CN107160780A - A kind of manufacture method of doubling glass - Google Patents

A kind of manufacture method of doubling glass Download PDF

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Publication number
CN107160780A
CN107160780A CN201710444079.0A CN201710444079A CN107160780A CN 107160780 A CN107160780 A CN 107160780A CN 201710444079 A CN201710444079 A CN 201710444079A CN 107160780 A CN107160780 A CN 107160780A
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China
Prior art keywords
glass
manufacture method
parts
doubling
doubling glass
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
CN201710444079.0A
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Chinese (zh)
Inventor
朱明静
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Hefei Steel Glass Products Co Ltd
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Hefei Steel Glass Products Co Ltd
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Filing date
Publication date
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Priority to CN201710444079.0A priority Critical patent/CN107160780A/en
Publication of CN107160780A publication Critical patent/CN107160780A/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/017Additives being an antistatic agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Joining Of Glass To Other Materials (AREA)

Abstract

A kind of manufacture method of doubling glass, comprises the following steps:First, by PVB resin dissolving in a solvent, the 25%PVB resin transparent shape liquid of solid content 15 is made;2nd, by nano material through speed lapping, homogeneous, surfactant, suspending agent, pH value conditioning agent, stabilizer are added Nanodispersion of the solid content 25 30% is made;3rd, the liquid PVB resin that step one is made is well mixed with the Nanodispersion that step 2 is made, the extruded machine extrusion of plasticizer is added after the drying glue material is made;4th, glue material made from step 3 is applied between the first glass baseplate and the second glass baseplate, be pressed, pressure suppresses 20 30min in 10 20Mpa, stands 24 days and can obtain finished product.Doubling glass manufacture method of the present invention, with energy-conservation the characteristics of, security is good, and glass breaking is not easy to hurt sb.'s feelings.

Description

A kind of manufacture method of doubling glass
Technical field
The invention belongs to glassmaking art, and in particular to a kind of manufacture method of doubling glass.
Background technology
Modern architecture high-rise building is in the majority, and designer likes designing big window-wall ratio, made in order to attractive in appearance and get better light Building energy consumption substantial increase, once and the too high glass breakage Falling Injury people's event of floor occur repeatedly.One building is being used During, it is very huge to obtain heat through windowpane, and summer air conditioner load is too big the problem of electric power the is inadequate puzzlement modern times occurs The development of metropolis.
Doubling glass is that a kind of pressed from both sides between two panels or divided glass is glued with binding material PVB or EVA intermediate coat, SGP films The knot advanced security glass that passed through HTHP is made together.
Current polyvinyl butyral resin(PVB)It is under catalyst action, through hutanal and the PVA aqueous solution be condensed instead Synthetic resin obtained by answering, with transparent, fast light, water-fast, film forming and erosion-resisting characteristics, to glass, metal, timber, ceramics, skin Leather, fiber and other material have preferable adhesive property, are the best adhesives of glass in the world, therefore it is mainly used in lamination Intermediate adhesion film layer is used as in safety glass manufacture.At present, about 89% PVB is used for the peace for producing building and automobile industry Full glass.
The doubling glass cement film used in doubling glass is a kind of polymer composite with hot adhesion, this kind of material Material can be used for layer glass between bonding, the security performance of glass can be improved to a certain extent, at the same play certain building, The decoration function of family etc..Current doubling glass cement membrane material is single layer structure, and it has the disadvantage:Film structure is single, is produced into This is higher, and particularly glued membrane top layer function is single, it is impossible to meet the use of a variety of environment.
The content of the invention
It is an object of the invention to provide a kind of manufacture method of doubling glass, mechanical property of the invention is good, membrane structure is more Sample, during glass gluing, is not likely to produce bubble or deformation, obtained doubling glass caking property is good, significantly improves folder The tensile strength and compression strength of glue glass, reduce the percent defective caused by the stress inhomogeneous between glass.
The invention provides following technical scheme:
A kind of manufacture method of doubling glass, comprises the following steps:
First, by PVB resin dissolving in a solvent, solid content 15-25%PVB resin transparent shape liquid is made;
2nd, by nano material through speed lapping, homogeneous, surfactant, suspending agent, pH value conditioning agent, stabilizer is added and is made Nanodispersion of the solid content in 25-30%;
3rd, the liquid PVB resin that step one is made is well mixed with the Nanodispersion that step 2 is made, added after the drying Glue material is made in the extruded machine extrusion of plasticizer;
4th, glue material made from step 3 is applied between the first glass baseplate and the second glass baseplate, by the first glass baseplate Clean up, be then sequentially laminated with the second glass baseplate, the first glass baseplate, glue material, the second glass are followed successively by from top to bottom Glass base material, then carry out under negative pressure of vacuum, heat, apply and keep pressure, glue material is thoroughly melted the first glass baseplate and The air that two glass baseplates are bonded together and are completely exhausted out therebetween is pressed, and pressure suppresses 20- in 10-20Mpa 30min, stands 2-4 days and can obtain finished product.
It is preferred that, the doubling glass includes the raw material of following parts by weight:10-14 parts of PVB resin, nano material 13-15 Part, 6-9 parts of surfactant, 4-7 parts of suspending agent, 5-8 parts of pH value conditioning agent, 6-8 parts of stabilizer and 8-12 parts of plasticizer.
It is preferred that, the PVB resin has three layers, and intermediate layer is PVB film, and two layers of use tackifying resin is used as carrier up and down Resin.
It is preferred that, contain vanadium dioxide nano powder in the PVB film.
It is preferred that, antioxidant, coupling agent, stearic acid, antistatic additive and UV absorption are also added with the tackifying resin Agent.
It is preferred that, the solvent of the step one is ethanol, ethyl ester, butyl ester or cyclohexanone.
It is preferred that, the nano material of the step 2 is silica or aluminum oxide.
It is preferred that, the step 4 finished product is placed in humidity and stood in 30-40%, temperature in 25-35 DEG C of environment.
The beneficial effects of the invention are as follows:
Mechanical property of the invention is good, membrane structure is diversified, during glass gluing, is not likely to produce bubble or deformation, is made Doubling glass caking property it is good, significantly improve the tensile strength and compression strength of doubling glass, reduce due between glass Stress inhomogeneous caused by percent defective.
Vanadium dioxide nano powder is with the addition of in the present invention, the purpose of reflection infrared ray and sunshine is reached, can answer extensively For building energy conservation, in terms of vehicle window heat-insulation;And by vanadium dioxide nano powder and other raw material compounding uses, improve folder The stability and service life of glue glass.
Doubling glass manufacture method of the present invention is simple, with low cost, the characteristics of with energy-conservation, and security is good, glass breaking It is not easy to hurt sb.'s feelings, is adapted to industrialization mass production.
Embodiment
Embodiment 1
A kind of manufacture method of doubling glass, comprises the following steps:
First, by PVB resin dissolving in a solvent, solid content 15%PVB resin transparent shape liquid is made;
2nd, by nano material through speed lapping, homogeneous, surfactant, suspending agent, pH value conditioning agent, stabilizer is added and is made Nanodispersion of the solid content 30%;
3rd, the liquid PVB resin that step one is made is well mixed with the Nanodispersion that step 2 is made, added after the drying Glue material is made in the extruded machine extrusion of plasticizer;
4th, glue material made from step 3 is applied between the first glass baseplate and the second glass baseplate, by the first glass baseplate Clean up, be then sequentially laminated with the second glass baseplate, the first glass baseplate, glue material, the second glass are followed successively by from top to bottom Glass base material, then carry out under negative pressure of vacuum, heat, apply and keep pressure, glue material is thoroughly melted the first glass baseplate and The air that two glass baseplates are bonded together and are completely exhausted out therebetween is pressed, and pressure suppresses 30min in 10Mpa, quiet Put 2 days and can obtain finished product.
Doubling glass includes the raw material of following parts by weight:14 parts of PVB resin, 13 parts of nano material, 9 parts of surfactant, 12 parts of 4 parts of suspending agent, 8 parts of pH value conditioning agent, 6 parts of stabilizer and plasticizer.
PVB resin has three layers, and intermediate layer is PVB film, and two layers of use tackifying resin is used as vector resin up and down.
Contain vanadium dioxide nano powder in PVB film.
Antioxidant, coupling agent, stearic acid, antistatic additive and ultraviolet absorber are also added with tackifying resin.
The solvent of step one is ethyl ester.
The nano material of step 2 is silica.
Step 4 finished product is placed in humidity and stood in environment of the 40%, temperature at 25 DEG C.
Embodiment 2
A kind of manufacture method of doubling glass, comprises the following steps:
First, by PVB resin dissolving in a solvent, solid content 15%PVB resin transparent shape liquid is made;
2nd, by nano material through speed lapping, homogeneous, surfactant, suspending agent, pH value conditioning agent, stabilizer is added and is made Nanodispersion of the solid content 25%;
3rd, the liquid PVB resin that step one is made is well mixed with the Nanodispersion that step 2 is made, added after the drying Glue material is made in the extruded machine extrusion of plasticizer;
4th, glue material made from step 3 is applied between the first glass baseplate and the second glass baseplate, by the first glass baseplate Clean up, be then sequentially laminated with the second glass baseplate, the first glass baseplate, glue material, the second glass are followed successively by from top to bottom Glass base material, then carry out under negative pressure of vacuum, heat, apply and keep pressure, glue material is thoroughly melted the first glass baseplate and The air that two glass baseplates are bonded together and are completely exhausted out therebetween is pressed, and pressure suppresses 20min in 10Mpa, quiet Put 2 days and can obtain finished product.
Doubling glass includes the raw material of following parts by weight:10 parts of PVB resin, 13 parts of nano material, 6 parts of surfactant, 8 parts of 4 parts of suspending agent, 5 parts of pH value conditioning agent, stabilizer part and plasticizer.
PVB resin has three layers, and intermediate layer is PVB film, and two layers of use tackifying resin is used as vector resin up and down.
Contain vanadium dioxide nano powder in PVB film.
Antioxidant, coupling agent, stearic acid, antistatic additive and ultraviolet absorber are also added with tackifying resin.
The solvent of step one is ethanol.
The nano material of step 2 is silica.
Step 4 finished product is placed in humidity and stood in environment of the 30%, temperature at 25 DEG C.
Embodiment 3
A kind of manufacture method of doubling glass, comprises the following steps:
First, by PVB resin dissolving in a solvent, solid content 25%PVB resin transparent shape liquid is made;
2nd, by nano material through speed lapping, homogeneous, surfactant, suspending agent, pH value conditioning agent, stabilizer is added and is made Nanodispersion of the solid content 30%;
3rd, the liquid PVB resin that step one is made is well mixed with the Nanodispersion that step 2 is made, added after the drying Glue material is made in the extruded machine extrusion of plasticizer;
4th, glue material made from step 3 is applied between the first glass baseplate and the second glass baseplate, by the first glass baseplate Clean up, be then sequentially laminated with the second glass baseplate, the first glass baseplate, glue material, the second glass are followed successively by from top to bottom Glass base material, then carry out under negative pressure of vacuum, heat, apply and keep pressure, glue material is thoroughly melted the first glass baseplate and The air that two glass baseplates are bonded together and are completely exhausted out therebetween is pressed, and pressure suppresses 30min in 20Mpa, quiet Put 4 days and can obtain finished product.
Doubling glass includes the raw material of following parts by weight:14 parts of PVB resin, 15 parts of nano material, 9 parts of surfactant, 12 parts of 7 parts of suspending agent, 8 parts of pH value conditioning agent, 8 parts of stabilizer and plasticizer.
PVB resin has three layers, and intermediate layer is PVB film, and two layers of use tackifying resin is used as vector resin up and down.
Contain vanadium dioxide nano powder in PVB film.
Antioxidant, coupling agent, stearic acid, antistatic additive and ultraviolet absorber are also added with tackifying resin.
The solvent of step one is cyclohexanone.
The nano material of step 2 is aluminum oxide.
Step 4 finished product is placed in humidity and stood in environment of the 40%, temperature at 35 DEG C.
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (8)

1. a kind of manufacture method of doubling glass, it is characterised in that comprise the following steps:
First, by PVB resin dissolving in a solvent, solid content 15-25%PVB resin transparent shape liquid is made;
2nd, by nano material through speed lapping, homogeneous, surfactant, suspending agent, pH value conditioning agent, stabilizer is added and is made Nanodispersion of the solid content in 25-30%;
3rd, the liquid PVB resin that step one is made is well mixed with the Nanodispersion that step 2 is made, added after the drying Glue material is made in the extruded machine extrusion of plasticizer;
4th, glue material made from step 3 is applied between the first glass baseplate and the second glass baseplate, by the first glass baseplate Clean up, be then sequentially laminated with the second glass baseplate, the first glass baseplate, glue material, the second glass are followed successively by from top to bottom Glass base material, then carry out under negative pressure of vacuum, heat, apply and keep pressure, glue material is thoroughly melted the first glass baseplate and The air that two glass baseplates are bonded together and are completely exhausted out therebetween is pressed, and pressure suppresses 20- in 10-20Mpa 30min, stands 2-4 days and can obtain finished product.
2. a kind of manufacture method of doubling glass according to claim 1, it is characterised in that the doubling glass include with The raw material of lower parts by weight:10-14 parts of PVB resin, 13-15 parts of nano material, 6-9 parts of surfactant, 4-7 parts of suspending agent, PH It is worth 8-12 parts of 5-8 parts of conditioning agent, 6-8 parts of stabilizer and plasticizer.
3. the manufacture method of a kind of doubling glass according to claim 2, it is characterised in that the PVB resin has three layers, Intermediate layer is PVB film, and two layers of use tackifying resin is used as vector resin up and down.
4. the manufacture method of a kind of doubling glass according to claim 3, it is characterised in that contain in the PVB film Vanadium dioxide nano powder.
5. the manufacture method of a kind of doubling glass according to claim 3, it is characterised in that also add in the tackifying resin Added with antioxidant, coupling agent, stearic acid, antistatic additive and ultraviolet absorber.
6. a kind of manufacture method of doubling glass according to claim 1, it is characterised in that the solvent of the step one is Ethanol, ethyl ester, butyl ester or cyclohexanone.
7. a kind of manufacture method of doubling glass according to claim 1, it is characterised in that the nanometer material of the step 2 Expect for silica or aluminum oxide.
8. the manufacture method of a kind of doubling glass according to claim 1, it is characterised in that the step 4 finished product is placed in Humidity is stood in 30-40%, temperature in 25-35 DEG C of environment.
CN201710444079.0A 2017-06-13 2017-06-13 A kind of manufacture method of doubling glass Withdrawn CN107160780A (en)

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CN201710444079.0A CN107160780A (en) 2017-06-13 2017-06-13 A kind of manufacture method of doubling glass

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108865003A (en) * 2018-07-04 2018-11-23 云南阳光利生玻璃科技有限公司 A kind of laminated glass of high-adhesive-strength and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103641336A (en) * 2013-08-23 2014-03-19 南京凯尚信息科技有限公司 Ultraviolet and infrared ray-proof thermal insulation adhesive laminated glass
CN104591552A (en) * 2015-02-09 2015-05-06 孙宁 Laminated glass and preparation method thereof
CN105481269A (en) * 2014-09-15 2016-04-13 池州市英派科技有限公司 Manufacturing method of laminated glass

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103641336A (en) * 2013-08-23 2014-03-19 南京凯尚信息科技有限公司 Ultraviolet and infrared ray-proof thermal insulation adhesive laminated glass
CN105481269A (en) * 2014-09-15 2016-04-13 池州市英派科技有限公司 Manufacturing method of laminated glass
CN104591552A (en) * 2015-02-09 2015-05-06 孙宁 Laminated glass and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108865003A (en) * 2018-07-04 2018-11-23 云南阳光利生玻璃科技有限公司 A kind of laminated glass of high-adhesive-strength and preparation method thereof

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