CN107163326B - Ventilative waterproof adhesive tape compound is glued and adhesive tape raincoat - Google Patents
Ventilative waterproof adhesive tape compound is glued and adhesive tape raincoat Download PDFInfo
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- CN107163326B CN107163326B CN201710379571.4A CN201710379571A CN107163326B CN 107163326 B CN107163326 B CN 107163326B CN 201710379571 A CN201710379571 A CN 201710379571A CN 107163326 B CN107163326 B CN 107163326B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D3/00—Overgarments
- A41D3/02—Overcoats
- A41D3/04—Raincoats
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a breathable waterproof adhesive tape composite adhesive, which comprises a surface adhesive and a bottom adhesive, wherein the surface adhesive comprises: styrene butadiene rubber, sulfur, an accelerator, an activator, an anti-aging agent, a filler and a softener; the filler comprises: air permeable material, pottery clay and carbon black. The invention provides a breathable waterproof adhesive tape composite adhesive, and also provides a breathable adhesive tape raincoat and a preparation method thereof.
Description
Technical Field
The invention belongs to the field of rubber materials, and relates to a breathable waterproof adhesive tape composite adhesive and an adhesive tape raincoat.
Background
The raincoat is a common rain gear for people, and is an essential rain shielding tool especially when riding a bicycle or a motorcycle in rainy days; in the existing raincoat preparation process, people usually glue a layer of surface glue on cloth, vulcanize the surface glue, polish the edge bonding part of the adhesive tape, cut the cloth according to a specific size, brush the bonding glue paste at the bottom edge bonding part, bond and form the raincoat. Therefore, the existing manufacturing process adopts the existing primer and surface glue, has the defect of air impermeability, and has no measure for ensuring air permeability in the design and forming procedures. When the raincoat is sanded, only the edge bonding part of the adhesive tape is sanded, so that the existing raincoat has the defect of air impermeability.
Disclosure of Invention
The invention aims to solve the problems and provides the breathable waterproof adhesive tape composite adhesive, and the prepared adhesive tape composite adhesive can achieve the effects of breathability and waterproofness by adding the rice straw powder into the styrene butadiene rubber.
The invention also discloses a rubber-covered raincoat and a preparation method thereof.
In order to achieve the purposes, the invention adopts the technical scheme that: the breathable waterproof adhesive tape composite adhesive comprises a surface adhesive and a base adhesive, wherein the surface adhesive comprises the following components in parts by weight: 80-120 parts of butadiene styrene rubber, 1.5-2.5 parts of sulfur, 4.1-6.8 parts of accelerator, 5.5-8.5 parts of activator, 2.9-5.1 parts of anti-aging agent, 181 parts of filler 142 and 24-30 parts of softener; the filler comprises the following components in parts by weight: 30-40 parts of breathable material, 100 parts of pottery clay and 125 parts of carbon black.
In the surface glue, the softening agent is preferably engine oil.
In the surface glue, the accelerant comprises the following components in parts by weight: 2-3 parts of accelerator CZ, 1.5-2 parts of accelerator DM, 0.5-1.5 parts of accelerator D and 0.1-0.3 part of accelerator TT.
In the surface glue, the activating agent comprises the following components in parts by weight: 3-5 parts of active zinc oxide and 2.5-3.5 parts of stearic acid.
In the surface glue, the anti-aging agent comprises the following components in parts by weight: 0.4-0.6 part of anti-aging agent H, 2-601 parts of anti-aging agent FHD and 1.5-2.5 parts of paraffin.
In the surface glue, the breathable material comprises the following components in parts by weight: 0-40 parts of mineral molecular sieve, 0-40 parts of hemp powder and 0-40 parts of straw powder, wherein the breathable material at least comprises one of the mineral molecular sieve, the hemp powder and the straw powder.
The primer comprises the following components in parts by weight: 80-120 parts of butadiene-styrene rubber, 1.5-2 parts of sulfur, 2.4-3.8 parts of accelerator, 3.3-4.7 parts of activator, 1-1.6 parts of anti-aging agent and 75-135 parts of filler.
Preferably, in the primer, the accelerator comprises the following components in parts by weight: 1-1.5 parts of accelerator CZ, 1-1.5 parts of accelerator DM and 0.4-0.8 part of accelerator TT.
Preferably, in the primer, the activator comprises the following components in parts by weight: 2.5 to 3.5 parts of active zinc oxide and 0.8 to 1.2 parts of stearic acid.
Preferably, in the primer, the anti-aging agent comprises the following components in parts by weight: 0.2-0.4 part of anti-aging agent H and 1.2 parts of anti-aging agent FHD-600.8.
Preferably, in the primer, the filler comprises the following components in parts by weight: 70-110 parts of calcium carbonate and 5-25 parts of breathable material.
In the primer, the breathable material comprises the following components in parts by weight: 0-25 parts of mineral molecular sieve, 0-25 parts of hemp powder and 0-25 parts of straw powder, wherein the breathable material at least comprises the mineral molecular sieve,
One of hemp powder and straw powder.
Preferably, in the face and base glues, the air-permeable material is powder obtained by grinding, pulverizing and sieving with a 300-mesh sieve.
Preferably, the carbon black is selected from highly wear-resistant carbon blacks.
In the surface glue and the bottom glue, the mineral molecular sieve is as follows: the kaolin used in oil refineries is calcined at high temperature to obtain the particles.
The adhesive raincoat comprises the breathable waterproof adhesive tape composite adhesive, an adhesive tape and adhesive cement arranged at the bonding part of the edge of the adhesive tape; the adhesive tape is sequentially provided with a primer and a surface adhesive of the composite adhesive. The adhesive cement is conventional, and people can select the adhesive cement according to needs, so that the adhesive cement is adhered to the edge of the adhesive tape to prevent the adhesive cement from falling off.
The preparation method of the adhesive raincoat comprises the following steps:
A. mixing to respectively prepare base rubber and surface rubber;
B. adding gasoline into the primer, and beating the primer into primer mucilage by a beating machine;
C. calendering, scraping bottom glue paste on the cloth, and pressing surface glue on the bottom glue paste to obtain a rubberized fabric;
D. c, vulcanizing the pressed adhesive tape in the step C;
E. d, polishing the adhesive surface of the adhesive tape vulcanized in the step D;
F. cutting the polished adhesive tape;
G. brushing adhesive cement on the adhesive part at the edge of the adhesive tape, and drying;
H. bonding and forming to obtain the raincoat.
The invention has the beneficial effects that:
1. according to the invention, the breathable materials (the mineral molecular sieve, the hemp powder and the straw powder) are added into the styrene-butadiene rubber, and the breathable materials and the styrene-butadiene rubber are mutually cooperated, so that the adhesive tape composite rubber can be fluffy, and the breathable and waterproof effects are achieved.
2. When the adhesive-coated raincoat is prepared, the adhesive surface of the adhesive is completely polished, so that the air permeability of the adhesive-coated raincoat is better.
3. The invention adopts the adhesive cement to bond the edges of the adhesive tapes so as to prevent the adhesive tapes from falling off.
4. The invention adopts a plurality of accelerators such as the accelerator CZ and the accelerator D to achieve the synergistic effect of a plurality of materials.
5. The invention adopts the age inhibitor H and the age inhibitor FHD-60 to play a role in mutual synergy, can better prevent the compound adhesive and the prepared raincoat from aging, and prolongs the service life.
6. The invention adopts sulfur as a vulcanizing agent, and the vulcanizing agent and the accelerator are used together, so that a good synergistic effect can be achieved, the crosslinking performance of rubber can be improved, and the vulcanization efficiency of the rubber can be improved.
7. According to the invention, gasoline is added into the base glue, so that the base glue is beaten in the beater more uniformly and the cross-linking type is better.
8. The styrene butadiene rubber is selected as the main rubber material, has excellent comprehensive performance and good weather aging resistance, and can obviously prolong the service life of the clothes.
9. The invention selects the air permeable materials (mineral molecular sieve, hemp powder and straw powder) which have excellent green and environmental protection performance and are zero-pollution to the environment.
10. The invention adopts the engine oil, so that the prepared face glue can be softened, and the elasticity is increased.
11. The mineral molecular sieve is a catalyst used in oil refineries, and the main components of the mineral molecular sieve are aluminum oxide and silicon dioxide, also known as kaolin. The invention relates to a method for processing kaolin used in an oil refinery, which comprises the steps of using kaolin used in the oil refinery as a waste, carrying out high-temperature calcination on the kaolin, removing heavy metals and other harmful substances, achieving the effect of loosening and porosity, adding the kaolin into styrene butadiene rubber, and using the kaolin as a raincoat, wherein the kaolin used in the oil refinery can absorb some heavy metals and other harmful substances and can be buried as the waste.
Detailed Description
The present invention is described in detail below for the purpose of better understanding technical solutions of the present invention by those skilled in the art, and the description of the present invention is only exemplary and explanatory and should not be construed as limiting the scope of the present invention in any way.
The following are specific examples
Example 1
A breathable waterproof adhesive tape composite adhesive comprises a surface adhesive and a bottom adhesive;
the surface glue comprises the following components in parts by weight: 80 parts of butadiene styrene rubber, 1.5 parts of sulfur, 4.1 parts of accelerator, 5.5 parts of activator, 2.9 parts of anti-aging agent, 142 parts of filler and 24 parts of engine oil; the filler comprises the following components in parts by weight: 30 parts of breathable materials, 100 parts of argil and 12 parts of carbon black.
In the surface glue, the accelerant comprises the following components in parts by weight: 2 parts of accelerator CZ, 1.5 parts of accelerator DM, 0.5 part of accelerator D and 0.1 part of accelerator TT.
In the surface glue, the activating agent comprises the following components in parts by weight: 3 parts of active zinc oxide and 2.5 parts of stearic acid.
In the surface glue, the anti-aging agent comprises the following components in parts by weight: 0.4 part of anti-aging agent H, 1.5 parts of paraffin and FHD-601 parts of anti-aging agent.
In the surface glue, the breathable material comprises the following components in parts by weight: 10 parts of hemp powder and 20 parts of straw powder.
The primer comprises the following components in parts by weight: 80 parts of butadiene styrene rubber, 1.5 parts of sulfur, 2.4 parts of accelerator, 2.5 parts of active zinc oxide, 0.8 part of stearic acid, 70 parts of calcium carbonate, 1 part of anti-aging agent and 5 parts of straw powder.
In the primer, the accelerant comprises the following components in parts by weight: 1 part of accelerator CZ, 1 part of accelerator DM and 0.4 part of accelerator TT.
In the primer, the anti-aging agent comprises the following components in parts by weight: 0.2 part of anti-aging agent H and 0.78 part of anti-aging agent FHD-600.8 part.
The adhesive raincoat comprises the breathable waterproof adhesive tape composite adhesive, an adhesive tape and adhesive cement arranged at the bonding part of the edge of the adhesive tape; the adhesive tape is sequentially provided with a primer and a surface adhesive of the composite adhesive. The adhesive cement is conventional, and people can select the adhesive cement according to needs, so that the adhesive cement is adhered to the edge of the adhesive tape to prevent the adhesive cement from falling off.
The preparation method of the adhesive raincoat comprises the following steps:
A. mixing to respectively prepare base rubber and surface rubber;
B. adding gasoline into the primer, and beating the primer into primer mucilage by a beating machine;
C. calendering, scraping bottom glue paste on the cloth, and pressing surface glue on the bottom glue paste to obtain a rubberized fabric;
D. c, vulcanizing the pressed adhesive tape in the step C;
E. d, polishing the adhesive surface of the adhesive tape vulcanized in the step D;
F. cutting the polished adhesive tape;
G. brushing adhesive cement on the adhesive part at the edge of the adhesive tape, and drying;
H. bonding and forming to obtain the raincoat.
Example 2
A breathable waterproof adhesive tape composite adhesive comprises a surface adhesive and a bottom adhesive;
the surface glue comprises the following components in parts by weight: 120 parts of butadiene-styrene rubber, 2.5 parts of sulfur, 6.8 parts of accelerator, 8.5 parts of activator, 5.1 parts of anti-aging agent, 181 parts of filler and 30 parts of engine oil; the filler comprises the following components in parts by weight: 40 parts of breathable materials, 125 parts of argil and 16 parts of carbon black.
In the surface glue, the accelerant comprises the following components in parts by weight: 3 parts of accelerator CZ, 2 parts of accelerator DM, 1.5 parts of accelerator D and 0.3 part of accelerator TT.
In the surface glue, the activating agent comprises the following components in parts by weight: 5 parts of active zinc oxide and 3.5 parts of stearic acid.
In the surface glue, the anti-aging agent comprises the following components in parts by weight: 0.6 part of anti-aging agent H, 2.5 parts of paraffin and FHD-602 parts of anti-aging agent.
In the surface glue, the breathable material comprises the following components in parts by weight: 40 parts of hemp powder.
The primer comprises the following components in parts by weight: 120 parts of butadiene-styrene rubber, 2 parts of sulfur, 3.8 parts of an accelerator, 3.5 parts of active zinc oxide, 1.2 parts of stearic acid, 110 parts of calcium carbonate, 1.6 parts of an anti-aging agent, 10 parts of straw powder and 15 parts of a mineral molecular sieve.
In the primer, the accelerant comprises the following components in parts by weight: 1.5 parts of accelerator CZ, 1.5 parts of accelerator DM and 0.8 part of accelerator TT.
In the primer, the anti-aging agent comprises the following components in parts by weight: 0.4 part of anti-aging agent H and 601.2 parts of anti-aging agent FHD.
The adhesive raincoat comprises the breathable waterproof adhesive tape composite adhesive, an adhesive tape and adhesive cement arranged at the bonding part of the edge of the adhesive tape; the adhesive tape is sequentially provided with a primer and a surface adhesive of the composite adhesive. The adhesive cement is conventional, and people can select the adhesive cement according to needs, so that the adhesive cement is adhered to the edge of the adhesive tape to prevent the adhesive cement from falling off.
The preparation method of the raincoat is the same as that in the example 1, except that the components in the corresponding parts by weight are replaced by the components in the example 2.
Example 3
A breathable waterproof adhesive tape composite adhesive comprises a surface adhesive and a bottom adhesive;
the surface glue comprises the following components in parts by weight: 100 parts of butadiene styrene rubber, 2 parts of sulfur, 5.4 parts of accelerator, 7 parts of activator, 4 parts of anti-aging agent, 163 parts of filler and 27 parts of engine oil; the filler comprises the following components in parts by weight: 35 parts of breathable materials, 114 parts of pottery clay and 14 parts of carbon black.
In the surface glue, the accelerant comprises the following components in parts by weight: 2.5 parts of accelerator CZ, 1.7 parts of accelerator DM, 1 part of accelerator D and 0.2 part of accelerator TT.
In the surface glue, the activating agent comprises the following components in parts by weight: 4 parts of active zinc oxide and 3 parts of stearic acid.
In the surface glue, the anti-aging agent comprises the following components in parts by weight: 0.5 part of anti-aging agent H, 601.5 parts of anti-aging agent FHD and 2 parts of paraffin.
In the surface glue, the breathable material comprises the following components in parts by weight: 15 parts of mineral molecular sieve and 20 parts of straw powder.
The primer comprises the following components in parts by weight: 100 parts of butadiene styrene rubber, 1.8 parts of sulfur, 3 parts of accelerator, 3 parts of active zinc oxide, 1 part of stearic acid, 90 parts of antioxidant, 5 parts of straw powder and 10 parts of hemp powder.
In the primer, the accelerant comprises the following components in parts by weight: 1.2 parts of accelerator CZ, 1.2 parts of accelerator DM and 0.6 part of accelerator TT.
In the primer, the anti-aging agent comprises the following components in parts by weight: 0.3 part of anti-aging agent H and 601 parts of anti-aging agent FHD.
The adhesive raincoat comprises the breathable waterproof adhesive tape composite adhesive, an adhesive tape and adhesive cement arranged at the bonding part of the edge of the adhesive tape; the adhesive tape is sequentially provided with a primer and a surface adhesive of the composite adhesive. The adhesive cement is conventional, and people can select the adhesive cement according to needs, so that the adhesive cement is adhered to the edge of the adhesive tape to prevent the adhesive cement from falling off.
The preparation method of the raincoat is the same as that in example 1, except that the components in the corresponding parts by weight are replaced by the components in example 3.
It should be noted that, in this document, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
The principles and embodiments of the present invention are explained herein using specific examples, which are presented only to assist in understanding the method and its core concepts of the present invention. The foregoing is only a preferred embodiment of the present invention, and it should be noted that there are objectively infinite specific structures due to the limited character expressions, and it will be apparent to those skilled in the art that a plurality of modifications, decorations or changes may be made without departing from the principle of the present invention, and the technical features described above may be combined in a suitable manner; such modifications, variations, combinations, or adaptations of the invention using its spirit and scope, as defined by the claims, may be directed to other uses and embodiments.
Claims (5)
1. The breathable waterproof adhesive tape composite adhesive is characterized by comprising a surface adhesive and a bottom adhesive, wherein the surface adhesive comprises the following components in parts by weight: 80-120 parts of butadiene styrene rubber, 1.5-2.5 parts of sulfur, 4.1-6.8 parts of accelerator, 5.5-8.5 parts of activator, 2.9-5.1 parts of anti-aging agent, 181 parts of filler 142 and 24-30 parts of softener; the filler comprises the following components in parts by weight: 30-40 parts of breathable material, 100 parts of pottery clay and 125 parts of carbon black;
the breathable material comprises the following components in parts by weight: 0-40 parts of mineral molecular sieve, 0-40 parts of hemp powder and 0-40 parts of straw powder, wherein the breathable material at least comprises one of the mineral molecular sieve, the hemp powder and the straw powder;
the mineral molecular sieve is as follows: carrying out high-temperature calcination treatment on kaolin used in an oil refinery to obtain particles;
the primer comprises the following components in parts by weight: 80-120 parts of butadiene styrene rubber, 1.5-2 parts of sulfur, 2.4-3.8 parts of accelerator, 3.3-4.7 parts of activator, 1-1.6 parts of anti-aging agent and 75-135 parts of filler;
in the primer, the filler comprises the following components in parts by weight: 70-110 parts of calcium carbonate and 5-25 parts of a breathable material;
in the primer, the breathable material comprises the following components in parts by weight: 0-25 parts of mineral molecular sieve, 0-25 parts of hemp powder and 0-25 parts of straw powder, wherein the breathable material at least comprises one of the mineral molecular sieve, the hemp powder and the straw powder.
2. The breathable waterproof adhesive tape composite adhesive according to claim 1, wherein the promoter comprises the following components in parts by weight: 2-3 parts of accelerator CZ, 1.5-2 parts of accelerator DM, 0.5-1.5 parts of accelerator D and 0.1-0.3 part of accelerator TT.
3. The air-permeable waterproof adhesive tape compound glue according to claim 1, wherein an activator in the surface glue comprises the following components in parts by weight: 3-5 parts of active zinc oxide and 2.5-3.5 parts of stearic acid.
4. A rubberized raincoat comprising the breathable waterproof rubberized composite glue of any one of claims 1 to 3, further comprising a rubberized fabric, and a bonding mucilage disposed at the bonding of the edges of the rubberized fabric; the adhesive tape is sequentially provided with a primer and a surface adhesive of the composite adhesive.
5. The method for preparing the rubber-covered raincoat as claimed in claim 4, comprising the following steps:
A. mixing to respectively prepare base rubber and surface rubber;
B. adding gasoline into the primer, and beating the primer into primer mucilage by a beating machine;
C. calendering, scraping bottom glue paste on the cloth, and pressing surface glue on the bottom glue paste to obtain a rubberized fabric;
D. c, vulcanizing the pressed adhesive tape in the step C;
E. d, polishing the adhesive surface of the adhesive tape vulcanized in the step D;
F. cutting the polished adhesive tape;
G. brushing adhesive cement on the adhesive part at the edge of the adhesive tape, and drying;
H. bonding and forming to obtain the raincoat.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710379571.4A CN107163326B (en) | 2017-05-25 | 2017-05-25 | Ventilative waterproof adhesive tape compound is glued and adhesive tape raincoat |
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| CN201710379571.4A CN107163326B (en) | 2017-05-25 | 2017-05-25 | Ventilative waterproof adhesive tape compound is glued and adhesive tape raincoat |
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| CN107163326B true CN107163326B (en) | 2020-02-18 |
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| CN111038079B (en) * | 2018-10-12 | 2021-11-19 | 浙江森马服饰股份有限公司 | Water-based elastic pyrograph process without adhesive edge |
| CN110746688B (en) * | 2019-10-18 | 2022-01-18 | 温州大学 | Waterproof ventilated membrane |
| CN112443660B (en) * | 2020-11-16 | 2023-04-14 | 中国化工株洲橡胶研究设计院有限公司 | Cloth-sandwiched rubber leather cup and manufacturing method thereof |
| CN113667424A (en) * | 2021-09-13 | 2021-11-19 | 恩平市盈嘉丰胶粘制品有限公司 | Breathable waterproof composite adhesive tape and preparation method thereof |
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| CN105518211A (en) * | 2013-06-28 | 2016-04-20 | 布伦南企业有限公司 | Coated fabrics |
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| EP0622488B1 (en) * | 1993-04-28 | 1997-07-02 | Akzo Nobel N.V. | Waterproof, breathable rainwear and waterproof articles of foam plastic |
| US5789025A (en) * | 1995-12-15 | 1998-08-04 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Fire resistant, moisture barrier membrane |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105518211A (en) * | 2013-06-28 | 2016-04-20 | 布伦南企业有限公司 | Coated fabrics |
Non-Patent Citations (1)
| Title |
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| 汗麻粉体涂层织物的制备及其抗紫外性的研究;陆琳玲;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20170215;第25,48-51页 * |
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Address after: 414000 China (Hunan) Pilot Free Trade Zone, Yueyang District, Yueyang City, Hunan Province Patentee after: Jihua Rubber Industry Co.,Ltd. Address before: No.71 Dongting North Road, Yueyanglou District, Yueyang City, Hunan Province 414000 Patentee before: JIHUA 3517 RUBBER PRODUCTS Co.,Ltd. |
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| CP03 | Change of name, title or address |