive |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110157364A (en) * | 2019-04-30 | 2019-08-23 | 青岛光电医疗科技有限公司 | A kind of medical conductive pressure sensitive adhesive and preparation method thereof and resulting electrode slice |
| CN114456746A (en) * | 2021-12-30 | 2022-05-10 | 国科温州研究院(温州生物材料与工程研究所) | Composite hydrogel patch and preparation method thereof |
| CN115820199A (en) * | 2022-12-09 | 2023-03-21 | 浙江工业大学 | Modified black talc antibacterial conductive pressure-sensitive adhesive, medical electrode slice and preparation method thereof |
| CN115820199B (en) * | 2022-12-09 | 2024-05-03 | 浙江工业大学 | Modified black talcum antibacterial conductive pressure-sensitive adhesive, medical electrode slice and preparation method thereof |
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| CN110157364B (en) * | 2019-04-30 | 2022-02-11 | 青岛光电医疗科技有限公司 | Medical conductive pressure-sensitive adhesive, preparation method thereof and electrode slice prepared from same |
| CN114456746A (en) * | 2021-12-30 | 2022-05-10 | 国科温州研究院(温州生物材料与工程研究所) | Composite hydrogel patch and preparation method thereof |
| CN115820199A (en) * | 2022-12-09 | 2023-03-21 | 浙江工业大学 | Modified black talc antibacterial conductive pressure-sensitive adhesive, medical electrode slice and preparation method thereof |
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